{"status":"ok","message-type":"work","message-version":"1.0.0","message":{"indexed":{"date-parts":[[2026,4,14]],"date-time":"2026-04-14T01:44:43Z","timestamp":1776131083221,"version":"3.50.1"},"reference-count":72,"publisher":"Springer Science and Business Media LLC","issue":"7","license":[{"start":{"date-parts":[[2025,6,26]],"date-time":"2025-06-26T00:00:00Z","timestamp":1750896000000},"content-version":"tdm","delay-in-days":0,"URL":"https:\/\/www.springernature.com\/gp\/researchers\/text-and-data-mining"},{"start":{"date-parts":[[2025,6,26]],"date-time":"2025-06-26T00:00:00Z","timestamp":1750896000000},"content-version":"vor","delay-in-days":0,"URL":"https:\/\/www.springernature.com\/gp\/researchers\/text-and-data-mining"}],"funder":[{"DOI":"10.13039\/501100003593","name":"Conselho Nacional de Desenvolvimento Cient\u00edfico e Tecnol\u00f3gico","doi-asserted-by":"publisher","id":[{"id":"10.13039\/501100003593","id-type":"DOI","asserted-by":"publisher"}]},{"DOI":"10.13039\/501100002322","name":"Coordena\u00e7\u00e3o de Aperfei\u00e7oamento de Pessoal de N\u00edvel Superior","doi-asserted-by":"publisher","id":[{"id":"10.13039\/501100002322","id-type":"DOI","asserted-by":"publisher"}]},{"DOI":"10.13039\/501100004901","name":"Funda\u00e7\u00e3o de Amparo \u00e0 Pesquisa do Estado de Minas Gerais","doi-asserted-by":"publisher","id":[{"id":"10.13039\/501100004901","id-type":"DOI","asserted-by":"publisher"}]}],"content-domain":{"domain":["link.springer.com"],"crossmark-restriction":false},"short-container-title":["Environ Geochem Health"],"published-print":{"date-parts":[[2025,7]]},"DOI":"10.1007\/s10653-025-02597-4","type":"journal-article","created":{"date-parts":[[2025,6,26]],"date-time":"2025-06-26T15:39:59Z","timestamp":1750952399000},"update-policy":"https:\/\/doi.org\/10.1007\/springer_crossmark_policy","source":"Crossref","is-referenced-by-count":2,"title":["Bioaccessibility and availability of trace elements coprecipitated with aluminum-substituted iron oxides"],"prefix":"10.1007","volume":"47","author":[{"given":"Daniel","family":"Kroehling","sequence":"first","affiliation":[],"role":[{"role":"author","vocabulary":"crossref"}]},{"given":"Renato Welmer","family":"Veloso","sequence":"additional","affiliation":[],"role":[{"role":"author","vocabulary":"crossref"}]},{"given":"Jaime Wilson Vargas","family":"de Mello","sequence":"additional","affiliation":[],"role":[{"role":"author","vocabulary":"crossref"}]},{"given":"Andr\u00e9 Mundstock Xavier","family":"de Carvalho","sequence":"additional","affiliation":[],"role":[{"role":"author","vocabulary":"crossref"}]},{"given":"Marcelo Fernandes","family":"de Oliveira","sequence":"additional","affiliation":[],"role":[{"role":"author","vocabulary":"crossref"}]},{"given":"Isabela Cristina Filardi","family":"Vasques","sequence":"additional","affiliation":[],"role":[{"role":"author","vocabulary":"crossref"}]}],"member":"297","published-online":{"date-parts":[[2025,6,26]]},"reference":[{"issue":"6","key":"2597_CR1","doi-asserted-by":"publisher","first-page":"1615","DOI":"10.2136\/sssaj1994.03615995005800060005x","volume":"58","author":"CC Ainsworth","year":"1994","unstructured":"Ainsworth, C. C., Pilon, J. L., Gassman, P. L., & Van Der Sluys, W. G. (1994). Cobalt, cadmium, and lead sorption to hydrous iron oxide: Residence time effect. Soil Science Society of America Journal, 58(6), 1615\u20131623. https:\/\/doi.org\/10.2136\/sssaj1994.03615995005800060005x","journal-title":"Soil Science Society of America Journal"},{"key":"2597_CR2","doi-asserted-by":"publisher","first-page":"53","DOI":"10.1016\/j.chemgeo.2015.06.011","volume":"410","author":"J Antelo","year":"2015","unstructured":"Antelo, J., Arce, F., & Fiol, S. (2015). Arsenate and phosphate adsorption on ferrihydrite nanoparticles. Synergetic interaction with calcium ions. Chemical Geology, 410, 53\u201362. https:\/\/doi.org\/10.1016\/j.chemgeo.2015.06.011","journal-title":"Chemical Geology"},{"key":"2597_CR3","doi-asserted-by":"publisher","DOI":"10.1016\/j.envpol.2021.116482","author":"DC Ant\u00f4nio","year":"2021","unstructured":"Ant\u00f4nio, D. C., Caldeira, C. L., Freitas, E. T. F., Delbem, I. D., Gasparon, M., Olusegun, S. J., & Ciminelli, V. S. T. (2021). Effects of aluminum and soil mineralogy on arsenic bioaccessibility. Environmental Pollution. https:\/\/doi.org\/10.1016\/j.envpol.2021.116482","journal-title":"Environmental Pollution"},{"issue":"1\u20133","key":"2597_CR4","doi-asserted-by":"publisher","first-page":"745","DOI":"10.1016\/j.jhazmat.2009.01.040","volume":"167","author":"JA Baig","year":"2009","unstructured":"Baig, J. A., Kazi, T. G., Arain, M. B., Shah, A. Q., Sarfraz, R. A., Afridi, H. I., Kandhro, G. A., Jamali, M. K., & Khan, S. (2009). Arsenic fractionation in sediments of different origins using BCR sequential and single extraction methods. Journal of