{"status":"ok","message-type":"work","message-version":"1.0.0","message":{"indexed":{"date-parts":[[2025,10,26]],"date-time":"2025-10-26T12:31:29Z","timestamp":1761481889283,"version":"build-2065373602"},"reference-count":70,"publisher":"Wiley","issue":"29","license":[{"start":{"date-parts":[[2023,8,1]],"date-time":"2023-08-01T00:00:00Z","timestamp":1690848000000},"content-version":"vor","delay-in-days":0,"URL":"http:\/\/onlinelibrary.wiley.com\/termsAndConditions#vor"}],"funder":[{"DOI":"10.13039\/100009122","name":"Ministry of Higher Education and Scientific Research","doi-asserted-by":"publisher","award":["5-6\/2013-TS.VII"],"award-info":[{"award-number":["5-6\/2013-TS.VII"]}],"id":[{"id":"10.13039\/100009122","id-type":"DOI","asserted-by":"publisher"}]}],"content-domain":{"domain":["chemistry-europe.onlinelibrary.wiley.com"],"crossmark-restriction":true},"short-container-title":["ChemistrySelect"],"published-print":{"date-parts":[[2023,8,4]]},"abstract":"<jats:title>Abstract<\/jats:title>\n                  <jats:p>\n                    This study reports the electrochemical synthesis of different morphologies of bismuth iodide and bismuth oxyiodide on graphite surfaces from acidic baths containing bismuth nitrate, sodium nitrate, iodine and ethylene glycol by a simple pH control. Linear sweep voltammetry analyses determined the potential window for the reduction of iodine where bismuth ions do not get reduced. The concentration of the iodide ions in the bath is regulated by the applied potential. At pH\u20050.2 and 0.5, bismuth is predominantly present as free Bi\n                    <jats:sup>3+<\/jats:sup>\n                    ions, which react with iodide to form bismuth triiodide. On the other hand, even at slightly elevated pH\u20051.0 and 2.0, bismuth is predominantly complexed by water, nitrates and ethylene glycol. These complexes react with the iodide ions to form bismuth oxyiodide. Pure triiodide phase comprising polygonal platelets is obtained at pH\u20050.2. Pure oxyiodide phase comprising novel microflower\u2010like morphology formed from interlinked nano\u2010disks is obtained at pH\u20052.0.\n                  <\/jats:p>","DOI":"10.1002\/slct.202302055","type":"journal-article","created":{"date-parts":[[2023,8,1]],"date-time":"2023-08-01T23:12:42Z","timestamp":1690931562000},"update-policy":"https:\/\/doi.org\/10.1002\/crossmark_policy","source":"Crossref","is-referenced-by-count":1,"title":["pH\u2010Dependent Synthesis of Pure\u2010Phase BiI\n                    <sub>3<\/sub>\n                    and BiOI by Electrodeposition**"],"prefix":"10.1002","volume":"8","author":[{"given":"G. Mohan","family":"Kumar","sequence":"first","affiliation":[{"name":"Center of Excellence in Advanced Materials and Green Technologies Amrita School of Engineering  Coimbatore Amrita Vishwa Vidyapeetham India"},{"name":"Department of Chemical Engineering and Materials Science Amrita School of Engineering  Coimbatore Amrita Vishwa Vidyapeetham India"}]},{"given":"Deepak Suresh","family":"Varma","sequence":"additional","affiliation":[{"name":"Center of Excellence in Advanced Materials and Green Technologies Amrita School of Engineering  Coimbatore Amrita Vishwa Vidyapeetham India"},{"name":"Department of Chemical Engineering and Materials Science Amrita School of Engineering  Coimbatore Amrita Vishwa Vidyapeetham India"}]},{"given":"Sathiskumar","family":"Jothi","sequence":"additional","affiliation":[{"name":"Aerospace Materials and Battery Development Division  Space 4.0 Limited England UK"},{"name":"Artificial Intelligence R&amp;D Division Big Data Science &amp; Technology Limited  Greater London UK"}]},{"given":"Devaraj","family":"Ramasamy","sequence":"additional","affiliation":[{"name":"proMetheus Instituto Polit\u00e9cnico de Viana do Castelo  4900-347 Viana do Castelo Portugal"}]},{"given":"Jo\u00e3o C. 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