{"status":"ok","message-type":"work","message-version":"1.0.0","message":{"indexed":{"date-parts":[[2026,4,4]],"date-time":"2026-04-04T09:35:50Z","timestamp":1775295350369,"version":"3.50.1"},"publisher-location":"Cham","reference-count":199,"publisher":"Springer International Publishing","isbn-type":[{"value":"9783319263311","type":"print"},{"value":"9783319263335","type":"electronic"}],"license":[{"start":{"date-parts":[[2015,1,1]],"date-time":"2015-01-01T00:00:00Z","timestamp":1420070400000},"content-version":"tdm","delay-in-days":0,"URL":"http:\/\/www.springer.com\/tdm"}],"content-domain":{"domain":["link.springer.com"],"crossmark-restriction":false},"short-container-title":[],"published-print":{"date-parts":[[2015]]},"DOI":"10.1007\/128_2015_653","type":"book-chapter","created":{"date-parts":[[2015,8,25]],"date-time":"2015-08-25T13:19:49Z","timestamp":1440508789000},"page":"157-201","update-policy":"https:\/\/doi.org\/10.1007\/springer_crossmark_policy","source":"Crossref","is-referenced-by-count":48,"title":["Site-Selective Reactions with Peptide-Based Catalysts"],"prefix":"10.1007","author":[{"given":"Michael W.","family":"Giuliano","sequence":"first","affiliation":[],"role":[{"role":"author","vocabulary":"crossref"}]},{"given":"Scott J.","family":"Miller","sequence":"additional","affiliation":[],"role":[{"role":"author","vocabulary":"crossref"}]}],"member":"297","published-online":{"date-parts":[[2015,8,26]]},"reference":[{"key":"653_CR1","doi-asserted-by":"publisher","first-page":"8711","DOI":"10.1039\/C4OB01754D","volume":"12","author":"M Matsumoto","year":"2014","unstructured":"Matsumoto M, Lee SJ, Gagne MR, Waters ML (2014) Cross-strand histidine-aromatic interactions enhance acyl-transfer rates in beta-hairpin peptide catalysts. Org Biomol Chem 12:8711\u20138718","journal-title":"Org Biomol Chem"},{"key":"653_CR2","doi-asserted-by":"publisher","first-page":"15817","DOI":"10.1021\/ja503012g","volume":"136","author":"M Matsumoto","year":"2014","unstructured":"Matsumoto M, Lee SJ, Waters ML, Gagne MR (2014) A catalyst selection protocol that identifies biomimetic motifs from \u03b2-hairpin libraries. J Am Chem Soc 136:15817\u201315820","journal-title":"J Am Chem Soc"},{"key":"653_CR3","doi-asserted-by":"publisher","first-page":"929","DOI":"10.1002\/anie.198009291","volume":"19","author":"S Julia","year":"1980","unstructured":"Julia S, Masana J, Vega JC (1980) \u201cSynthetic enzymes\u201d. Highly stereoselective epoxidation of a chalcone in a triphasic toluene-water-poly[(S)-alanine] system. Angew Chem Int Ed 19:929\u2013931","journal-title":"Angew Chem Int Ed"},{"key":"653_CR4","doi-asserted-by":"publisher","first-page":"2145","DOI":"10.1016\/S0968-0896(99)00144-3","volume":"7","author":"MJ Porter","year":"1999","unstructured":"Porter MJ, Roberts SM, Skidmore J (1999) Polyamino acids as catalysts in asymmetric synthesis. Bioorg Med Chem 7:2145\u20132156","journal-title":"Bioorg Med Chem"},{"key":"653_CR5","doi-asserted-by":"publisher","first-page":"2481","DOI":"10.1016\/S0040-4020(02)00122-9","volume":"58","author":"ER Jarvo","year":"2002","unstructured":"Jarvo ER, Miller SJ (2002) Amino acids and peptides as asymmetric organocatalysts. Tetrahedron 58:2481\u20132495","journal-title":"Tetrahedron"},{"key":"653_CR6","doi-asserted-by":"publisher","first-page":"601","DOI":"10.1021\/ar030061c","volume":"37","author":"SJ Miller","year":"2004","unstructured":"Miller SJ (2004) In search of peptide-based catalysts for asymmetric organic synthesis. Acc Chem Res 37:601\u2013610","journal-title":"Acc Chem Res"},{"key":"653_CR7","doi-asserted-by":"publisher","first-page":"5759","DOI":"10.1021\/cr068377w","volume":"107","author":"EA Colby Davie","year":"2007","unstructured":"Colby Davie EA, Mennen SM, Xu Y, Miller SJ (2007) Asymmetric catalysis mediated by synthetic peptides. Chem Rev 107:5759\u20135812","journal-title":"Chem Rev"},{"key":"653_CR8","doi-asserted-by":"publisher","first-page":"12036","DOI":"10.1039\/c1cc15237h","volume":"47","author":"H Wenemers","year":"2011","unstructured":"Wenemers H (2011) Asymmetric catalysis with peptides. Chem Commun 47:12036\u201312041","journal-title":"Chem Commun"},{"key":"653_CR9","doi-asserted-by":"publisher","first-page":"40","DOI":"10.1016\/j.cbpa.2014.09.011","volume":"22","author":"B Lewandowski","year":"2014","unstructured":"Lewandowski B, Wennemers H (2014) Asymmetric catalysis with short-chain peptides. Curr Opin Chem Biol 22:40\u201346","journal-title":"Curr Opin Chem Biol"},{"key":"653_CR10","doi-asserted-by":"publisher","first-page":"175","DOI":"10.1002\/9780470147191.ch3","volume-title":"Topics in stereochemistry","author":"HB Kagan","year":"1979","unstructured":"Kagan HB, Fiaud JC (1979) New approaches in asymmetric synthesis. In: Eliel EL, Allinger NL (eds) Topics in stereochemistry, vol 10. Wiley, Hoboken, pp 175\u2013285"},{"key":"653_CR11","doi-asserted-by":"publisher","first-page":"249","DOI":"10.1002\/9780470147276.ch4","volume-title":"Topics in stereochemistry","author":"HB Kagan","year":"1988","unstructured":"Kagan HB, Fiaud JC (1988) Kinetic resolution. In: Eliel EL, Wilen SH (eds) Topics in stereochemistry, vol 18. Wiley, Hoboken, pp 249\u2013330"},{"key":"653_CR12","doi-asserted-by":"publisher","first-page":"257","DOI":"10.1002\/9780470147313.ch5","volume-title":"Topics in stereochemistry","author":"DR Fenwick","year":"1999","unstructured":"Fenwick DR, Kagan HB (1999) Asymmetric amplification. In: Denmark SE (ed) Topics in stereochemistry, vol 122. Wiley, Hoboken, pp 257\u2013296"},{"key":"653_CR13","doi-asserted-by":"publisher","first-page":"1912","DOI":"10.1126\/science.1075762","volume":"298","author":"G Manning","year":"2002","unstructured":"Manning G, Whyte DB, Martinez R, Hunter T, Sudarsanam S (2002) The protein kinase complement of the human genome. Science 298:1912\u20131934","journal-title":"Science"},{"key":"653_CR14","doi-asserted-by":"publisher","first-page":"3","DOI":"10.1098\/rstb.1983.0033","volume":"302","author":"EG Krebs","year":"1983","unstructured":"Krebs EG (1983) Historical perspectives on protein phosphorylation and a classification system for protein kinases. Philos Trans R Soc Lond B Biol Sci 302:3\u201311","journal-title":"Philos Trans R Soc Lond B Biol Sci"},{"key":"653_CR15","volume-title":"Handbook of chemical glycosylation: advances in stereoselectivity and therapeutic relevance","year":"2008","unstructured":"Demchenko AV (ed) (2008) Handbook of chemical glycosylation: advances in stereoselectivity and therapeutic relevance. Wiley-VCH, Weinheim"},{"key":"653_CR16","doi-asserted-by":"publisher","DOI":"10.1002\/9783527618255","volume-title":"Carbohydrates in chemistry and biology","author":"B Ernst","year":"2000","unstructured":"Ernst B, Hart GW, Sinay P (2000) Protecting groups: effects on reactivity, glycosylation stereoselectivity, and coupling efficiency. In: Green LG, Ley SV (eds) Carbohydrates in chemistry and biology. Wiley-VCH, Weinheim"},{"key":"653_CR17","doi-asserted-by":"publisher","first-page":"3193","DOI":"10.1002\/cber.191404703125","volume":"47","author":"E Fischer","year":"1914","unstructured":"Fischer E (1914) \u00dcber Phosphors\u00e4ureester des Methyl-glucosids und Theophyllin-glucosids. Ber Chem 47:3193\u20133205","journal-title":"Ber Chem"},{"key":"653_CR18","doi-asserted-by":"publisher","first-page":"3741","DOI":"10.1021\/ja01571a035","volume":"79","author":"JG Moffatt","year":"1957","unstructured":"Moffatt JG, Khorana HG (1957) Carbodiimides. VII. Tetra-p-nitrophenyl pyrophosphate, a new phosphorylating agent. J Am Chem Soc 79:3741\u20133746","journal-title":"J Am Chem Soc"},{"key":"653_CR19","doi-asserted-by":"publisher","first-page":"3747","DOI":"10.1021\/ja01571a036","volume":"79","author":"RW Chambers","year":"1957","unstructured":"Chambers RW, Moffatt JG, Khorana HG (1957) Nucleoside polyphosphates. IV. A new synthesis of guanosine-5\u2032-phosphate. J Am Chem Soc 79:3747","journal-title":"J Am Chem Soc"},{"key":"653_CR20","doi-asserted-by":"publisher","first-page":"10125","DOI":"10.1021\/ja016779+","volume":"123","author":"BR Sculimbrene","year":"2001","unstructured":"Sculimbrene BR, Miller SJ (2001) Discovery of a catalytic asymmetric phosphorylation through selection of a minimal kinase mimic: a concise total synthesis of D-myo-inositol-1-phosphate. J Am Chem Soc 123:10125\u201310126","journal-title":"J Am Chem Soc"},{"key":"653_CR21","doi-asserted-by":"publisher","first-page":"11653","DOI":"10.1021\/ja027402m","volume":"124","author":"BR Sculimbrene","year":"2002","unstructured":"Sculimbrene BR, Morgan AJ, Miller SJ (2002) Enantiodivergence in small-molecule catalysis of asymmetric phosphorylation: concise total syntheses of the enantiomeric D-myo-inositol-1-phosphate and D-myo-inositol-3-phosphate. J Am Chem Soc 124:11653\u201311656","journal-title":"J Am Chem Soc"},{"key":"653_CR22","doi-asserted-by":"crossref","unstructured":"Sculimbrene BR, Morgan AJ, Miller SJ (2003) Nonenzymatic peptide-based catalytic asymmetric phosphorylation of inositol derivatives. Chem Commun 1781\u20131785","DOI":"10.1039\/b304015c"},{"key":"653_CR23","doi-asserted-by":"crossref","unstructured":"Agranoff BW, Fisher SK (1991) Inositol phosphates and derivatives: synthesis, biochemistry, and