{"status":"ok","message-type":"work","message-version":"1.0.0","message":{"indexed":{"date-parts":[[2026,1,15]],"date-time":"2026-01-15T05:47:32Z","timestamp":1768456052940,"version":"3.49.0"},"reference-count":36,"publisher":"Springer Science and Business Media LLC","issue":"9","license":[{"start":{"date-parts":[[2018,8,18]],"date-time":"2018-08-18T00:00:00Z","timestamp":1534550400000},"content-version":"tdm","delay-in-days":0,"URL":"http:\/\/www.springer.com\/tdm"}],"funder":[{"DOI":"10.13039\/501100001809","name":"National Natural Science Foundation of China","doi-asserted-by":"publisher","award":["21575080"],"award-info":[{"award-number":["21575080"]}],"id":[{"id":"10.13039\/501100001809","id-type":"DOI","asserted-by":"publisher"}]},{"DOI":"10.13039\/501100001809","name":"National Natural Science Foundation of China","doi-asserted-by":"publisher","award":["21275091"],"award-info":[{"award-number":["21275091"]}],"id":[{"id":"10.13039\/501100001809","id-type":"DOI","asserted-by":"publisher"}]},{"DOI":"10.13039\/501100001809","name":"National Natural Science Foundation of China","doi-asserted-by":"publisher","award":["41776110"],"award-info":[{"award-number":["41776110"]}],"id":[{"id":"10.13039\/501100001809","id-type":"DOI","asserted-by":"publisher"}]}],"content-domain":{"domain":["link.springer.com"],"crossmark-restriction":false},"short-container-title":["Microchim Acta"],"published-print":{"date-parts":[[2018,9]]},"DOI":"10.1007\/s00604-018-2952-x","type":"journal-article","created":{"date-parts":[[2018,8,18]],"date-time":"2018-08-18T03:03:36Z","timestamp":1534561416000},"update-policy":"https:\/\/doi.org\/10.1007\/springer_crossmark_policy","source":"Crossref","is-referenced-by-count":27,"title":["Functional ZnS:Mn(II) quantum dot modified with L-cysteine and 6-mercaptonicotinic acid as a fluorometric probe for copper(II)"],"prefix":"10.1007","volume":"185","author":[{"given":"Jiangru","family":"Wang","sequence":"first","affiliation":[],"role":[{"role":"author","vocabulary":"crossref"}]},{"given":"Jialuo","family":"Yu","sequence":"additional","affiliation":[],"role":[{"role":"author","vocabulary":"crossref"}]},{"given":"Xiaoyan","family":"Wang","sequence":"additional","affiliation":[],"role":[{"role":"author","vocabulary":"crossref"}]},{"given":"Liyan","family":"Wang","sequence":"additional","affiliation":[],"role":[{"role":"author","vocabulary":"crossref"}]},{"given":"Bowei","family":"Li","sequence":"additional","affiliation":[],"role":[{"role":"author","vocabulary":"crossref"}]},{"given":"Dazhong","family":"Shen","sequence":"additional","affiliation":[],"role":[{"role":"author","vocabulary":"crossref"}]},{"given":"Qi","family":"Kang","sequence":"additional","affiliation":[],"role":[{"role":"author","vocabulary":"crossref"}]},{"given":"Lingxin","family":"Chen","sequence":"additional","affiliation":[],"role":[{"role":"author","vocabulary":"crossref"}]}],"member":"297","published-online":{"date-parts":[[2018,8,18]]},"reference":[{"key":"2952_CR1","doi-asserted-by":"publisher","first-page":"389","DOI":"10.1016\/j.snb.2015.02.027","volume":"212","author":"LK Kumawat","year":"2015","unstructured":"Kumawat LK, Mergu N, Singh AK, Gupta VK (2015) A novel optical sensor for copper ions based on