{"status":"ok","message-type":"work","message-version":"1.0.0","message":{"indexed":{"date-parts":[[2026,4,2]],"date-time":"2026-04-02T20:11:12Z","timestamp":1775160672837,"version":"3.50.1"},"reference-count":45,"publisher":"Wiley","issue":"5","license":[{"start":{"date-parts":[[2024,12,23]],"date-time":"2024-12-23T00:00:00Z","timestamp":1734912000000},"content-version":"vor","delay-in-days":0,"URL":"http:\/\/onlinelibrary.wiley.com\/termsAndConditions#vor"}],"funder":[{"DOI":"10.13039\/100008054","name":"Fundaci\u00f3n Ram\u00f3n Areces","doi-asserted-by":"publisher","award":["XXXIV Convocatoria Ciencias de la Vida y de la Materia"],"award-info":[{"award-number":["XXXIV Convocatoria Ciencias de la Vida y de la Materia"]}],"id":[{"id":"10.13039\/100008054","id-type":"DOI","asserted-by":"publisher"}]},{"DOI":"10.13039\/501100001871","name":"Funda\u00e7\u00e3o para a Ci\u00eancia e a Tecnologia","doi-asserted-by":"publisher","award":["CEECINST\/00010\/2021\/CP1770\/CT0011"],"award-info":[{"award-number":["CEECINST\/00010\/2021\/CP1770\/CT0011"]}],"id":[{"id":"10.13039\/501100001871","id-type":"DOI","asserted-by":"publisher"}]}],"content-domain":{"domain":["onlinelibrary.wiley.com"],"crossmark-restriction":true},"short-container-title":["Small"],"published-print":{"date-parts":[[2025,2]]},"abstract":"<jats:title>Abstract<\/jats:title><jats:p>The oxidative cross\u2010coupling of benzyl alcohol (BA) and benzylamine (BZA) is employed for the production of the corresponding imine, N\u2010benzylidenebenzylamine (BZI), under visible light irradiation (light\u2010emitting diodes (LE\u00a0with <jats:italic>\u03bb<\/jats:italic><jats:sub>max<\/jats:sub> = 417\u00a0nm) and mild reaction conditions. The cesium bismuth halide perovskites (Cs<jats:sub>2<\/jats:sub>Bi<jats:sub>3<\/jats:sub>Br<jats:sub>9<\/jats:sub>, CBB) are synthesized by a one\u2010step solution process as a sustainable alternative for the widely used Pb\u2010halide perovskites. The CBB photocatalyst is immobilized on a polyethylene terephthalate (PET) structure designed explicitly for three\u2010dimensional (3D) printing to operate in both batch and continuous modes to overcome the need for a final catalyst separation step. The complete conversion of BZA and BA is achieved after 1\u00a0h, yielding 70% of BZI in basic medium operating in batch mode. Comparable results are found between the suspended and immobilized catalysts for imine production. Additionally, continuous production of BZI is successfully achieved using immobilized CBB, with a maximum yield of 0.35\u00a0m<jats:sc>m<\/jats:sc> of BZI after a 2\u00a0h reaction. The supported CBB perovskites demonstrate high stability after multiple uses. Finally, a comprehensive photocatalytic pathway for cross\u2010coupling BZA with BA is proposed.<\/jats:p>","DOI":"10.1002\/smll.202409037","type":"journal-article","created":{"date-parts":[[2024,12,23]],"date-time":"2024-12-23T09:26:26Z","timestamp":1734945986000},"update-policy":"https:\/\/doi.org\/10.1002\/crossmark_policy","source":"Crossref","is-referenced-by-count":7,"title":["Photocatalytic Oxidative Coupling of Benzyl Alcohol and Benzylamine for Imine Synthesis Using Immobilized Cs<sub>3<\/sub>Bi<sub>2<\/sub>Br<sub>9<\/sub> Perovskite"],"prefix":"10.1002","volume":"21","author":[{"ORCID":"https:\/\/orcid.org\/0000-0003-4254-7074","authenticated-orcid":false,"given":"Joana C.","family":"Lopes","sequence":"first","affiliation":[{"name":"LSRE\u2010LCM \u2013 Laboratory of Separation and Reaction Engineering \u2013 Laboratory of Catalysis and Materials Faculty of Engineering University of Porto  Rua Dr Roberto Frias Porto 4200\u2010465 Portugal"},{"name":"ALiCE \u2013 Associate Laboratory in Chemical Engineering Faculty of Engineering