{"status":"ok","message-type":"work","message-version":"1.0.0","message":{"indexed":{"date-parts":[[2026,1,15]],"date-time":"2026-01-15T22:15:06Z","timestamp":1768515306074,"version":"3.49.0"},"reference-count":36,"publisher":"Wiley","issue":"37","license":[{"start":{"date-parts":[[2018,10,2]],"date-time":"2018-10-02T00:00:00Z","timestamp":1538438400000},"content-version":"vor","delay-in-days":0,"URL":"http:\/\/onlinelibrary.wiley.com\/termsAndConditions#vor"}],"funder":[{"name":"Funda\u00e7\u00e3o para a Ci\u00eancia e Tecnologia (FCT)","award":["PEst-OE\/QUI\/UI0612\/2013"],"award-info":[{"award-number":["PEst-OE\/QUI\/UI0612\/2013"]}]},{"name":"FCT","award":["SFRH\/BPD\/86693\/2012"],"award-info":[{"award-number":["SFRH\/BPD\/86693\/2012"]}]}],"content-domain":{"domain":["chemistry-europe.onlinelibrary.wiley.com"],"crossmark-restriction":true},"short-container-title":["ChemistrySelect"],"published-print":{"date-parts":[[2018,10,9]]},"abstract":"<jats:title>Abstract<\/jats:title>\n                  <jats:p>\n                    This study presents a stable, selective and reusable catalyst prepared by a biomass\u2010derived acid\u2010biochar (\n                    <jats:italic>acid\u2010char<\/jats:italic>\n                    ) functionalized with the organometallic complex [MoI\n                    <jats:sub>2<\/jats:sub>\n                    (CO)\n                    <jats:sub>3<\/jats:sub>\n                    (MeCN)\n                    <jats:sub>2<\/jats:sub>\n                    ] (\n                    <jats:italic>Mo<\/jats:italic>\n                    ), yielding a material where the [MoI\n                    <jats:sub>2<\/jats:sub>\n                    (CO)\n                    <jats:sub>3<\/jats:sub>\n                    ] core is coordinated at surface functional groups of the\n                    <jats:italic>acid\u2010char<\/jats:italic>\n                    material. The characterization of this catalyst, denoted as\n                    <jats:italic>Mo@acid\u2010char<\/jats:italic>\n                    , by using various complementary techniques confirmed the successful immobilization of the [MoI\n                    <jats:sub>2<\/jats:sub>\n                    (CO)\n                    <jats:sub>3<\/jats:sub>\n                    ] core at the surface of the acid\u2010char material. The catalytic activity of the material was evaluated for olefin epoxidation reactions of\n                    <jats:italic>cis<\/jats:italic>\n                    \u2010cyclooctene and\n                    <jats:italic>R<\/jats:italic>\n                    \u2010(+)\u2010limonene, varying relevant reaction parameters such as temperature, solvent and oxidant ratio. The\n                    <jats:italic>Mo@acid\u2010char<\/jats:italic>\n                    showed an excellent selectivity for epoxide products at mild temperature (ca. 328\u2005K). Interestingly, the catalyst exhibited its highest activity when the reaction was carried out under solventless conditions, allowing the catalysts reuse for several cycles. Thus, the synthesized\n                    <jats:italic>Mo@acid\u2010char<\/jats:italic>\n                    contributed for a sustainable use of biomass waste (e.\u2009g., sisal) through the development of environmentally friendly processes avoiding the use of solvents.\n                  <\/jats:p>","DOI":"10.1002\/slct.201802055","type":"journal-article","created":{"date-parts":[[2018,10,2]],"date-time":"2018-10-02T10:33:44Z","timestamp":1538476424000},"page":"10357-10363","update-policy":"https:\/\/doi.org\/10.1002\/crossmark_policy","source":"Crossref","is-referenced-by-count":4,"title":["Solventless Olefin Epoxidation Using a Mo\u2013Loaded Sisal Derived Acid\u2010Char Catalyst"],"prefix":"10.1002","volume":"3","author":[{"given":"C\u00e9cile","family":"Petit","sequence":"first","affiliation":[{"name":"Centro de Qu\u00edmica e Bioqu\u00edmica and Centro de Qu\u00edmica Estrutural, Faculdade de Ci\u00eancias Universidade de Lisboa  1749-016 Lisboa