{"status":"ok","message-type":"work","message-version":"1.0.0","message":{"indexed":{"date-parts":[[2026,11,10]],"date-time":"2026-11-10T00:38:14Z","timestamp":1794271094376,"version":"4.9.0"},"reference-count":72,"publisher":"Springer Science and Business Media LLC","issue":"9","license":[{"start":{"date-parts":[[2022,11,7]],"date-time":"2022-11-07T00:00:00Z","timestamp":1667779200000},"content-version":"tdm","delay-in-days":0,"URL":"https:\/\/www.springernature.com\/gp\/researchers\/text-and-data-mining"},{"start":{"date-parts":[[2022,11,7]],"date-time":"2022-11-07T00:00:00Z","timestamp":1667779200000},"content-version":"vor","delay-in-days":0,"URL":"https:\/\/www.springernature.com\/gp\/researchers\/text-and-data-mining"}],"content-domain":{"domain":["link.springer.com"],"crossmark-restriction":false},"short-container-title":["Environ Sci Pollut Res"],"DOI":"10.1007\/s11356-022-23832-w","type":"journal-article","created":{"date-parts":[[2022,11,7]],"date-time":"2022-11-07T08:10:54Z","timestamp":1667808654000},"page":"24575-24589","update-policy":"https:\/\/doi.org\/10.1007\/springer_crossmark_policy","source":"Crossref","is-referenced-by-count":8,"title":["Enhanced photocatalytic activity of hydrozincite-TiO2 nanocomposite by copper for removal of pharmaceutical pollutant mefenamic acid in aqueous solution"],"prefix":"10.1007","volume":"30","author":[{"given":"Lekbira","family":"EL Mersly","sequence":"first","affiliation":[],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"EL Mountassir","family":"EL Mouchtari","sequence":"additional","affiliation":[],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"El Mostafa","family":"Moujahid","sequence":"additional","affiliation":[],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Samir","family":"Briche","sequence":"additional","affiliation":[],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Abdelaaziz","family":"Alaoui Tahiri","sequence":"additional","affiliation":[],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Claude","family":"Forano","sequence":"additional","affiliation":[],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Vanessa","family":"Pr\u00e9vot","sequence":"additional","affiliation":[],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0003-3126-7157","authenticated-orcid":false,"given":"Salah","family":"Rafqah","sequence":"additional","affiliation":[],"role":[{"vocabulary":"crossref","role":"author"}]}],"member":"297","published-online":{"date-parts":[[2022,11,7]]},"reference":[{"key":"23832_CR1","doi-asserted-by":"publisher","first-page":"331","DOI":"10.1016\/j.jpha.2014.04.003","volume":"4","author":"H Abdolmohammad-Zadeh","year":"2014","unstructured":"Abdolmohammad-Zadeh H, Morshedzadeh F, Rahimpour E (2014) Trace analysis of mefenamic acid in human serum and pharmaceutical wastewater samples after pre-concentration with Ni\u2013Al layered double hydroxide nano-particles. Journal of Pharmaceutical Analysis 4:331\u2013338. https:\/\/doi.org\/10.1016\/j.jpha.2014.04.003","journal-title":"Journal of Pharmaceutical Analysis"},{"key":"23832_CR2","unstructured":"Ansari R, Mosayebzadeh Z (2010) Removal of Eosin Y, an anionic dye, from aqueous solutions using conducting electroactive polymers. Polymer Journal 541\u2013551"},{"key":"23832_CR3","doi-asserted-by":"publisher","first-page":"13","DOI":"10.1007\/s10311-009-0239-5","volume":"9","author":"L Araujo","year":"2011","unstructured":"Araujo L, Villa N, Camargo N et al (2011) Persistence of gemfibrozil, naproxen and mefenamic acid in natural waters. Environ Chem Lett 9:13\u201318. https:\/\/doi.org\/10.1007\/s10311-009-0239-5","journal-title":"Environ Chem Lett"},{"key":"23832_CR4","doi-asserted-by":"publisher","first-page":"2081","DOI":"10.1039\/c4nj00051j","volume":"38","author":"K Assaker","year":"2014","unstructured":"Assaker K, Carteret C, Roques-Carmes T et al (2014) Influence of Zn ion addition on the properties of ordered mesoporous TiO2. New J Chem 38:2081. https:\/\/doi.org\/10.1039\/c4nj00051j","journal-title":"New J Chem"},{"key":"23832_CR5","doi-asserted-by":"publisher","first-page":"12585","DOI":"10.1007\/s11356-015-4537-0","volume":"22","author":"P Chen","year":"2015","unstructured":"Chen P, Lv W, Chen Z et al (2015) Phototransformation of mefenamic acid