{"status":"ok","message-type":"work","message-version":"1.0.0","message":{"indexed":{"date-parts":[[2025,10,3]],"date-time":"2025-10-03T09:03:44Z","timestamp":1759482224202},"reference-count":0,"publisher":"Wiley","issue":"11-12","license":[{"start":{"date-parts":[[2011,3,11]],"date-time":"2011-03-11T00:00:00Z","timestamp":1299801600000},"content-version":"vor","delay-in-days":0,"URL":"http:\/\/onlinelibrary.wiley.com\/termsAndConditions#vor"}],"content-domain":{"domain":[],"crossmark-restriction":false},"short-container-title":["Phys. Status Solidi C"],"published-print":{"date-parts":[[2011,11]]},"abstract":"<jats:title>Abstract<\/jats:title><jats:p>A family of antimony tellurite glasses of the composition (55\u2010x)TeO<jats:sub>2<\/jats:sub>\u201010Sb<jats:sub>2<\/jats:sub>O<jats:sub>3<\/jats:sub>\u201035B<jats:sub>2<\/jats:sub>O<jats:sub>3<\/jats:sub> mixed with different concentrations of TiO<jats:sub>2<\/jats:sub> (0 to 2 mol%) were prepared and crystalized. The samples were characterized by XRD and SEM techniques; spectroscopic (optical absorption and Raman) and PIB properties have been investigated. Randomly distributed crystals were identified by SEM. The XRD studies have revealed the presence of Sb<jats:sub>2<\/jats:sub>Te<jats:sub>2<\/jats:sub>O<jats:sub>7<\/jats:sub>, Sb<jats:sub>2<\/jats:sub>Te<jats:sub>2<\/jats:sub>O<jats:sub>9<\/jats:sub>, TiTe<jats:sub>3<\/jats:sub>O<jats:sub>8,<\/jats:sub>TiBO<jats:sub>3<\/jats:sub> crystalline phases in these samples. The diffraction data also indicated that, the antimony ions coexist in Sb<jats:sup>5+<\/jats:sup> state with Sb<jats:sup>3+<\/jats:sup> state in these samples; however, the concentration of Sb<jats:sup>3+<\/jats:sup> ions seems to be dominant over Sb<jats:sup>5+<\/jats:sup> ions in the samples containing lower concentrations of TiO<jats:sub>2<\/jats:sub>. Optical absorption spectral studies have indicated that a considerable proportion of Ti ions do exist in Ti<jats:sup>3+<\/jats:sup> state in addition to Ti<jats:sup>4+<\/jats:sup> state and the redox ratio seems to be increasing with increase in the concentration of TiO<jats:sub>2<\/jats:sub>. The Raman spectral studies have revealed the presence of several conventional structural groups viz., TeO<jats:sub>4<\/jats:sub>, SbO<jats:sub>3<\/jats:sub>, BO<jats:sub>3<\/jats:sub>, BO<jats:sub>4<\/jats:sub>, TiO<jats:sub>4,<\/jats:sub>TiO<jats:sub>6<\/jats:sub> in the glass ceramic network; these studies have also indicated a growing degree of disorder in the glass ceramic with increase in the concentration of TiO<jats:sub>2<\/jats:sub>. The experiments on PIB with 7 ns 1064 nm Nd:YAG laser beam indicated the maximum intensity of birefringence for the sample crystallized with 2.0 mol% of TiO<jats:sub>2<\/jats:sub>. This result combined with the optical absorption studies allowed us to conclusion that Ti ion surrounding ligands play principal role in the observed PIB effects (\u00a9 2011 WILEY\u2010VCH Verlag GmbH &amp; Co. KGaA, Weinheim)<\/jats:p>","DOI":"10.1002\/pssc.201000750","type":"journal-article","created":{"date-parts":[[2011,3,11]],"date-time":"2011-03-11T10:22:13Z","timestamp":1299838933000},"page":"3082-3086","source":"Crossref","is-referenced-by-count":4,"title":["Influence of titanium ions on spectroscopic properties of TeO<sub>2<\/sub>\u2010Sb<sub>2<\/sub>O<sub>3<\/sub>\u2010B<sub>2<\/sub>O<sub>3<\/sub>: TiO<sub>2<\/sub> glass ceramics"],"prefix":"10.1002","volume":"8","author":[{"given":"T.","family":"Satyanarayana","sequence":"first","affiliation":[]},{"given":"Y.","family":"Gandhi","sequence":"additional","affiliation":[]},{"given":"M. A.","family":"Valente","sequence":"additional","affiliation":[]},{"given":"I. V.","family":"Kityk","sequence":"additional","affiliation":[]},{"given":"N.","family":"Veeraiah","sequence":"additional","affiliation":[]}],"member":"311","published-online":{"date-parts":[[2011,3,11]]},"container-title":["physica status solidi c"],"original-title":[],"language":"en","link":[{"URL":"https:\/\/api.wiley.com\/onlinelibrary\/tdm\/v1\/articles\/10.1002%2Fpssc.201000750","content-type":"unspecified","content-version":"vor","intended-application":"text-mining"},{"URL":"https:\/\/onlinelibrary.wiley.com\/doi\/pdf\/10.1002\/pssc.201000750","content-type":"application\/pdf","content-version":"vor","intended-application":"text-mining"},{"URL":"https:\/\/onlinelibrary.wiley.com\/doi\/pdf\/10.1002\/pssc.201000750","content-type":"unspecified","content-version":"vor","intended-application":"similarity-checking"}],"deposited":{"date-parts":[[2023,8,31]],"date-time":"2023-08-31T09:12:20Z","timestamp":1693473140000},"score":1,"resource":{"primary":{"URL":"https:\/\/onlinelibrary.wiley.com\/doi\/10.1002\/pssc.201000750"}},"subtitle":[],"short-title":[],"issued":{"date-parts":[[2011,3,11]]},"references-count":0,"journal-issue":{"issue":"11-12","published-print":{"date-parts":[[2011,11]]}},"alternative-id":["10.1002\/pssc.201000750"],"URL":"https:\/\/doi.org\/10.1002\/pssc.201000750","archive":["Portico"],"relation":{},"ISSN":["1862-6351","1610-1642"],"issn-type":[{"value":"1862-6351","type":"print"},{"value":"1610-1642","type":"electronic"}],"subject":[],"published":{"date-parts":[[2011,3,11]]}}}