{"status":"ok","message-type":"work","message-version":"1.0.0","message":{"indexed":{"date-parts":[[2026,10,29]],"date-time":"2026-10-29T20:53:06Z","timestamp":1793307186363,"version":"4.5.0"},"reference-count":63,"publisher":"Springer Science and Business Media LLC","issue":"10","license":[{"start":{"date-parts":[[2024,9,29]],"date-time":"2024-09-29T00:00:00Z","timestamp":1727568000000},"content-version":"tdm","delay-in-days":0,"URL":"https:\/\/www.springernature.com\/gp\/researchers\/text-and-data-mining"},{"start":{"date-parts":[[2024,9,29]],"date-time":"2024-09-29T00:00:00Z","timestamp":1727568000000},"content-version":"vor","delay-in-days":0,"URL":"https:\/\/www.springernature.com\/gp\/researchers\/text-and-data-mining"}],"content-domain":{"domain":["link.springer.com"],"crossmark-restriction":false},"short-container-title":["Microchim Acta"],"published-print":{"date-parts":[[2024,10]]},"DOI":"10.1007\/s00604-024-06720-7","type":"journal-article","created":{"date-parts":[[2024,9,29]],"date-time":"2024-09-29T10:01:43Z","timestamp":1727604103000},"update-policy":"https:\/\/doi.org\/10.1007\/springer_crossmark_policy","source":"Crossref","is-referenced-by-count":27,"title":["Tailoring 3D-printed sensor properties with reduced-graphene oxide: improved conductive filaments"],"prefix":"10.1007","volume":"191","author":[{"given":"Michele V. C. O.","family":"Silva","sequence":"first","affiliation":[],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Mayane S.","family":"Carvalho","sequence":"additional","affiliation":[],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Luiz R. G.","family":"Silva","sequence":"additional","affiliation":[],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Raquel G.","family":"Rocha","sequence":"additional","affiliation":[],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Luciana V.","family":"Cambraia","sequence":"additional","affiliation":[],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Bruno C.","family":"Janegitz","sequence":"additional","affiliation":[],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Edson","family":"Nossol","sequence":"additional","affiliation":[],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Rodrigo A. A.","family":"Mu\u00f1oz","sequence":"additional","affiliation":[],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Eduardo M.","family":"Richter","sequence":"additional","affiliation":[],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"J\u00e9ssica S.","family":"Stefano","sequence":"additional","affiliation":[],"role":[{"vocabulary":"crossref","role":"author"}]}],"member":"297","published-online":{"date-parts":[[2024,9,29]]},"reference":[{"key":"6720_CR1","doi-asserted-by":"publisher","first-page":"47","DOI":"10.1146\/ANNUREV-ANCHEM-091120-093659\/CITE\/REFWORKS","volume":"14","author":"A Abdalla","year":"2021","unstructured":"Abdalla A, Patel BA (2021) 3D printed electrochemical sensors. Annu Rev Anal Chem 14:47\u201363. https:\/\/doi.org\/10.1146\/ANNUREV-ANCHEM-091120-093659\/CITE\/REFWORKS","journal-title":"Annu Rev Anal Chem"},{"key":"6720_CR2","doi-asserted-by":"publisher","first-page":"2740","DOI":"10.1039\/C5CS00714C","volume":"45","author":"A Ambrosi","year":"2016","unstructured":"Ambrosi A, Pumera M (2016) 3D-printing technologies for electrochemical applications. Chem Soc Rev 45:2740\u20132755. https:\/\/doi.org\/10.1039\/C5CS00714C","journal-title":"Chem Soc Rev"},{"key":"6720_CR3","doi-asserted-by":"publisher","first-page":"110","DOI":"10.1016\/J.TRAC.2018.03.016","volume":"103","author":"CL Manzanares Palenzuela","year":"2018","unstructured":"Manzanares Palenzuela CL, Pumera M (2018) (Bio)analytical chemistry enabled by 3D printing: sensors and biosensors. TrAC Trends Anal Chem 103:110\u2013118. https:\/\/doi.org\/10.1016\/J.TRAC.2018.03.016","journal-title":"TrAC Trends Anal