{"status":"ok","message-type":"work","message-version":"1.0.0","message":{"indexed":{"date-parts":[[2026,4,29]],"date-time":"2026-04-29T00:03:37Z","timestamp":1777421017700,"version":"3.51.4"},"reference-count":65,"publisher":"Springer Science and Business Media LLC","issue":"2","license":[{"start":{"date-parts":[[2014,4,1]],"date-time":"2014-04-01T00:00:00Z","timestamp":1396310400000},"content-version":"tdm","delay-in-days":0,"URL":"https:\/\/www.springernature.com\/gp\/researchers\/text-and-data-mining"},{"start":{"date-parts":[[2014,4,1]],"date-time":"2014-04-01T00:00:00Z","timestamp":1396310400000},"content-version":"vor","delay-in-days":0,"URL":"https:\/\/www.springernature.com\/gp\/researchers\/text-and-data-mining"}],"content-domain":{"domain":["link.springer.com"],"crossmark-restriction":false},"short-container-title":["Orig Life Evol Biosph"],"published-print":{"date-parts":[[2014,4]]},"DOI":"10.1007\/s11084-014-9373-6","type":"journal-article","created":{"date-parts":[[2014,11,21]],"date-time":"2014-11-21T17:31:35Z","timestamp":1416591095000},"page":"143-157","update-policy":"https:\/\/doi.org\/10.1007\/springer_crossmark_policy","source":"Crossref","is-referenced-by-count":9,"title":["Reaction Between CH2 and HCCN: A Theoretical Approach to Acrylonitrile Formation in the Interstellar Medium"],"prefix":"10.1007","volume":"44","author":[{"family":"Shivani","sequence":"first","affiliation":[],"role":[{"role":"author","vocabulary":"crossref"}]},{"given":"Alka","family":"Misra","sequence":"additional","affiliation":[],"role":[{"role":"author","vocabulary":"crossref"}]},{"given":"Poonam","family":"Tandon","sequence":"additional","affiliation":[],"role":[{"role":"author","vocabulary":"crossref"}]}],"member":"297","published-online":{"date-parts":[[2014,11,22]]},"reference":[{"key":"9373_CR1","doi-asserted-by":"publisher","first-page":"1365","DOI":"10.1073\/pnas.55.6.1365","volume":"55","author":"PH Abelson","year":"1966","unstructured":"Abelson PH (1966) Chemical events on the primitive earth. Proc Natl Acad Sci 55:1365\u20131372","journal-title":"Proc Natl Acad Sci"},{"key":"9373_CR2","doi-asserted-by":"publisher","first-page":"493","DOI":"10.1051\/0004-6361:20078956","volume":"479","author":"M Ag\u00fandez","year":"2008","unstructured":"Ag\u00fandez M, Fonfr\u00eda JP, Cernicharo J, Pardo JR, Gu\u00e9lin M (2008) Detection of circumstellar CH2CHCN, CH2CN, CH2CCH, and H2CS. Astron Astrophys 479:493\u2013501","journal-title":"Astron Astrophys"},{"key":"9373_CR3","doi-asserted-by":"publisher","first-page":"2937","DOI":"10.1021\/jp045733a","volume":"109","author":"MP Andersson","year":"2005","unstructured":"Andersson MP, Uvdal P (2005) New scale factors for harmonic vibrational frequencies using the B3LYP density functional method with the triple-\u0153 basis Set 6\u2013311\u2009+\u2009G(d, p). J Phys Chem A 109:2937\u20132941","journal-title":"J Phys Chem A"},{"key":"9373_CR4","doi-asserted-by":"crossref","unstructured":"Barone V (2005) Anharmonic vibrational properties by a fully automated second-order perturbative approach. J. Chem. Phys, 122:014108-1-014108-10","DOI":"10.1063\/1.1824881"},{"key":"9373_CR5","doi-asserted-by":"publisher","first-page":"564","DOI":"10.1086\/161148","volume":"270","author":"DR