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To design such treatments, it is imperative to determine the total PTE amounts released from the excavated rocks and consider their spatial distribution. Within this context, the present study aimed to clarify (i) the spatial distribution of PTE contents released from 100 m<jats:sup>3<\/jats:sup> of excavated shale deposited in a temporary storage pit, and (ii) the geochemical parameters that control such distribution. A total of 50 shale samples were collected from a temporary storage pit of rocks. These samples were subjected to the analysis for the determination of the released and total PTE amounts, and other chemical properties. No linear relationship was detected between the released and total PTE amounts. An error of\u2009\u00b1\u200930% was estimated based on a sample of 10 rocks. The geochemical parameters controlling the PTE contents released from the excavated shale differed depending on PTE types. The release of arsenic and selenium was mainly controlled by the amount of amorphous iron, while that of lead and chromium was controlled by the amount of inorganic colloidal particles with size under 0.45-\u03bcm. This study suggested that the preparation of 10 mixed rock samples collected from temporary storage pits leads to an estimation of released PTE amounts with a 30% error. In addition, the actual PTE amount released from excavated rocks containing high and low amounts of amorphous iron and inorganic colloidal particles, respectively, would differ little from the estimated amounts.<\/jats:p>","DOI":"10.1007\/s10653-025-02577-8","type":"journal-article","created":{"date-parts":[[2025,6,10]],"date-time":"2025-06-10T08:55:19Z","timestamp":1749545719000},"update-policy":"https:\/\/doi.org\/10.1007\/springer_crossmark_policy","source":"Crossref","is-referenced-by-count":1,"title":["Determination of geochemical parameters that control the spatial distribution of potentially toxic elements released from excavated shale at a temporary storage pit"],"prefix":"10.1007","volume":"47","author":[{"given":"Shoji","family":"Suzuki","sequence":"first","affiliation":[],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Toshihiko","family":"Miura","sequence":"additional","affiliation":[],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Kenichi","family":"Ito","sequence":"additional","affiliation":[],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Masahiko","family":"Katoh","sequence":"additional","affiliation":[],"role":[{"vocabulary":"crossref","role":"author"}]}],"member":"297","published-online":{"date-parts":[[2025,6,10]]},"reference":[{"key":"2577_CR1","doi-asserted-by":"publisher","first-page":"141","DOI":"10.1016\/j.chemgeo.2018.02.032","volume":"483","author":"J Bassil","year":"2018","unstructured":"Bassil, J., Naveau, A., Bueno, M., Razack, M., & Kazpard, V. 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