therapeutic potential. In Reitz AB (ed) ACS Symposium series 463, American Chemical Society, Washington, p 20","DOI":"10.1021\/bk-1991-0463.ch002"},{"key":"653_CR24","volume-title":"The inositol phosphates: chemical synthesis and biological significance","author":"DC Billington","year":"1993","unstructured":"Billington DC (1993) The inositol phosphates: chemical synthesis and biological significance. VCH, New York"},{"key":"653_CR25","first-page":"11638","volume":"121","author":"MC Pirrung","year":"1999","unstructured":"Pirrung MC (1999) Histidine kinases and two-component signal transduction systems. Chem Biol 121:11638\u201311643","journal-title":"Chem Biol"},{"key":"653_CR26","doi-asserted-by":"publisher","first-page":"44","DOI":"10.1021\/cb200445w","volume":"7","author":"JM Kee","year":"2012","unstructured":"Kee JM, Muir TW (2012) Chasing phosphohistidine, an elusive sibling in the phosphoamino acid family. ACS Chem Biol 7:44\u201351","journal-title":"ACS Chem Biol"},{"key":"653_CR27","doi-asserted-by":"publisher","first-page":"6496","DOI":"10.1021\/ja0108584","volume":"123","author":"GT Copeland","year":"2001","unstructured":"Copeland GT, Miller SJ (2001) Selection of enantioselective acyl transfer catalysts from a pooled peptide library through a fluorescence-based activity assay: an approach to kinetic resolution of secondary alcohols of broad structural scope. J Am Chem Soc 123:6496\u20136502","journal-title":"J Am Chem Soc"},{"key":"653_CR28","doi-asserted-by":"publisher","first-page":"11638","DOI":"10.1021\/ja9931776","volume":"121","author":"ER Jarvo","year":"1999","unstructured":"Jarvo ER, Copeland GT, Papaioannou N, Bonitatebus PJ, Miller SJ (1999) A biomimetic approach to asymmetric acyl transfer catalysis. J Am Chem Soc 121:11638\u201311643","journal-title":"J Am Chem Soc"},{"key":"653_CR29","doi-asserted-by":"publisher","first-page":"1423","DOI":"10.1039\/p19890001423","volume":"1","author":"DC Billington","year":"1989","unstructured":"Billington DC, Baker R, Kulagowski JJ, Mawer IM, Vacca JP, deSolms SJ, Huff JR (1989) The total synthesis of myo-inositol phosphates via myo-inositol orthoformate. J Chem Soc Perkin Trans 1:1423\u20131429","journal-title":"J Chem Soc Perkin Trans"},{"key":"653_CR30","doi-asserted-by":"publisher","first-page":"327","DOI":"10.1038\/35073015","volume":"2","author":"RF Irvine","year":"2001","unstructured":"Irvine RF, Schell MJ (2001) Back in the water: the return of the inositol phosphates. Nat Rev Mol Cell Biol 2:327\u2013338","journal-title":"Nat Rev Mol Cell Biol"},{"key":"653_CR31","doi-asserted-by":"publisher","first-page":"619","DOI":"10.1016\/j.chembiol.2004.03.025","volume":"11","author":"GD Prestwich","year":"2004","unstructured":"Prestwich GD (2004) Phosphoinositide signaling: from affinity probes to pharmaceutical targets. Chem Biol 11:619\u2013637","journal-title":"Chem Biol"},{"key":"653_CR32","doi-asserted-by":"publisher","first-page":"651","DOI":"10.1038\/nature05185","volume":"443","author":"G Di Paolo","year":"2006","unstructured":"Di Paolo G, de Camilli P (2006) Phosphoinositides in cell regulation and membrane dynamics. Nature 443:651\u2013657","journal-title":"Nature"},{"key":"653_CR33","doi-asserted-by":"publisher","first-page":"13182","DOI":"10.1021\/ja0466098","volume":"126","author":"BR Sculimbrene","year":"2004","unstructured":"Sculimbrene BR, Xu Y, Miller SJ (2004) Asymmetric syntheses of phosphatidylinositol-3-phosphates with saturated and unsaturated side chains through catalytic asymmetric phosphorylation. J Am Chem Soc 126:13182\u201313183","journal-title":"J Am Chem Soc"},{"key":"653_CR34","doi-asserted-by":"publisher","first-page":"15370","DOI":"10.1021\/ja047360x","volume":"126","author":"AJ Morgan","year":"2004","unstructured":"Morgan AJ, Wang YK, Roberts MF, Miller SJ (2004) Chemistry and biology of deoxy-myo-inositol phosphates: stereospecificity of substrate interactions within an archaeal and a bacterial IMPase. J Am Chem Soc 126:15370\u201315371","journal-title":"J Am Chem Soc"},{"key":"653_CR35","doi-asserted-by":"publisher","first-page":"6923","DOI":"10.1021\/jo0610816","volume":"71","author":"AJ Morgan","year":"2006","unstructured":"Morgan AJ, Komiya S, Xu Y, Miller SJ (2006) Unified total syntheses of the inositol polyphosphates: D-I-3,5,6P3, D-I-3,4,5P3, and D-I-3,4,5,6P4 via catalytic enantioselective and site-selective phosphorylation. J Org Chem 71:6923\u20136931","journal-title":"J Org Chem"},{"key":"653_CR36","doi-asserted-by":"publisher","first-page":"4919","DOI":"10.1021\/jo060702s","volume":"71","author":"Y Xu","year":"2006","unstructured":"Xu Y, Sculimbrene BR, Miller SJ (2006) Streamlined synthesis of phosphatidylinositol (PI), PI3P, PI3,5P2, and deoxygenated analogues as potential biological probes. J Org Chem 71:4919\u20134928","journal-title":"J Org Chem"},{"key":"653_CR37","doi-asserted-by":"publisher","first-page":"4158","DOI":"10.1002\/anie.200900480","volume":"48","author":"CM Longo","year":"2009","unstructured":"Longo CM, Wei Y, Roberts MF, Miller SJ (2009) Asymmetric syntheses of L, L- and L, D-di-myo-inositol-1,1\u2032-phosphate and their behavior as stabilizers of enzyme activity at extreme temperatures. Angew Chem Int Ed 48:4158\u20134161","journal-title":"Angew Chem Int Ed"},{"key":"653_CR38","doi-asserted-by":"crossref","first-page":"3660","DOI":"10.1128\/aem.60.10.3660-3664.1994","volume":"60","author":"R Cuilla","year":"1994","unstructured":"Cuilla R, Burrgraf S, Stetter KO, Roberts MF (1994) Occurrence and role of di-myo-inositol-1,1\u2032-phosphate in Methanococcus igneus. Appl Environ Microbiol 60:3660\u20133664","journal-title":"Appl Environ Microbiol"},{"key":"653_CR39","doi-asserted-by":"crossref","first-page":"3785","DOI":"10.1128\/JB.180.15.3785-3792.1998","volume":"180","author":"L Chen","year":"1998","unstructured":"Chen L, Spiliotis ET, Roberts MF (1998) Biosynthesis of di-myo-inositol-1,1\u2032-phosphate, a novel osmolyte in hyperthermophilic Archaea. J Bacteriol 180:3785\u20133792","journal-title":"J Bacteriol"},{"key":"653_CR40","doi-asserted-by":"publisher","first-page":"412","DOI":"10.1021\/ja410750a","volume":"136","author":"BD Chandler","year":"2014","unstructured":"Chandler BD, Burkhardt AL, Foley K, Cullis C, Driscoll D, D\u2019Amore NR, Miller SJ (2014) A fully synthetic and biochemically validated phosphatidyl inositol-3-phosphate hapten via asymmetric synthesis and native chemical ligation. J Am Chem Soc 136:412\u2013418","journal-title":"J Am Chem Soc"},{"key":"653_CR41","doi-asserted-by":"publisher","first-page":"597","DOI":"10.1016\/S0968-4328(99)00036-0","volume":"6","author":"JR Harris","year":"1999","unstructured":"Harris JR, Markl J (1999) Keyhole limpet hemocyanin (KLH): a biomedical review. Micron 6:597\u2013623","journal-title":"Micron"},{"key":"653_CR42","volume-title":"Antibodies: a laboratory manual","author":"E Harlow","year":"1988","unstructured":"Harlow E, Lane D (1988) Antibodies: a laboratory manual. Cold Spring Harbor, New York, Chapter 5"},{"key":"653_CR43","volume-title":"Bioconjugate techniques","author":"GT Hermanson","year":"2008","unstructured":"Hermanson GT (2008) Bioconjugate techniques, 2nd edn. Academic, New York, Chapter 19","edition":"2"},{"key":"653_CR44","doi-asserted-by":"publisher","first-page":"4805","DOI":"10.1021\/jo00096a023","volume":"59","author":"SF Martin","year":"1994","unstructured":"Martin SF, Josey JA, Wong YL, Dean DW (1994) General method for the synthesis of phospholipid derivatives of 1,2-O-diacyl-sn-glycerols. J Org Chem 59:4805\u20134820","journal-title":"J Org Chem"},{"key":"653_CR45","doi-asserted-by":"publisher","first-page":"776","DOI":"10.1126\/science.7973629","volume":"266","author":"PE Dawson","year":"1994","unstructured":"Dawson PE, Muir TW, Clark-Lewis I, Kent SBH (1994) Synthesis of proteins by native chemical ligation. Science 266:776\u2013779","journal-title":"Science"},{"key":"653_CR46","doi-asserted-by":"publisher","first-page":"6640","DOI":"10.1021\/ja058344i","volume":"128","author":"ECB Johnson","year":"2006","unstructured":"Johnson ECB, Kent SBH (2006) Insights into the mechanism and catalysis of the native chemical ligation reaction. J Am Chem Soc 128:6640\u20136646","journal-title":"J Am Chem Soc"},{"key":"653_CR47","doi-asserted-by":"publisher","first-page":"91","DOI":"10.1146\/annurev.biophys.34.040204.144700","volume":"34","author":"BL Nilsson","year":"2005","unstructured":"Nilsson BL, Soellner MB, Raines RT (2005) Chemical synthesis of proteins. Annu Rev Biophys Biomol Struct 34:91\u2013118","journal-title":"Annu Rev Biophys Biomol Struct"},{"key":"653_CR48","doi-asserted-by":"publisher","first-page":"1061","DOI":"10.1002\/cbic.201000165","volume":"11","author":"GM Fang","year":"2010","unstructured":"Fang GM, Cui HK, Zheng JS, Liu L (2010) Chemoselective ligation of peptide phenyl esters with N-terminal cysteines. ChemBioChem 11:1061\u20131065","journal-title":"ChemBioChem"},{"key":"653_CR49","doi-asserted-by":"publisher","first-page":"3021","DOI":"10.1021\/ol051061a","volume":"7","author":"CA Lewis","year":"2005","unstructured":"Lewis CA, Sculimbrene BR, Xu Y, Miller SJ (2005) Desymmetrization of glycerol derivatives with peptide-based acylation catalysts. Org