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The extracellular CdS crystallites were &amp;lt;10\u00a0nm in size with yields of ~3\u00a0g\/L of growth medium\/month with demonstrated reproducibility and scalability up to 24\u00a0L. During synthesis, Thermoanaerobacter cultures reduced thiosulfate and sulfite salts to H2S, which reacted with Cd2+ cations to produce thermodynamically favored NP in a single step at 65\u00a0\u00b0C with catalytic nucleation on the cell surfaces. Photoluminescence (PL) analysis of dry CdS NP revealed an exciton-dominated PL peak at 440\u00a0nm, having a narrow full width at half maximum of 10\u00a0nm. A PL spectrum of CdS NP produced by dissimilatory sulfur reducing bacteria was dominated by features associated with radiative exciton relaxation at the surface. High reproducibility of CdS NP PL features important for scale-up conditions was confirmed from test tubes to 24\u00a0L batches at a small fraction of the manufacturing cost associated with conventional inorganic NP production processes.<\/jats:p>","DOI":"10.1007\/s10295-013-1321-3","type":"journal-article","created":{"date-parts":[[2013,9,4]],"date-time":"2013-09-04T07:44:04Z","timestamp":1378280644000},"page":"1263-1271","source":"Crossref","is-referenced-by-count":31,"title":["Scalable economic extracellular synthesis of CdS nanostructured particles by a non-pathogenic thermophile"],"prefix":"10.1093","volume":"40","author":[{"given":"Ji-Won","family":"Moon","sequence":"first","affiliation":[{"name":"grid.135519.a 0000000404462659 Biosciences Division Oak Ridge National Laboratory (ORNL) 37831 Oak Ridge TN USA"}],"role":[{"role":"author","vocabulary":"crossref"}]},{"given":"Ilia N","family":"Ivanov","sequence":"additional","affiliation":[{"name":"grid.135519.a 0000000404462659 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