phthalocyanine tetrasulfonic acid. Sensors Actuators B Chem 212:389\u2013394","journal-title":"Sensors Actuators B Chem"},{"issue":"38","key":"2952_CR2","doi-asserted-by":"publisher","first-page":"16000","DOI":"10.1021\/ja307316s","volume":"134","author":"J Jo","year":"2012","unstructured":"Jo J, Lee HY, Liu W, Olasz A, Chen CH, Lee D (2012) Reactivity-based detection of copper(II) ion in water: oxidative cyclization of azoaromatics as fluorescence turn-on signaling mechanism. J Am Chem Soc 134(38):16000\u201316007","journal-title":"J Am Chem Soc"},{"key":"2952_CR3","doi-asserted-by":"publisher","first-page":"317","DOI":"10.1146\/annurev.neuro.30.051606.094232","volume":"30","author":"E Madsen","year":"2007","unstructured":"Madsen E, Gitlin JD (2007) Copper and iron disorders of the brain. Annu Rev Neurosci 30:317\u2013337","journal-title":"Annu Rev Neurosci"},{"key":"2952_CR4","doi-asserted-by":"publisher","first-page":"8566","DOI":"10.1021\/ac101659d","volume":"82","author":"Y Su","year":"2010","unstructured":"Su Y, Lan G, Chen W, Chang H (2010) Detection of copper ions through recovery of the fluorescence of DNA-templated copper\/silver nanoclusters in the presence of mercaptopropionic acid. Anal Chem 82:8566\u20138572","journal-title":"Anal Chem"},{"issue":"1","key":"2952_CR5","doi-asserted-by":"publisher","first-page":"121","DOI":"10.1016\/j.talanta.2005.02.019","volume":"67","author":"RJ Cassella","year":"2005","unstructured":"Cassella RJ, Magalh\u00e3es OIB, Couto MT, Lima ELS, Neves MAFS, Coutinho FMB (2005) Synthesis and application of a functionalized resin for flow injection\/FAAS copper determination in waters. Talanta 67(1):121\u2013128","journal-title":"Talanta"},{"key":"2952_CR6","doi-asserted-by":"publisher","first-page":"6074","DOI":"10.1021\/ac0700528","volume":"79","author":"JS Becker","year":"2007","unstructured":"Becker JS, Matusch A, Depboylu C, Dobrowolska J, Zoriy MV (2007) Quantitative imaging of selenium, copper, and zinc in thin sections of biological tissues (slugs-genus Arion) measured by laser ablationinductively coupled plasma mass spectrometry. Anal Chem 79:6074\u20136080","journal-title":"Anal Chem"},{"key":"2952_CR7","doi-asserted-by":"publisher","first-page":"925","DOI":"10.1016\/j.electacta.2016.06.009","volume":"210","author":"SR Smith","year":"2016","unstructured":"Smith SR, Zhou C, Baron JY, Choi Y, Lipkowski J (2016) Elucidating the interfacial interactions of copper and ammonia with the sulfur passive layer during thiosulfate mediated gold leaching. Electrochim Acta 210:925\u2013934","journal-title":"Electrochim Acta"},{"key":"2952_CR8","doi-asserted-by":"publisher","first-page":"5094","DOI":"10.1039\/C7AY01335C","volume":"9","author":"Q Gao","year":"2017","unstructured":"Gao Q, Ji L, Wang QN, Yin K, Li JH, Chen LX (2017) Colorimetric sensor for highly sensitive and selective detection of copper ion. Anal Methods 9:5094\u20135100","journal-title":"Anal Methods"},{"key":"2952_CR9","doi-asserted-by":"crossref","unstructured":"Yu C, Zhang J, Li J, Liu P, Wei P, Chen L (2011) Fluorescent probe for copper(II) ion based on a rhodamine spirolactame derivative, and its application to fluorescent imaging in living cells. Microchim Acta 