Hazardous Materials, 167(1\u20133), 745\u2013751. https:\/\/doi.org\/10.1016\/j.jhazmat.2009.01.040","journal-title":"Journal of Hazardous Materials"},{"issue":"19","key":"2597_CR5","doi-asserted-by":"publisher","first-page":"18813","DOI":"10.1007\/s11356-018-2100-5","volume":"25","author":"GS Barcelos","year":"2018","unstructured":"Barcelos, G. S., Veloso, R. W., de Mello, J. W. V., & Gasparon, M. (2018). Immobilization of Eu and Ho from synthetic acid mine drainage by precipitation with Fe and Al (hydr)oxides. Environmental Science and Pollution Research, 25(19), 18813\u201318822. https:\/\/doi.org\/10.1007\/s11356-018-2100-5","journal-title":"Environmental Science and Pollution Research"},{"issue":"2","key":"2597_CR6","doi-asserted-by":"publisher","first-page":"410","DOI":"10.1016\/0021-9797(81)90337-4","volume":"83","author":"MM Benjamin","year":"1981","unstructured":"Benjamin, M. M., & Leckie, J. O. (1981). Competitive adsorption of Cd, Cu, Zn, and Pb on amorphous iron oxyhydroxide. Journal of Colloid and Interface Science, 83(2), 410\u2013419. https:\/\/doi.org\/10.1016\/0021-9797(81)90337-4","journal-title":"Journal of Colloid and Interface Science"},{"issue":"2","key":"2597_CR7","doi-asserted-by":"publisher","first-page":"313","DOI":"10.1006\/jcis.1999.6263","volume":"215","author":"P Bonnissel-Gissinger","year":"1999","unstructured":"Bonnissel-Gissinger, P., Alnot, M., Lickes, J.-P., Ehrhardt, J.-J., & Behra, P. (1999). Modeling the adsorption of mercury(II) on (hydr)oxides II: \u03b1-FeOOH (goethite) and amorphous silica. Journal of Colloid and Interface Science, 215(2), 313\u2013322. https:\/\/doi.org\/10.1006\/jcis.1999.6263","journal-title":"Journal of Colloid and Interface Science"},{"key":"2597_CR8","unstructured":"Brazil. (2010). Guidelines for evaluation of risks to human health from exposure to chemical contaminants (in Portuguese)."},{"issue":"1","key":"2597_CR9","doi-asserted-by":"publisher","first-page":"37","DOI":"10.1111\/j.1365-2389.1988.tb01192.x","volume":"39","author":"GW Bruemmer","year":"1988","unstructured":"Bruemmer, G. W., Gerth, J., & Tiller, K. G. (1988). Reaction kinetics of the adsorption and desorption of nickel, zinc and cadmium by goethite. I. Adsorption and diffusion of metals. Journal of Soil Science, 39(1), 37\u201352. https:\/\/doi.org\/10.1111\/j.1365-2389.1988.tb01192.x","journal-title":"Journal of Soil Science"},{"issue":"3","key":"2597_CR10","doi-asserted-by":"publisher","first-page":"476","DOI":"10.1021\/acsearthspacechem.0c00013","volume":"4","author":"ED Burton","year":"2020","unstructured":"Burton, E. D., Hockmann, K., & Karimian, N. (2020). Antimony sorption to goethite: Effects of Fe(II)-catalyzed recrystallization. ACS Earth and Space Chemistry, 4(3), 476\u2013487. https:\/\/doi.org\/10.1021\/acsearthspacechem.0c00013","journal-title":"ACS Earth and Space Chemistry"},{"key":"2597_CR11","doi-asserted-by":"publisher","first-page":"134","DOI":"10.1016\/j.chemgeo.2014.12.029","volume":"396","author":"D Canil","year":"2015","unstructured":"Canil, D., Crockford, P. W., Rossin, R., & Telmer, K. (2015). Mercury in some arc crustal rocks and mantle peridotites and relevance to the moderately volatile element budget of the Earth. Chemical Geology, 396, 134\u2013142. https:\/\/doi.org\/10.1016\/j.chemgeo.2014.12.029","journal-title":"Chemical Geology"},{"key":"2597_CR12","doi-asserted-by":"publisher","first-page":"120629","DOI":"10.1016\/j.envpol.2022.120629","volume":"316","author":"CR C\u00e1novas","year":"2023","unstructured":"C\u00e1novas, C. R., Quispe, D., Mac\u00edas, F., Callej\u00f3n-Leblic, B., Arias-Borrego, A., Garc\u00eda-Barrera, T., & Nieto, J. M. (2023). Potential release and bioaccessibility of metal\/loids from mine wastes deposited in historical abandoned sulfide mines. Environmental Pollution, 316, 120629. https:\/\/doi.org\/10.1016\/j.envpol.2022.120629","journal-title":"Environmental Pollution"},{"key":"2597_CR13","doi-asserted-by":"publisher","first-page":"261","DOI":"10.1016\/j.jhazmat.2018.03.037","volume":"353","author":"VST Ciminelli","year":"2018","unstructured":"Ciminelli, V. S. T., Ant\u00f4nio, D. C., Caldeira, C. L., Freitas, E. T. F., Delbem, I. D., Fernandes, M. M., Gasparon, M., & Ng, J. C. (2018). Low arsenic bioaccessibility by fixation in nanostructured iron (hydr)oxides: Quantitative identification of As-bearing phases. Journal of Hazardous Materials, 353, 261\u2013270. https:\/\/doi.org\/10.1016\/j.jhazmat.2018.03.037","journal-title":"Journal of Hazardous Materials"},{"key":"2597_CR15","doi-asserted-by":"publisher","DOI":"10.1002\/3527602097","author":"RM Cornell","year":"2003","unstructured":"Cornell, R. M., & Schwertmann, U. (2003). The iron oxides. Wiley. https:\/\/doi.org\/10.1002\/3527602097","journal-title":"Wiley"},{"key":"2597_CR14","unstructured":"CONAMA. (2009). Resolu\u00e7\u00e3o 