Portugal"}]},{"given":"Miguel V.","family":"Silva","sequence":"additional","affiliation":[{"name":"Centro de Qu\u00edmica e Bioqu\u00edmica and Centro de Qu\u00edmica Estrutural, Faculdade de Ci\u00eancias Universidade de Lisboa  1749-016 Lisboa Portugal"}]},{"given":"Ana S.","family":"Mestre","sequence":"additional","affiliation":[{"name":"Centro de Qu\u00edmica e Bioqu\u00edmica and Centro de Qu\u00edmica Estrutural, Faculdade de Ci\u00eancias Universidade de Lisboa  1749-016 Lisboa Portugal"}]},{"given":"Conchi O.","family":"Ania","sequence":"additional","affiliation":[{"name":"CEMHTI (UPR 3079) CNRS Universit\u00e9 d'Orl\u00e9ans  45071 Orl\u00e9ans France"}]},{"given":"Pedro D.","family":"Vaz","sequence":"additional","affiliation":[{"name":"ISIS Neutron &amp; Muon Source Rutherford Appleton Laboratory, Chilton, Didcot  Oxfordshire OX11 0QX United Kingdom"},{"name":"CICECO \u2013 Aveiro Institute of Materials Department of Chemistry University of Aveiro  3810-193 Aveiro Portugal"}]},{"given":"Ana P.","family":"Carvalho","sequence":"additional","affiliation":[{"name":"Centro de Qu\u00edmica e Bioqu\u00edmica and Centro de Qu\u00edmica Estrutural, Faculdade de Ci\u00eancias Universidade de Lisboa  1749-016 Lisboa Portugal"}]},{"ORCID":"https:\/\/orcid.org\/0000-0001-8750-7813","authenticated-orcid":false,"given":"Carla D.","family":"Nunes","sequence":"additional","affiliation":[{"name":"Centro de Qu\u00edmica e Bioqu\u00edmica and Centro de Qu\u00edmica Estrutural, Faculdade de Ci\u00eancias Universidade de Lisboa  1749-016 Lisboa Portugal"}]}],"member":"311","published-online":{"date-parts":[[2018,10,2]]},"reference":[{"key":"e_1_2_6_1_1","doi-asserted-by":"publisher","DOI":"10.1021\/acs.chemrev.7b00776"},{"key":"e_1_2_6_2_1","first-page":"45","author":"Ennaert T.","year":"2016","journal-title":"Chem. Soc. Rev."},{"key":"e_1_2_6_3_1","doi-asserted-by":"publisher","DOI":"10.1021\/cr050989d"},{"key":"e_1_2_6_4_1","doi-asserted-by":"publisher","DOI":"10.1039\/a806702c"},{"key":"e_1_2_6_5_1","doi-asserted-by":"publisher","DOI":"10.1016\/1381-1169(95)00089-5"},{"key":"e_1_2_6_6_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.micromeso.2012.02.044"},{"key":"e_1_2_6_7_1","doi-asserted-by":"publisher","DOI":"10.1002\/adsc.201500441"},{"key":"e_1_2_6_8_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.jcat.2017.12.014"},{"key":"e_1_2_6_9_1","doi-asserted-by":"publisher","DOI":"10.1039\/B401830C"},{"key":"e_1_2_6_10_1","doi-asserted-by":"publisher","DOI":"10.1002\/adma.201605446"},{"key":"e_1_2_6_11_1","doi-asserted-by":"publisher","DOI":"10.1002\/cctc.201600316"},{"key":"e_1_2_6_12_1","doi-asserted-by":"publisher","DOI":"10.1039\/C6DT00514D"},{"key":"e_1_2_6_13_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.cattod.2012.04.018"},{"key":"e_1_2_6_14_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.jiec.2017.08.026"},{"key":"e_1_2_6_15_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.biortech.2010.08.100"},{"key":"e_1_2_6_16_1","doi-asserted-by":"crossref","unstructured":"A.\u2005S. Mestre A.\u2005P. Carvalho Nanoporous Carbon Synthesis:An Old Story with Exciting New Chapters in Porosity ed. T. Ghrib InTech London 2018 pp. 37\u201368.","DOI":"10.5772\/intechopen.72476"},{"key":"e_1_2_6_17_1","unstructured":"\u201cTransforming our world: the 2030 agenda for sustainable development\u201d to be found under https:\/\/sustainabledevelopment.un.org\/content\/documents\/21252030%20Agenda%20for%20Sustainable%20Development%20web.pdf 2015."},{"key":"e_1_2_6_18_1","doi-asserted-by":"publisher","DOI":"10.1039\/c0cc03204b"},{"key":"e_1_2_6_19_1","unstructured":"\u00a0"},{"key":"e_1_2_6_20_2","unstructured":"M.\u2005N. Shen G.\u2005J. Zajaczek ARCO GB1195504-A 1968;"},{"key":"e_1_2_6_21_2","unstructured":"J. Kollar Halcon US3350422-A US3351635-A 1967."},{"key":"e_1_2_6_22_1","unstructured":"A.\u2005S. Mestre F. Hesse C. Freire C.\u2005O. Ania A.