Lett 7:3021\u20133023","journal-title":"Org Lett"},{"key":"653_CR50","doi-asserted-by":"publisher","first-page":"8869","DOI":"10.1016\/j.tet.2003.05.002","volume":"59","author":"KS Griswold","year":"2003","unstructured":"Griswold KS, Miller SJ (2003) A peptide-based catalyst approach to regioselective functionalization of carbohydrates. Tetrahedron 59:8869\u20138875","journal-title":"Tetrahedron"},{"key":"653_CR51","doi-asserted-by":"publisher","first-page":"8134","DOI":"10.1021\/ja047845l","volume":"126","author":"JW Evans","year":"2004","unstructured":"Evans JW, Fierman MB, Miller SJ, Ellman JA (2004) Catalytic enantioselective synthesis of sulfinate esters through the dynamic resolution of tert-butanesulfinyl chloride. J Am Chem Soc 126:8134\u20138135","journal-title":"J Am Chem Soc"},{"key":"653_CR52","doi-asserted-by":"publisher","first-page":"1525","DOI":"10.1021\/ja00239a036","volume":"109","author":"SL Schreiber","year":"1987","unstructured":"Schreiber SL, Schreiber TS, Smith DB (1987) Reactions that proceed with a combination of enantiotopic group and diastereotopic face selectivity can deliver products with very high enantiomeric excess: experimental support of a mathematical model. J Am Chem Soc 109:1525\u20131529","journal-title":"J Am Chem Soc"},{"key":"653_CR53","doi-asserted-by":"publisher","first-page":"3169","DOI":"10.1021\/ja963275g","volume":"119","author":"T Kawabata","year":"1997","unstructured":"Kawabata T, Nagato M, Takasu K, Fuji K (1997) Nonenzymatic kinetic resolution of racemic alcohols through an \u201cinduced fit\u201d process. J Am Chem Soc 119:3169\u20133170","journal-title":"J Am Chem Soc"},{"key":"653_CR54","doi-asserted-by":"crossref","unstructured":"Kawabata T, Yamamoto K, Momose Y, Yoshida H, Nagaoka Y, Fuji K (2001) Kinetic resolution of amino alcohol derivatives with a chiral nucleophilic catalyst: access to enantiopure cyclic cis-amino alcohols. Chem Commun 2700\u20132701","DOI":"10.1039\/b108753c"},{"key":"653_CR55","doi-asserted-by":"publisher","first-page":"12890","DOI":"10.1021\/ja074882e","volume":"129","author":"T Kawabata","year":"2007","unstructured":"Kawabata T, Muramatsu W, Nishio T, Shibata T, Schedel H (2007) A catalytic one-step process for the chemo- and regioselective acylation of monosaccharides. J Am Chem Soc 129:12890\u201312895","journal-title":"J Am Chem Soc"},{"key":"653_CR56","doi-asserted-by":"publisher","first-page":"8802","DOI":"10.1021\/jo901569v","volume":"74","author":"Y Ueda","year":"2009","unstructured":"Ueda Y, Muramatsu W, Mishiro K, Furuta T, Kawabata T (2009) Functional group tolerance in organocatalytic regioselective acylation of carbohydrates. J Org Chem 74:8802\u20138805","journal-title":"J Org Chem"},{"key":"653_CR57","doi-asserted-by":"publisher","first-page":"8260","DOI":"10.1021\/ja3046684","volume":"134","author":"CL Williamson","year":"2012","unstructured":"Williamson CL, Chan L, Taylor MS (2012) Regioselective, borinic acid-catalyzed monoacylation, sulfonylation, and alkylation of diols and carbohydrates: expansion of substrate and mechanistic studies. J Am Chem Soc 134:8260\u20138267","journal-title":"J Am Chem Soc"},{"key":"653_CR58","doi-asserted-by":"publisher","first-page":"295","DOI":"10.1021\/ar500371z","volume":"48","author":"MS Taylor","year":"2015","unstructured":"Taylor MS (2015) Catalysis based on reversible covalent interactions of organoboron compounds. Acc Chem Res 48:295\u2013305","journal-title":"Acc Chem Res"},{"key":"653_CR59","doi-asserted-by":"publisher","first-page":"790","DOI":"10.1038\/nchem.1726","volume":"5","author":"X Sun","year":"2013","unstructured":"Sun X, Lee H, Lee S, Tan KL (2013) Catalyst recognition of cis-1,2-diols enables site-selective functionalization of complex molecules. Nat Chem 5:790\u2013795","journal-title":"Nat Chem"},{"key":"653_CR60","doi-asserted-by":"publisher","first-page":"768","DOI":"10.1038\/nchem.1708","volume":"5","author":"N Manville","year":"2013","unstructured":"Manville N, Alite H, Haeffner F, Hoveyda AH, Snapper ML (2013) Enantioselective silyl protection of alcohols promoted by a combination of chiral and achiral Lewis basic catalysts. Nat Chem 5:768\u2013774","journal-title":"Nat Chem"},{"key":"653_CR61","doi-asserted-by":"publisher","first-page":"4710","DOI":"10.1021\/ol402023c","volume":"15","author":"TP Blaisdell","year":"2013","unstructured":"Blaisdell TP, Lee S, Kasaplar P, Sun X, Tan KL (2013) Practical silyl protection of ribonucleosides. Org Lett 15:4710\u20134713","journal-title":"Org Lett"},{"key":"653_CR62","doi-asserted-by":"publisher","first-page":"10494","DOI":"10.1021\/jo4012909","volume":"78","author":"X Sun","year":"2013","unstructured":"Sun X, Worthy AD, Tan KL (2013) Resolution of terminal 1,2-diols via silyl transfer. J Org Chem 78:10494\u201310499","journal-title":"J Org Chem"},{"key":"653_CR63","doi-asserted-by":"publisher","first-page":"790","DOI":"10.1038\/nchem.1726","volume":"5","author":"X Sun","year":"2013","unstructured":"Sun X, Lee H, Lee S, Tan KL (2013) Catalyst recognition of cis-1,2-diols enables site-selective functionalization of complex molecules. Nature Chem 5:790\u2013795","journal-title":"Nature Chem"},{"key":"653_CR64","doi-asserted-by":"publisher","first-page":"64","DOI":"10.1038\/nature05102","volume":"443","author":"Y Zhao","year":"2006","unstructured":"Zhao Y, Rodrigo J, Hoveyda AH, Snapper ML (2006) Enantioselective silyl protection of alcohols catalysed by amino-acid-based small molecule. Nature 443:64\u201370","journal-title":"Nature"},{"key":"653_CR65","doi-asserted-by":"publisher","first-page":"425","DOI":"10.1039\/a900566h","volume":"16","author":"BJ Rawlings","year":"1999","unstructured":"Rawlings BJ (1999) Biosynthesis of polyketides (other than actinomycete macrolides). Nat Prod Rep 16:425\u2013484","journal-title":"Nat Prod Rep"},{"key":"653_CR66","doi-asserted-by":"publisher","first-page":"1","DOI":"10.1007\/3-540-48146-X_1","volume":"209","author":"B Shen","year":"2000","unstructured":"Shen B (2000) Biosynthesis of aromatic polyketides. Top Curr Chem 209:1\u201351","journal-title":"Top Curr Chem"},{"key":"653_CR67","doi-asserted-by":"publisher","first-page":"461","DOI":"10.1021\/np068054v","volume":"70","author":"DJ Newman","year":"2007","unstructured":"Newman DJ, Cragg GM (2007) Natural products as sources of new drugs over the last 25 years. J Nat Prod 70:461\u2013477","journal-title":"J Nat Prod"},{"key":"653_CR68","doi-asserted-by":"publisher","first-page":"4","DOI":"10.1021\/ar7000414","volume":"41","author":"CT Walsh","year":"2008","unstructured":"Walsh CT (2008) The chemical versatility of natural product assembly lines. Acc Chem Res 41:4\u201310","journal-title":"Acc Chem Res"},{"key":"653_CR69","doi-asserted-by":"publisher","first-page":"3670","DOI":"10.1016\/j.bbagen.2013.02.008","volume":"1830","author":"GM Cragg","year":"2013","unstructured":"Cragg GM, Newman DJ (2013) Natural products: a continuing source of novel drug leads. Biochim Biophys Acta 1830:3670\u20133695","journal-title":"Biochim Biophys Acta"},{"key":"653_CR70","doi-asserted-by":"publisher","first-page":"4688","DOI":"10.1002\/anie.200806121","volume":"48","author":"C Hertweck","year":"2009","unstructured":"Hertweck C (2009) The biosynthetic logic of polyketide diversity. Angew Chem Int Ed 48:4688\u20134716","journal-title":"Angew Chem Int Ed"},{"key":"653_CR71","doi-asserted-by":"publisher","first-page":"7506","DOI":"10.1002\/anie.200602780","volume":"45","author":"B Schetter","year":"2006","unstructured":"Schetter B, Mahrwald R (2006) Modern aldol methods for the total synthesis of polyketides. Angew Chem Int Ed 45:7506\u20137525","journal-title":"Angew Chem Int Ed"},{"key":"653_CR72","doi-asserted-by":"publisher","first-page":"504","DOI":"10.1039\/c3np70076c","volume":"31","author":"AMR Dechert-Schmitt","year":"2014","unstructured":"Dechert-Schmitt AMR, Schmitt DC, Gao X, Itoh T, Krische MJ (2014) Polyketide construction via hydrohydroxyalkylation and related alcohol C-H functionalizations. Reinventing the chemistry of carbonyl addition. Nat Prod Rep 31:504\u2013513","journal-title":"Nat Prod Rep"},{"key":"653_CR73","first-page":"777","volume":"13","author":"SM Dalby","year":"2010","unstructured":"Dalby SM, Paterson I (2010) Synthesis of polyketide natural products and analogs as promising anticancer agents. Curr Opin Drug Discov Devel 13:777\u2013794","journal-title":"Curr Opin Drug Discov Devel"},{"key":"653_CR74","doi-asserted-by":"publisher","first-page":"63","DOI":"10.1126\/science.282.5386.63","volume":"282","author":"DE Cane","year":"1998","unstructured":"Cane DE, Walsh CT, Khosla C (1998) Harnessing the biosynthetic code: combinations, permutations, and mutations. Science 282:63\u201368","journal-title":"Science"},{"key":"653_CR75","doi-asserted-by":"publisher","first-page":"2875","DOI":"10.1021\/bi500290t","volume":"53","author":"C Khosla","year":"2014","unstructured":"Khosla C, Herschlag D, Cane DE, Walsh CT (2014) Assembly line polyketide synthases: mechanistic insights and unsolved problems. Biochemistry 53:2875\u20132883","journal-title":"Biochemistry"},{"key":"653_CR76","doi-asserted-by":"publisher","first-page":"201","DOI":"10.1146\/annurev.mi.49.100195.001221","volume":"49","author":"CR