Chem"},{"key":"6720_CR4","doi-asserted-by":"publisher","first-page":"73","DOI":"10.1016\/j.aca.2020.03.028","volume":"1118","author":"RM Cardoso","year":"2020","unstructured":"Cardoso RM, Kalinke C, Rocha RG et al (2020) Additive-manufactured (3D-printed) electrochemical sensors: a critical review. Anal Chim Acta 1118:73\u201391. https:\/\/doi.org\/10.1016\/j.aca.2020.03.028","journal-title":"Anal Chim Acta"},{"key":"6720_CR5","doi-asserted-by":"publisher","first-page":"6417","DOI":"10.1021\/acs.analchem.1c05523","volume":"94","author":"JS Stefano","year":"2022","unstructured":"Stefano JS, Kalinke C, Da Rocha RG et al (2022) Electrochemical (bio)sensors enabled by fused deposition modeling-based 3D printing: a guide to selecting designs, printing parameters, and post-treatment protocols. Anal Chem 94:6417\u20136429. https:\/\/doi.org\/10.1021\/acs.analchem.1c05523","journal-title":"Anal Chem"},{"key":"6720_CR6","doi-asserted-by":"publisher","first-page":"365","DOI":"10.1016\/j.esci.2022.07.003","volume":"2","author":"KR Ryan","year":"2022","unstructured":"Ryan KR, Down MP, Hurst NJ et al (2022) Additive manufacturing (3D printing) of electrically conductive polymers and polymer nanocomposites and their applications. eScience 2:365\u2013381. https:\/\/doi.org\/10.1016\/j.esci.2022.07.003","journal-title":"eScience"},{"key":"6720_CR7","doi-asserted-by":"publisher","DOI":"10.1016\/J.CEJ.2021.131433","volume":"425","author":"J Mu\u00f1oz","year":"2021","unstructured":"Mu\u00f1oz J, Pumera M (2021) 3D-printed COVID-19 immunosensors with electronic readout. Chem Eng J 425:131433. https:\/\/doi.org\/10.1016\/J.CEJ.2021.131433","journal-title":"Chem Eng J"},{"key":"6720_CR8","doi-asserted-by":"publisher","DOI":"10.1016\/j.mser.2023.100754","volume":"156","author":"A Sharma","year":"2023","unstructured":"Sharma A, Faber H, Khosla A, Anthopoulos TD (2023) 3D printed electrochemical devices for bio-chemical sensing: a review. Mater Sci Eng R Rep 156:100754. https:\/\/doi.org\/10.1016\/j.mser.2023.100754","journal-title":"Mater Sci Eng R Rep"},{"key":"6720_CR9","doi-asserted-by":"publisher","first-page":"859","DOI":"10.1002\/elan.201900658","volume":"32","author":"JG Walters","year":"2020","unstructured":"Walters JG, Ahmed S, Terrero Rodr\u00edguez IM, O\u2019Neil GD (2020) Trace analysis of heavy metals (Cd, Pb, Hg) using native and modified 3D printed graphene\/poly(lactic acid) composite electrodes. Electroanalysis 32:859\u2013866. https:\/\/doi.org\/10.1002\/elan.201900658","journal-title":"Electroanalysis"},{"key":"6720_CR10","doi-asserted-by":"publisher","first-page":"1207","DOI":"10.1039\/c9an01926j","volume":"145","author":"C Kalinke","year":"2020","unstructured":"Kalinke C, Neumsteir NV, Aparecido GDO et al (2020) Comparison of activation processes for 3D printed PLA-graphene electrodes: electrochemical properties and application for sensing of dopamine. Analyst 145:1207\u20131218. https:\/\/doi.org\/10.1039\/c9an01926j","journal-title":"Analyst"},{"key":"6720_CR11","doi-asserted-by":"publisher","first-page":"56","DOI":"10.1016\/J.ELECOM.2018.12.006","volume":"99","author":"GD O\u2019Neil","year":"2019","unstructured":"O\u2019Neil GD, Ahmed S, Halloran K et al (2019) Single-step fabrication of electrochemical flow cells utilizing multi-material 3D printing. Electrochem commun 99:56\u201360. https:\/\/doi.org\/10.1016\/J.ELECOM.2018.12.006","journal-title":"Electrochem commun"},{"key":"6720_CR12","doi-asserted-by":"publisher","first-page":"73","DOI":"10.1016\/J.MATTOD.2023.11.002","volume":"71","author":"RD Crapnell","year":"2023","unstructured":"Crapnell RD, Kalinke C, Silva LRG et al (2023) Additive manufacturing electrochemistry: an overview of producing bespoke conductive additive manufacturing filaments. Mater Today 71:73\u201390. https:\/\/doi.org\/10.1016\/J.MATTOD.2023.11.002","journal-title":"Mater Today"},{"key":"6720_CR13","doi-asserted-by":"publisher","first-page":"8374","DOI":"10.1039\/c9cc03774h","volume":"55","author":"MP