{"status":"ok","message-type":"work","message-version":"1.0.0","message":{"indexed":{"date-parts":[[2025,10,26]],"date-time":"2025-10-26T12:08:30Z","timestamp":1761480510704,"version":"build-2065373602"},"reference-count":52,"publisher":"Wiley","issue":"18","license":[{"start":{"date-parts":[[2016,11,4]],"date-time":"2016-11-04T00:00:00Z","timestamp":1478217600000},"content-version":"vor","delay-in-days":3,"URL":"http:\/\/onlinelibrary.wiley.com\/termsAndConditions#vor"}],"content-domain":{"domain":["chemistry-europe.onlinelibrary.wiley.com"],"crossmark-restriction":true},"short-container-title":["ChemistrySelect"],"published-print":{"date-parts":[[2016,11]]},"abstract":"<jats:title>Abstract<\/jats:title>\n                  <jats:p>\n                    We report on significant efficiency enhancement of bulk heterojunction organic photovoltaic cells based on blends of poly(9,9\u2010dioctylfluorene\u2010alt\u2010bithiophene), F8T2, or poly[[4,8\u2010bis[(2\u2010ethylhexyl)oxy]benzo[1,2\u2010b:4,5\u2010b\u2032]dithiophene\u20102,6\u2010diyl][3\u2010fluoro\u20102\u2010[(2\u2010ethylhexyl)carbonyl]thieno[3,4\u2010b]thiophenediyl], PTB7, with [6,6]\u2010phenyl\u2010C61\u2010butyric acid methyl ester, PC\n                    <jats:sub>61<\/jats:sub>\n                    BM, upon thermally depositing a layer of a phenanthroline derivative, 4,7\u2010diphenyl\u20101,10\u2010phenanthroline, BPhen, or 2,9\u2010dimethyl\u20104,7\u2010diphenyl\u20101,10\u2010phenanthroline, BCP, and LiF. We found that both phenanthroline derivatives form nanostructured layers and that the introduction of the LiF layer is crucial for the cells performance improvement. The interface between BPhen and LiF was investigated by X\u2010ray photoelectron spectroscopy (XPS). This analysis suggested that charge\u2010transfer doping of BPhen by fluoride is at the origin of improved electron transport throughout the BPhen layer. The best performing cells display power conversion efficiencies of 2.89\u2009% and 5.89\u2009%, for the blend with F8T2 and PTB7, respectively.\n                  <\/jats:p>","DOI":"10.1002\/slct.201600574","type":"journal-article","created":{"date-parts":[[2016,11,4]],"date-time":"2016-11-04T12:02:16Z","timestamp":1478260936000},"page":"5638-5646","update-policy":"https:\/\/doi.org\/10.1002\/crossmark_policy","source":"Crossref","is-referenced-by-count":2,"title":["Understanding the Role of Phenanthroline as Interlayer in Bulk Heterojunction Organic Photovoltaic Cells"],"prefix":"10.1002","volume":"1","author":[{"ORCID":"https:\/\/orcid.org\/0000-0003-4320-8998","authenticated-orcid":false,"given":"Joana","family":"Farinhas","sequence":"first","affiliation":[{"name":"Instituto de Telecomunica\u00e7\u00f5es Instituto Superior T\u00e9cnico Universidade de Lisboa  Av. Rovisco Pais, 1 P-1049-001 Lisboa Portugal"}]},{"ORCID":"https:\/\/orcid.org\/0000-0002-6784-6540","authenticated-orcid":false,"given":"Ana M.","family":"Ferraria","sequence":"additional","affiliation":[{"name":"Centro de Qu\u00edmica F\u00edsica Molecular and IN Instituto Superior T\u00e9cnico Universidade de Lisboa  Av. Rovisco Pais, 1 P-1049-001 Lisboa Portugal"}]},{"ORCID":"https:\/\/orcid.org\/0000-0002-3131-4219","authenticated-orcid":false,"given":"Ana M. B.","family":"do\u2005Rego","sequence":"additional","affiliation":[{"name":"Centro de Qu\u00edmica F\u00edsica Molecular and IN Instituto Superior T\u00e9cnico Universidade de Lisboa  Av. Rovisco Pais, 1 P-1049-001 Lisboa Portugal"}]},{"ORCID":"https:\/\/orcid.org\/0000-0002-0783-2657","authenticated-orcid":false,"given":"Jorge","family":"Morgado","sequence":"additional","affiliation":[{"name":"Instituto de Telecomunica\u00e7\u00f5es Instituto Superior T\u00e9cnico Universidade de Lisboa  Av. 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