Hutchinson","year":"1995","unstructured":"Hutchinson CR, Fuji I (1995) Polyketide synthase gene manipulation: a structure-function approach in engineering novel antibiotics. Annu Rev Microbiol 49:201\u2013238","journal-title":"Annu Rev Microbiol"},{"key":"653_CR77","doi-asserted-by":"publisher","first-page":"367","DOI":"10.1126\/science.277.5324.367","volume":"277","author":"JR Jacobsen","year":"1997","unstructured":"Jacobsen JR, Hutchinson CR, Cane DE, Khosla C (1997) Precursor-directed biosynthesis of erythromycin analogs by an engineered polyketide synthase. Science 277:367\u2013369","journal-title":"Science"},{"key":"653_CR78","doi-asserted-by":"publisher","first-page":"189","DOI":"10.1016\/j.tibs.2015.02.001","volume":"40","author":"C Hertweck","year":"2015","unstructured":"Hertweck C (2015) Decoding and reprogramming complex polyketide assemblylines: prospects for synthetic biology. Trends Biochem Sci 40:189\u2013199","journal-title":"Trends Biochem Sci"},{"key":"653_CR79","doi-asserted-by":"publisher","first-page":"6062","DOI":"10.1021\/ja01579a059","volume":"79","author":"PF Wiley","year":"1957","unstructured":"Wiley PF, Gerzon K, Flynn EH, Sigal MV, Weaver O, Quarck UC, Chauvette RR, Monahan R (1957) Erythromycin. X. Structure of erythromycin. J Am Chem Soc 79:6062\u20136070","journal-title":"J Am Chem Soc"},{"key":"653_CR80","doi-asserted-by":"publisher","first-page":"628","DOI":"10.7164\/antibiotics.50.628","volume":"50","author":"JW Kim","year":"1997","unstructured":"Kim JW, Adachi H, Kazuo SY, Hayakwa Y, Seto H (1997) Apoptolidin, a new apoptosis inducer in transformed cells from Nocardiopsis sp. J Antibiot 50:628\u2013630","journal-title":"J Antibiot"},{"key":"653_CR81","doi-asserted-by":"publisher","first-page":"127","DOI":"10.1039\/b312213c","volume":"2","author":"RE Taylor","year":"2004","unstructured":"Taylor RE, Chen Y, Galvin GM, Prabba PK (2004) Conformation-activity relationships in polyketide natural products. Towards to biologically active conformation of epothilone. Org Biomol Chem 2:127\u2013132","journal-title":"Org Biomol Chem"},{"key":"653_CR82","doi-asserted-by":"publisher","first-page":"1183","DOI":"10.1039\/C5NP00014A","volume":"32","author":"EM Larsen","year":"2015","unstructured":"Larsen EM, Wilson MR, Taylor RE (2015) Conformation-activity relationships of polyketide natural products. Nat Prod Rep 32:1183\u20131206","journal-title":"Nat Prod Rep"},{"key":"653_CR83","doi-asserted-by":"publisher","first-page":"1451","DOI":"10.1016\/j.addr.2005.04.002","volume":"57","author":"GD Wright","year":"2005","unstructured":"Wright GD (2005) Bacterial resistance to antibiotics: enzymatic degradation and modification. Adv Drug Deliv Rev 57:1451\u20131470","journal-title":"Adv Drug Deliv Rev"},{"key":"653_CR84","doi-asserted-by":"publisher","first-page":"775","DOI":"10.1038\/35021219","volume":"406","author":"CT Walsh","year":"2005","unstructured":"Walsh CT (2005) Molecular mechanisms that confer antibacterial drug resistance. Nature 406:775\u2013781","journal-title":"Nature"},{"key":"653_CR85","doi-asserted-by":"publisher","first-page":"12222","DOI":"10.1021\/ja0733686","volume":"129","author":"S Peddibhotia","year":"2007","unstructured":"Peddibhotia S, Dang Y, Liu JO, Romo D (2007) Simultaneous arming and structure\/activity studies of natural products employing O-H insertions: an expedient and versatile strategy for natural products-based chemical genetics. J Am Chem Soc 129:12222\u201312231","journal-title":"J Am Chem Soc"},{"key":"653_CR86","doi-asserted-by":"publisher","first-page":"318","DOI":"10.1039\/c3np70087a","volume":"31","author":"O Robles","year":"2014","unstructured":"Robles O, Romo D (2014) Chemo- and site-selective derivatizations of natural products enabling biological studies. Nat Prod Rep 31:318\u2013334","journal-title":"Nat Prod Rep"},{"key":"653_CR87","doi-asserted-by":"publisher","first-page":"5616","DOI":"10.1002\/anie.200601490","volume":"45","author":"CA Lewis","year":"2006","unstructured":"Lewis CA, Miller SJ (2006) Site-selective derivatization and remodeling of erythromycin A by using simple peptide-based chiral catalysts. Angew Chem Int Ed 45:5616\u20135619","journal-title":"Angew Chem Int Ed"},{"key":"653_CR88","doi-asserted-by":"publisher","first-page":"6007","DOI":"10.1016\/j.bmcl.2008.09.019","volume":"18","author":"CA Lewis","year":"2008","unstructured":"Lewis CA, Merkel J, Miller SJ (2008) Catalytic site-selective synthesis and evaluation of a series of erythromycin analogs. Bioorg Med Chem Lett 18:6007\u20136011","journal-title":"Bioorg Med Chem Lett"},{"key":"653_CR89","doi-asserted-by":"publisher","first-page":"631","DOI":"10.1021\/jm00276a017","volume":"15","author":"PH Jones","year":"1972","unstructured":"Jones PH, Perun TJ, Rowley EK, Baker EJ (1972) Chemical modifications of erythromycin antibiotics. 3. Synthesis of 4\u2033 and 11 esters of erythromycin A and B. J Med Chem 15:631\u2013634","journal-title":"J Med Chem"},{"key":"653_CR90","doi-asserted-by":"publisher","first-page":"635","DOI":"10.1021\/jm00276a018","volume":"15","author":"YC Martin","year":"1972","unstructured":"Martin YC, Jones PH, Perun TJ, Grundy WE, Bell S, Bower RR, Shipkowitz NL (1972) Chemical modification of erythromycin antibiotics. 4. Structure-activity relations of erythromycin esters. J Med Chem 15:635\u2013638","journal-title":"J Med Chem"},{"key":"653_CR91","doi-asserted-by":"publisher","first-page":"4105","DOI":"10.1021\/ja00088a067","volume":"116","author":"TS Haque","year":"1994","unstructured":"Haque TS, Little JC, Gellman SH (1994) \u2018Mirror image\u2019 reverse turns promote \u03b2-hairpin formation. J Am Chem Soc 116:4105\u20134106","journal-title":"J Am Chem Soc"},{"key":"653_CR92","doi-asserted-by":"publisher","first-page":"6975","DOI":"10.1021\/ja960429j","volume":"118","author":"TS Haque","year":"1996","unstructured":"Haque TS, Little JC, Gellman SH (1996) Stereochemical requirements for \u03b2-hairpin formation: model studies with four-residue peptides and depsipeptides. J Am Chem Soc 118:6975\u20136985","journal-title":"J Am Chem Soc"},{"key":"653_CR93","doi-asserted-by":"publisher","first-page":"717","DOI":"10.1016\/S1367-5931(98)80109-9","volume":"2","author":"SH Gellman","year":"1998","unstructured":"Gellman SH (1998) Minimal models systems for \u03b2-sheet secondary structure in proteins. Curr Opin Chem Biol 2:717\u2013725","journal-title":"Curr Opin Chem Biol"},{"key":"653_CR94","doi-asserted-by":"publisher","first-page":"201","DOI":"10.1039\/p29910000201","volume":"2","author":"JS Davies","year":"1991","unstructured":"Davies JS, Everett JR, Hatton IK, Hunt E, Tyler JW, Zomaya II, Slawin AMZ, Williams DJ (1991) NMR spectroscopic and X-ray crystallographic studies on the structure, stereochemistry and conformation of a series of 9,11 cyclic aminals of (9S)-9-N-methylerythromyclamine A. J Chem Soc Perkin Trans 2:201\u2013214","journal-title":"J Chem Soc Perkin Trans"},{"key":"653_CR95","doi-asserted-by":"publisher","first-page":"1481","DOI":"10.1039\/p29910001481","volume":"2","author":"JR Everett","year":"1991","unstructured":"Everett JR, Hunt E, Tyler JW (1991) Ketone-hemiacetal tautomerism in erythromycin A in non-aqueous solutions. An NMR spectroscopic study. J Chem Soc Perkin Trans 2:1481\u20131487","journal-title":"J Chem Soc Perkin Trans"},{"key":"653_CR96","doi-asserted-by":"crossref","first-page":"159","DOI":"10.1128\/am.18.2.159-165.1969","volume":"18","author":"PL Tardrew","year":"1969","unstructured":"Tardrew PL, Mao JCH, Kenney D (1969) Antibacterial activity of 2\u2032esters of erythromycin. Appl Microbiol 18:159\u2013165","journal-title":"Appl Microbiol"},{"key":"653_CR97","doi-asserted-by":"publisher","first-page":"1864","DOI":"10.1021\/np9004932","volume":"72","author":"CA Lewis","year":"2009","unstructured":"Lewis CA, Longcore KE, Miller SJ, Wender PA (2009) An approach to the site-selective diversification of apoptolidin A with peptide-based catalysts. J Nat Prod 72:1864\u20131869","journal-title":"J Nat Prod"},{"key":"653_CR98","doi-asserted-by":"publisher","first-page":"3819","DOI":"10.1021\/ol0266222","volume":"4","author":"PA Wender","year":"2002","unstructured":"Wender PA, Gulledge AV, Jankowski OD, Seto H (2002) Isoapoptolidin: structure and activity of the ring-expanded isomer of apoptolidin. Org Lett 4:3819\u20133822","journal-title":"Org Lett"},{"key":"653_CR99","doi-asserted-by":"publisher","first-page":"3823","DOI":"10.1021\/ol026829v","volume":"4","author":"JD Pennington","year":"2002","unstructured":"Pennington JD, Williams HJ, Salomon AR, Sulikowski GA (2002) Toward a stable apoptolidin derivative: identification of isoapoptolidin and selective deglycosylation of apoptolidin. Org Lett 4:3823\u20133825","journal-title":"Org Lett"},{"key":"653_CR100","doi-asserted-by":"publisher","first-page":"589","DOI":"10.1021\/ol052800q","volume":"8","author":"PA Wender","year":"2006","unstructured":"Wender PA, Jankowski OD, Longcore K, Tabet EA, Seto H, Tomikawa T (2006) Correlation of F0F1-ATPase inhibition and antiproliferative activity of apoptolidin analogues. Org Lett 8:589\u2013592","journal-title":"Org Lett"},{"key":"653_CR101","doi-asserted-by":"publisher","first-page":"799","DOI":"10.1038\/385799a0","volume":"385","author":"P