174(3\u22124):247\u2212255","DOI":"10.1007\/s00604-011-0623-2"},{"issue":"4","key":"2952_CR10","doi-asserted-by":"publisher","first-page":"856","DOI":"10.1021\/ol9029066","volume":"12","author":"S Goswami","year":"2010","unstructured":"Goswami S, Sen D, Das NK (2010) A new highly selective, ratiometric and colorimetric fluorescence sensor for Cu2+ with a remarkable red shift in absorption and emission spectra based on internal charge transfer. Org Lett 12(4):856\u2013859","journal-title":"Org Lett"},{"issue":"23","key":"2952_CR11","doi-asserted-by":"publisher","first-page":"5277","DOI":"10.1039\/c0ob00553c","volume":"8","author":"C Yu","year":"2010","unstructured":"Yu C, Zhang J, Wang R, Chen L (2010) Highly sensitive and selective colorimetric and off-on fluorescent probe for Cu2+ based on rhodamine derivative. Org Biomol Chem 8(23):5277\u20135279","journal-title":"Org Biomol Chem"},{"issue":"44","key":"2952_CR12","doi-asserted-by":"publisher","first-page":"7756","DOI":"10.1016\/j.tetlet.2007.09.029","volume":"48","author":"S Kamila","year":"2007","unstructured":"Kamila S, Callan JF, Mulrooney RC, Middleton M (2007) A novel fluorescent chemosensor for cu(II) in aqueous solution based on a \u03b2-aminobisphosphonate receptor. Tetrahedron Lett 48(44):7756\u20137760","journal-title":"Tetrahedron Lett"},{"issue":"14","key":"2952_CR13","doi-asserted-by":"publisher","first-page":"6220","DOI":"10.1021\/ac3012126","volume":"84","author":"Y Dong","year":"2012","unstructured":"Dong Y, Wang R, Li G, Chen C, Chi Y, Chen G (2012) Polyamine-functionalized carbon quantum dots as fluorescent probes for selective and sensitive detection of copper ions. Anal Chem 84(14):6220\u20136224","journal-title":"Anal Chem"},{"key":"2952_CR14","doi-asserted-by":"publisher","first-page":"647","DOI":"10.1016\/j.snb.2014.02.053","volume":"196","author":"Y Liu","year":"2014","unstructured":"Liu Y, Zhao Y, Zhang Y (2014) One-step green synthesized fluorescent carbon nanodots from bamboo leaves for copper(II) ion detection. Sensors Actuators B Chem 196:647\u2013652","journal-title":"Sensors Actuators B Chem"},{"issue":"11","key":"2952_CR15","doi-asserted-by":"publisher","first-page":"2527","DOI":"10.1016\/j.saa.2003.12.039","volume":"60","author":"H Xie","year":"2004","unstructured":"Xie H, Liang J, Zhang Z, Liu Y, He Z, Pang D (2004) Luminescent CdSe-ZnS quantum dots as selective Cu2+ probe. Spectrochim Acta A 60(11):2527\u20132530","journal-title":"Spectrochim Acta A"},{"key":"2952_CR16","doi-asserted-by":"publisher","first-page":"516","DOI":"10.1016\/j.snb.2013.09.009","volume":"190","author":"F Wang","year":"2014","unstructured":"Wang F, Gu Z, Lei W, Wang W, Xia X, Hao Q (2014) Graphene quantum dots as a fluorescent sensing platform for highly efficient detection of copper(II) ions. Sensors Actuators B Chem 190:516\u2013522","journal-title":"Sensors Actuators B Chem"},{"issue":"13\u221214","key":"2952_CR17","doi-asserted-by":"publisher","first-page":"2139","DOI":"10.1007\/s00604-015-1548-y","volume":"182","author":"N Yu","year":"2015","unstructured":"Yu N, Peng H, Xiong H, Wu X, Wang X, Li Y, Chen L (2015) Graphene quantum dots combined with copper(II) ions as a fluorescent probe for turn-on detection of sulfide ions. Microchim Acta 182(13\u221214):2139\u20132146","journal-title":"Microchim