Browne","year":"2019","unstructured":"Browne MP, Pumera M (2019) Impurities in graphene\/PLA 3D-printing filaments dramatically influence the electrochemical properties of the devices. Chem Commun 55:8374\u20138377. https:\/\/doi.org\/10.1039\/c9cc03774h","journal-title":"Chem Commun"},{"key":"6720_CR14","doi-asserted-by":"publisher","first-page":"1120","DOI":"10.1039\/c9ta11949c","volume":"8","author":"MP Browne","year":"2020","unstructured":"Browne MP, Urbanova V, Plutnar J et al (2020) Inherent impurities in 3D-printed electrodes are responsible for catalysis towards water splitting. J Mater Chem A 8:1120\u20131126. https:\/\/doi.org\/10.1039\/c9ta11949c","journal-title":"J Mater Chem A"},{"key":"6720_CR15","doi-asserted-by":"publisher","unstructured":"Stefano JS, Guterres e Silva LR, Rocha RG et al (2021) New conductive filament ready-to-use for 3D-printing electrochemical (bio)sensors: towards the detection of SARS-CoV-2. Anal Chim Acta 339372. https:\/\/doi.org\/10.1016\/J.ACA.2021.339372","DOI":"10.1016\/J.ACA.2021.339372"},{"key":"6720_CR16","doi-asserted-by":"publisher","DOI":"10.1016\/J.CEJ.2019.122343","volume":"381","author":"CW Foster","year":"2020","unstructured":"Foster CW, Elbardisy HM, Down MP et al (2020) Additively manufactured graphitic electrochemical sensing platforms. Chem Eng J 381:122343. https:\/\/doi.org\/10.1016\/J.CEJ.2019.122343","journal-title":"Chem Eng J"},{"key":"6720_CR17","doi-asserted-by":"publisher","first-page":"2978","DOI":"10.1021\/acssuschemeng.2c06514","volume":"11","author":"E Sigley","year":"2023","unstructured":"Sigley E, Kalinke C, Crapnell RD et al (2023) Circular economy electrochemistry: creating additive manufacturing feedstocks for caffeine detection from post-industrial coffee pod waste. ACS Sustain Chem Eng 11:2978\u20132988. https:\/\/doi.org\/10.1021\/acssuschemeng.2c06514","journal-title":"ACS Sustain Chem Eng"},{"key":"6720_CR18","doi-asserted-by":"publisher","DOI":"10.1016\/J.ADDMA.2023.103643","volume":"72","author":"O Urra Sanchez","year":"2023","unstructured":"Urra Sanchez O, Besharatloo H, Yus J et al (2023) Material thermal extrusion of conductive 3D electrodes using highly loaded graphene and graphite colloidal feedstock. Addit Manuf 72:103643. https:\/\/doi.org\/10.1016\/J.ADDMA.2023.103643","journal-title":"Addit Manuf"},{"key":"6720_CR19","doi-asserted-by":"publisher","first-page":"15086","DOI":"10.1021\/ACS.ANALCHEM.3C03193\/ASSET\/IMAGES\/LARGE\/AC3C03193_0005.JPEG","volume":"95","author":"IVS Arantes","year":"2023","unstructured":"Arantes IVS, Crapnell RD, Bernalte E et al (2023) Mixed graphite\/carbon black recycled PLA conductive additive manufacturing filament for the electrochemical detection of oxalate. Anal Chem 95:15086\u201315093. https:\/\/doi.org\/10.1021\/ACS.ANALCHEM.3C03193\/ASSET\/IMAGES\/LARGE\/AC3C03193_0005.JPEG","journal-title":"Anal Chem"},{"key":"6720_CR20","doi-asserted-by":"publisher","DOI":"10.1016\/J.FOODCHEM.2022.135038","volume":"406","author":"LR Guterres Silva","year":"2023","unstructured":"Guterres Silva LR, Santos Stefano J, Corn\u00e9lio Ferreira Nocelli R, Campos Janegitz B (2023) 3D electrochemical device obtained by additive manufacturing for sequential determination of paraquat and carbendazim in food samples. Food Chem 406:135038. https:\/\/doi.org\/10.1016\/J.FOODCHEM.2022.135038","journal-title":"Food Chem"},{"key":"6720_CR21","doi-asserted-by":"publisher","first-page":"1","DOI":"10.1371\/journal.pone.0049365","volume":"7","author":"SJ Leigh","year":"2012","unstructured":"Leigh SJ, Bradley RJ, Purssell CP et al (2012) A simple, low-cost conductive composite material for 3D printing of electronic sensors. PLoS ONE 7:1\u20136. https:\/\/doi.org\/10.1371\/journal.pone.0049365","journal-title":"PLoS ONE"},{"key":"6720_CR22","doi-asserted-by":"publisher","unstructured":"Wuamprakhon