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However, 3D printing graphene\u2010containing inks may present challenges because of their unsuitable shape retention or the fact that the concentration of the graphene component can hinder photocrosslinking. This study explores embedded 3D printing to process a chemically crosslinkable poly(ethylene glycol) ink with a high (4%\u2009w\/v) graphene oxide concentration (PEG\/GO). Given the PEG\/GO ink's insufficient shape retention and slow crosslinking, various support baths are screened, with the microparticulate bath of the crystal self\u2010healing embedding bioprinting (CLADDING) method proving most effective. The interstitial solution of the CLADDING bath influences the mechanical properties of printed PEG\/GO constructs. Multilayered PEG\/GO cylindrical constructs with &lt;500\u2009\u03bcm filament width and up to 4.5\u2009mm height (30 layers) are fabricated, presenting better tensile properties when printed within CLADDING in calcium chloride (vs. baths in crosslinking initiators). The surface of PEG\/GO constructs is anti\u2010adhesive toward human foreskin fibroblasts, and their extracts are cytocompatible. Hence, embedded 3D printing emerges as an innovative strategy to surpass limitations of shaping graphene\u2010containing hydrogels into complex geometries, broadening the biomanufacturing possibilities for diverse biomedical applications requiring kPa\u2010range mechanical properties.<\/jats:p>","DOI":"10.1002\/smsc.202500278","type":"journal-article","created":{"date-parts":[[2025,11,8]],"date-time":"2025-11-08T10:05:27Z","timestamp":1762596327000},"source":"Crossref","is-referenced-by-count":0,"title":["Embedded 3D Printing of Graphene Oxide\u2010Containing, Chemically Crosslinkable Poly(Ethylene Glycol) Inks"],"prefix":"10.1002","volume":"5","author":[{"ORCID":"https:\/\/orcid.org\/0000-0001-6938-3810","authenticated-orcid":false,"given":"Helena P.","family":"Ferreira","sequence":"first","affiliation":[{"name":"i3S \u2013 Instituto de Investiga\u00e7\u00e3o e Inova\u00e7\u00e3o em Sa\u00fade Universidade do Porto  Rua Alfredo Allen 208 4200\u2010135 Porto Portugal"},{"name":"INEB 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