420\/2009 (in Portuguese). https:\/\/www.ibama.gov.br\/component\/legislacao\/?view=legislacao&force=1&legislacao=115509"},{"issue":"11","key":"2597_CR16","doi-asserted-by":"publisher","first-page":"3050","DOI":"10.1021\/la00035a051","volume":"9","author":"RJ Crawford","year":"1993","unstructured":"Crawford, R. J., Harding, I. H., & Mainwaring, D. E. (1993). Adsorption and coprecipitation of single heavy metal ions onto the hydrated oxides of iron and chromium. Langmuir, 9(11), 3050\u20133056. https:\/\/doi.org\/10.1021\/la00035a051","journal-title":"Langmuir"},{"issue":"18","key":"2597_CR17","doi-asserted-by":"publisher","first-page":"4182","DOI":"10.1021\/es030309t","volume":"37","author":"S Dixit","year":"2003","unstructured":"Dixit, S., & Hering, J. G. (2003). Comparison of Arsenic(V) and Arsenic(III) sorption onto iron oxide minerals: Implications for arsenic mobility. Environmental Science & Technology, 37(18), 4182\u20134189. https:\/\/doi.org\/10.1021\/es030309t","journal-title":"Environmental Science & Technology"},{"key":"2597_CR18","doi-asserted-by":"publisher","first-page":"151191","DOI":"10.1016\/j.scitotenv.2021.151191","volume":"806","author":"MS Ferreira","year":"2022","unstructured":"Ferreira, M. S., Fontes, M. P. F., Lima, M. T. W. D. C., Cordeiro, S. G., Wyatt, N. L. P., Lima, H. N., & Fendorf, S. (2022). Human health risk assessment and geochemical mobility of rare earth elements in Amazon soils. Science of the Total Environment, 806, 151191. https:\/\/doi.org\/10.1016\/j.scitotenv.2021.151191","journal-title":"Science of the Total Environment"},{"key":"2597_CR19","doi-asserted-by":"publisher","first-page":"340","DOI":"10.1016\/j.chemosphere.2015.05.101","volume":"138","author":"ETF Freitas","year":"2015","unstructured":"Freitas, E. T. F., Montoro, L. A., Gasparon, M., & Ciminelli, V. S. T. (2015). Natural attenuation of arsenic in the environment by immobilization in nanostructured hematite. Chemosphere, 138, 340\u2013347. https:\/\/doi.org\/10.1016\/j.chemosphere.2015.05.101","journal-title":"Chemosphere"},{"key":"2597_CR20","doi-asserted-by":"publisher","first-page":"91","DOI":"10.1016\/j.chemosphere.2016.05.044","volume":"158","author":"ETF Freitas","year":"2016","unstructured":"Freitas, E. T. F., Stroppa, D. G., Montoro, L. A., de Mello, J. W. V., Gasparon, M., & Ciminelli, V. S. T. (2016). Arsenic entrapment by nanocrystals of Al-magnetite: The role of Al in crystal growth and As retention. Chemosphere, 158, 91\u201399. https:\/\/doi.org\/10.1016\/j.chemosphere.2016.05.044","journal-title":"Chemosphere"},{"key":"2597_CR21","doi-asserted-by":"publisher","first-page":"16255","DOI":"10.1038\/s41598-018-34172-6","volume":"8","author":"M Ganguly","year":"2018","unstructured":"Ganguly, M., Dib, S., & Ariya, P. A. (2018). Fast, cost-effective and energy efficient mercury removal-recycling technology. Science and Reports, 8, 16255. https:\/\/doi.org\/10.1038\/s41598-018-34172-6","journal-title":"Science and Reports"},{"key":"2597_CR22","doi-asserted-by":"publisher","first-page":"128272","DOI":"10.1016\/j.jclepro.2021.128272","volume":"315","author":"M Gil-D\u00edaz","year":"2021","unstructured":"Gil-D\u00edaz, M., Rodr\u00edguez-Alonso, J., Maffiotte, C. A., Baraga\u00f1o, D., Mill\u00e1n, R., & Lobo, M. C. (2021). Iron nanoparticles are efficient at removing mercury from polluted waters. Journal of Cleaner Production, 315, 128272. https:\/\/doi.org\/10.1016\/j.jclepro.2021.128272","journal-title":"Journal of Cleaner Production"},{"issue":"2","key":"2597_CR23","doi-asserted-by":"publisher","first-page":"413","DOI":"10.2136\/sssaj2002.0413","volume":"66","author":"S Goldberg","year":"2002","unstructured":"Goldberg, S. (2002). Competitive adsorption of arsenate and arsenite on oxides and clay minerals. Soil Science Society of America Journal, 66(2), 413. https:\/\/doi.org\/10.2136\/sssaj2002.0413","journal-title":"Soil Science Society of America Journal"},{"key":"2597_CR24","doi-asserted-by":"publisher","first-page":"595","DOI":"10.1016\/j.marpolbul.2019.04.022","volume":"142","author":"H Hassan","year":"2019","unstructured":"Hassan, H., Elezz, A. A., Abuasali, M., & AlSaadi, H. (2019). Baseline concentrations of mercury species within sediments from Qatar\u2019s coastal marine zone. Marine Pollution Bulletin, 142, 595\u2013602. https:\/\/doi.org\/10.1016\/j.marpolbul.2019.04.022","journal-title":"Marine Pollution Bulletin"},{"issue":"2","key":"2597_CR25","doi-asserted-by":"publisher","first-page":"49","DOI":"10.1007\/s10653-025-02360-9","volume":"47","author":"Z-Y Huang","year":"2025","unstructured":"Huang, Z.-Y., Syu, C.-H., & Hseu, Z.