P, Crapnell RD, Sigley E et al (2023) Recycled additive manufacturing feedstocks for fabricating high voltage, low-cost aqueous supercapacitors. Adv Sustain Syst 7. https:\/\/doi.org\/10.1002\/adsu.202200407","DOI":"10.1002\/adsu.202200407"},{"key":"6720_CR23","doi-asserted-by":"publisher","first-page":"2397","DOI":"10.1021\/acsaenm.3c00345","volume":"1","author":"IVS Arantes","year":"2023","unstructured":"Arantes IVS, Crapnell RD, Whittingham MJ et al (2023) Additive manufacturing of a portable electrochemical sensor with a recycled conductive filament for the detection of atropine in spiked drink samples. ACS Appl Eng Mater 1:2397\u20132406. https:\/\/doi.org\/10.1021\/acsaenm.3c00345","journal-title":"ACS Appl Eng Mater"},{"key":"6720_CR24","doi-asserted-by":"publisher","first-page":"7484","DOI":"10.1021\/acs.chemmater.8b02062","volume":"30","author":"A Maurel","year":"2018","unstructured":"Maurel A, Courty M, Fleutot B et al (2018) Highly loaded graphite-polylactic acid composite-based filaments for lithium-ion battery three-dimensional printing. Chem Mater 30:7484\u20137493. https:\/\/doi.org\/10.1021\/acs.chemmater.8b02062","journal-title":"Chem Mater"},{"key":"6720_CR25","doi-asserted-by":"publisher","DOI":"10.1016\/J.CEJ.2023.143513","volume":"467","author":"C Kalinke","year":"2023","unstructured":"Kalinke C, Crapnell RD, Sigley E et al (2023) Recycled additive manufacturing feedstocks with carboxylated multi-walled carbon nanotubes toward the detection of yellow fever virus cDNA. Chem Eng J 467:143513. https:\/\/doi.org\/10.1016\/J.CEJ.2023.143513","journal-title":"Chem Eng J"},{"key":"6720_CR26","doi-asserted-by":"publisher","first-page":"13620","DOI":"10.1021\/acs.langmuir.6b03602","volume":"32","author":"CW Chang","year":"2016","unstructured":"Chang CW, Liao YC (2016) Accelerated sedimentation velocity assessment for nanowires stabilized in a non-newtonian fluid. Langmuir 32:13620\u201313626. https:\/\/doi.org\/10.1021\/acs.langmuir.6b03602","journal-title":"Langmuir"},{"key":"6720_CR27","doi-asserted-by":"publisher","first-page":"1027","DOI":"10.1002\/ELAN.200900571","volume":"22","author":"Y Shao","year":"2010","unstructured":"Shao Y, Wang J, Wu H et al (2010) Graphene based electrochemical sensors and biosensors: a review. Electroanalysis 22:1027\u20131036. https:\/\/doi.org\/10.1002\/ELAN.200900571","journal-title":"Electroanalysis"},{"key":"6720_CR28","doi-asserted-by":"publisher","DOI":"10.1016\/J.BIOS.2020.112033","volume":"156","author":"F Arduini","year":"2020","unstructured":"Arduini F, Cinti S, Mazzaracchio V et al (2020) Carbon black as an outstanding and affordable nanomaterial for electrochemical (bio)sensor design. Biosens Bioelectron 156:112033. https:\/\/doi.org\/10.1016\/J.BIOS.2020.112033","journal-title":"Biosens Bioelectron"},{"key":"6720_CR29","doi-asserted-by":"publisher","DOI":"10.1016\/J.JPBA.2022.115032","volume":"221","author":"LMC Ferreira","year":"2022","unstructured":"Ferreira LMC, Silva PS, Augusto KKL et al (2022) Using nanostructured carbon black-based electrochemical (bio)sensors for pharmaceutical and biomedical analyses: a comprehensive review. J Pharm Biomed Anal 221:115032. https:\/\/doi.org\/10.1016\/J.JPBA.2022.115032","journal-title":"J Pharm Biomed Anal"},{"key":"6720_CR30","doi-asserted-by":"publisher","unstructured":"Crapnell RD, Arantes IVS, Camargo JR et al (2024) Multi-walled carbon nanotubes\/carbon black\/rPLA for high-performance conductive additive manufacturing filament and the simultaneous detection of acetaminophen and phenylephrine. Microchim Acta 191. https:\/\/doi.org\/10.1007\/s00604-023-06175-2","DOI":"10.1007\/s00604-023-06175-2"},{"key":"6720_CR31","doi-asserted-by":"publisher","unstructured":"Thangamani R, Perumal VL, Vinodha S (2020) Graphene modified electrochemical sensors for toxic chemicals. pp 