Linnane","year":"1997","unstructured":"Linnane P, Magnus N, Magnus P (1997) Induction of molecular asymmetry by a remote chiral group. Nature 385:799\u2013801","journal-title":"Nature"},{"key":"653_CR102","doi-asserted-by":"publisher","first-page":"966","DOI":"10.1038\/nature02933","volume":"431","author":"J Clayden","year":"2004","unstructured":"Clayden J, Lund A, Vallverdu L, Helliwell M (2004) Ultra-remote stereocontrol by conformational communication of information along a carbon chain. Nature 431:966\u2013971","journal-title":"Nature"},{"key":"653_CR103","doi-asserted-by":"publisher","first-page":"151","DOI":"10.1002\/anie.201308264","volume":"53","author":"L Byrne","year":"2014","unstructured":"Byrne L, Sola J, Boddaert T, Marcelli T, Adams RW, Morris GA, Clayden J (2014) Foldamer-mediated remote stereocontrol: >1,60 asymmetric induction. Angew Chem Int Ed 53:151\u2013155","journal-title":"Angew Chem Int Ed"},{"key":"653_CR104","doi-asserted-by":"publisher","first-page":"16454","DOI":"10.1021\/ja067840j","volume":"128","author":"CA Lewis","year":"2006","unstructured":"Lewis CA, Chiu A, Kubryk M, Balsells J, Pollard D, Esser CK, Murry J, Reamer RA, Hansen KB, Miller SJ (2006) Remote desymmetrization at near-nanometer group separation catalyzed by a miniaturized enzyme mimic. J Am Chem Soc 128:16454\u201316455","journal-title":"J Am Chem Soc"},{"key":"653_CR105","doi-asserted-by":"publisher","first-page":"16358","DOI":"10.1021\/ja807120z","volume":"130","author":"CA Lewis","year":"2008","unstructured":"Lewis CA, Gustafson JL, Chiu A, Balsells J, Pollard D, Murry J, Reamer RA, Hansen KB, Miller SJ (2008) A case of remote asymmetric induction in the peptide-catalyzed desymmetrization of a bis(phenol). J Am Chem Soc 130:16358\u201316455","journal-title":"J Am Chem Soc"},{"key":"653_CR106","doi-asserted-by":"publisher","first-page":"1307","DOI":"10.1021\/cr00020a002","volume":"93","author":"A Hoveyda","year":"1993","unstructured":"Hoveyda A, Evans DA, Fu GC (1993) Substrate-directable chemical reactions. Chem Rev 93:1307\u20131370","journal-title":"Chem Rev"},{"key":"653_CR107","doi-asserted-by":"publisher","first-page":"15016","DOI":"10.1021\/ja508185d","volume":"136","author":"FK Yoshimoto","year":"2014","unstructured":"Yoshimoto FK, Guengerich FP (2014) Mechanism of the third oxidative step in the conversion of androgens to estrogens by cytochrome P450 19A1 steroid aromatase. J Am Chem Soc 136:15016\u201315025","journal-title":"J Am Chem Soc"},{"key":"653_CR108","doi-asserted-by":"publisher","first-page":"3248","DOI":"10.1074\/jbc.M114.627265","volume":"290","author":"PS Pallan","year":"2015","unstructured":"Pallan PS, Nagy LD, Li L, Gonzalez E, Kramlinger VM, Azumaya CM, Waterman MR, Guengerich FP, Egli M, Wawrzak Z (2015) Structural and kinetic basis of steroid 17\u03b1,20-lyase activity in teleost fish cytochrome P450 17A1 and its absence in cytochrome P450 17A2. J Biol Chem 290:3248\u20133268","journal-title":"J Biol Chem"},{"key":"653_CR109","doi-asserted-by":"publisher","first-page":"947","DOI":"10.1210\/er.2003-0030","volume":"25","author":"AH Payne","year":"2004","unstructured":"Payne AH, Hales DB (2004) Overview of steroidogenic enzymes in the pathway from cholesterol to active steroid hormones. Endocr Rev 25:947\u2013970","journal-title":"Endocr Rev"},{"key":"653_CR110","doi-asserted-by":"publisher","first-page":"1574","DOI":"10.1039\/p19750001574","volume":"1","author":"DHR Barton","year":"1975","unstructured":"Barton DHR, McCombie SW (1975) A new method for the deoxygenation of secondary alcohols. J Chem Soc Perkin Trans 1:1574\u20131585","journal-title":"J Chem Soc Perkin Trans"},{"key":"653_CR111","doi-asserted-by":"publisher","first-page":"8969","DOI":"10.1016\/S0040-4020(01)86502-9","volume":"47","author":"DHR Barton","year":"1991","unstructured":"Barton DHR, Blundell P, Dorchak J, Jang DO, Jaszberenyi J (1991) The invention of radical reactions. Part XXI. Simple methods for the radical deoxygenation of primary alcohols. Tetrahedron 47:8969\u20138984","journal-title":"Tetrahedron"},{"key":"653_CR112","doi-asserted-by":"publisher","first-page":"7435","DOI":"10.1016\/S0040-4020(01)90359-X","volume":"48","author":"DHR Barton","year":"1992","unstructured":"Barton DHR, Dorchak J, Jaszberenyi J (1992) The invention of radical reactions. Part XXIV. Relative rates of acylation and radical deoxygenation of secondary alcohols. Tetrahedron 48:7435\u20137446","journal-title":"Tetrahedron"},{"key":"653_CR113","doi-asserted-by":"publisher","first-page":"1774","DOI":"10.1021\/jo702334z","volume":"73","author":"M Sanchez-Rosello","year":"2008","unstructured":"Sanchez-Rosello M, Puchlopek ALA, Morgan AJ, Miller SJ (2008) Site-selective catalysis of phenyl thionoformate transfer as a tool for regioselective deoxygenation of polyols. J Org Chem 73:1774\u20131782","journal-title":"J Org Chem"},{"key":"653_CR114","doi-asserted-by":"publisher","first-page":"20620","DOI":"10.1073\/pnas.1001111107","volume":"107","author":"PA Jordan","year":"2010","unstructured":"Jordan PA, Kayser-Bricker KJ, Miller SJ (2010) Asymmetric phosphorylation through catalytic P(III) phosphoramidite transfer: enantioselective synthesis of D-myo-inositol-6-phosphate. Proc Natl Acad Sci U S A 107:20620\u201320624","journal-title":"Proc Natl Acad Sci U S A"},{"key":"653_CR115","unstructured":"Sculimbrene BR (2004). Catalytic asymmetric phosphorylation. Ph.D. thesis. Boston College, Boston"},{"key":"653_CR116","doi-asserted-by":"publisher","first-page":"278","DOI":"10.1021\/ar00009a005","volume":"24","author":"MH Carruthers","year":"1991","unstructured":"Carruthers MH (1991) Chemical synthesis of DNA and DNA analogs. Acc Chem Res 24:278\u2013284","journal-title":"Acc Chem Res"},{"key":"653_CR117","unstructured":"Vlasuk GP, Webb TR, Abelman MM, Pearson DA, Miller TA (21, 1999) US Patent 5492895"},{"key":"653_CR118","doi-asserted-by":"publisher","first-page":"11758","DOI":"10.1021\/ja970685b","volume":"119","author":"Y Hayakawa","year":"1997","unstructured":"Hayakawa Y, Katoka M (1997) Preparation of short oligonucleotides via the phosphoramidite method using a tetrazole promoter in a catalytic manner. J Am Chem Soc 119:11758\u201311762","journal-title":"J Am Chem Soc"},{"key":"653_CR119","doi-asserted-by":"publisher","first-page":"2907","DOI":"10.1002\/anie.201109033","volume":"51","author":"PA Jordan","year":"2012","unstructured":"Jordan PA, Miller SJ (2012) An approach to the site-selective deoxygenation of hydroxyl groups based on catalytic phosphoramidite transfer. Angew Chem Int Ed 51:2907\u20132911","journal-title":"Angew Chem Int Ed"},{"key":"653_CR120","doi-asserted-by":"publisher","first-page":"13190","DOI":"10.1021\/ja0462777","volume":"126","author":"L Zhang","year":"2004","unstructured":"Zhang L, Koreeda M (2004) Radical deoxygenation of hydroxyl groups via phosphites. J Am Chem Soc 126:13190\u201313191","journal-title":"J Am Chem Soc"},{"key":"653_CR121","doi-asserted-by":"publisher","first-page":"630","DOI":"10.1038\/nchem.410","volume":"1","author":"KW Fiori","year":"2009","unstructured":"Fiori KW, Puchlopek ALA, Miller SJ (2009) Enantioselective sulfonylation reactions mediated by a tetrapeptide catalyst. Nat Chem 1:630\u2013634","journal-title":"Nat Chem"},{"key":"653_CR122","doi-asserted-by":"publisher","first-page":"631","DOI":"10.1038\/ja.2014.111","volume":"67","author":"MS Butler","year":"2014","unstructured":"Butler MS, Hansford KA, Blaskovich MAT, Halai R, Cooper MA (2014) Glycopeptide antibiotics: back to the future. J Antibiot 67:631\u2013644","journal-title":"J Antibiot"},{"key":"653_CR123","doi-asserted-by":"publisher","first-page":"730","DOI":"10.1002\/anie.200390202","volume":"42","author":"BK Hubbard","year":"2003","unstructured":"Hubbard BK, Walsh CT (2003) Vancomycin assembly: nature\u2019s way. Angew Chem Int Ed 42:730\u2013765","journal-title":"Angew Chem Int Ed"},{"key":"653_CR124","first-page":"2097","volume":"38","author":"KC Nicolaou","year":"1999","unstructured":"Nicolaou KC, Boddy CNC, Brase S, Winissinger N (1999) Chemistry, biology, and medicine of the glycopeptide antibiotics. Angew Chem Int Ed 38:2097\u20132152","journal-title":"Angew Chem Int Ed"},{"key":"653_CR125","doi-asserted-by":"publisher","first-page":"469","DOI":"10.1039\/np9961300469","volume":"13","author":"DH Williams","year":"1996","unstructured":"Williams DH (1996) The glycopeptide story \u2013 how to kill the deadly \u2018superbugs.