-Y. (2025). Evaluating the bioavailability of rare earth elements in paddy soils and their uptake in rice grains for human health risk. Environmental Geochemistry and Health, 47(2), 49. https:\/\/doi.org\/10.1007\/s10653-025-02360-9","journal-title":"Environmental Geochemistry and Health"},{"key":"2597_CR26","doi-asserted-by":"publisher","first-page":"157","DOI":"10.1016\/j.jhazmat.2017.02.009","volume":"330","author":"S Jeong","year":"2017","unstructured":"Jeong, S., Yang, K., Jho, E. H., & Nam, K. (2017). Importance of chemical binding type between As and iron-oxide on bioaccessibility in soil: Test with synthesized two line ferrihydrite. Journal of Hazardous Materials, 330, 157\u2013164. https:\/\/doi.org\/10.1016\/j.jhazmat.2017.02.009","journal-title":"Journal of Hazardous Materials"},{"issue":"15","key":"2597_CR27","doi-asserted-by":"publisher","first-page":"3131","DOI":"10.1021\/es991414z","volume":"34","author":"HW Langner","year":"2000","unstructured":"Langner, H. W., & Inskeep, W. P. (2000). Microbial reduction of arsenate in the presence of ferrihydrite. Environmental Science & Technology, 34(15), 3131\u20133136. https:\/\/doi.org\/10.1021\/es991414z","journal-title":"Environmental Science & Technology"},{"issue":"23","key":"2597_CR28","doi-asserted-by":"publisher","first-page":"7277","DOI":"10.1021\/es061284b","volume":"40","author":"A-K Leuz","year":"2006","unstructured":"Leuz, A.-K., M\u00f6nch, H., & Johnson, C. A. (2006). Sorption of Sb(III) and Sb(V) to goethite: Influence on Sb(III) oxidation and mobilization. Environmental Science & Technology, 40(23), 7277\u20137282. https:\/\/doi.org\/10.1021\/es061284b","journal-title":"Environmental Science & Technology"},{"key":"2597_CR29","doi-asserted-by":"publisher","first-page":"118935","DOI":"10.1016\/j.envres.2024.118935","volume":"252","author":"Y Liang","year":"2024","unstructured":"Liang, Y., Xiang, Y., Wei, Z., Avena, M., Xiong, J., Hou, J., Wang, M., & Tan, W. (2024). Complexation mechanism of Pb2+ on Al-substituted hematite: A modeling study and theoretical calculation. Environmental Research, 252, 118935. https:\/\/doi.org\/10.1016\/j.envres.2024.118935","journal-title":"Environmental Research"},{"key":"2597_CR30","doi-asserted-by":"publisher","first-page":"148202","DOI":"10.1016\/j.scitotenv.2021.148202","volume":"790","author":"Y Liang","year":"2021","unstructured":"Liang, Y., Yu, D., Jin, J., Xiong, J., Hou, J., Wang, M., & Tan, W. (2021). Microstructure of Al-substituted goethite and its adsorption performance for Pb(II) and As(V). Science of the Total Environment, 790, 148202. https:\/\/doi.org\/10.1016\/j.scitotenv.2021.148202","journal-title":"Science of the Total Environment"},{"issue":"12","key":"2597_CR31","doi-asserted-by":"publisher","first-page":"2837","DOI":"10.3390\/ijerph15122837","volume":"15","author":"H Liu","year":"2018","unstructured":"Liu, H., Pourret, O., Guo, H., Martinez, R. E., & Zouhri, L. (2018). Impact of hydrous manganese and ferric oxides on the behavior of aqueous rare earth elements (REE): Evidence from a modeling approach and implication for the sink of REE. International Journal of Environmental Research and Public Health, 15(12), 2837. https:\/\/doi.org\/10.3390\/ijerph15122837","journal-title":"International Journal of Environmental Research and Public Health"},{"key":"2597_CR32","doi-asserted-by":"publisher","first-page":"124667","DOI":"10.1016\/j.jclepro.2020.124667","volume":"283","author":"J Liu","year":"2021","unstructured":"Liu, J., Zhang, A., Chen, Y., Zhou, X., Zhou, A., & Cao, H. (2021). Bioaccessibility, source impact and probabilistic health risk of the toxic metals in PM2.5 based on lung fluids test and Monte Carlo simulations. Journal of Cleaner Production, 283, 124667. https:\/\/doi.org\/10.1016\/j.jclepro.2020.124667","journal-title":"Journal of Cleaner Production"},{"issue":"16","key":"2597_CR33","doi-asserted-by":"publisher","first-page":"4547","DOI":"10.1016\/j.gca.2011.05.035","volume":"75","author":"P Lu","year":"2011","unstructured":"Lu, P., Nuhfer, N. T., Kelly, S., Li, Q., Konishi, H., Elswick, E., & Zhu, C. (2011). Lead coprecipitation with iron oxyhydroxide nano-particles. Geochimica Et Cosmochimica Acta, 75(16), 4547\u20134561. https:\/\/doi.org\/10.1016\/j.gca.2011.05.035","journal-title":"Geochimica Et Cosmochimica Acta"},{"key":"2597_CR34","doi-asserted-by":"publisher","first-page":"e0170261","DOI":"10.1590\/18069657rbcs20170261","volume":"42","author":"JWV Mello","year":"2018","unstructured":"Mello, J. W. V., Gasparon, M., & Silva, J. (2018). Effectiveness of arsenic co-precipitation with Fe\u2013Al hydroxides for treatment of contaminated water. Revista Brasileira De Ciencia Do Solo, 42, e0170261. https:\/\/doi.org\/10.1590\/18069657rbcs20170261","journal-title":"Revista Brasileira De Ciencia Do Solo"},{"issue":"12","key":"2597_CR35","doi-asserted-by":"publisher","first-page":"668","DOI":"10.1007\/s10661-016-5690-8","volume":"188","author":"VF Melo","year":"2016","unstructured":"Melo, V. F., Batista, A. H., Gilkes, R. J., & Rate, A. W. (2016). Relationship