Bates","year":"1983","unstructured":"Bates DR (1983) Theory of molecular formation by radiative assosiation in interstellar clouds. Astrophys J 270:564\u2013577","journal-title":"Astrophys J"},{"key":"9373_CR6","doi-asserted-by":"publisher","first-page":"5648","DOI":"10.1063\/1.464913","volume":"98","author":"AD Becke","year":"1993","unstructured":"Becke AD (1993) Density-functional thermochemistry. III The Role of Exact Exchange. J Chem Phys 98:5648\u20135652","journal-title":"J Chem Phys"},{"key":"9373_CR7","doi-asserted-by":"publisher","first-page":"365","DOI":"10.1086\/380306","volume":"601","author":"MP Bernstein","year":"2004","unstructured":"Bernstein MP, Ashbourn SFM, Sandford SA, Allamandola LJ (2004) The lifetimes of nitriles (CN) and acids (COOH) during ultraviolet photolysis and their survival in space. Astrophys J 601:365\u2013370","journal-title":"Astrophys J"},{"key":"9373_CR8","doi-asserted-by":"publisher","first-page":"196","DOI":"10.1063\/1.1696454","volume":"43","author":"RA Breinhmin","year":"1965","unstructured":"Breinhmin RA, Kempf RJ, Gramas JV, Skell PS (1965) Electron paramagnetic resonance of triplet alternant methylenes. Propargylene and Homologs. J Chem Phys 43:196\u2013200","journal-title":"J Chem Phys"},{"key":"9373_CR9","unstructured":"Chakrabarti S, Chakrabarti SK (2000) Can DNA bases be produced during molecular cloud collapse? A&A 354:L6\u2013L8"},{"key":"9373_CR10","doi-asserted-by":"publisher","first-page":"11116","DOI":"10.1021\/jp0760758","volume":"111","author":"PK Chattaraj","year":"2007","unstructured":"Chattaraj PK, Giri S (2007) Stability, reactivity and aromaticity of compounds of a multivalent superatom. J Phys Chem A 111:11116\u2013111121","journal-title":"J Phys Chem A"},{"key":"9373_CR11","doi-asserted-by":"publisher","first-page":"294","DOI":"10.1086\/521014","volume":"668","author":"HM Cuppen","year":"2007","unstructured":"Cuppen HM, Herbst E (2007) Simulation of the formation and morphology of Ice mantles on interstellar grains. Astrophys J 668:294\u2013309","journal-title":"Astrophys J"},{"key":"9373_CR12","doi-asserted-by":"publisher","first-page":"545","DOI":"10.1111\/j.1365-2966.2011.19503.x","volume":"418","author":"A Das","year":"2011","unstructured":"Das A, Chakrabarti SK (2011) Composition and evolution of interstellar grain mantle under the effects of photodissociation. MNRAS 418:545\u2013555","journal-title":"MNRAS"},{"key":"9373_CR13","doi-asserted-by":"publisher","first-page":"457","DOI":"10.1016\/j.newast.2008.01.003","volume":"13","author":"A Das","year":"2008","unstructured":"Das A, Chakrabarti SK, Acharyya K, Chakrabarti S (2008) Time evolution of simple molecules during proto-star collapse. NEWA 13:457\u2013467","journal-title":"NEWA"},{"key":"9373_CR14","doi-asserted-by":"publisher","first-page":"4334","DOI":"10.1063\/1.433724","volume":"66","author":"A Dendramis","year":"1977","unstructured":"Dendramis A, Leroi GE (1977) Matrix isolation spectroscopic study of the free radical HCCN. J Chem Phys 66:4334\u20134340","journal-title":"J Chem Phys"},{"key":"9373_CR15","doi-asserted-by":"publisher","first-page":"2138","DOI":"10.1073\/pnas.051502898","volume":"98","author":"P