\u2019. Nat Prod Rep 13:469\u2013477","journal-title":"Nat Prod Rep"},{"key":"653_CR126","doi-asserted-by":"publisher","first-page":"507","DOI":"10.1126\/science.284.5422.1985","volume":"284","author":"G Min","year":"1999","unstructured":"Min G, Chen Z, Onishi HR, Kohler J, Silver LL, Kerns R, Fukuzawa S, Thompson C, Kahne D (1999) Vancomycin derivatives that inhibit peptidoglycan biosynthesis without binding D-Ala-D-Ala. Science 284:507\u2013511","journal-title":"Science"},{"key":"653_CR127","doi-asserted-by":"publisher","first-page":"12608","DOI":"10.1021\/ja0027665","volume":"122","author":"R Kerns","year":"2000","unstructured":"Kerns R, Dong SD, Fukuzawa S, Carbeck J, Kohler J, Silver LL, Kahne D (2000) The role of hydrophobic substituents in the biological activity of glycopeptide antibiotics. J Am Chem Soc 122:12608\u201312609","journal-title":"J Am Chem Soc"},{"key":"653_CR128","doi-asserted-by":"publisher","first-page":"12722","DOI":"10.1021\/ja0166693","volume":"123","author":"B Sun","year":"2001","unstructured":"Sun B, Chen Z, Eggert US, Shaw SJ, LaTour JV, Kahne D (2001) Hybrid glycopeptide antibiotics. J Am Chem Soc 123:12722\u201312723","journal-title":"J Am Chem Soc"},{"key":"653_CR129","doi-asserted-by":"publisher","first-page":"13998","DOI":"10.1021\/ja045147v","volume":"126","author":"H Lin","year":"2004","unstructured":"Lin H, Walsh CT (2004) A chemoenzymatic approach to glycopeptide antibiotics. J Am Chem Soc 126:13998\u201314003","journal-title":"J Am Chem Soc"},{"key":"653_CR130","doi-asserted-by":"publisher","first-page":"3250","DOI":"10.1021\/ja043849e","volume":"127","author":"C Leimkuhler","year":"2005","unstructured":"Leimkuhler C, Chen L, Barrett D, Panzone G, Sun B, Falcone B, Oberthuer M, Walker S, Kahne D (2005) Differential inhibition of Staphylococcus aureus PBP2 by glycopeptide antibiotics. J Am Chem Soc 127:3250\u20133251","journal-title":"J Am Chem Soc"},{"key":"653_CR131","doi-asserted-by":"publisher","first-page":"957","DOI":"10.1039\/C1CS15125H","volume":"41","author":"PA Ashford","year":"2012","unstructured":"Ashford PA, Bew SP (2012) Recent advances in the synthesis of new glycopeptide antibiotics. Chem Soc Rev 41:957\u2013978","journal-title":"Chem Soc Rev"},{"key":"653_CR132","doi-asserted-by":"publisher","first-page":"1127","DOI":"10.1128\/AAC.49.3.1127-1134.2005","volume":"49","author":"DL Higgins","year":"2005","unstructured":"Higgins DL, Chang R, Debabov DV, Leung J, Wu T, Krause KM, Sandvik E, Hubbard JM, Kaniga K, Schmidt DE et al (2005) Telavancin, a multifunctional lipoglycopeptide, disrupts both cell wall synthesis and cell membrane integrity in methicillin-resistant Staphylococcus aureus. Antimicrob Agents Chemother 49:1127\u20131134","journal-title":"Antimicrob Agents Chemother"},{"key":"653_CR133","doi-asserted-by":"publisher","first-page":"859","DOI":"10.2165\/11534440-000000000-00000","volume":"70","author":"GC Zhanel","year":"2010","unstructured":"Zhanel GC, Calic D, Schweizer F, Zelenitsky S, Adam H, Lagace-Wiens PRS, Rubinstein E, Gin AS, Hoban DJ, Karlowsky JA (2010) New lipoglycopeptides: a comparative review of dalbavancin, oritavancin, and telavancin. Drugs 70:859\u2013886","journal-title":"Drugs"},{"key":"653_CR134","doi-asserted-by":"publisher","first-page":"943","DOI":"10.1007\/BF01967563","volume":"8","author":"PE Reynolds","year":"1989","unstructured":"Reynolds PE (1989) Structure, biochemistry, and mechanism of action of glycopeptide antibiotics. Eur J Clin Microbiol Infect Dis 8:943\u2013950","journal-title":"Eur J Clin Microbiol Infect Dis"},{"key":"653_CR135","doi-asserted-by":"publisher","first-page":"4581","DOI":"10.1021\/ja00090a006","volume":"116","author":"JP Mackay","year":"1994","unstructured":"Mackay JP, Gerhard U, Beauregard DA, Williams DH, Westwell MS, Searle MS (1994) Glycopeptide antibiotic activity and the possible role of dimerization: a model for biological signaling. J Am Chem Soc 116:4581\u20134590","journal-title":"J Am Chem Soc"},{"key":"653_CR136","doi-asserted-by":"publisher","first-page":"9064","DOI":"10.1021\/ja026342h","volume":"124","author":"SD Dong","year":"2002","unstructured":"Dong SD, Oberthuer M, Losey HC, Anderson JW, Eggert US, Peczuh MW, Walsh CT, Kahne D (2002) The structural basis for induction of VanB resistance. J Am Chem Soc 124:9064\u20139065","journal-title":"J Am Chem Soc"},{"key":"653_CR137","doi-asserted-by":"publisher","first-page":"9314","DOI":"10.1021\/ja035901x","volume":"125","author":"CC McComas","year":"2003","unstructured":"McComas CC, Crowley BM, Boger DL (2003) Partitioning the loss in vancomycin binding affinity or D-Ala-D-Lac into lost H-bond and repulsive lone pair contributions. J Am Chem Soc 125:9314\u20139315","journal-title":"J Am Chem Soc"},{"key":"653_CR138","doi-asserted-by":"publisher","first-page":"2885","DOI":"10.1021\/ja0572912","volume":"128","author":"BM Crowley","year":"2006","unstructured":"Crowley BM, Boger DL (2006) Total synthesis and evaluation of [\u03a8[CH2NH]Tpg4]vancomycin aglycon: reengineering vancomycin for dual D-Ala-D-Ala and D-Ala-D-Lac binding. J Am Chem Soc 128:2885\u20132892","journal-title":"J Am Chem Soc"},{"key":"653_CR139","doi-asserted-by":"publisher","first-page":"13946","DOI":"10.1021\/ja207142h","volume":"133","author":"J Xie","year":"2011","unstructured":"Xie J, Pierce JG, James RC, Okano A, Boger DL (2011) A redesigned vancomycin engineered for dual D-Ala-D-Ala and D-Ala-D-Lac binding exhibits potent antimicrobial activity against vancomycin-resistant bacteria. J Am Chem Soc 133:13946\u201313949","journal-title":"J Am Chem Soc"},{"key":"653_CR140","doi-asserted-by":"publisher","first-page":"1284","DOI":"10.1021\/ja209937s","volume":"134","author":"J Xie","year":"2012","unstructured":"Xie J, Okano A, Pierce JG, James RC, Stamm S, Crane CM, Boger DL (2012) Total synthesis of [\u03a8[C(\u2550S)NH]Tpg4]vancomycin aglycon, [\u03a8[C(\u2550NH)NH]Tpg4]vancomycin aglycon, and related key compounds: reengineering vancomycin for dual D-Ala-D-Ala and D-Ala-D-Lac binding. J Am Chem Soc 134:1284\u20131297","journal-title":"J Am Chem Soc"},{"key":"653_CR141","doi-asserted-by":"publisher","first-page":"10408","DOI":"10.1021\/bi00107a007","volume":"30","author":"TDH Bugg","year":"1991","unstructured":"Bugg TDH, Wright GD, Dutka-Malen S, Arthur M, Courvalin P, Walsh CT (1991) Molecular basis for vancomycin resistance in Enterococus faecium BM4147: biosynthesis of a depsipeptide peptidoglycan precursor by vancomycin resistance proteins VanH and VanA. Biochemistry 30:10408\u201310415","journal-title":"Biochemistry"},{"key":"653_CR142","doi-asserted-by":"publisher","first-page":"21","DOI":"10.1016\/S1074-5521(96)90079-4","volume":"3","author":"CT Walsh","year":"1996","unstructured":"Walsh CT, Fisher SL, Park IS, Prahalad M, Wu Z (1996) Bacterial resistance to vancomycin: five genes and one missing hydrogen bond tell the story. Chem Biol 3:21\u201328","journal-title":"Chem Biol"},{"key":"653_CR143","doi-asserted-by":"publisher","first-page":"308","DOI":"10.1126\/science.8392747","volume":"261","author":"CT Walsh","year":"1993","unstructured":"Walsh CT (1993) Vancomycin resistance: decoding the molecular logic. Science 261:308\u2013309","journal-title":"Science"},{"key":"653_CR144","doi-asserted-by":"publisher","first-page":"2234","DOI":"10.1073\/pnas.1117280109","volume":"109","author":"KC Gray","year":"2012","unstructured":"Gray KC, Palacios DS, Dailey I, Endo MM, Uno BE, Wilcock BC, Burke MD (2012) Amphotericin primarily kills yeast by simply binding ergosterol. Proc Natl Acad Sci U S A 109:2234\u20132239","journal-title":"Proc Natl Acad Sci U S A"},{"key":"653_CR145","doi-asserted-by":"publisher","first-page":"924","DOI":"10.1021\/ml200202y","volume":"2","author":"S Hanessian","year":"2011","unstructured":"Hanessian S, Giguere A, Grzyb J, Maianti JP, Saavedra OM, Aggen JB, Linsell MS, Goldblum AA, Hildebrandt DJ, Kane TR, Dozzo P, Gliedt MJ, Matias RD, Feeney LA, Armstrong ES (2011) Toward overcoming Staphylococcus aureus aminoglycoside resistance mechanism with a functionally designed neomycin analogue. ACS Med Chem Lett 2:924\u2013928","journal-title":"ACS Med Chem Lett"},{"key":"653_CR146","doi-asserted-by":"publisher","first-page":"7117","DOI":"10.1002\/chem.200900231","volume":"15","author":"AM Szpilman","year":"2009","unstructured":"Szpilman AM, Cereghetti DM, Manthorpe JM, Wurtz NR, Carreira EM (2009) Synthesis and biophysical studies on 35-deoxy amphotericin B methyl ester. Chem Eur J 15:7117\u20137128","journal-title":"Chem Eur J"},{"key":"653_CR147","doi-asserted-by":"publisher","first-page":"677","DOI":"10.7164\/antibiotics.27.677","volume":"27","author":"KL Fujisawa","year":"1974","unstructured":"Fujisawa KL, Hoshiya T, Kawaguchi H (1974) Aminoglycoside antiobiotics. VII. Acute toxicity of aminoglycoside antibiotics. J Antibiot 27:677\u2013681","journal-title":"J Antibiot"},{"key":"653_CR148","doi-asserted-by":"publisher","first-page":"8150","DOI":"10.1021\/ja068602r","volume":"129","author":"BR Griffith","year":"2007","unstructured":"Griffith BR, Krepel C, Fu X, Blanchard S, Ahmed A, Edmiston CE, Thorson JS (2007) Model for antibiotic optimization via neoglycosylation: synthesis of liponeoglycopeptides active against VRE. J Am Chem Soc 129:8150\u20138155","journal-title":"J Am Chem Soc"},{"key":"653_CR149","doi-asserted-by":"publisher","first-page":"1237","DOI":"10.1021\/ja983504u","volume":"121","author":"C Thompson","year":"1999","unstructured":"Thompson C, Ge M, Kahne D (1999) Synthesis of vancomycin from the aglycon. J Am Chem Soc 121:1237\u20131244","journal-title":"J Am Chem Soc"},{"key":"653_CR150","doi-asserted-by":"publisher","first-page":"9755","DOI":"10.1021\/ja302692j","volume":"134","author":"BS Fowler","year":"2012","unstructured":"Fowler BS, Lammerhold KM, Miller SJ (2012) Catalytic site-selective thiocarbonylations and deoxygenations of vancomycin reveal hydroxy-dependent conformational effects. J Am Chem Soc 134:9755\u20139761","journal-title":"J