between heavy metals and minerals extracted from soil clay by standard and novel acid extraction procedures. Environmental Monitoring and Assessment, 188(12), 668. https:\/\/doi.org\/10.1007\/s10661-016-5690-8","journal-title":"Environmental Monitoring and Assessment"},{"issue":"1","key":"2597_CR36","doi-asserted-by":"publisher","first-page":"11","DOI":"10.1016\/S1002-0160(20)60017-0","volume":"31","author":"X Mo","year":"2021","unstructured":"Mo, X., Siebecker, M. G., Gou, W., Li, L., & Li, W. (2021). A review of cadmium sorption mechanisms on soil mineral surfaces revealed from synchrotron-based X-ray absorption fine structure spectroscopy: Implications for soil remediation. Pedosphere, 31(1), 11\u201327. https:\/\/doi.org\/10.1016\/S1002-0160(20)60017-0","journal-title":"Pedosphere"},{"issue":"6","key":"2597_CR37","doi-asserted-by":"publisher","first-page":"208","DOI":"10.1007\/s10653-024-02002-6","volume":"46","author":"S Mouttoucomarassamy","year":"2024","unstructured":"Mouttoucomarassamy, S., Virk, H. S., & Dharmalingam, S. N. (2024). Evaluation and health risk assessment of arsenic and potentially toxic elements pollution in groundwater of Majha Belt, Punjab, India. Environmental Geochemistry and Health, 46(6), 208. https:\/\/doi.org\/10.1007\/s10653-024-02002-6","journal-title":"Environmental Geochemistry and Health"},{"key":"2597_CR38","doi-asserted-by":"publisher","first-page":"143577","DOI":"10.1016\/j.scitotenv.2020.143577","volume":"758","author":"Z Ning","year":"2021","unstructured":"Ning, Z., Liu, E., Yao, D., Xiao, T., Ma, L., Liu, Y., Li, H., & Liu, C. (2021). Contamination, oral bioaccessibility and human health risk assessment of thallium and other metal(loid)s in farmland soils around a historic Tl Hg mining area. Science of the Total Environment, 758, 143577. https:\/\/doi.org\/10.1016\/j.scitotenv.2020.143577","journal-title":"Science of the Total Environment"},{"issue":"7","key":"2597_CR39","doi-asserted-by":"publisher","first-page":"1803","DOI":"10.2113\/econgeo.110.7.1803","volume":"110","author":"NHS Oliver","year":"2015","unstructured":"Oliver, N. H. S., Thomson, B., Freitas-Silva, F. H., Holcombe, R. J., Rusk, B., Almeida, B. S., Faure, K., Davidson, G. R., Esper, E. L., Guimar\u00e3es, P. J., & Dardenne, M. A. (2015). Local and regional mass transfer during thrusting, veining, and boudinage in the genesis of the giant shale-hosted Paracatu Gold Deposit, Minas Gerais, Brazil. Economic Geology, 110(7), 1803\u20131834. https:\/\/doi.org\/10.2113\/econgeo.110.7.1803","journal-title":"Economic Geology"},{"issue":"7","key":"2597_CR40","doi-asserted-by":"publisher","first-page":"266","DOI":"10.1007\/s12665-017-6583-z","volume":"76","author":"AG Pietralonga","year":"2017","unstructured":"Pietralonga, A. G., de Mendon\u00e7a, B. A. F., Barcelos, G. S., de Mello, J. W. V., & Abrah\u00e3o, W. A. P. (2017). Lanthanum immobilization by iron and aluminum colloids. Environmental Earth Sciences, 76(7), 266. https:\/\/doi.org\/10.1007\/s12665-017-6583-z","journal-title":"Environmental Earth Sciences"},{"key":"2597_CR41","doi-asserted-by":"publisher","first-page":"156545","DOI":"10.1016\/j.scitotenv.2022.156545","volume":"838","author":"O Pourret","year":"2022","unstructured":"Pourret, O., Bollinger, J.-C., Hursthouse, A., & van Hullebusch, E. D. (2022). Sorption vs adsorption: The words they are a-changin\u2019, not the phenomena. Science of the Total Environment, 838, 156545. https:\/\/doi.org\/10.1016\/j.scitotenv.2022.156545","journal-title":"Science of the Total Environment"},{"issue":"19\u201320","key":"2597_CR42","doi-asserted-by":"publisher","first-page":"2971","DOI":"10.1016\/S0016-7037(99)00263-X","volume":"63","author":"SR Randall","year":"1999","unstructured":"Randall, S. R., Sherman, D. M., Ragnarsdottir, K. V., & Collins, C. R. (1999). The mechanism of cadmium surface complexation on iron oxyhydroxide minerals. Geochimica Et Cosmochimica Acta, 63(19\u201320), 2971\u20132987. https:\/\/doi.org\/10.1016\/S0016-7037(99)00263-X","journal-title":"Geochimica Et Cosmochimica Acta"},{"issue":"1","key":"2597_CR43","doi-asserted-by":"publisher","first-page":"57","DOI":"10.1039\/a807854h","volume":"1","author":"G Rauret","year":"1999","unstructured":"Rauret, G., L\u00f3pez-S\u00e1nchez, J. F., Sahuquillo, A., Rubio, R., Davidson, C., Ure, A., & Quevauviller, Ph. (1999). Improvement of the BCR three step sequential extraction procedure prior to the certification of new sediment and soil reference materials. Journal of Environmental Monitoring, 1(1), 57\u201361. https:\/\/doi.org\/10.1039\/a807854h","journal-title":"Journal of Environmental Monitoring"},{"key":"2597_CR44","doi-asserted-by":"publisher","first-page":"199","DOI":"10.1016\/j.microc.2018.04.006","volume":"140","author":"PS Rezende","year":"2018","unstructured":"Rezende, P. S., Silva, N. C., Moura, W. D., & Windm\u00f6ller, C. C. (2018). Quantification