Ehrenfreund","year":"2001","unstructured":"Ehrenfreund P, Glavin DP, Botta O, Cooper G, Bada JL (2001) Extraterrestrial amino acids in Orgueil and Ivuna: tracing the parent body of CI type carbonaceous chondrites. Proc Natl Acad Sci 98:2138\u20132141","journal-title":"Proc Natl Acad Sci"},{"key":"9373_CR16","doi-asserted-by":"publisher","first-page":"1427","DOI":"10.1088\/0034-4885\/65\/10\/202","volume":"65","author":"P Ehrenfreund","year":"2002","unstructured":"Ehrenfreund P, Irvine W, Becker L, Blank J, Brucato JR, Colangeli L, Derenne S, Despois D, Dutrey A, Fraaije H, Lazcano A, Owen T, Robert F, an International Space Science Institute ISSI-Team (2002) Astrophysical and astrochemical insights into the origin of life. Rep Prog Phys 65:1427\u20131487","journal-title":"Rep Prog Phys"},{"key":"9373_CR17","first-page":"88","volume":"262","author":"HK Ervasti","year":"2007","unstructured":"Ervasti HK, Jobst KJ, Gerbaux P, Burgers PC, Ruttink PJA, Terlouw JK (2007) The acrylonitrile dimer ion: A study of its dissociation via self-catalysis, self-protonation and cyclization into the pyrimidine radical cation. Int. J. Mass Spectrom 262:88\u2013100","journal-title":"Mass Spectrom"},{"key":"9373_CR18","doi-asserted-by":"publisher","first-page":"211","DOI":"10.1016\/j.cplett.2009.10.017","volume":"482","author":"HK Ervasti","year":"2009","unstructured":"Ervasti HK, Jobst KJ, Gerbaux P, Burgers PC, Ruttink PJA, Terlouw JK (2009) The reaction of the acrylonitrile ion CH2\u2009=\u2009CH\u2009\u2212\u2009C\u2009\u2261\u2009N\u00b7\u2009+ with HCN: Proton-transport catalysis vs formation of ionized pyrimidine. Chem Phys Let 482:211\u2013216","journal-title":"Chem Phys Let"},{"key":"9373_CR19","doi-asserted-by":"publisher","first-page":"L127","DOI":"10.1086\/181726","volume":"195","author":"FF Gardner","year":"1975","unstructured":"Gardner FF, Winnewisser G (1975) The Detection of interstellar vinyl cyanide (Acrylonitrile). Astrophys J 195:L127\u2013L130","journal-title":"Astrophys J"},{"key":"9373_CR20","doi-asserted-by":"publisher","first-page":"927","DOI":"10.1051\/0004-6361:20065560","volume":"557","author":"RT Garrod","year":"2006","unstructured":"Garrod RT, Herbst E (2006) Formation of methyl formate and other organic species in the warm-Up phase of Hot molecular cores. Astron Astrophys 557:927\u2013936","journal-title":"Astron Astrophys"},{"key":"9373_CR21","doi-asserted-by":"publisher","first-page":"283","DOI":"10.1086\/588035","volume":"682","author":"RT Garrod","year":"2008","unstructured":"Garrod RT, Widicus Weaver SL, Herbst E (2008) Complex chemistry in star-forming regions: an expanded Gas-grain warm-Up chemical model. Astrophys J 682:283\u2013302","journal-title":"Astrophys J"},{"key":"9373_CR22","doi-asserted-by":"crossref","unstructured":"Geerlings P, De Proft F, Langenaeker W (2003) Conceptual Density Functional Theory. Chem Rev, 103-1793-1873","DOI":"10.1021\/cr990029p"},{"key":"9373_CR23","doi-asserted-by":"publisher","first-page":"107","DOI":"10.1063\/1.555589","volume":"8","author":"MCL Gerry","year":"1979","unstructured":"Gerry MCL, Yamada K, Winnewisser G (1979) Microwave spectra of molecules of astrophysical interest: XIV. Vinyl cyanide (acrylonitrile). J