\u2005P. Carvalho From low density biomass to high grade activated carbons: high performing adsorbents for ibuprofen and iopamidol Extended Abstract The World Conference on Carbon Penn State (US) 10\u201315 July 2016"},{"key":"e_1_2_6_23_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.biortech.2010.07.031"},{"key":"e_1_2_6_24_1","unstructured":"J.\u2005F. Moulder W.\u2005F. Stickle P.\u2005E. Sobol K.\u2005D. Bomben Handbook of Photoelectron Spectroscopy Ed. J. Chastain Perkin Elmer Corp.: Minnesota USA 1992."},{"key":"e_1_2_6_25_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.apcata.2011.09.012"},{"key":"e_1_2_6_26_1","doi-asserted-by":"crossref","unstructured":"T.\u2005J. Bandosz C.\u2005O. Ania Surface chemistry of activated carbons and its characterization in Activated Carbon Surface in Environmental Remediation T.\u2005J. Bandosz ed. Academic Press Amesterdam 2006 pp. 159\u2013229.","DOI":"10.1016\/S1573-4285(06)80013-X"},{"key":"e_1_2_6_27_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.molcata.2006.04.023"},{"key":"e_1_2_6_28_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.jcat.2013.08.032"},{"key":"e_1_2_6_29_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.fuel.2011.11.025"},{"key":"e_1_2_6_30_1","unstructured":"T. Vu I. Yarovsky A.\u2005L. Chaffee Molecular modeling of water interactions with fossil wood from Victorian brown coal in 12thInternational Conference on Coal Science and Technology 2005 Okinawa Japan; October 9\u201314 2005. p. 1\u201313."},{"key":"e_1_2_6_31_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.jcat.2008.03.023"},{"key":"e_1_2_6_32_1","doi-asserted-by":"publisher","DOI":"10.2174\/1877944111101020146"},{"key":"e_1_2_6_33_1","doi-asserted-by":"publisher","DOI":"10.1002\/ejic.200400852"},{"key":"e_1_2_6_34_1","doi-asserted-by":"publisher","DOI":"10.1021\/om8009206"},{"key":"e_1_2_6_35_1","doi-asserted-by":"publisher","DOI":"10.1021\/om9002522"},{"key":"e_1_2_6_36_1","doi-asserted-by":"publisher","DOI":"10.1002\/chem.200304887"}],"container-title":["ChemistrySelect"],"original-title":[],"language":"en","link":[{"URL":"https:\/\/api.wiley.com\/onlinelibrary\/tdm\/v1\/articles\/10.1002%2Fslct.201802055","content-type":"application\/pdf","content-version":"vor","intended-application":"text-mining"},{"URL":"https:\/\/onlinelibrary.wiley.com\/doi\/pdf\/10.1002\/slct.201802055","content-type":"application\/pdf","content-version":"vor","intended-application":"text-mining"},{"URL":"https:\/\/onlinelibrary.wiley.com\/doi\/full-xml\/10.1002\/slct.201802055","content-type":"application\/xml","content-version":"vor","intended-application":"text-mining"},{"URL":"https:\/\/onlinelibrary.wiley.com\/doi\/am-pdf\/10.1002\/slct.201802055","content-type":"application\/pdf","content-version":"am","intended-application":"syndication"},{"URL":"https:\/\/chemistry-europe.onlinelibrary.wiley.com\/doi\/pdf\/10.1002\/slct.201802055","content-type":"unspecified","content-version":"vor","intended-application":"similarity-checking"}],"deposited":{"date-parts":[[2025,10,26]],"date-time":"2025-10-26T15:42:29Z","timestamp":1761493349000},"score":1,"resource":{"primary":{"URL":"https:\/\/chemistry-europe.onlinelibrary.wiley.com\/doi\/10.1002\/slct.201802055"}},"subtitle":[],"short-title":[],"issued":{"date-parts":[[2018,10,2]]},"references-count":36,"journal-issue":{"issue":"37","published-print":{"date-parts":[[2018,10,9]]}},"alternative-id":["10.1002\/slct.201802055"],"URL":"https:\/\/doi.org\/10.1002\/slct.201802055","archive":["Portico"],"relation":{},"ISSN":["2365-6549","2365-6549"],"issn-type":[{"value":"2365-6549","type":"print"},{"value":"2365-6549","type":"electronic"}],"subject":[],"published":{"date-parts":[[2018,10,2]]},"assertion":[{"value":"2018-07-04","order":0,"name":"received","label":"Received","group":{"name":"publication_history","label":"Publication History"}},{"value":"2018-09-19","order":2,"name":"accepted","label":"Accepted","group":{"name":"publication_history","label":"Publication History"}},{"value":"2018-10-02","order":3,"name":"published","label":"Published","group":{"name":"publication_history","label":"Publication History"}}]}}