and speciation of mercury in streams and rivers sediment samples from Paracatu, MG, Brazil, using a direct mercury analyzer\u00ae. Microchemical Journal, 140, 199\u2013206. https:\/\/doi.org\/10.1016\/j.microc.2018.04.006","journal-title":"Microchemical Journal"},{"issue":"10","key":"2597_CR45","doi-asserted-by":"publisher","first-page":"1765","DOI":"10.1021\/acsearthspacechem.0c00149","volume":"4","author":"MP Schmidt","year":"2020","unstructured":"Schmidt, M. P., Siciliano, S. D., & Peak, D. (2020). Spectroscopic quantification of inner- and outer-sphere oxyanion complexation kinetics: ionic strength and background cation effect on sulfate adsorption to hematite. ACS Earth and Space Chemistry, 4(10), 1765\u20131776. https:\/\/doi.org\/10.1021\/acsearthspacechem.0c00149","journal-title":"ACS Earth and Space Chemistry"},{"issue":"1","key":"2597_CR46","doi-asserted-by":"publisher","first-page":"36","DOI":"10.1346\/CCMN.1984.0320105","volume":"32","author":"DG Schulze","year":"1984","unstructured":"Schulze, D. G. (1984). The influence of aluminum on iron oxides. VIII. Unit-cell dimensions of Al-substituted goethites and estimation of Al from them. Clays and Clay Minerals, 32(1), 36\u201344. https:\/\/doi.org\/10.1346\/CCMN.1984.0320105","journal-title":"Clays and Clay Minerals"},{"key":"2597_CR47","doi-asserted-by":"publisher","DOI":"10.1002\/9783527613229","volume-title":"Iron oxides in the laboratary","year":"2000","unstructured":"Schwertmann, U., & Cornell, R. M. (Eds.). (2000). Iron oxides in the laboratary. Wiley. https:\/\/doi.org\/10.1002\/9783527613229"},{"key":"2597_CR48","doi-asserted-by":"publisher","first-page":"379","DOI":"10.2136\/sssabookser1.2ed.c8","volume-title":"Iron oxides","author":"U Schwertmann","year":"1989","unstructured":"Schwertmann, U., & Taylor, R. M. (1989). Iron oxides (pp. 379\u2013438). Wiley. https:\/\/doi.org\/10.2136\/sssabookser1.2ed.c8"},{"issue":"1","key":"2597_CR49","doi-asserted-by":"publisher","first-page":"20230065","DOI":"10.1515\/revac-2023-0065","volume":"42","author":"M Senila","year":"2023","unstructured":"Senila, M. (2023). Metal and metalloid monitoring in water by passive sampling\u2013a review. Reviews in Analytical Chemistry, 42(1), 20230065. https:\/\/doi.org\/10.1515\/revac-2023-0065","journal-title":"Reviews in Analytical Chemistry"},{"key":"2597_CR50","doi-asserted-by":"publisher","first-page":"106061","DOI":"10.1016\/j.jfca.2024.106061","volume":"128","author":"M Senila","year":"2024","unstructured":"Senila, M., Resz, M.-A., Torok, I., & Senila, L. (2024). Nutritional composition and health risk of toxic metals of some edible wild mushrooms growing in a mining area of Apuseni Mountains, Western Carpathians. Journal of Food Composition and Analysis, 128, 106061. https:\/\/doi.org\/10.1016\/j.jfca.2024.106061","journal-title":"Journal of Food Composition and Analysis"},{"key":"2597_CR51","doi-asserted-by":"publisher","first-page":"114870","DOI":"10.1016\/j.ecoenv.2023.114870","volume":"256","author":"J Shentu","year":"2023","unstructured":"Shentu, J., Fang, Y., Wang, Y., Cui, Y., & Zhu, M. (2023). Bioaccessibility and reliable human health risk assessment of heavy metals in typical abandoned industrial sites of southeastern China. Ecotoxicology and Environmental Safety, 256, 114870. https:\/\/doi.org\/10.1016\/j.ecoenv.2023.114870","journal-title":"Ecotoxicology and Environmental Safety"},{"issue":"19","key":"2597_CR52","doi-asserted-by":"publisher","first-page":"5684","DOI":"10.1016\/j.watres.2010.06.056","volume":"44","author":"J Silva","year":"2010","unstructured":"Silva, J., Mello, J. W. V., Gasparon, M., Abrah\u00e3o, W. A. P., Ciminelli, V. S. T., & Jong, T. (2010). The role of Al-Goethites on arsenate mobility. Water Research, 44(19), 5684\u20135692. https:\/\/doi.org\/10.1016\/j.watres.2010.06.056","journal-title":"Water Research"},{"key":"2597_CR53","doi-asserted-by":"publisher","first-page":"126544","DOI":"10.1016\/j.jhazmat.2021.126544","volume":"420","author":"TGF Souza","year":"2021","unstructured":"Souza, T. G. F., Freitas, E. T. F., Mohallem, N. D. S., & Ciminelli, V. S. T. (2021). Defects induced by Al substitution enhance As(V) adsorption on ferrihydrites. Journal of Hazardous Materials, 420, 126544. https:\/\/doi.org\/10.1016\/j.jhazmat.2021.126544","journal-title":"Journal of Hazardous Materials"},{"key":"2597_CR54","volume-title":"The chemistry of soils","author":"G Sposito","year":"2008","unstructured":"Sposito, G. (2008). The chemistry of soils (2nd ed.). Oxford University Press.","edition":"2"},{"issue":"6","key":"2597_CR55","doi-asserted-by":"publisher","first-page":"1469","DOI":"10.1007\/s10653-017-9982-x","volume":"39","author":"G Sun","year":"2017","unstructured":"Sun, G., Li, Z., Liu, T., Chen, J., Wu, T., & Feng, X. (2017). Rare