Phys Chem Ref Data 8:107\u2013123","journal-title":"J Phys Chem Ref Data"},{"key":"9373_CR24","doi-asserted-by":"publisher","first-page":"455","DOI":"10.1089\/ast.2006.0112","volume":"7","author":"R Glaser","year":"2007","unstructured":"Glaser R, Hodgen B, Farrelly D, McKee E (2007) Adenine synthesis in interstellar space: mechanisms of prebiotic pyrimidine-ring formation of monocyclic HCN-pentamers. Astrobiology 7:455\u201370","journal-title":"Astrobiology"},{"key":"9373_CR25","doi-asserted-by":"publisher","first-page":"10","DOI":"10.1016\/j.ijms.2008.07.001","volume":"278","author":"K Gluch","year":"2008","unstructured":"Gluch K, Cytawa J, Michalak L (2008) Electron impact ionization of acrylonitrile. Int J Mass Spectrom 278:10\u201314","journal-title":"Int J Mass Spectrom"},{"key":"9373_CR26","unstructured":"Guelin M, Cernicharo J (1991) Astronomical detection of the HCCN radical. Towards a new family of carbon-chain molecules?. ApJ, 244:21\u201324"},{"key":"9373_CR27","doi-asserted-by":"publisher","first-page":"A129","DOI":"10.1051\/0004-6361\/201015557","volume":"528","author":"VP Gupta","year":"2011","unstructured":"Gupta VP, Tandon P, Rawat P, Singh RN, Singh A (2011) Quantum chemical study of a new reaction pathway for the adenine formation in the interstellar space. Astron Astrophys 528:A129\u2013A134","journal-title":"Astron Astrophys"},{"key":"9373_CR28","doi-asserted-by":"publisher","first-page":"167","DOI":"10.1086\/191713","volume":"82","author":"TI Hasegawa","year":"1992","unstructured":"Hasegawa TI, Herbst E, Leung CH (1992) Models of gas-grain chemistry in dense interstellar clouds with complex organic molecules. ApJS 82:167\u2013195","journal-title":"ApJS"},{"key":"9373_CR29","doi-asserted-by":"publisher","first-page":"127","DOI":"10.1016\/0168-1176(86)80014-3","volume":"73","author":"M Heni","year":"1986","unstructured":"Heni M, Illenberger E (1986) Electron attachment by saturated nitriles, acrylonitrile (C2H3CN), and benzonitrile (C6H5CN). Int J Mass Spectrom 73:127\u2013144, Ion Processes","journal-title":"Int J Mass Spectrom"},{"key":"9373_CR30","doi-asserted-by":"publisher","first-page":"168","DOI":"10.1039\/a909040a","volume":"30","author":"E Herbst","year":"2001","unstructured":"Herbst E (2001) The Chemistry of Interstellar Space. Chem Soc Rev 30:168\u2013176","journal-title":"Chem Soc Rev"},{"key":"9373_CR31","doi-asserted-by":"publisher","first-page":"505","DOI":"10.1086\/152436","volume":"185","author":"E Herbst","year":"1973","unstructured":"Herbst E, Klemberer W (1973) The formation and depletion of molecules in dense interstellar clouds. Astrophys J 185:505\u2013533","journal-title":"Astrophys J"},{"key":"9373_CR32","doi-asserted-by":"publisher","first-page":"271","DOI":"10.1086\/191314","volume":"69","author":"E Herbst","year":"1989","unstructured":"Herbst E, Leung CM (1989) Gas-phase production of complex hydrocarbons, cyanopolyynes, and related compounds in dense interstellar clouds. ApJS 69:271\u2013300","journal-title":"ApJS"},{"key":"9373_CR33","doi-asserted-by":"publisher","first-page":"259","DOI":"10.1086\/175070","volume":"438","author":"JM Hollis","year":"1995","unstructured":"Hollis JM, Jewell PR, Lovas FJ (1995) Confirmation of