1\u201324. https:\/\/doi.org\/10.21741\/9781644900956-1","DOI":"10.21741\/9781644900956-1"},{"key":"6720_CR32","doi-asserted-by":"publisher","first-page":"414","DOI":"10.1007\/s00604-022-05511-2","volume":"189","author":"JS Stefano","year":"2022","unstructured":"Stefano JS, Silva LRGe, Janegitz BC (2022) New carbon black-based conductive filaments for the additive manufacture of improved electrochemical sensors by fused deposition modeling. Microchim Acta 189:414. https:\/\/doi.org\/10.1007\/s00604-022-05511-2","journal-title":"Microchim Acta"},{"key":"6720_CR33","doi-asserted-by":"publisher","first-page":"12844","DOI":"10.1021\/acs.analchem.9b02573","volume":"91","author":"EM Richter","year":"2019","unstructured":"Richter EM, Rocha DP, Cardoso RM et al (2019) Complete additively manufactured (3D-printed) electrochemical sensing platform. Anal Chem 91:12844\u201312851. https:\/\/doi.org\/10.1021\/acs.analchem.9b02573","journal-title":"Anal Chem"},{"key":"6720_CR34","doi-asserted-by":"publisher","first-page":"1","DOI":"10.3390\/bios8020053","volume":"8","author":"AGM Ferrari","year":"2018","unstructured":"Ferrari AGM, Foster CW, Kelly PJ et al (2018) Determination of the electrochemical area of screen-printed electrochemical sensing platforms. Biosensors 8:1\u201310. https:\/\/doi.org\/10.3390\/bios8020053","journal-title":"Biosensors"},{"key":"6720_CR35","doi-asserted-by":"publisher","first-page":"10","DOI":"10.1016\/J.ACA.2020.07.034","volume":"1132","author":"RM Cardoso","year":"2020","unstructured":"Cardoso RM, Rocha DP, Rocha RG et al (2020) 3D-printing pen versus desktop 3D-printers: Fabrication of carbon black\/polylactic acid electrodes for single-drop detection of 2,4,6-trinitrotoluene. Anal Chim Acta 1132:10\u201319. https:\/\/doi.org\/10.1016\/J.ACA.2020.07.034","journal-title":"Anal Chim Acta"},{"key":"6720_CR36","doi-asserted-by":"publisher","first-page":"1788","DOI":"10.1039\/D1AY00181G","volume":"13","author":"RG Rocha","year":"2021","unstructured":"Rocha RG, Ribeiro JS, Santana MHP et al (2021) 3D-printing for forensic chemistry: voltammetric determination of cocaine on additively manufactured graphene\u2013polylactic acid electrodes. Anal Methods 13:1788\u20131794. https:\/\/doi.org\/10.1039\/D1AY00181G","journal-title":"Anal Methods"},{"key":"6720_CR37","doi-asserted-by":"publisher","unstructured":"Rocha DP, Rocha RG, Castro SVF et al (2021) Posttreatment of 3D\u2010printed surfaces for electrochemical applications: a critical review on proposed protocols. Electrochem Sci Adv 1\u201315. https:\/\/doi.org\/10.1002\/elsa.202100136","DOI":"10.1002\/elsa.202100136"},{"key":"6720_CR38","doi-asserted-by":"publisher","first-page":"837","DOI":"10.1016\/J.SNB.2018.11.013","volume":"281","author":"PL dos Santos","year":"2019","unstructured":"dos Santos PL, Katic V, Loureiro HC et al (2019) Enhanced performance of 3D printed graphene electrodes after electrochemical pre-treatment: role of exposed graphene sheets. Sensors Actuators B Chem 281:837\u2013848. https:\/\/doi.org\/10.1016\/J.SNB.2018.11.013","journal-title":"Sensors Actuators B Chem"},{"key":"6720_CR39","doi-asserted-by":"publisher","DOI":"10.1016\/J.BIOS.2020.112684","volume":"170","author":"VAOP Silva","year":"2020","unstructured":"Silva VAOP, Fernandes-Junior WS, Rocha DP et al (2020) 3D-printed reduced graphene oxide\/polylactic acid electrodes: a new prototyped platform for sensing and biosensing applications. Biosens Bioelectron 170:112684. https:\/\/doi.org\/10.1016\/J.BIOS.2020.112684","journal-title":"Biosens Bioelectron"},{"key":"6720_CR40","doi-asserted-by":"publisher","first-page":"1098","DOI":"10.1039\/C3AY26476A","volume":"5","author":"EP Randviir","year":"2013","unstructured":"Randviir EP, Banks CE (2013) Electrochemical impedance spectroscopy: an overview of bioanalytical applications. Anal Methods 5:1098\u20131115. https:\/\/doi.org\/10.1039\/C3AY26476A","journal-title":"Anal