Am Chem Soc"},{"key":"653_CR151","doi-asserted-by":"publisher","first-page":"2367","DOI":"10.1021\/jm501872s","volume":"58","author":"S Yoganathan","year":"2015","unstructured":"Yoganathan S, Miller SJ (2015) Structure diversificiation of vancomycin through peptide-catalyzed, site-selective lipidation: a catalysis-based approach to combat glycopeptide-resistant pathogens. J Med Chem 58:2367\u20132377","journal-title":"J Med Chem"},{"key":"653_CR152","doi-asserted-by":"publisher","first-page":"2870","DOI":"10.1021\/ja9107897","volume":"132","author":"BS Fowler","year":"2010","unstructured":"Fowler BS, Mikochik PJ, Miller SJ (2010) Peptide-catalyzed kinetic resolution of formamides and thioformamides as an entry to nonracemic amines. J Am Chem Soc 132:2870\u20132871","journal-title":"J Am Chem Soc"},{"key":"653_CR153","doi-asserted-by":"publisher","first-page":"12414","DOI":"10.1021\/ja406067v","volume":"135","author":"S Han","year":"2013","unstructured":"Han S, Miller SJ (2013) Asymmetric catalysis at a distance: catalytic, site-selective phosphorylation of teicoplanin. J Am Chem Soc 135:12414\u201312421","journal-title":"J Am Chem Soc"},{"key":"653_CR154","doi-asserted-by":"publisher","first-page":"8550","DOI":"10.1021\/jo501625f","volume":"79","author":"S Han","year":"2014","unstructured":"Han S, Le BV, Hajare HS, Baxter RHG, Miller SJ (2014) X-Ray crystal structure of teicoplanin-A2-2 bound to a catalytic peptide sequence via the carrier protein strategy. J Org Chem 79:8550\u20138556","journal-title":"J Org Chem"},{"key":"653_CR155","doi-asserted-by":"publisher","first-page":"1224","DOI":"10.1039\/c0mb00320d","volume":"7","author":"HC Chan","year":"2011","unstructured":"Chan HC, Huang YT, Lyu SY, Huang CJ, Li YS, Liu YC, Chou CC, Tsai MD, Li TL (2011) Regioselective deacetylation based on teicoplanin-complexed Orf2* crystal structures. Mol Biosyst 7:1224\u20131231","journal-title":"Mol Biosyst"},{"key":"653_CR156","doi-asserted-by":"publisher","first-page":"845","DOI":"10.1042\/bj1240845","volume":"124","author":"M Nieto","year":"1971","unstructured":"Nieto M, Perkins HR (1971) The specificity of combination between ristocetins and peptides related to bacterial cell-wall mucopeptide precursors. Biochem J 124:845\u2013852","journal-title":"Biochem J"},{"key":"653_CR157","first-page":"520","volume":"D69","author":"NJ Economou","year":"2013","unstructured":"Economou NJ, Zentner IJ, Lazo E, Jakonicic J, Stojanoff V, Weeks SD, Gratsky KC, Cocklin S, Loll PJ (2013) Structure of the complex between teicoplanin and a bacterial cell-wall peptide: use of a carrier-protein approach. Acta Crystallogr D69:520\u2013533","journal-title":"Acta Crystallogr"},{"key":"653_CR158","doi-asserted-by":"publisher","first-page":"4637","DOI":"10.1021\/ja208755j","volume":"134","author":"NJ Economou","year":"2012","unstructured":"Economou NJ, Nahoum V, Weeks SD, Gratsky KC, Zentner IJ, Townsend TM, Bhuiya MW, Cocklin S, Loll PJ (2012) A carrier protein strategy yields the structure of dalbavancin. J Am Chem Soc 134:4637\u20134645","journal-title":"J Am Chem Soc"},{"key":"653_CR159","doi-asserted-by":"publisher","first-page":"6705","DOI":"10.1073\/pnas.95.12.6705","volume":"95","author":"TW Muir","year":"1998","unstructured":"Muir TW, Sondhi D, Cole PA (1998) Expressed protein ligation: a general method for protein engineering. Proc Natl Acad Sci U S A 95:6705\u20136710","journal-title":"Proc Natl Acad Sci U S A"},{"key":"653_CR160","doi-asserted-by":"publisher","first-page":"249","DOI":"10.1146\/annurev.biochem.72.121801.161900","volume":"72","author":"TW Muir","year":"2013","unstructured":"Muir TW (2013) Semisynthesis of proteins by expressed protein ligation. Annu Rev Biochem 72:249\u2013289","journal-title":"Annu Rev Biochem"},{"key":"653_CR161","doi-asserted-by":"publisher","first-page":"1251","DOI":"10.1126\/science.1188403","volume":"328","author":"J Gustafson","year":"2010","unstructured":"Gustafson J, Lim D, Miller SJ (2010) Dynamic kinetic resolution of biaryl atropisomers via peptide-catalyzed asymmetric bromination. Science 328:1251\u20131255","journal-title":"Science"},{"key":"653_CR162","doi-asserted-by":"publisher","first-page":"694","DOI":"10.1126\/science.1214948","volume":"335","author":"E Garand","year":"2012","unstructured":"Garand E, Kamrath MZ, Jordan PA, Wolk AB, McCoy AB, Miller SJ (2012) Determination of non-covalent docking by IR spectroscopy of cold gas-phase complexes. Science 335:694\u2013698","journal-title":"Science"},{"key":"653_CR163","doi-asserted-by":"publisher","first-page":"2963","DOI":"10.1021\/ja400082x","volume":"135","author":"KT Barrett","year":"2013","unstructured":"Barrett KT, Miller SJ (2013) Enantioselective synthesis of atropisomeric benzamides through peptide-catalyzed bromination. J Am Chem Soc 135:2963\u20132966","journal-title":"J Am Chem Soc"},{"key":"653_CR164","doi-asserted-by":"publisher","first-page":"71","DOI":"10.1038\/nature13189","volume":"509","author":"KT Barrett","year":"2014","unstructured":"Barrett KT, Metrano AJ, Rablen PR, Miller SJ (2014) Spontaneous transfer of chirality in an atropisomerically enriched two-axis system. Nature 509:71\u201375","journal-title":"Nature"},{"key":"653_CR165","doi-asserted-by":"publisher","first-page":"20655","DOI":"10.1073\/pnas.1005296107","volume":"107","author":"SE Denmark","year":"2010","unstructured":"Denmark SE, Burk MT (2010) Lewis base catalysis of bromo- and iodolactonization and cycloetherification. Proc Natl Acad Sci U S A 107:20655\u201320660","journal-title":"Proc Natl Acad Sci U S A"},{"key":"653_CR166","doi-asserted-by":"publisher","first-page":"6120","DOI":"10.1021\/ja301566t","volume":"134","author":"TP Pathak","year":"2012","unstructured":"Pathak TP, Miller SJ (2012) Site-selective bromination of vancomycin. J Am Chem Soc 134:6120\u20136123","journal-title":"J Am Chem Soc"},{"key":"653_CR167","doi-asserted-by":"publisher","first-page":"8415","DOI":"10.1021\/ja4038998","volume":"135","author":"TP Pathak","year":"2013","unstructured":"Pathak TP, Miller SJ (2013) Chemical tailoring of teicoplanin with site-selective reactions. J Am Chem Soc 135:8415\u20138422","journal-title":"J Am Chem Soc"},{"key":"653_CR168","doi-asserted-by":"publisher","first-page":"8210","DOI":"10.1039\/c0cc03691a","volume":"47","author":"X Fu","year":"2011","unstructured":"Fu X, Tan CH (2011) Mechanistic considerations of guanidine-catalyzed reactions. Chem Commun 47:8210\u20138222","journal-title":"Chem Commun"},{"key":"653_CR169","doi-asserted-by":"publisher","first-page":"6173","DOI":"10.1002\/anie.200502017","volume":"44","author":"KW Anderson","year":"2005","unstructured":"Anderson KW, Buchwald SL (2005) General catalysts for the Suzuki-Miyaura and Songoashira coupling reactions of aryl chlorides and for the coupling of challenging substrate combinations in water. Angew Chem Int Ed 44:6173\u20136177","journal-title":"Angew Chem Int Ed"},{"key":"653_CR170","doi-asserted-by":"publisher","first-page":"1252","DOI":"10.1021\/ja00838a054","volume":"97","author":"EE Van Temelen","year":"1975","unstructured":"Van Temelen EE, Heys JR (1975) Enzymic epoxidation of squalene variants. J Am Chem Soc 97:1252\u20131253","journal-title":"J Am Chem Soc"},{"key":"653_CR171","doi-asserted-by":"publisher","first-page":"13679","DOI":"10.1073\/pnas.0903187106","volume":"106","author":"G Maayan","year":"2009","unstructured":"Maayan G, Ward MD, Kirshenbaum K (2009) Folded biomimetic oligomers for enantioselective catalysis. Proc Natl Acad Sci U S A 106:13679\u201313684","journal-title":"Proc Natl Acad Sci U S A"},{"key":"653_CR172","doi-asserted-by":"publisher","first-page":"90","DOI":"10.1002\/bip.20413","volume":"84","author":"A Berkessel","year":"2006","unstructured":"Berkessel A, Koch B, Toniolo C, Rainaldi M, Broxterman QB, Kaptein B (2006) Asymmetric enone epoxidation by short solid-phase bound peptides: further evidence for catalyst helicity and catalytic activity of individual peptide strands. Biopolymers 84:90\u201396","journal-title":"Biopolymers"},{"key":"653_CR173","doi-asserted-by":"publisher","first-page":"84","DOI":"10.1002\/1521-3765(20020104)8:1<84::AID-CHEM84>3.0.CO;2-N","volume":"8","author":"F Formagio","year":"2002","unstructured":"Formagio F, Boncio M, Crisma M, Peggion C, Mezzato S, Polese A, Barazza A, Antonello S, Maran F, Broxterman QB, Kaptein B, Kamphuis J, Vitale RM, Saviano M, Benedetti E, Toniolo C (2002) Nitroxyl peptides as catalysts of enantioselective oxidations. Chem Eur J 8:84\u201393","journal-title":"Chem Eur J"},{"key":"653_CR174","doi-asserted-by":"publisher","first-page":"8710","DOI":"10.1021\/ja073055a","volume":"129","author":"G Peris","year":"2007","unstructured":"Peris G, Jakobsche CE, Miller SJ (2007) Aspartate-catalyzed asymmetric epoxidation reactions. J Am Chem Soc 129:8710\u20138711","journal-title":"J Am Chem Soc"},{"key":"653_CR175","doi-asserted-by":"publisher","first-page":"6809","DOI":"10.1002\/ange.200802223","volume":"120","author":"CE Jakobsche","year":"2008","unstructured":"Jakobsche CE, Peris G, Miller SJ (2008) Functional analysis of an aspartate-based epoxidation catalyst with amide-to-alkene peptidomimetic catalyst analogues. Angew Chem Int Ed 