interstellar methylene. Astrophys J 438:259\u2013264","journal-title":"Astrophys J"},{"key":"9373_CR34","doi-asserted-by":"publisher","first-page":"17354","DOI":"10.1021\/j100048a008","volume":"99","author":"M Ichihashi","year":"1995","unstructured":"Ichihashi M, Tsukuda T, Nonose S, Kondow TJ (1995) Collision-induced dissociation of acrylonitrile cluster ions: geometrical structure of polymerized cluster anion. Phys Chem 99:17354\u201317358","journal-title":"Phys Chem"},{"key":"9373_CR35","doi-asserted-by":"publisher","first-page":"243","DOI":"10.1016\/j.cplett.2007.11.039","volume":"450","author":"KJ Jobst","year":"2008","unstructured":"Jobst KJ, Hasan SA, Terlouw JK (2008) Does the ion-molecule reaction between HC\u2009\u2261\u2009CH\u02d9+ and HCN lead to CH2\u2009=\u2009CH-C\u2009\u2261\u2009N\u02d9+? A computational and experimental study of the reverse process. Chem Phys Let 450:243\u2013247","journal-title":"Chem Phys Let"},{"key":"9373_CR36","doi-asserted-by":"publisher","first-page":"3873","DOI":"10.5012\/bkcs.2011.32.11.3873","volume":"32","author":"SH Jung","year":"2011","unstructured":"Jung SH, Lee G-H, Choe JC (2011) Isomerization and dissociation of the acrylonitrile radical cation: a theoretical study. Bull Korean Chem Soc 32:3873\u20133879","journal-title":"Bull Korean Chem Soc"},{"key":"9373_CR37","doi-asserted-by":"publisher","first-page":"1575","DOI":"10.1063\/1.1700219","volume":"20","author":"D Kivelson","year":"1952","unstructured":"Kivelson D, Wilson EB (1952) Approximate treatment of the effect of centrifugal distortion on the rotational energy levels of asymmetric-rotor molecules. J Chem Phys 20:1575\u20131579","journal-title":"J Chem Phys"},{"key":"9373_CR38","doi-asserted-by":"crossref","unstructured":"Laas JC, Garrod RT, Herbst E., Widicus Weaver S. L. (2011) Contributions From Grain Surface And Gas Phase Chemistry To The Formation Of Methyl Formate And Its Structural Isomers. ApJ, 728(1):71(9\u00a0pp)","DOI":"10.1088\/0004-637X\/728\/1\/71"},{"key":"9373_CR39","doi-asserted-by":"publisher","first-page":"785","DOI":"10.1103\/PhysRevB.37.785","volume":"37B","author":"CT Lee","year":"1988","unstructured":"Lee CT, Yang WT, Parr RG (1988) Development of the Colle-Salvetti correlation-energy formula into a functional of the electron-density. Phys Rev 37B:785\u2013789","journal-title":"Phys Rev"},{"key":"9373_CR40","first-page":"1613","volume":"12","author":"L Majumdar","year":"2012","unstructured":"Majumdar L, Das A, Chakrabarti SK, Chakrabarti S (2012) Hydro-chemical study of the evolution of interstellar pre-biotic molecules during the collapse of molecular clouds. RAA 12:1613\u20131624","journal-title":"RAA"},{"key":"9373_CR41","doi-asserted-by":"publisher","first-page":"15","DOI":"10.1016\/j.newast.2012.09.002","volume":"20","author":"L Majumdar","year":"2013","unstructured":"Majumdar L, Das A, Chakrabarti SK, Chakrabarti S (2013) Study of the chemical evolution and spectral signatures of some interstellar precursor molecules of adenine, glycine alanine. NEWA 20:15\u201323","journal-title":"NEWA"},{"key":"9373_CR42","volume-title":"GAR2PED","author":"JML Martin","year":"1995","unstructured":"Martin JML, Van Alsenoy C (1995) GAR2PED. University