Methods"},{"key":"6720_CR41","doi-asserted-by":"publisher","first-page":"32078","DOI":"10.1039\/C5RA02877A","volume":"5","author":"PKS Mural","year":"2015","unstructured":"Mural PKS, Sharma M, Madras G, Bose S (2015) A critical review on in situ reduction of graphene oxide during preparation of conducting polymeric nanocomposites. RSC Adv 5:32078\u201332087. https:\/\/doi.org\/10.1039\/C5RA02877A","journal-title":"RSC Adv"},{"key":"6720_CR42","doi-asserted-by":"publisher","DOI":"10.1016\/j.matpr.2023.03.381","author":"A Sharma","year":"2023","unstructured":"Sharma A, Jain P, Bajpai R et al (2023) Synthesis of ultra-thin graphene oxide\/reduced graphene oxide nanocomposites and examine their properties. Mater Today Proc. https:\/\/doi.org\/10.1016\/j.matpr.2023.03.381","journal-title":"Mater Today Proc"},{"key":"6720_CR43","doi-asserted-by":"publisher","DOI":"10.1016\/j.apsusc.2020.147990","volume":"536","author":"AY Lee","year":"2021","unstructured":"Lee AY, Yang K, Anh ND et al (2021) Raman study of D* band in graphene oxide and its correlation with reduction. Appl Surf Sci 536:147990. https:\/\/doi.org\/10.1016\/j.apsusc.2020.147990","journal-title":"Appl Surf Sci"},{"key":"6720_CR44","doi-asserted-by":"publisher","DOI":"10.1016\/j.flatc.2022.100422","volume":"35","author":"T Anusuya","year":"2022","unstructured":"Anusuya T, Pathak DK, Kumar R, Kumar V (2022) Deconvolution and quantification of defect types from the first order Raman spectra of graphene oxide derivatives. FlatChem 35:100422. https:\/\/doi.org\/10.1016\/j.flatc.2022.100422","journal-title":"FlatChem"},{"key":"6720_CR45","doi-asserted-by":"publisher","first-page":"2810","DOI":"10.1039\/d1ma01023a","volume":"3","author":"PW Albers","year":"2022","unstructured":"Albers PW, Leich V, Ramirez-Cuesta AJ et al (2022) The characterisation of commercial 2D carbons: graphene, graphene oxide and reduced graphene oxide. Mater Adv 3:2810\u20132826. https:\/\/doi.org\/10.1039\/d1ma01023a","journal-title":"Mater Adv"},{"key":"6720_CR46","doi-asserted-by":"publisher","first-page":"16","DOI":"10.1002\/elan.201400409","volume":"27","author":"M Carbone","year":"2015","unstructured":"Carbone M, Gorton L, Antiochia R (2015) An overview of the latest graphene-based sensors for glucose detection: the effects of graphene defects. Electroanalysis 27:16\u201331. https:\/\/doi.org\/10.1002\/elan.201400409","journal-title":"Electroanalysis"},{"key":"6720_CR47","doi-asserted-by":"publisher","DOI":"10.1016\/j.carbon.2023.118479","volume":"215","author":"J Moon","year":"2023","unstructured":"Moon J, Yun H, Ukai J et al (2023) Correlation function of specific capacity and electrical conductivity on carbon materials by multivariate analysis. Carbon N Y 215:118479. https:\/\/doi.org\/10.1016\/j.carbon.2023.118479","journal-title":"Carbon N Y"},{"key":"6720_CR48","doi-asserted-by":"publisher","first-page":"20489","DOI":"10.1021\/acs.jpcc.7b06236","volume":"121","author":"D L\u00f3pez-D\u00edaz","year":"2017","unstructured":"L\u00f3pez-D\u00edaz D, L\u00f3pez Holgado M, Garc\u00eda-Fierro JL, Vel\u00e1zquez MM (2017) Evolution of the Raman spectrum with the chemical composition of graphene oxide. J Phys Chem C 121:20489\u201320497. https:\/\/doi.org\/10.1021\/acs.jpcc.7b06236","journal-title":"J Phys Chem C"},{"key":"6720_CR49","doi-asserted-by":"publisher","first-page":"16","DOI":"10.1016\/j.coelec.2019.04.013","volume":"17","author":"P Li","year":"2019","unstructured":"Li P, Li X, Chen W (2019) Recent advances in electrochemical sensors for the detection of 2, 4, 6-trinitrotoluene. Curr Opin Electrochem 17:16\u201322. https:\/\/doi.org\/10.1016\/j.coelec.2019.04.013","journal-title":"Curr Opin Electrochem"},{"key":"6720_CR50","doi-asserted-by":"publisher","DOI":"10.1016\/j.chemosphere.2023.139796","volume":"340","author":"GP Siqueira","year":"2023","unstructured":"Siqueira GP, Ara\u00fajo DAG, de Faria LV et al (2023) A novel 3D-printed