Acta"},{"issue":"4","key":"2952_CR18","doi-asserted-by":"publisher","first-page":"1323","DOI":"10.1007\/s00604-015-1693-3","volume":"183","author":"MR Chao","year":"2016","unstructured":"Chao MR, Hu CW, Chen JL (2016) Fluorometric determination of copper(II) using CdTe quantum dots coated with 1(2-thiazolylazo)-2-naphthol and an ionic liquid. Microchim Acta 183(4):1323\u20131332","journal-title":"Microchim Acta"},{"key":"2952_CR19","doi-asserted-by":"publisher","first-page":"322","DOI":"10.1039\/C6AY02486F","volume":"9","author":"JJ Qin","year":"2017","unstructured":"Qin JJ, Dong BH, Gao RJ, Su G, Han JW, Li X, Liu W, Wang W, Cao LX (2017) Water-soluble silica-coated ZnS:Mn nanoparticles as fluorescent sensors for the detection of ultratrace copper(II) ions in seawater. Anal Methods 9:322\u2013328","journal-title":"Anal Methods"},{"issue":"3\u20134","key":"2952_CR20","doi-asserted-by":"publisher","first-page":"753","DOI":"10.1007\/s00604-014-1382-7","volume":"182","author":"XD Zheng","year":"2015","unstructured":"Zheng XD, Pan JM, Gao L, Wei X, Dai JD, Shi WD, Yan YS (2015) Silica nanoparticles doped with a europium(III) complex and coated with an ion imprinted polymer for rapid determination of copper(II). Microchim Acta 182(3\u20134):753\u2013761","journal-title":"Microchim Acta"},{"issue":"3","key":"2952_CR21","doi-asserted-by":"publisher","first-page":"188","DOI":"10.1007\/s00604-018-2720-y","volume":"185","author":"XG Chen","year":"2018","unstructured":"Chen XG, Lu QJ, Liu D, Wu CY, Liu ML, Li HT, Zhang YY, Yao SZ (2018) Highly sensitive and selective determination of copper(II) based on a dual catalytic effect and by using silicon nanoparticles as a fluorescent probe. Microchim Acta 185(3):188 (7 pages)","journal-title":"Microchim Acta"},{"issue":"7","key":"2952_CR22","doi-asserted-by":"publisher","first-page":"2185","DOI":"10.1007\/s00604-016-1854-z","volume":"183","author":"LC Kong","year":"2016","unstructured":"Kong LC, Chu XF, Ling X, Ma GY, Yao YY, Meng YH, Liu WW (2016) Biocompatible glutathione-capped gold nanoclusters for dual fluorescent sensing and imaging of copper(II) and temperature in human cells and bacterial cells. Microchim Acta 183(7):2185\u20132195","journal-title":"Microchim Acta"},{"issue":"26","key":"2952_CR23","doi-asserted-by":"publisher","first-page":"3385","DOI":"10.1016\/j.tetlet.2010.04.099","volume":"51","author":"N Singh","year":"2010","unstructured":"Singh N, Kaur N, McCaughan B, Callan JF (2010) Ratiometric fluorescent detection of cu(II) in semi-aqueous solution using a two-fluorophore approach. Tetrahedron Lett 51(26):3385\u20133387","journal-title":"Tetrahedron Lett"},{"key":"2952_CR24","doi-asserted-by":"publisher","first-page":"146","DOI":"10.1016\/j.aca.2013.05.015","volume":"786","author":"B Cao","year":"2013","unstructured":"Cao B, Yuan C, Liu B, Jiang C, Guan G, Han M (2013) Ratiometric fluorescence detection of mercuric ion based on the nanohybrid of fluorescence carbon dots and quantum dots. Anal Chim Acta 786:146\u2013152","journal-title":"Anal Chim Acta"},{"key":"2952_CR25","doi-asserted-by":"publisher","first-page":"8427","DOI":"10.1039\/C6NR01912A","volume":"8","author":"P Wu","year":"2016","unstructured":"Wu P, Hou X, Xu