120:6809\u20136813","journal-title":"Angew Chem Int Ed"},{"key":"653_CR176","doi-asserted-by":"publisher","first-page":"9104","DOI":"10.1021\/ja202706g","volume":"133","author":"F Kolundzic","year":"2011","unstructured":"Kolundzic F, Noshi MN, Tjandra M, Movassaghi M, Miller SJ (2011) Chemoselective and enantioselective oxidation of indoles employing aspartyl peptide catalysts. J Am Chem Soc 133:9104\u20139111","journal-title":"J Am Chem Soc"},{"key":"653_CR177","doi-asserted-by":"publisher","first-page":"293","DOI":"10.1038\/nature13273","volume":"509","author":"EV Mercado-Marin","year":"2014","unstructured":"Mercado-Marin EV, Garcia-Reynaga P, Romminger S, Pimenta EF, Romney DK, Lodewyk MW, Williams DE, Andersen RJ, Miller SJ, Tantillo DJ, Berlinck RGS, Sarpong R (2014) Total synthesis and isolation of citrinalin and cyclopiamine congeners. Nature 509:293\u2013294","journal-title":"Nature"},{"key":"653_CR178","doi-asserted-by":"publisher","first-page":"8089","DOI":"10.1021\/ja801899v","volume":"130","author":"V Gnanadesikan","year":"2008","unstructured":"Gnanadesikan V, Corey EJ (2008) A strategy for position-selective epoxidation of polyprenols. J Am Chem Soc 130:8089\u20138093","journal-title":"J Am Chem Soc"},{"key":"653_CR179","doi-asserted-by":"publisher","first-page":"6939","DOI":"10.1021\/jo00077a001","volume":"58","author":"S Chang","year":"1993","unstructured":"Chang S, Lee NH, Jacobsen EN (1993) Regio- and enantioselective catalytic epoxidation of conjugated polyenes. Formal synthesis of LTA4 methyl ester. J Org Chem 58:6939\u20136941","journal-title":"J Org Chem"},{"key":"653_CR180","doi-asserted-by":"publisher","first-page":"4475","DOI":"10.1002\/anie.200600840","volume":"45","author":"CP Burke","year":"2006","unstructured":"Burke CP, Shi Y (2006) Regio- and enantioselective epoxidation of dienes by a chiral dioxirane: synthesis of optically active vinyl cis-epoxides. Angew Chem Int Ed 45:4475\u20134478","journal-title":"Angew Chem Int Ed"},{"key":"653_CR181","doi-asserted-by":"publisher","first-page":"5849","DOI":"10.1002\/anie.200601742","volume":"45","author":"AU Barlan","year":"2006","unstructured":"Barlan AU, Baak A, Yamamoto H (2006) Enantioselective oxidation of olefins catalyzed by a chiral bishydroxamic acid complex of molybdenum. Angew Chem Int Ed 45:5849\u20135852","journal-title":"Angew Chem Int Ed"},{"key":"653_CR182","doi-asserted-by":"publisher","first-page":"990","DOI":"10.1038\/nchem.1469","volume":"4","author":"PA Lichtor","year":"2012","unstructured":"Lichtor PA, Miller SJ (2012) Combinatorial evolution of site- and enantioselective catalysts for polyene epoxidation. Nat Chem 4:990\u2013995","journal-title":"Nat Chem"},{"key":"653_CR183","doi-asserted-by":"publisher","first-page":"5301","DOI":"10.1021\/ja410567a","volume":"136","author":"PA Lichtor","year":"2014","unstructured":"Lichtor PA, Miller SJ (2014) Experimental lineage and functional analysis of a remotely directed peptide epoxidation catalyst. J Am Chem Soc 136:5301\u20135308","journal-title":"J Am Chem Soc"},{"key":"653_CR184","doi-asserted-by":"publisher","first-page":"4504","DOI":"10.1039\/C4SC01440E","volume":"5","author":"NC Abascal","year":"2014","unstructured":"Abascal NC, Lichtor PA, Giuliano MW, Miller SJ (2014) Function-oriented investigations of a peptide-based catalyst that mediates enantioselective allylic alcohol epoxidation. Chem Sci 5:4504\u20134511","journal-title":"Chem Sci"},{"key":"653_CR185","doi-asserted-by":"publisher","first-page":"321","DOI":"10.1021\/co200010v","volume":"13","author":"PA Lichtor","year":"2011","unstructured":"Lichtor PA, Miller SJ (2011) One-bead-one-catalyst approach to aspartic acid-based oxidation catalyst discovery. ACS Comb Sci 13:321\u2013326","journal-title":"ACS Comb Sci"},{"key":"653_CR186","doi-asserted-by":"publisher","first-page":"201","DOI":"10.1016\/j.cbpa.2010.11.020","volume":"15","author":"EM Brustad","year":"2011","unstructured":"Brustad EM, Arnold FH (2011) Optimizing non-natural protein function with directed evolution. Curr Opin Chem Biol 15:201\u2013210","journal-title":"Curr Opin Chem Biol"},{"key":"653_CR187","doi-asserted-by":"publisher","first-page":"11491","DOI":"10.1002\/anie.201206904","volume":"51","author":"K Foo","year":"2012","unstructured":"Foo K, Usui I, Gotz DCG, Werner EW, Holte D, Baran PS (2012) Scalable, enantioselective synthesis of germacrenes and related sesquiterpenes inspired by terpene cyclase phase logic. Angew Chem Int Ed 51:11491\u201311495","journal-title":"Angew Chem Int Ed"},{"key":"653_CR188","doi-asserted-by":"publisher","first-page":"1691","DOI":"10.1126\/science.1083622","volume":"299","author":"TP Yoon","year":"2003","unstructured":"Yoon TP, Jacobsen EN (2003) Privileged chiral catalysts. Science 299:1691\u20131693","journal-title":"Science"},{"key":"653_CR189","doi-asserted-by":"publisher","first-page":"6729","DOI":"10.1021\/ja00360a040","volume":"105","author":"R Breslow","year":"1983","unstructured":"Breslow R, Gellman SH (1983) Intramolecular nitrene C-H insertions mediated by transition-metal complexes as nitrogen analogues of cytochrome P-450 reactions. J Am Chem Soc 105:6729\u20136730","journal-title":"J Am Chem Soc"},{"key":"653_CR190","doi-asserted-by":"crossref","unstructured":"Breslow R, Gellman SH (1982) Tosylamidation of cyclohexane by a cytochrome P-450 model. J Chem Soc Chem Commun 1400\u20131401","DOI":"10.1039\/c39820001400"},{"key":"653_CR191","doi-asserted-by":"publisher","first-page":"170","DOI":"10.1021\/ar50150a002","volume":"13","author":"R Breslow","year":"1980","unstructured":"Breslow R (1980) Biomimetic control of chemical selectivity. Acc Chem Res 13:170\u2013177","journal-title":"Acc Chem Res"},{"key":"653_CR192","doi-asserted-by":"publisher","first-page":"7570","DOI":"10.1021\/ja00045a043","volume":"114","author":"D Xu","year":"1992","unstructured":"Xu D, Crispino GA, Sharpless KB (1992) Selective asymmetric dihydroxylation (AD) of dienes. J Am Chem Soc 114:7570\u20137571","journal-title":"J Am Chem Soc"},{"key":"653_CR193","doi-asserted-by":"publisher","first-page":"1345","DOI":"10.1016\/0040-4020(94)01021-Q","volume":"51","author":"H Becker","year":"1995","unstructured":"Becker H, Soler MA, Sharpless KB (1995) Selective asymmetric dhihydroxylation of polyenes. Tetrahedron 51:1345\u20131376","journal-title":"Tetrahedron"},{"key":"653_CR194","doi-asserted-by":"publisher","first-page":"2483","DOI":"10.1021\/cr00032a009","volume":"94","author":"HC Kolb","year":"1994","unstructured":"Kolb HC, VanNieuwenhze MS, Sharpless KB (1994) Catalytic asymmetric dihydroxylation. Chem Rev 94:2483\u20132547","journal-title":"Chem Rev"},{"key":"653_CR195","doi-asserted-by":"crossref","unstructured":"Jacobsen EN, Pfaltz A, Yamamoto H (eds) (1999) Comprehensive asymmetric catalysis, vol I\u2013III and Supplement 1. Springer, New York","DOI":"10.1007\/978-3-642-58571-5"},{"key":"653_CR196","doi-asserted-by":"publisher","first-page":"783","DOI":"10.1126\/science.1148597","volume":"318","author":"MS Chen","year":"2007","unstructured":"Chen MS, White MC (2007) A predictably selective aliphatic C-H oxidation reaction for complex molecule synthesis. Science 318:783\u2013787","journal-title":"Science"},{"key":"653_CR197","doi-asserted-by":"publisher","first-page":"3362","DOI":"10.1002\/anie.201006368","volume":"50","author":"T Newhouse","year":"2011","unstructured":"Newhouse T, Baran PS (2011) If C-H bonds could talk: selective C-H bond oxidation. Angew Chem Int Ed 50:3362\u20133374","journal-title":"Angew Chem Int Ed"},{"key":"653_CR198","doi-asserted-by":"publisher","first-page":"4587","DOI":"10.1002\/anie.201411745","volume":"54","author":"F Vohidov","year":"2015","unstructured":"Vohidov F, Coughlin JM, Ball ZT (2015) Rhodium(II) metallopeptie catalyst design enables fine control in selective functionalization of natural SH3 domains. Angew Chem Int Ed 54:4587\u20134591","journal-title":"Angew Chem Int Ed"},{"key":"653_CR199","doi-asserted-by":"publisher","first-page":"560","DOI":"10.1021\/ar300261h","volume":"46","author":"ZT Ball","year":"2012","unstructured":"Ball ZT (2012) Designing enzyme-like catalysts: a rhodium(II) metallopeptide case study. Acc Chem Res 46:560\u2013570","journal-title":"Acc Chem Res"}],"container-title":["Topics in Current Chemistry","Site-Selective Catalysis"],"original-title":[],"language":"en","link":[{"URL":"https:\/\/link.springer.com\/content\/pdf\/10.1007\/128_2015_653","content-type":"unspecified","content-version":"vor","intended-application":"similarity-checking"}],"deposited":{"date-parts":[[2023,2,15]],"date-time":"2023-02-15T15:27:39Z","timestamp":1676474859000},"score":1,"resource":{"primary":{"URL":"https:\/\/link.springer.com\/10.1007\/128_2015_653"}},"subtitle":[],"short-title":[],"issued":{"date-parts":[[2015]]},"ISBN":["9783319263311","9783319263335"],"references-count":199,"URL":"https:\/\/doi.org\/10.1007\/128_2015_653","relation":{},"ISSN":["0340-1022","1436-5049"],"issn-type":[{"value":"0340-1022","type":"print"},{"value":"1436-5049","type":"electronic"}],"subject":[],"published":{"date-parts":[[2015]]},"assertion":[{"value":"26 August 2015","order":1,"name":"first_online","label":"First Online","group":{"name":"ChapterHistory","label":"Chapter History"}}]}}