of Antwerp, Computer Software"},{"key":"9373_CR43","doi-asserted-by":"publisher","first-page":"149","DOI":"10.1086\/161271","volume":"272","author":"HE Matthews","year":"1983","unstructured":"Matthews HE, Sears TJ (1983) The detection of Vinyl Cyanide in TMC-1. Astrophys J 272:149\u2013153","journal-title":"Astrophys J"},{"issue":"10","key":"9373_CR44","doi-asserted-by":"publisher","first-page":"1795","DOI":"10.1139\/p65-173","volume":"43","author":"AJ Merer","year":"1965","unstructured":"Merer AJ, Travis DN (1965) Absorption spectrum of the CCN radical. Can J Phys 43(10):1795\u20131830","journal-title":"Can J Phys"},{"key":"9373_CR45","doi-asserted-by":"publisher","first-page":"319","DOI":"10.1016\/j.jms.2008.03.016","volume":"251","author":"HSP Muller","year":"2008","unstructured":"Muller HSP, Belloche A, Menten KM, Comito C, Schilke P (2008) Rotational spectroscopy of isotopic vinyl cyanide, H2CCHCN, in the laboratory and in space. J Mol Spectectrosc 251:319\u2013325","journal-title":"J Mol Spectectrosc"},{"key":"9373_CR46","doi-asserted-by":"crossref","unstructured":"Orgel LE (2004) Prebiotic chemistry and origin of the RNA world. Biochem Mol Biol 39:99\u2013123","DOI":"10.1080\/10409230490460765"},{"key":"9373_CR47","doi-asserted-by":"publisher","first-page":"7512","DOI":"10.1021\/ja00364a005","volume":"105","author":"RG Parr","year":"1983","unstructured":"Parr RG, Pearson RG (1983) Absolute hardness: comparison parameter to absolute electronegativity. J Am Chem Soc 105:7512\u20137516","journal-title":"J Am Chem Soc"},{"key":"9373_CR48","volume-title":"Density functional theory of atoms and molecules","author":"RG Parr","year":"1989","unstructured":"Parr RG, Yang W (1989) Density functional theory of atoms and molecules. Oxford University Press, Oxford"},{"key":"9373_CR49","doi-asserted-by":"publisher","first-page":"1922","DOI":"10.1021\/ja983494x","volume":"121","author":"RG Parr","year":"1999","unstructured":"Parr RG, Szentpaly L, Lui S (1999) Electrophilicity index. J Am Chem Soc 121:1922\u20131924","journal-title":"J Am Chem Soc"},{"key":"9373_CR50","doi-asserted-by":"publisher","first-page":"438","DOI":"10.1093\/mnras\/257.3.438","volume":"257","author":"S Petrie","year":"1992","unstructured":"Petrie S, Freeman CG, McEwan MJ (1992) The ion-molecule chemistry of acrylonitrile - Astrochemical implications. Mon Not R Astr Soc 257:438\u2013444","journal-title":"Mon Not R Astr Soc"},{"key":"9373_CR51","doi-asserted-by":"crossref","unstructured":"Polehampton ET, Menten KM, Br\u00fcnken S, Winnewisser G, Baluteau J-P (2005) Far-infrared detection of methylene A&A 431:203\u2013213","DOI":"10.1051\/0004-6361:20041598"},{"key":"9373_CR52","doi-asserted-by":"publisher","first-page":"81","DOI":"10.1016\/0016-7037(82)90293-9","volume":"46","author":"F Robert","year":"1982","unstructured":"Robert F, Epstein S (1982) The concentration and isotopic composition of hydrogen, carbon and nitrogen in carbonaceous meteorites Geochim. Cosmochim Acta 46:81\u201385","journal-title":"Cosmochim Acta"},{"key":"9373_CR53","doi-asserted-by":"publisher","first-page":"16502","DOI":"10.1021\/jp960976r","volume":"100","author":"AP Scott","year":"1996","unstructured":"Scott AP, Radom L (1996) Reported