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The presence of pendant arms provide with coordinative NxOy donor atoms in the smaller macrocycles, the high number of donor atoms between 7 and 10, and the dinuclear composition obtained in all the systems examined, point out that in the formed solid complexes both Ca<jats:sup>2+<\/jats:sup> ions could be located inside of the macrocycle cavities. Transmetallation reaction of a lanthanide(III) complex, [L<jats:sup>5<\/jats:sup>Sm](ClO<jats:sub>4<\/jats:sub>)<jats:sub>3<\/jats:sub>\u00b79H<jats:sub>2<\/jats:sub>O, with Ca(ClO<jats:sub>4<\/jats:sub>)<jats:sub>2<\/jats:sub>\u00b7xH<jats:sub>2<\/jats:sub>O leads the formation of the new dinuclear orange [L<jats:sup>5<\/jats:sup>Ca<jats:sub>2<\/jats:sub>](ClO<jats:sub>4<\/jats:sub>)<jats:sub>4<\/jats:sub>\u00b73H<jats:sub>2<\/jats:sub>O complex, manifesting the versatility of this macrocyclic cavity.<\/jats:p><jats:p>All complexes have been characterized by microanalysis, IR, UV\u2010vis, <jats:sup>1<\/jats:sup>H NMR spectroscopy, FAB mass spectrometry, FAAS spectroscopy, and conductivity measurements.<\/jats:p>","DOI":"10.1002\/zaac.200400039","type":"journal-article","created":{"date-parts":[[2004,5,26]],"date-time":"2004-05-26T15:10:50Z","timestamp":1085584250000},"page":"914-920","update-policy":"http:\/\/dx.doi.org\/10.1002\/crossmark_policy","source":"Crossref","is-referenced-by-count":3,"title":["Synthesis and Spectroscopic Characterization of Dinuclear Calcium Complexes with Oxa\u2010Aza Macrocyclic Ligands"],"prefix":"10.1002","volume":"630","author":[{"given":"Carlos","family":"Lodeiro","sequence":"first","affiliation":[]},{"given":"Emilia","family":"B\u00e9rtolo","sequence":"additional","affiliation":[]},{"given":"Jos\u00e9 Luis","family":"Capelo","sequence":"additional","affiliation":[]},{"given":"Rufina","family":"Bastida","sequence":"additional","affiliation":[]}],"member":"311","published-online":{"date-parts":[[2004,5,26]]},"reference":[{"key":"e_1_2_1_2_2","unstructured":"a) H. 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