University of Porto  Rua Dr Roberto Frias Porto 4200\u2010465 Portugal"}]},{"given":"Manuel","family":"Pe\u00f1as\u2010Garz\u00f3n","sequence":"additional","affiliation":[{"name":"LSRE\u2010LCM \u2013 Laboratory of Separation and Reaction Engineering \u2013 Laboratory of Catalysis and Materials Faculty of Engineering University of Porto  Rua Dr Roberto Frias Porto 4200\u2010465 Portugal"},{"name":"ALiCE \u2013 Associate Laboratory in Chemical Engineering Faculty of Engineering University of Porto  Rua Dr Roberto Frias Porto 4200\u2010465 Portugal"}]},{"given":"Maria J.","family":"Sampaio","sequence":"additional","affiliation":[{"name":"LSRE\u2010LCM \u2013 Laboratory of Separation and Reaction Engineering \u2013 Laboratory of Catalysis and Materials Faculty of Engineering University of Porto  Rua Dr Roberto Frias Porto 4200\u2010465 Portugal"},{"name":"ALiCE \u2013 Associate Laboratory in Chemical Engineering Faculty of Engineering University of Porto  Rua Dr Roberto Frias Porto 4200\u2010465 Portugal"}]},{"given":"Cl\u00e1udia G.","family":"Silva","sequence":"additional","affiliation":[{"name":"LSRE\u2010LCM \u2013 Laboratory of Separation and Reaction Engineering \u2013 Laboratory of Catalysis and Materials Faculty of Engineering University of Porto  Rua Dr Roberto Frias Porto 4200\u2010465 Portugal"},{"name":"ALiCE \u2013 Associate Laboratory in Chemical Engineering Faculty of Engineering University of Porto  Rua Dr Roberto Frias Porto 4200\u2010465 Portugal"}]},{"given":"Joaquim L.","family":"Faria","sequence":"additional","affiliation":[{"name":"LSRE\u2010LCM \u2013 Laboratory of Separation and Reaction Engineering \u2013 Laboratory of Catalysis and Materials Faculty of Engineering University of Porto  Rua Dr Roberto Frias Porto 4200\u2010465 Portugal"},{"name":"ALiCE \u2013 Associate Laboratory in Chemical Engineering Faculty of Engineering University of Porto  Rua Dr Roberto Frias Porto 4200\u2010465 Portugal"}]}],"member":"311","published-online":{"date-parts":[[2024,12,23]]},"reference":[{"key":"e_1_2_8_1_1","doi-asserted-by":"publisher","DOI":"10.1021\/acscatal.5b01479"},{"key":"e_1_2_8_2_1","doi-asserted-by":"publisher","DOI":"10.1021\/acs.orglett.5b00949"},{"key":"e_1_2_8_2_2","doi-asserted-by":"publisher","DOI":"10.1021\/jacs.5b13519"},{"key":"e_1_2_8_3_1","doi-asserted-by":"publisher","DOI":"10.1002\/anie.201409601"},{"key":"e_1_2_8_3_2","doi-asserted-by":"publisher","DOI":"10.1021\/ol4010118"},{"key":"e_1_2_8_3_3","doi-asserted-by":"publisher","DOI":"10.1021\/acscatal.8b04175"},{"key":"e_1_2_8_4_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.jcis.2022.09.020"},{"key":"e_1_2_8_4_2","doi-asserted-by":"publisher","DOI":"10.1016\/j.cattod.2023.114045"},{"key":"e_1_2_8_4_3","doi-asserted-by":"publisher","DOI":"10.1016\/j.apcata.2022.118660"},{"key":"e_1_2_8_4_4","doi-asserted-by":"publisher","DOI":"10.1016\/j.apcatb.2020.119863"},{"key":"e_1_2_8_5_1","doi-asserted-by":"publisher","DOI":"10.1021\/cs300756f"},{"key":"e_1_2_8_6_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.jcat.2016.07.021"},{"key":"e_1_2_8_6_2","doi-asserted-by":"publisher","DOI":"10.1016\/j.jcat.2018.02.033"},{"key":"e_1_2_8_7_1","doi-asserted-by":"publisher","DOI":"10.1021\/acsanm.9b01264"},{"key":"e_1_2_8_8_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.apcatb.2018.06.067"},{"key":"e_1_2_8_9_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.mcat.2020.111122"},{"key":"e_1_2_8_10_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.mcat.2019.110533"},{"key":"e_1_2_8_11_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.apcatb.2022.121264"},{"key":"e_1_2_8_12_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.cattod.2018.10.008"},{"key":"e_1_2_8_13_1","doi-asserted-by":"publisher","DOI":"10.1039\/D3NR00124E"},{"key":"e_1_2_8_13_2","doi-asserted-by":"publisher","DOI":"10.1016\/j.jallcom.2021.162326"},{"key":"e_1_2_8_14_1","volume-title":"Handbook