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Ground-level ozone is a secondary pollutant generated through sunlight-driven reactions between nitrogen oxides (NO<jats:sub>x<\/jats:sub>) and VOCs. Its levels have increased since the industrial revolution and reactions involving ozone drive many chemical processes in the troposphere. While ozone precursors often originate in urban areas, winds may carry these hundreds of kilometres, causing ozone formation to also occur in less populated rural regions. Under elevated ozone conditions, ozonolysis of bVOCs can result in quantitative and qualitative changes in the gas phase, reducing the concentrations of certain bVOCs and resulting in the formation of other compounds. Such changes can result in disruption of bVOC-mediated behavioural or ecological interactions. Through a series of gas-phase experiments using Gas Chromatography Mass Spectrometry (GC-MS) and Proton Transfer Reaction Mass Spectrometry (PTR-MS), we investigated the products and their yields from the ozonolysis of a range of ubiquitous bVOCs, which were selected because of their importance in mediating ecological interactions such as pollinator and natural enemy attraction and plant-to-plant communication, namely: (<jats:italic>E<\/jats:italic>)-\u03b2-ocimene, isomers of \u03b1 and \u03b2-farnesene, \u03b1-terpinene and 6-methyl-5-hepten-2-one. New products from the ozonolysis of these compounds were identified, and the formation of these compounds is consistent with terpene-ozone oxidation mechanisms. We present the degradation mechanism of our model bVOCs and identify their reaction products. We discuss the potential ecological implications of the degradation of each bVOC and of the formation of reaction products.<\/jats:p>","DOI":"10.1007\/s10886-023-01467-6","type":"journal-article","created":{"date-parts":[[2024,1,9]],"date-time":"2024-01-09T19:02:31Z","timestamp":1704826951000},"page":"129-142","update-policy":"https:\/\/doi.org\/10.1007\/springer_crossmark_policy","source":"Crossref","is-referenced-by-count":11,"title":["Atmospheric Degradation of Ecologically Important Biogenic Volatiles: Investigating the Ozonolysis of (E)-\u03b2-Ocimene, Isomers of \u03b1 and \u03b2-Farnesene, \u03b1-Terpinene and 6-Methyl-5-Hepten-2-One, and Their Gas-Phase Products"],"prefix":"10.1007","volume":"50","author":[{"given":"Dalila","family":"Touhami","sequence":"first","affiliation":[],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Adedayo O.","family":"Mofikoya","sequence":"additional","affiliation":[],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Robbie D.","family":"Girling","sequence":"additional","affiliation":[],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Ben","family":"Langford","sequence":"additional","affiliation":[],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Pawel K.","family":"Misztal","sequence":"additional","affiliation":[],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Christian","family":"Pfrang","sequence":"additional","affiliation":[],"role":[{"vocabulary":"crossref","role":"author"}]}],"member":"297","published-online":{"date-parts":[[2024,1,9]]},"reference":[{"key":"1467_CR1","unstructured":"Air Quality Expert Group (2021) Ozone in the UK - recent trends and future projections. https:\/\/uk-air.defra.gov.uk\/library\/reports?report_id=1064.\u00a0Accessed 14 Nov 2023"},{"key":"1467_CR2","doi-asserted-by":"publisher","DOI":"10.1371\/journal.pone.0208825","volume":"13","author":"WJF Acton","year":"2018","unstructured":"Acton WJF, Jud W, Ghirardo A, Wohlfahrt G, Hewitt CN, Taylor JE, Hansel A (2018) The effect of ozone fumigation on the biogenic volatile organic compounds (BVOCs) emitted from Brassica napus above-and below-ground. 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