energies include zero-point energy corrections scaled by 0.9806. J Phys Chem 100:16502\u201316513","journal-title":"J Phys Chem"},{"key":"9373_CR54","doi-asserted-by":"publisher","first-page":"713","DOI":"10.1007\/s11224-012-0112-1","volume":"24","author":"RN Singh","year":"2013","unstructured":"Singh RN, Amit K, Tiwari RK, Poonam R, Rajiv M (2013) Synthesis, molecular structure, and spectral analyses of ethyl-4-[(2,4-dinitrophenyl)-hydrazonomethyl]-3,5-dimethyl-1H-pyrrole-2-carboxylate. Struct Chem 24:713\u2013724","journal-title":"Struct Chem"},{"key":"9373_CR55","first-page":"275","volume":"14","author":"A Singh","year":"2014","unstructured":"Singh A, Shivani MA, Tandon P (2014) Formation of cyanoallene (buta-2, 3-dienenitrile) in the interstellar medium: a quantum chemical and spectroscopic study. RAA 14:275\u2013284","journal-title":"RAA"},{"key":"9373_CR56","doi-asserted-by":"publisher","first-page":"12243","DOI":"10.1073\/pnas.0601750103","volume":"103","author":"LE Snyder","year":"2006","unstructured":"Snyder LE (2006) Interferometric observations of large biologically interesting interstellar and cometary molecules. PNAS 103:12243\u201312248","journal-title":"PNAS"},{"key":"9373_CR57","doi-asserted-by":"publisher","first-page":"8382","DOI":"10.1021\/ja00071a054","volume":"115","author":"J Sun","year":"1993","unstructured":"Sun J, Gr\u00fctzmacher HF, Lifshitz CJ (1993) Ion\/molecule reactions of carbon cluster ions and acrylonitrile. J Am Chem Soc 115:8382\u20138388","journal-title":"J Am Chem Soc"},{"key":"9373_CR58","doi-asserted-by":"publisher","first-page":"791","DOI":"10.1086\/307914","volume":"525","author":"N Takagi","year":"1999","unstructured":"Takagi N, Fukuzawa K, Osamura Y, Schaefer HF III (1999) Ion-molecule reactions producing HC3NH+ in interstellar space: forbiddenness of the reaction between cyclic C3H3\n                  + and the N atom. ApJ 525:791\u2013798","journal-title":"ApJ"},{"key":"9373_CR59","unstructured":"NTP Technical Report (2001) Toxicology And Carcinogenesis Studies Of Acrylonitrile (CAS No.107-13-1), 1\u2013197"},{"key":"9373_CR60","doi-asserted-by":"publisher","first-page":"317","DOI":"10.1088\/0004-637X\/695\/1\/317","volume":"695","author":"E Vigren","year":"2009","unstructured":"Vigren E, Hamberg M, Zhaunerchyk V, Kaminska M, Thomas RD, Larsson M, Millar TJ, Walsh C, Geppert WD (2009) The dissociative recombination of protonated acrylonitrile, Ch2chcnh+, with implications for the nitrile chemistry in dark molecular clouds and the upper atmosphere of titan. Astrophys J 695:317\u2013324","journal-title":"Astrophys J"},{"key":"9373_CR61","doi-asserted-by":"publisher","first-page":"175","DOI":"10.1086\/507467","volume":"647","author":"V Vuitton","year":"2006","unstructured":"Vuitton V, Yelle RV, Anicich VG (2006) The nitrogen chemistry of Titan\u2019s upper atmosphere revealed. ApJL 647:175\u2013178","journal-title":"ApJL"},{"key":"9373_CR62","doi-asserted-by":"publisher","first-page":"1","DOI":"10.1016\/0022-2852(73)90131-8","volume":"48","author":"G Winnewisser","year":"1973","unstructured":"Winnewisser G, Gerry MCL (1973) Microwave spectrum and centrifugal distortion constants of vinyl cyanide. J Mol Spectrosc 