J, Chen H (2016) Ratiometric fluorescence, electrochemilumine-scence, and photoelectrochemical chemo\/biosensing based on semiconductor quantum dots. Nanoscale 8:8427\u20138442","journal-title":"Nanoscale"},{"issue":"23","key":"2952_CR26","doi-asserted-by":"publisher","first-page":"11727","DOI":"10.1021\/ac503134r","volume":"86","author":"K Zhang","year":"2014","unstructured":"Zhang K, Yu T, Liu F, Sun M, Yu H, Liu B, Zhang Z, Jiang H, Wang S (2014) Selective fluorescence turn-on and ratiometric detection of organophosphate using dual-emitting Mn-doped ZnS nanocrystal probe. Anal Chem 86(23):11727\u201311733","journal-title":"Anal Chem"},{"issue":"2","key":"2952_CR27","doi-asserted-by":"publisher","first-page":"561","DOI":"10.1006\/jcis.2000.6894","volume":"227","author":"R Kho","year":"2000","unstructured":"Kho R, Torres-Mart\u00ednez CL, Mehra RK (2000) A simple colloidal synthesis for gram-quantity production of water-soluble ZnS nanocrystal powders. Colloid Interf Sci 227(2):561\u2013566","journal-title":"Colloid Interf Sci"},{"issue":"1","key":"2952_CR28","doi-asserted-by":"publisher","first-page":"104","DOI":"10.1016\/j.snb.2008.09.028","volume":"139","author":"M Koneswaran","year":"2009","unstructured":"Koneswaran M, Narayanaswamy R (2009) L-cysteine-capped ZnS quantum dots based fluorescence sensor for Cu2+ ion. Sensors Actuators B Chem 139(1):104\u2013109","journal-title":"Sensors Actuators B Chem"},{"issue":"13","key":"2952_CR29","doi-asserted-by":"publisher","first-page":"6188","DOI":"10.1021\/ac501290u","volume":"86","author":"L Lu","year":"2014","unstructured":"Lu L, Yang G, Xia Y (2014) From pair to single: sole fluorophore for ratiometric sensing by dual-emitting quantum dots. Anal Chem 86(13):6188\u20136191","journal-title":"Anal Chem"},{"issue":"10","key":"2952_CR30","doi-asserted-by":"publisher","first-page":"2379","DOI":"10.1039\/C3AN02380J","volume":"139","author":"K Zhang","year":"2014","unstructured":"Zhang K, Yang L, Zhu H, Ma F, Zhang Z, Wang S (2014) Selective visual detection of trace trinitrotoluene residues based on dual-color fluorescence of graphene oxide\u2013nanocrystals hybrid probe. Analyst 139(10):2379\u20132385","journal-title":"Analyst"},{"issue":"4","key":"2952_CR31","doi-asserted-by":"publisher","first-page":"1738","DOI":"10.1016\/j.talanta.2011.06.071","volume":"85","author":"J Duan","year":"2011","unstructured":"Duan J, Jiang X, Ni S, Yang M, Zhan J (2011) Facile synthesis of n-acetyl-l-cysteine capped zns quantum dots as an eco-friendly fluorescence sensor for Hg2+. Talanta 85(4):1738\u20131743","journal-title":"Talanta"},{"issue":"4","key":"2952_CR32","doi-asserted-by":"publisher","first-page":"595","DOI":"10.1039\/C3TC31937G","volume":"2","author":"Y Lou","year":"2014","unstructured":"Lou Y, Zhao Y, Chen J, Zhu JJ (2014) Metal ions optical sensing by semiconductor quantum dots. Mater Chem C 2(4):595\u2013613","journal-title":"Mater Chem C"},{"issue":"11","key":"2952_CR33","doi-asserted-by":"publisher","first-page":"5977","DOI":"10.1039\/C6NR00430J","volume":"8","author":"Y Wang","year":"2016","unstructured":"Wang Y, Zhang C, Chen X, Yang B, Yang L, Jiang C, Zhang Z (2016) Ratiometric fluorescent paper sensor utilizing hybrid carbon dots\u2013quantum dots for