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This review, composed of four sections, reports the work we have carried out over the last 10\u2005years on the synthesis of amide cross\u2010linked alkyl\/siloxane hybrids by means of sol\u2010gel chemistry and self\u2010directed assembly\/self\u2010organization routes relying on weak interactions (hydrophobic interactions and hydrogen bonding). The various as\u2010produced lamellar structures displaying a myriad of morphologies, often closely resembling those found in natural materials, are discussed. The major role played by the synthetic conditions (pH, water content, co\u2010solvent(s) nature\/concentration and dopant presence\/concentration), the alkyl chains (length and presence of ramification or not) and the number of the amide cross\u2010links present in the precursor, is evidenced. Examples of highly organized hybrids structures incorporating ionic species (alkali and alkaline earth metal salts) and optically\u2010active centers (organic dyes and lanthanide ions) are described. A useful qualitative relationship deduced between the emission quantum yield of the ordered hybrid materials and the degree of order of the hydrogen\u2010bonded network is highlighted.<\/jats:p>","DOI":"10.1002\/tcr.201700096","type":"journal-article","created":{"date-parts":[[2018,2,6]],"date-time":"2018-02-06T08:43:48Z","timestamp":1517906628000},"page":"724-736","update-policy":"http:\/\/dx.doi.org\/10.1002\/crossmark_policy","source":"Crossref","is-referenced-by-count":7,"title":["Structuring of Amide Cross\u2010Linked Non\u2010Bridged and Bridged Alkyl\u2010Based Silsesquioxanes"],"prefix":"10.1002","volume":"18","author":[{"given":"S. C.","family":"Nunes","sequence":"first","affiliation":[{"name":"CICS \u2013 Health Sciences Research Center and Chemistry Department University of Beira Interior  Rua Marqu\u00eas D'\u00c1vila e Bolama 6201-001 Covilh\u00e3 Portugal"}]},{"given":"V.","family":"de\u2005Zea\u2005Bermudez","sequence":"additional","affiliation":[{"name":"Chemistry Department and CQ-VR University of Tr\u00e1s-os-Montes e Alto Douro Quinta de Prados  5000-801 Vila Real Portugal"}]}],"member":"311","published-online":{"date-parts":[[2018,2,6]]},"reference":[{"key":"e_1_2_5_1_1","doi-asserted-by":"publisher","DOI":"10.1016\/S1369-7021(09)70156-7"},{"key":"e_1_2_5_2_1","unstructured":"Nanoscience and Nanotechnologies: Opportunities and Uncertainties. 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