graphite\/polylactic acid sensor for the electrochemical determination of 2,4,6-trinitrotoluene residues in environmental waters. Chemosphere 340:139796. https:\/\/doi.org\/10.1016\/j.chemosphere.2023.139796","journal-title":"Chemosphere"},{"key":"6720_CR51","doi-asserted-by":"publisher","first-page":"4243","DOI":"10.1021\/JP209631X\/SUPPL_FILE\/JP209631X_SI_002.TXT","volume":"116","author":"CK Chua","year":"2012","unstructured":"Chua CK, Pumera M, Rul\u00ed\u0161ek L (2012) Reduction pathways of 2,4,6-trinitrotoluene: an electrochemical and theoretical study. J Phys Chem C 116:4243\u20134251. https:\/\/doi.org\/10.1021\/JP209631X\/SUPPL_FILE\/JP209631X_SI_002.TXT","journal-title":"J Phys Chem C"},{"key":"6720_CR52","doi-asserted-by":"publisher","first-page":"97","DOI":"10.1016\/S0021-9673(99)00392-1","volume":"844","author":"A Hilmi","year":"1999","unstructured":"Hilmi A, Luong JHT, Nguyen AL (1999) Determination of explosives in soil and ground water by liquid chromatography\u2013amperometric detection. J Chromatogr A 844:97\u2013110. https:\/\/doi.org\/10.1016\/S0021-9673(99)00392-1","journal-title":"J Chromatogr A"},{"key":"6720_CR53","first-page":"126","volume":"201","author":"DAC Brownson","year":"2016","unstructured":"Brownson DAC, Banks CE (2016) Handbook of graphene electrochemistry. Springer, London 201:126","journal-title":"Springer, London"},{"key":"6720_CR54","doi-asserted-by":"publisher","first-page":"218","DOI":"10.1016\/j.apmt.2017.11.010","volume":"10","author":"SJ Rowley-Neale","year":"2018","unstructured":"Rowley-Neale SJ, Randviir EP, Abo Dena AS, Banks CE (2018) An overview of recent applications of reduced graphene oxide as a basis of electroanalytical sensing platforms. Appl Mater Today 10:218\u2013226. https:\/\/doi.org\/10.1016\/j.apmt.2017.11.010","journal-title":"Appl Mater Today"},{"key":"6720_CR55","doi-asserted-by":"publisher","first-page":"48","DOI":"10.1016\/J.TRAC.2019.02.025","volume":"114","author":"L Poltorak","year":"2019","unstructured":"Poltorak L, Sudh\u00f6lter EJR, de Puit M (2019) Electrochemical cocaine (bio)sensing. From solid electrodes to soft junctions. TrAC Trends Anal Chem 114:48\u201355. https:\/\/doi.org\/10.1016\/J.TRAC.2019.02.025","journal-title":"TrAC Trends Anal Chem"},{"key":"6720_CR56","doi-asserted-by":"publisher","DOI":"10.1016\/J.TALANTA.2021.122990","volume":"238","author":"A Arman","year":"2022","unstructured":"Arman A, Sa\u011flam \u015e, \u00dczer A, Apak R (2022) Electrochemical determination of nitroaromatic explosives using glassy carbon\/multi walled carbon nanotube\/polyethyleneimine electrode coated with gold nanoparticles. Talanta 238:122990. https:\/\/doi.org\/10.1016\/J.TALANTA.2021.122990","journal-title":"Talanta"},{"key":"6720_CR57","doi-asserted-by":"publisher","DOI":"10.1016\/J.MTCHEM.2023.101759","volume":"34","author":"S Javaid","year":"2023","unstructured":"Javaid S, Azhar MR, Li X et al (2023) Metal organic frameworks with carbon black for the enhanced electrochemical detection of 2,4,6-trinitrotoluene. Mater Today Chem 34:101759. https:\/\/doi.org\/10.1016\/J.MTCHEM.2023.101759","journal-title":"Mater Today Chem"},{"key":"6720_CR58","doi-asserted-by":"publisher","DOI":"10.1016\/J.TALANTA.2019.120410","volume":"208","author":"ZW Wang","year":"2020","unstructured":"Wang ZW, Liu HJ, Li CY et al (2020) Mesoporous g-C3N4\/\u03b2-CD nanocomposites modified glassy carbon electrode for electrochemical determination of 2,4,6-trinitrotoluene. Talanta 208:120410. https:\/\/doi.org\/10.1016\/J.TALANTA.2019.120410","journal-title":"Talanta"},{"key":"6720_CR59","doi-asserted-by":"publisher","first-page":"12494","DOI":"10.1039\/C1CC15697G","volume":"47","author":"X Lu","year":"2011","unstructured":"Lu X, Qi H, Zhang X et al (2011) Highly dispersive Ag nanoparticles on functionalized graphene for an excellent electrochemical sensor of nitroaromatic compounds. Chem Commun 