the visual determination of copper ions. Nanoscale 8(11):5977\u20135984","journal-title":"Nanoscale"},{"key":"2952_CR34","doi-asserted-by":"publisher","first-page":"35","DOI":"10.1016\/j.snb.2014.06.054","volume":"203","author":"Y Ding","year":"2014","unstructured":"Ding Y, Shen SZ, Sun H, Sun K, Liu F (2014) Synthesis of l-glutathione-capped-ZnSe quantum dots for the sensitive and selective determination of copper ion in aqueous solutions. Sensors Actuators B Chem 203:35\u201343","journal-title":"Sensors Actuators B Chem"},{"key":"2952_CR35","doi-asserted-by":"publisher","first-page":"143","DOI":"10.1016\/j.talanta.2018.01.073","volume":"184","author":"Y Jiao","year":"2018","unstructured":"Jiao Y, Zhou L, He H, Yin J, Gao Q, Wei J, Duan C, Peng X (2018) A novel rhodamine B-based \u201coff-on\u201d fluorescent sensor for selective recognition of copper (II) ions. Talanta 184:143\u2013148","journal-title":"Talanta"},{"key":"2952_CR36","doi-asserted-by":"publisher","first-page":"49","DOI":"10.1016\/j.jphotochem.2018.02.020","volume":"357","author":"X Wang","year":"2018","unstructured":"Wang X, Yu Z, Wang J, Shen J, Lu Y, Shen W, Lv Y, Sun X (2018) A water-soluble fluorescence \u201cturn on\u201d chemosensor for Cu2+ signaling: a combined photophysical and cell imaging study. J Photochem Photobiol A 357:49\u201359","journal-title":"J Photochem Photobiol A"}],"container-title":["Microchimica Acta"],"original-title":[],"language":"en","link":[{"URL":"http:\/\/link.springer.com\/article\/10.1007\/s00604-018-2952-x\/fulltext.html","content-type":"text\/html","content-version":"vor","intended-application":"text-mining"},{"URL":"http:\/\/link.springer.com\/content\/pdf\/10.1007\/s00604-018-2952-x.pdf","content-type":"application\/pdf","content-version":"vor","intended-application":"text-mining"},{"URL":"http:\/\/link.springer.com\/content\/pdf\/10.1007\/s00604-018-2952-x.pdf","content-type":"application\/pdf","content-version":"vor","intended-application":"similarity-checking"}],"deposited":{"date-parts":[[2019,9,24]],"date-time":"2019-09-24T02:40:58Z","timestamp":1569292858000},"score":1,"resource":{"primary":{"URL":"http:\/\/link.springer.com\/10.1007\/s00604-018-2952-x"}},"subtitle":[],"short-title":[],"issued":{"date-parts":[[2018,8,18]]},"references-count":36,"journal-issue":{"issue":"9","published-print":{"date-parts":[[2018,9]]}},"alternative-id":["2952"],"URL":"https:\/\/doi.org\/10.1007\/s00604-018-2952-x","relation":{},"ISSN":["0026-3672","1436-5073"],"issn-type":[{"value":"0026-3672","type":"print"},{"value":"1436-5073","type":"electronic"}],"subject":[],"published":{"date-parts":[[2018,8,18]]},"assertion":[{"value":"25 May 2018","order":1,"name":"received","label":"Received","group":{"name":"ArticleHistory","label":"Article History"}},{"value":"3 August 2018","order":2,"name":"accepted","label":"Accepted","group":{"name":"ArticleHistory","label":"Article History"}},{"value":"18 August 2018","order":3,"name":"first_online","label":"First Online","group":{"name":"ArticleHistory","label":"Article History"}},{"value":"The authors declare they have no competing interests.","order":1,"name":"Ethics","group":{"name":"EthicsHeading","label":"Compliance with ethical standards"}}],"article-number":"420"}}