induced by nitrite ions in water: mechanism, toxicity, and degradation pathways. Environ Sci Pollut Res 22:12585\u201312596. https:\/\/doi.org\/10.1007\/s11356-015-4537-0","journal-title":"Environ Sci Pollut Res"},{"key":"23832_CR6","doi-asserted-by":"publisher","first-page":"203","DOI":"10.1007\/s00128-015-1680-8","volume":"96","author":"P Chen","year":"2016","unstructured":"Chen P, Wang FL, Yao K et al (2016a) Photodegradation of mefenamic acid in aqueous media: kinetics, toxicity, and photolysis products. Bull Environ Contam Toxicol 96:203\u2013209. https:\/\/doi.org\/10.1007\/s00128-015-1680-8","journal-title":"Bull Environ Contam Toxicol"},{"key":"23832_CR7","doi-asserted-by":"publisher","first-page":"203","DOI":"10.1007\/s00128-015-1680-8","volume":"96","author":"P Chen","year":"2016","unstructured":"Chen P, Wang FL, Yao K et al (2016b) Photodegradation of mefenamic acid in aqueous media: kinetics, toxicity and photolysis products. Bull Environ Contam Toxicol 96:203\u2013209. https:\/\/doi.org\/10.1007\/s00128-015-1680-8","journal-title":"Bull Environ Contam Toxicol"},{"key":"23832_CR8","doi-asserted-by":"publisher","first-page":"360","DOI":"10.1107\/S2052520617001664","volume":"73","author":"S Cherepanova","year":"2017","unstructured":"Cherepanova S, Markovskaya D, Kozlova E (2017) Identification of a deleterious phase in photocatalyst based on Cd 1\u2013x Zn x S\/Zn(OH) 2 by simulated XRD patterns. Acta Crystallogr B Struct Sci Cryst Eng Mater 73:360\u2013368. https:\/\/doi.org\/10.1107\/S2052520617001664","journal-title":"Acta Crystallogr B Struct Sci Cryst Eng Mater"},{"key":"23832_CR9","doi-asserted-by":"publisher","first-page":"206","DOI":"10.1016\/j.jenvman.2015.11.029","volume":"167","author":"R Colombo","year":"2016","unstructured":"Colombo R, Ferreira TCR, Ferreira RA, Lanza MRV (2016) Removal of mefenamic acid from aqueous solutions by oxidative process: Optimization through experimental design and HPLC\/UV analysis. J Environ Manage 167:206\u2013213. https:\/\/doi.org\/10.1016\/j.jenvman.2015.11.029","journal-title":"J Environ Manage"},{"key":"23832_CR10","doi-asserted-by":"publisher","first-page":"1658","DOI":"10.1007\/s11664-016-5209-7","volume":"46","author":"JC Contreras-Ruiz","year":"2017","unstructured":"Contreras-Ruiz JC, Mart\u00ednez-Gallegos S, Ordo\u00f1ez E et al (2017) Synthesis of hydroxide\u2013TiO2 compounds with photocatalytic activity for degradation of phenol. Journal of Elec Materi 46:1658\u20131668. https:\/\/doi.org\/10.1007\/s11664-016-5209-7","journal-title":"Journal of Elec Materi"},{"key":"23832_CR11","doi-asserted-by":"publisher","unstructured":"de Melo da Silva L, Pereira Cavalcante R, Fabbro Cunha R, et al (2016) Tolfenamic acid degradation by direct photolysis and the UV-ABC\/H2O2 process: factorial design, kinetics, identification of intermediates, and toxicity evaluation. Sci Total Environ 573:518\u2013531. https:\/\/doi.org\/10.1016\/j.scitotenv.2016.08.139","DOI":"10.1016\/j.scitotenv.2016.08.139"},{"key":"23832_CR12","doi-asserted-by":"publisher","first-page":"223","DOI":"10.1016\/j.apcatb.2003.10.015","volume":"48","author":"A de Paola","year":"2004","unstructured":"de Paola A, Garc\u0131\u0301a-L\u00f3pez E, Marci G et al (2004) Surface characterisation of metal ions loaded TiO2 photocatalysts: structure\u2013activity relationship. Appl Catalys B: Environ 48:223\u2013233. https:\/\/doi.org\/10.1016\/j.apcatb.2003.10.015","journal-title":"Appl Catalys B: Environ"},{"key":"23832_CR13","doi-asserted-by":"publisher","first-page":"87","DOI":"10.1016\/S0920-5861(02)00048-2","volume":"75","author":"A Di Paola","year":"2002","unstructured":"Di Paola A, Garc\u0131\u0301a-L\u00f3pez E, Marci G et al (2002) Photocatalytic degradation of organic compounds in aqueous systems by transition metal doped polycrystalline TiO2. Catalysis Today 75:87\u201393. https:\/\/doi.org\/10.1016\/S0920-5861(02)00048-2","journal-title":"Catalysis Today"},{"key":"23832_CR14","doi-asserted-by":"publisher","first-page":"118","DOI":"10.1016\/j.jsamd.2020.08.002","volume":"6","author":"L EL Mersly","year":"2021","unstructured":"EL Mersly L, El Mouchtari EM, Moujahid EM et al (2021) ZnCr-LDHs with dual adsorption and photocatalysis capability for the removal of acid orange 7 dye in