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All compounds were characterized by elemental analysis, infrared spectroscopy, thermal gravimetric analysis, and X\u2010ray diffraction. The compounds exhibit a three\u2010dimensional (3D) brick\u2010like structure with rectangular\u2010shaped nano\u2010scale channels along <jats:italic>a<\/jats:italic> axis direction, made up of wave\u2010like layers containing [<jats:italic>Ln<\/jats:italic>(pzdc)]<jats:sup>+<\/jats:sup> units, which are connected by one\u2010dimensional (1D) chain of [Co(pzdc)<jats:sub>2<\/jats:sub>]<jats:sup>2\u2013<\/jats:sup>. The catalytic properties of compounds <jats:bold>1<\/jats:bold> and <jats:bold>3<\/jats:bold> were investigated in the synthesis of cyanohydrins at room temperature under solventless conditions. They showed similar catalytic activities with very high conversions of benzaldehyde and high selectivity towards cyanohydrin. The control experiment without addition of the coordination polymers only reached 16\u2009% conversion. Other aldehydes could also be converted totally under shorter reaction times also with very high selectivities for the corresponding cyanohydrins. Compound <jats:bold>1<\/jats:bold> could also be recycled in another catalytic cycle.<\/jats:p>","DOI":"10.1002\/zaac.201700344","type":"journal-article","created":{"date-parts":[[2017,10,6]],"date-time":"2017-10-06T08:06:41Z","timestamp":1507277201000},"page":"1801-1808","update-policy":"https:\/\/doi.org\/10.1002\/crossmark_policy","source":"Crossref","is-referenced-by-count":10,"title":["Synthesis, Crystal Structure, and Catalytic Properties of Porous 3d\u20104f Heterometallic Coordination Polymers Constructed from Pyrazine\u20102,3\u2010dicarboxylic Acid"],"prefix":"10.1002","volume":"643","author":[{"given":"Ting\u2010Hai","family":"Yang","sequence":"first","affiliation":[{"name":"School of Chemistry &amp; Environmental Engineering Jiangsu University of Technology  213001 Changzhou P. R. 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