{"status":"ok","message-type":"work","message-version":"1.0.0","message":{"indexed":{"date-parts":[[2025,11,5]],"date-time":"2025-11-05T14:22:41Z","timestamp":1762352561102,"version":"build-2065373602"},"reference-count":65,"publisher":"Wiley","issue":"1","license":[{"start":{"date-parts":[[2017,1,11]],"date-time":"2017-01-11T00:00:00Z","timestamp":1484092800000},"content-version":"vor","delay-in-days":1,"URL":"http:\/\/onlinelibrary.wiley.com\/termsAndConditions#vor"}],"content-domain":{"domain":["chemistry-europe.onlinelibrary.wiley.com"],"crossmark-restriction":true},"short-container-title":["ChemistrySelect"],"published-print":{"date-parts":[[2017,1,10]]},"abstract":"<jats:title>Abstract<\/jats:title>\n                  <jats:p>\n                    Non\u2010porous bridged silsesquioxanes (BSs) were produced by sol\u2010gel reactions and self\u2010directed assembly, in the presence of an acid catalyst and a large excess of water, from bridged organosilane precursors (BOPs) synthesized by click chemistry. The rational design of the compounds, comprising an amine group and alkyl chains with variable length (n), pendant and anchored on a single position to a triazole ring, and the control of acid content (\n                    <jats:italic>w<\/jats:italic>\n                    , moles of acid per moles of BOP) enabled the tuning of the morphology and structure of the BSs. At n=6, 12 and 16, and\n                    <jats:italic>w<\/jats:italic>\n                    =0.2 amorphous hybrids were produced as uniform isotropic micro\u2010 to nanospheres. Structuring resulted at n =16 and\n                    <jats:italic>w<\/jats:italic>\n                    =1.2 or n=20 and\n                    <jats:italic>w<\/jats:italic>\n                    =0.2, yielding lamellar bilayer structures. In the case of the BS with n=20 and\n                    <jats:italic>w<\/jats:italic>\n                    =1.2 a lamellar bilayer phase and a minor hexagonal 2D structure emerged. The quite unusual formation of the latter structure was attributed to the presence of a chloride ion close to the proton located between the N(2) atom of the triazole ring and the amine group of the organic spacer, acting as a curvature agent.\n                  <\/jats:p>","DOI":"10.1002\/slct.201601806","type":"journal-article","created":{"date-parts":[[2017,1,13]],"date-time":"2017-01-13T08:06:05Z","timestamp":1484294765000},"page":"432-442","update-policy":"https:\/\/doi.org\/10.1002\/crossmark_policy","source":"Crossref","is-referenced-by-count":8,"title":["Structuring of Alkyl\u2010Triazole Bridged Silsesquioxanes"],"prefix":"10.1002","volume":"2","author":[{"given":"S. C.","family":"Nunes","sequence":"first","affiliation":[{"name":"CICS - Health Sciences Research Center and Chemistry Department University of Beira Interior  6201-001 Covilh\u00e3 Portugal"},{"name":"Department Chemistry University of Tr\u00e1s-os-Montes e Alto Douro  5000-801 Vila Real Portugal"}]},{"given":"G.","family":"Toquer","sequence":"additional","affiliation":[{"name":"Institut de Chimie S\u00e9parative de Marcoule (UMR 5257 CEA-CNRS-UM2-ENSCM), BP17171  30207 Bagnols sur C\u00e8ze France."}]},{"given":"M. A.","family":"Cardoso","sequence":"additional","affiliation":[{"name":"Department Chemistry University of Tr\u00e1s-os-Montes e Alto Douro  5000-801 Vila Real Portugal"},{"name":"Department of Physics, CICECO - Aveiro Institute of Materials University of Aveiro  3810-193 Aveiro Portugal."}]},{"given":"A.","family":"Mayoral","sequence":"additional","affiliation":[{"name":"Laboratorio de Microscopias Avanzadas Instituto de Nanociencia de Aragon Universidad de Zaragoza  50018 Zaragoza Spain."}]},{"given":"R. A. S.","family":"Ferreira","sequence":"additional","affiliation":[{"name":"Department of Physics, CICECO - Aveiro Institute of Materials University of Aveiro  3810-193 Aveiro Portugal."}]},{"given":"L. D.","family":"Carlos","sequence":"additional","affiliation":[{"name":"Department of Physics, CICECO - Aveiro Institute of Materials University of Aveiro  3810-193 Aveiro Portugal."}]},{"given":"P.","family":"Ferreira","sequence":"additional","affiliation":[{"name":"Department of Materials and Ceramic Engineering CICECO - Aveiro Institute of Materials University of Aveiro  3810-193 Aveiro Portugal."}]},{"given":"P.","family":"Almeida","sequence":"additional","affiliation":[{"name":"CICS - Health Sciences Research Center and Chemistry Department University of Beira Interior  6201-001 Covilh\u00e3 Portugal"}]},{"given":"X.","family":"Catto\u00ebn","sequence":"additional","affiliation":[{"name":"Inst NEEL Univ. Grenoble Alpes, Inst NEEL F-  38042 Grenoble, F38042 Grenoble France"}]},{"given":"M.","family":"Wong\u2005Chi\u2005Man","sequence":"additional","affiliation":[{"name":"Institut Charles Gerhardt Montpellier UMR5253 CNRS-ENSCM-UM  8, rue de l'\u00e9cole normale 34296 Montpellier France"}]},{"given":"V.","family":"de\u2005Zea\u2005Bermudez","sequence":"additional","affiliation":[{"name":"Department Chemistry University of Tr\u00e1s-os-Montes e Alto Douro  5000-801 Vila Real Portugal"},{"name":"CQ-VR, University of Tr\u00e1s-os-Montes e Alto Douro  5000-801 Vila Real Portugal"}]}],"member":"311","published-online":{"date-parts":[[2017,1,11]]},"reference":[{"key":"e_1_2_6_1_1","doi-asserted-by":"publisher","DOI":"10.1098\/rsta.2009.0011"},{"key":"e_1_2_6_2_1","doi-asserted-by":"publisher","DOI":"10.1126\/science.177.4047.393"},{"key":"e_1_2_6_3_1","doi-asserted-by":"publisher","DOI":"10.1126\/science.284.5411.87"},{"key":"e_1_2_6_4_1","doi-asserted-by":"publisher","DOI":"10.1002\/adma.200902019"},{"key":"e_1_2_6_5_1","doi-asserted-by":"publisher","DOI":"10.1126\/science.156.3775.636"},{"key":"e_1_2_6_6_1","doi-asserted-by":"publisher","DOI":"10.1039\/C4RA11300D"},{"key":"e_1_2_6_7_1","doi-asserted-by":"publisher","DOI":"10.1002\/3527602372"},{"key":"e_1_2_6_8_1","doi-asserted-by":"publisher","DOI":"10.1039\/b509097k"},{"volume-title":"The Physics and Chemistry of Sol-Gel Processing","year":"1990","author":"Brinker C. 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