earth elements in street dust and associated health risk in a municipal industrial base of central China. Environmental Geochemistry and Health, 39(6), 1469\u20131486. https:\/\/doi.org\/10.1007\/s10653-017-9982-x","journal-title":"Environmental Geochemistry and Health"},{"issue":"1\u20132","key":"2597_CR56","doi-asserted-by":"publisher","first-page":"107","DOI":"10.1016\/S0927-7757(01)00768-3","volume":"191","author":"P Trivedi","year":"2001","unstructured":"Trivedi, P., Axe, L., & Dyer, J. (2001). Adsorption of metal ions onto goethite: Single-adsorbate and competitive systems. Colloids and Surfaces a: Physicochemical and Engineering Aspects, 191(1\u20132), 107\u2013121. https:\/\/doi.org\/10.1016\/S0927-7757(01)00768-3","journal-title":"Colloids and Surfaces a: Physicochemical and Engineering Aspects"},{"key":"2597_CR57","volume-title":"Global mercury assessment","author":"UNEP","year":"2018","unstructured":"UNEP. (2018). Global mercury assessment. UNEP."},{"issue":"1\u20136","key":"2597_CR58","doi-asserted-by":"publisher","first-page":"49","DOI":"10.1007\/BF01245495","volume":"104","author":"AM Ure","year":"1991","unstructured":"Ure, A. M. (1991). Trace element speciation in soils, soil extracts and solutions. Mikrochimica Acta, 104(1\u20136), 49\u201357. https:\/\/doi.org\/10.1007\/BF01245495","journal-title":"Mikrochimica Acta"},{"issue":"1\u20134","key":"2597_CR59","doi-asserted-by":"publisher","first-page":"135","DOI":"10.1080\/03067319308027619","volume":"51","author":"AM Ure","year":"1993","unstructured":"Ure, A. M., Quevauviller, Ph., Muntau, H., & Griepink, B. (1993). Speciation of heavy metals in soils and sediments. An account of the improvement and harmonization of extraction techniques undertaken under the auspices of the BCR of the commission of the European communities. International Journal of Environmental Analytical Chemistry, 51(1\u20134), 135\u2013151. https:\/\/doi.org\/10.1080\/03067319308027619","journal-title":"International Journal of Environmental Analytical Chemistry"},{"key":"2597_CR62","unstructured":"USEPA. (1991). IRIS assessment on inorganic arsenic (CASRN 7440\u201338\u20132)."},{"key":"2597_CR60","volume-title":"Guidance for evaluating the oral bioavailability of metals in soils for use in human health risk assessment","author":"USEPA","year":"2007","unstructured":"USEPA. (2007a). Guidance for evaluating the oral bioavailability of metals in soils for use in human health risk assessment. USEPA."},{"key":"2597_CR63","unstructured":"USEPA. (2007b). Method 3051A (SW-846): Microwave assisted acid digestion of sediments, sludges, soils, and oils. https:\/\/www.epa.gov\/esam\/us-epa-method-3051a-microwave-assisted-acid-digestion-sediments-sludges-and-oils"},{"key":"2597_CR61","volume-title":"Standard operating procedure for an in vitro bioaccessibility assay for lead in soil","author":"USEPA","year":"2008","unstructured":"USEPA. (2008). Standard operating procedure for an in vitro bioaccessibility assay for lead in soil. USEPA."},{"issue":"13","key":"2597_CR64","doi-asserted-by":"publisher","first-page":"12967","DOI":"10.1007\/s11356-018-1458-8","volume":"25","author":"ICF Vasques","year":"2018","unstructured":"Vasques, I. C. F., de Mello, J. W. V., Veloso, R. W., Ferreira, V. P., & Abrah\u00e3o, W. A. P. (2018a). Arsenite removal from contaminated water by precipitation of aluminum, ferrous and ferric (hydr)oxides. Environmental Science and Pollution Research, 25(13), 12967\u201312980. https:\/\/doi.org\/10.1007\/s11356-018-1458-8","journal-title":"Environmental Science and Pollution Research"},{"issue":"6","key":"2597_CR65","doi-asserted-by":"publisher","first-page":"1339","DOI":"10.2134\/jeq2018.01.0014","volume":"47","author":"ICF Vasques","year":"2018","unstructured":"Vasques, I. C. F., de Mello, J. W. V., Veloso, R. W., Ferreira, V. P., & Abrah\u00e3o, W. A. P. (2018b). Effectiveness of ferric, ferrous, and aluminum (hydr)oxide coprecipitation to treat water contaminated with arsenate. Journal of Environmental Quality, 47(6), 1339\u20131346. https:\/\/doi.org\/10.2134\/jeq2018.01.0014","journal-title":"Journal of Environmental Quality"},{"key":"2597_CR66","doi-asserted-by":"publisher","first-page":"159819","DOI":"10.1016\/j.scitotenv.2022.159819","volume":"858","author":"C-C Wang","year":"2023","unstructured":"Wang, C.-C., Zhang, Q.-C., Kang, S.-G., Li, M.-Y., Zhang, M.-Y., Xu, W.