47:12494\u201312496. https:\/\/doi.org\/10.1039\/C1CC15697G","journal-title":"Chem Commun"},{"key":"6720_CR60","doi-asserted-by":"publisher","first-page":"557","DOI":"10.1016\/J.SNB.2016.12.024","volume":"243","author":"JM Freitas","year":"2017","unstructured":"Freitas JM, Ramos DLO, Sousa RMF et al (2017) A portable electrochemical method for cocaine quantification and rapid screening of common adulterants in seized samples. Sensors Actuators B Chem 243:557\u2013565. https:\/\/doi.org\/10.1016\/J.SNB.2016.12.024","journal-title":"Sensors Actuators B Chem"},{"key":"6720_CR61","doi-asserted-by":"publisher","first-page":"4639","DOI":"10.1039\/C9AN00618D","volume":"144","author":"A Florea","year":"2019","unstructured":"Florea A, Cowen T, Piletsky S, De Wael K (2019) Electrochemical sensing of cocaine in real samples based on electrodeposited biomimetic affinity ligands. Analyst 144:4639\u20134646. https:\/\/doi.org\/10.1039\/C9AN00618D","journal-title":"Analyst"},{"key":"6720_CR62","doi-asserted-by":"publisher","first-page":"14296","DOI":"10.1039\/C9RA01292C","volume":"9","author":"N Tavakkoli","year":"2019","unstructured":"Tavakkoli N, Soltani N, Mohammadi F (2019) A nanoporous gold-based electrochemical aptasensor for sensitive detection of cocaine. RSC Adv 9:14296\u201314301. https:\/\/doi.org\/10.1039\/C9RA01292C","journal-title":"RSC Adv"},{"key":"6720_CR63","doi-asserted-by":"publisher","DOI":"10.1016\/J.SNB.2021.130659","volume":"348","author":"M Parrilla","year":"2021","unstructured":"Parrilla M, Joosten F, De Wael K (2021) Enhanced electrochemical detection of illicit drugs in oral fluid by the use of surfactant-mediated solution. Sensors Actuators B Chem 348:130659. https:\/\/doi.org\/10.1016\/J.SNB.2021.130659","journal-title":"Sensors Actuators B Chem"}],"container-title":["Microchimica Acta"],"original-title":[],"language":"en","link":[{"URL":"https:\/\/link.springer.com\/content\/pdf\/10.1007\/s00604-024-06720-7.pdf","content-type":"application\/pdf","content-version":"vor","intended-application":"text-mining"},{"URL":"https:\/\/link.springer.com\/article\/10.1007\/s00604-024-06720-7\/fulltext.html","content-type":"text\/html","content-version":"vor","intended-application":"text-mining"},{"URL":"https:\/\/link.springer.com\/content\/pdf\/10.1007\/s00604-024-06720-7.pdf","content-type":"application\/pdf","content-version":"vor","intended-application":"similarity-checking"}],"deposited":{"date-parts":[[2024,10,12]],"date-time":"2024-10-12T06:13:08Z","timestamp":1728713588000},"score":1,"resource":{"primary":{"URL":"https:\/\/link.springer.com\/10.1007\/s00604-024-06720-7"}},"subtitle":[],"short-title":[],"issued":{"date-parts":[[2024,9,29]]},"references-count":63,"journal-issue":{"issue":"10","published-print":{"date-parts":[[2024,10]]}},"alternative-id":["6720"],"URL":"https:\/\/doi.org\/10.1007\/s00604-024-06720-7","relation":{},"ISSN":["0026-3672","1436-5073"],"issn-type":[{"value":"0026-3672","type":"print"},{"value":"1436-5073","type":"electronic"}],"subject":[],"published":{"date-parts":[[2024,9,29]]},"assertion":[{"value":"15 August 2024","order":1,"name":"received","label":"Received","group":{"name":"ArticleHistory","label":"Article History"}},{"value":"19 September 2024","order":2,"name":"accepted","label":"Accepted","group":{"name":"ArticleHistory","label":"Article History"}},{"value":"29 September 2024","order":3,"name":"first_online","label":"First Online","group":{"name":"ArticleHistory","label":"Article History"}},{"order":1,"name":"Ethics","group":{"name":"EthicsHeading","label":"Declarations"}},{"value":"This research did not involve human or animal samples.","order":2,"name":"Ethics","group":{"name":"EthicsHeading","label":"Ethical approval"}},{"value":"The authors declare no competing interests.","order":3,"name":"Ethics","group":{"name":"EthicsHeading","label":"Competing interests"}}],"article-number":"633"}}