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However, the use of EA\/IRMS to measure \u03b4\n                    <jats:sup>34<\/jats:sup>\n                    S in arsenides and sulfarsenides may not be straightforward. This difficulty can lead to potential health and environmental hazards in the workplace and analytical problems such as instrument contamination, memory effects, and a non-matrix-matched standardization of \u03b4\n                    <jats:sup>34<\/jats:sup>\n                    S measurements with suitable reference materials. To overcome these practical and analytical challenges, we developed a procedure for sulfur isotope analysis of arsenides, which can also be safely used for EA\/IRMS analysis of arsenic sulfides (i.e., realgar, orpiment, arsenopyrite, and arsenian pyrite), and mercury sulfides (cinnabar). The sulfur dioxide produced from off-line EA combustion was trapped in an aqueous barium chloride solution in a leak-free system and precipitated as barium sulfate after quantitative oxidation of hydrogen sulfite by hydrogen peroxide. The derived barium sulfate was analyzed by conventional EA\/IRMS, which bracketed the \u03b4\n                    <jats:sup>34<\/jats:sup>\n                    S values of the samples with three international sulfate reference materials. The protocol (BaSO\n                    <jats:sub>4<\/jats:sub>\n                    -EA\/IRMS) was validated by analyses of reference materials and laboratory standards of sulfate and sulfides and achieved accuracy and precision comparable with those of direct EA\/IRMS. The \u03b4\n                    <jats:sup>34<\/jats:sup>\n                    S values determined by BaSO\n                    <jats:sub>4<\/jats:sub>\n                    -EA\/IRMS in sulfides (arsenopyrite, arsenic, and mercury sulfides) samples from different origins were comparable to those obtained by EA\/IRMS, and no sulfur isotope fractionations were introduced during sample preparation. We report the first sulfur isotope data of arsenides obtained by BaSO\n                    <jats:sub>4<\/jats:sub>\n                    -EA\/IRMS.\n                  <\/jats:p>\n                  <jats:p>\n                    <jats:bold>Graphical abstract<\/jats:bold>\n                  <\/jats:p>","DOI":"10.1007\/s00216-021-03854-y","type":"journal-article","created":{"date-parts":[[2022,1,22]],"date-time":"2022-01-22T19:03:55Z","timestamp":1642878235000},"page":"2163-2179","update-policy":"https:\/\/doi.org\/10.1007\/springer_crossmark_policy","source":"Crossref","is-referenced-by-count":12,"title":["Safe, accurate, and precise sulfur isotope analyses of arsenides, sulfarsenides, and arsenic and mercury sulfides by conversion to barium sulfate before EA\/IRMS"],"prefix":"10.1007","volume":"414","author":[{"given":"Jorge E.","family":"Spangenberg","sequence":"first","affiliation":[],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Nicolas J.","family":"Saintilan","sequence":"additional","affiliation":[],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Sabina Strmi\u0107","family":"Palinka\u0161","sequence":"additional","affiliation":[],"role":[{"vocabulary":"crossref","role":"author"}]}],"member":"297","published-online":{"date-parts":[[2022,1,23]]},"reference":[{"key":"3854_CR1","doi-asserted-by":"publisher","first-page":"89","DOI":"10.1016\/S0009-2541(99)00082-0","volume":"161","author":"H Strauss","year":"1999","unstructured":"Strauss H. 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