-M., Xiang, P., & Ma, L. Q. (2023). Heavy metal(loid)s in agricultural soil from main grain production regions of China: Bioaccessibility and health risks to humans. Science of the Total Environment, 858, 159819. https:\/\/doi.org\/10.1016\/j.scitotenv.2022.159819","journal-title":"Science of the Total Environment"},{"issue":"4\u20135","key":"2597_CR67","doi-asserted-by":"publisher","first-page":"409","DOI":"10.1007\/s11051-005-6931-x","volume":"7","author":"GA Waychunas","year":"2005","unstructured":"Waychunas, G. A., Kim, C. S., & Banfield, J. F. (2005). Nanoparticulate iron oxide minerals in soils and sediments: unique properties and contaminant scavenging mechanisms. Journal of Nanoparticle Research, 7(4\u20135), 409\u2013433. https:\/\/doi.org\/10.1007\/s11051-005-6931-x","journal-title":"Journal of Nanoparticle Research"},{"issue":"22","key":"2597_CR68","doi-asserted-by":"publisher","first-page":"4436","DOI":"10.1021\/es010085j","volume":"35","author":"L Weng","year":"2001","unstructured":"Weng, L., Temminghoff, E. J. M., & Van Riemsdijk, W. H. (2001). Contribution of individual sorbents to the control of heavy metal activity in sandy soil. Environmental Science & Technology, 35(22), 4436\u20134443. https:\/\/doi.org\/10.1021\/es010085j","journal-title":"Environmental Science & Technology"},{"issue":"17","key":"2597_CR69","doi-asserted-by":"publisher","first-page":"11601","DOI":"10.1021\/acs.est.0c06927","volume":"55","author":"X Yan","year":"2021","unstructured":"Yan, X., Zhu, M., Li, W., Peacock, C. L., Ma, J., Wen, H., Liu, F., Zhou, Z., Zhu, C., & Yin, H. (2021). Cadmium isotope fractionation during adsorption and substitution with iron (Oxyhydr)oxides. Environmental Science & Technology, 55(17), 11601\u201311611. https:\/\/doi.org\/10.1021\/acs.est.0c06927","journal-title":"Environmental Science & Technology"},{"issue":"10","key":"2597_CR70","doi-asserted-by":"publisher","first-page":"2768","DOI":"10.1021\/acsearthspacechem.1c00159","volume":"5","author":"M Yang","year":"2021","unstructured":"Yang, M., Liang, X., Li, Y., He, H., Zhu, R., & Arai, Y. (2021). Ferrihydrite transformation impacted by adsorption and structural incorporation of rare earth elements. ACS Earth and Space Chemistry, 5(10), 2768\u20132777. https:\/\/doi.org\/10.1021\/acsearthspacechem.1c00159","journal-title":"ACS Earth and Space Chemistry"},{"issue":"1","key":"2597_CR71","doi-asserted-by":"publisher","first-page":"146","DOI":"10.1038\/s41467-024-55625-9","volume":"16","author":"Z Yang","year":"2025","unstructured":"Yang, Z., Yin, Y., Liang, M., Fu, W., Zhang, J., Liu, F., Zhang, W., & Pan, B. (2025). Incidental iron oxide nanoclusters drive confined Fenton-like detoxification of solid wastes towards sustainable resource recovery. Nature Communications, 16(1), 146. https:\/\/doi.org\/10.1038\/s41467-024-55625-9","journal-title":"Nature Communications"},{"key":"2597_CR72","doi-asserted-by":"publisher","first-page":"1","DOI":"10.1155\/2010\/387803","volume":"2010","author":"AJ Zimmerman","year":"2010","unstructured":"Zimmerman, A. J., & Weindorf, D. C. (2010). Heavy metal and trace metal analysis in soil by sequential extraction: A review of procedures. International Journal of Analytical Chemistry, 2010, 1\u20137. https:\/\/doi.org\/10.1155\/2010\/387803","journal-title":"International Journal of Analytical Chemistry"}],"container-title":["Environmental Geochemistry and Health"],"original-title":[],"language":"en","link":[{"URL":"https:\/\/link.springer.com\/content\/pdf\/10.1007\/s10653-025-02597-4.pdf","content-type":"application\/pdf","content-version":"vor","intended-application":"text-mining"},{"URL":"https:\/\/link.springer.com\/article\/10.1007\/s10653-025-02597-4\/fulltext.html","content-type":"text\/html","content-version":"vor","intended-application":"text-mining"},{"URL":"https:\/\/link.springer.com\/content\/pdf\/10.1007\/s10653-025-02597-4.pdf","content-type":"application\/pdf","content-version":"vor","intended-application":"similarity-checking"}],"deposited":{"date-parts":[[2025,7,4]],"date-time":"2025-07-04T11:54:00Z","timestamp":1751630040000},"score":1,"resource":{"primary":{"URL":"https:\/\/link.springer.com\/10.1007\/s10653-025-02597-4"}},"subtitle":[],"short-title":[],"issued":{"date-parts":[[2025,6,26]]},"references-count":72,"journal-issue":{"issue":"7","published-print":{"date-parts":[[2025,7]]}},"alternative-id":["2597"],"URL":"https:\/\/doi.org\/10.1007\/s10653-025-02597-4","relation":{},"ISSN":["0269-4042","1573-2983"],"issn-type":[{"value":"0269-4042","type":"print"},{"value":"1573-2983","type":"electronic"}],"subject":[],"published":{"date-parts":[[2025,6,26]]},"assertion":[{"value":"10 March 2025","order":1,"name":"received","label":"Received","group":{"name":"ArticleHistory","label":"Article History"}},{"value":"5 June 2025","order":2,"name":"accepted","label":"Accepted","group":{"name":"ArticleHistory","label":"Article History"}},{"value":"26 June 2025","order":3,"name":"first_online","label":"First Online","group":{"name":"ArticleHistory","label":"Article History"}},{"order":1,"name":"Ethics","group":{"name":"EthicsHeading","label":"Declaration"}},{"value":"The authors declare no competing interests.","order":2,"name":"Ethics","group":{"name":"EthicsHeading","label":"Competing interests"}}],"article-number":"285"}}