48:1\u201316","journal-title":"J Mol Spectrosc"},{"key":"9373_CR63","first-page":"67","volume":"331","author":"DE Woon","year":"2006","unstructured":"Woon DE (2006) Modeling chemical growth processes in Titan\u2019s atmosphere: theoretical rates for reactions between benzene and the ethynyl (C2H) and cyano (CN) radicals at low temperature and pressure. Chemphys 331:67\u201376","journal-title":"Chemphys"},{"key":"9373_CR64","doi-asserted-by":"publisher","first-page":"642","DOI":"10.1016\/j.icarus.2009.02.028","volume":"202","author":"DE Woon","year":"2009","unstructured":"Woon DE, Park J-Y (2009) Modeling chemical growth processes in Titan\u2019s atmosphere 2. Theoretical study of reactions between C2H and ethene, propene, 1-butene, 2-butene, isobutene, trimethylethene, and tetramethylethene. ICARUS 202:642\u2013655","journal-title":"ICARUS"},{"key":"9373_CR65","doi-asserted-by":"publisher","first-page":"110","DOI":"10.1016\/S1044-0305(02)00819-X","volume":"14","author":"YY Youn","year":"2003","unstructured":"Youn YY, Choe JC, Kim MS (2003) Discovery of long-lived excited electronic states of vinylchloride, vinylbromide, vinyliodide, and acrylonitrile cations. Am Soc Mass Spectrom 14:110\u2013116","journal-title":"Am Soc Mass Spectrom"}],"container-title":["Origins of Life and Evolution of Biospheres"],"original-title":[],"language":"en","link":[{"URL":"https:\/\/link.springer.com\/content\/pdf\/10.1007\/s11084-014-9373-6.pdf","content-type":"application\/pdf","content-version":"vor","intended-application":"text-mining"},{"URL":"https:\/\/link.springer.com\/article\/10.1007\/s11084-014-9373-6\/fulltext.html","content-type":"text\/html","content-version":"vor","intended-application":"text-mining"},{"URL":"http:\/\/link.springer.com\/content\/pdf\/10.1007\/s11084-014-9373-6","content-type":"unspecified","content-version":"vor","intended-application":"similarity-checking"},{"URL":"https:\/\/link.springer.com\/content\/pdf\/10.1007\/s11084-014-9373-6.pdf","content-type":"application\/pdf","content-version":"vor","intended-application":"similarity-checking"}],"deposited":{"date-parts":[[2024,1,2]],"date-time":"2024-01-02T17:12:06Z","timestamp":1704215526000},"score":1,"resource":{"primary":{"URL":"https:\/\/link.springer.com\/10.1007\/s11084-014-9373-6"}},"subtitle":[],"short-title":[],"issued":{"date-parts":[[2014,4]]},"references-count":65,"journal-issue":{"issue":"2","published-print":{"date-parts":[[2014,4]]}},"alternative-id":["9373"],"URL":"https:\/\/doi.org\/10.1007\/s11084-014-9373-6","relation":{},"ISSN":["0169-6149","1573-0875"],"issn-type":[{"value":"0169-6149","type":"print"},{"value":"1573-0875","type":"electronic"}],"subject":[],"published":{"date-parts":[[2014,4]]},"assertion":[{"value":"27 June 2014","order":1,"name":"received","label":"Received","group":{"name":"ArticleHistory","label":"Article History"}},{"value":"26 October 2014","order":2,"name":"accepted","label":"Accepted","group":{"name":"ArticleHistory","label":"Article History"}},{"value":"22 November 2014","order":3,"name":"first_online","label":"First Online","group":{"name":"ArticleHistory","label":"Article History"}},{"value":"This content has been made available to all.","name":"free","label":"Free to read"}]}}