of Heterogeneous Catalytic Hydrogenation for Organic Synthesis","author":"Nishimura S.","year":"2001"},{"key":"e_1_2_8_14_2","volume-title":"Catalytic Hydrogenation in Organic Syntheses","author":"Rylander P. N.","year":"1979"},{"key":"e_1_2_8_14_3","volume-title":"Slurry Reactors. In Handbook of Heterogeneous Catalysis","author":"Nedeltchev S.","year":"2008"},{"key":"e_1_2_8_15_1","doi-asserted-by":"publisher","DOI":"10.1002\/asia.201000010"},{"key":"e_1_2_8_15_2","doi-asserted-by":"publisher","DOI":"10.1002\/cssc.201000354"},{"key":"e_1_2_8_16_1","doi-asserted-by":"publisher","DOI":"10.1039\/b810396h"},{"key":"e_1_2_8_17_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.apcata.2020.117844"},{"key":"e_1_2_8_17_2","doi-asserted-by":"publisher","DOI":"10.1016\/j.surfin.2022.101938"},{"key":"e_1_2_8_18_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.solmat.2019.110214"},{"key":"e_1_2_8_18_2","doi-asserted-by":"publisher","DOI":"10.1002\/cctc.202301432"},{"key":"e_1_2_8_19_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.cattod.2019.03.050"},{"key":"e_1_2_8_20_1","unstructured":"Thermo Fisher Scientific. (s.d.) Labware Chemical Resistance Table.Thermo Fisher Scientific \u2013 DE https:\/\/tools.thermofisher.com\/content\/sfs\/brochures\/D20480.pdf."},{"key":"e_1_2_8_21_1","doi-asserted-by":"publisher","DOI":"10.1107\/S0567740877009984"},{"key":"e_1_2_8_22_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.apsusc.2015.09.109"},{"key":"e_1_2_8_23_1","doi-asserted-by":"publisher","DOI":"10.56530\/spectroscopy.ta9383e3"},{"key":"e_1_2_8_24_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.msec.2007.10.088"},{"key":"e_1_2_8_25_1","doi-asserted-by":"publisher","DOI":"10.1007\/s42452-021-04648-8"},{"key":"e_1_2_8_26_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.mee.2015.11.016"},{"key":"e_1_2_8_27_1","doi-asserted-by":"publisher","DOI":"10.3390\/app7050508"},{"key":"e_1_2_8_27_2","doi-asserted-by":"publisher","DOI":"10.1016\/S0926-860X(01)00953-X"},{"key":"e_1_2_8_28_1","doi-asserted-by":"publisher","DOI":"10.1002\/chem.201102779"},{"key":"e_1_2_8_29_1","doi-asserted-by":"publisher","DOI":"10.1039\/c2gc35714c"},{"key":"e_1_2_8_29_2","doi-asserted-by":"publisher","DOI":"10.1002\/tcr.201800170"},{"key":"e_1_2_8_29_3","doi-asserted-by":"publisher","DOI":"10.1016\/j.isci.2023.106659"}],"container-title":["Small"],"original-title":[],"language":"en","link":[{"URL":"https:\/\/onlinelibrary.wiley.com\/doi\/pdf\/10.1002\/smll.202409037","content-type":"unspecified","content-version":"vor","intended-application":"similarity-checking"}],"deposited":{"date-parts":[[2025,2,11]],"date-time":"2025-02-11T04:59:00Z","timestamp":1739249940000},"score":1,"resource":{"primary":{"URL":"https:\/\/onlinelibrary.wiley.com\/doi\/10.1002\/smll.202409037"}},"subtitle":[],"short-title":[],"issued":{"date-parts":[[2024,12,23]]},"references-count":45,"journal-issue":{"issue":"5","published-print":{"date-parts":[[2025,2]]}},"alternative-id":["10.1002\/smll.202409037"],"URL":"https:\/\/doi.org\/10.1002\/smll.202409037","archive":["Portico"],"relation":{},"ISSN":["1613-6810","1613-6829"],"issn-type":[{"value":"1613-6810","type":"print"},{"value":"1613-6829","type":"electronic"}],"subject":[],"published":{"date-parts":[[2024,12,23]]},"assertion":[{"value":"2024-10-31","order":0,"name":"received","label":"Received","group":{"name":"publication_history","label":"Publication History"}},{"value":"2024-12-23","order":3,"name":"published","label":"Published","group":{"name":"publication_history","label":"Publication History"}}],"article-number":"2409037"}}