aqueous solution. J Sci: Adv Mater Dev 6:118\u2013126. https:\/\/doi.org\/10.1016\/j.jsamd.2020.08.002","journal-title":"J Sci: Adv Mater Dev"},{"key":"23832_CR15","doi-asserted-by":"publisher","first-page":"113985","DOI":"10.1016\/j.jphotochem.2022.113985","volume":"430","author":"L EL Mersly","year":"2022","unstructured":"EL Mersly L, EL Mouchtari EM, Zefzoufi M et al (2022) Kinetics, mechanism studies and antibacterial activity of pharmaceutical sulfaguanidine under light irradiation in aqueous solution. J Photochem Photobiol A: Chem 430:113985. https:\/\/doi.org\/10.1016\/j.jphotochem.2022.113985","journal-title":"J Photochem Photobiol A: Chem"},{"key":"23832_CR16","doi-asserted-by":"publisher","DOI":"10.1016\/j.jphotochem.2019.112183","volume":"388","author":"EM El Mouchtari","year":"2020","unstructured":"El Mouchtari EM, Daou C, Rafqah S et al (2020) TiO2 and activated carbon of Argania Spinosa tree nutshells composites for the adsorption photocatalysis removal of pharmaceuticals from aqueous solution. J Photochem Photobiol, A 388:112183. https:\/\/doi.org\/10.1016\/j.jphotochem.2019.112183","journal-title":"J Photochem Photobiol, A"},{"key":"23832_CR17","doi-asserted-by":"publisher","first-page":"135","DOI":"10.1007\/s41742-020-00300-2","volume":"15","author":"EM El Mouchtari","year":"2021","unstructured":"El Mouchtari EM, Bahsis L, El Mersly L et al (2021) Insights in the aqueous and adsorbed photocatalytic degradation of carbamazepine by a biosourced composite: kinetics, mechanisms and DFT calculations. Int J Environ Res 15:135\u2013147. https:\/\/doi.org\/10.1007\/s41742-020-00300-2","journal-title":"Int J Environ Res"},{"key":"23832_CR18","doi-asserted-by":"crossref","unstructured":"Freundlich HMF (1906) \u00fcber die adsorption in losungen (Adsorption in Solution). Zeitschrift f\u00fcr Physimalato kalische Chemie 385\u2013490","DOI":"10.1515\/zpch-1907-5723"},{"key":"23832_CR19","doi-asserted-by":"publisher","first-page":"1051","DOI":"10.1107\/S0365110X64002651","volume":"17","author":"S Ghose","year":"1964","unstructured":"Ghose S (1964) The crystal structure of hydrozincite, Zn 5 (OH) 6 (CO 3) 2. Acta Cryst 17:1051\u20131057. https:\/\/doi.org\/10.1107\/S0365110X64002651","journal-title":"Acta Cryst"},{"key":"23832_CR20","unstructured":"Gimeno O, Rivas J, Encinas A, Beltran F (2010) Application of advanced oxidation processes to mefenamic acid elimination. Eng Technol Int J Nucl Quantum Eng 399\u2013401"},{"key":"23832_CR21","doi-asserted-by":"publisher","first-page":"1553","DOI":"10.1897\/06-495R.1","volume":"26","author":"M Gros","year":"2007","unstructured":"Gros M, Petrovi\u0107 M, Barcel\u00f3 D (2007) Wastewater treatment plants as a pathway for aquatic contamination by pharmaceuticals in the Ebro River Basin (Northeast Spain). Environ Toxicol Chem 26:1553. https:\/\/doi.org\/10.1897\/06-495R.1","journal-title":"Environ Toxicol Chem"},{"key":"23832_CR22","doi-asserted-by":"publisher","first-page":"453","DOI":"10.1016\/j.jpcs.2003.08.030","volume":"65","author":"M Intissar","year":"2004","unstructured":"Intissar M, Holler S, Malherbe F et al (2004) Incorporation of Ti4+ into layered double hydroxide sheets? The response by X-ray diffraction and absorption study. J Phys Chem Solids 65:453\u2013457. https:\/\/doi.org\/10.1016\/j.jpcs.2003.08.030","journal-title":"J Phys Chem Solids"},{"key":"23832_CR23","doi-asserted-by":"publisher","first-page":"121","DOI":"10.1016\/j.cattod.2016.11.021","volume":"284","author":"C Jaramillo-P\u00e1ez","year":"2017","unstructured":"Jaramillo-P\u00e1ez C, Nav\u00edo JA, Hidalgo MC, Mac\u00edas M (2017) High UV-photocatalytic activity of ZnO and Ag\/ZnO synthesized by a facile method. Catal Today 284:121\u2013128. https:\/\/doi.org\/10.1016\/j.cattod.2016.11.021","journal-title":"Catal Today"},{"key":"23832_CR24","doi-asserted-by":"publisher","first-page":"7627","DOI":"10.1039\/D0RA09318A","volume":"11","author":"K Jiang","year":"2021","unstructured":"Jiang K, Zhang J, Luo R et al (2021) A facile synthesis of Zn-doped TiO2 nanoparticles with highly exposed (001) facets for enhanced photocatalytic performance. RSC Adv 11:7627\u20137632. https:\/\/doi.org\/10.1039\/D0RA09318A","journal-title":"RSC Adv"},{"key":"23832_CR25","doi-asserted-by":"publisher","first-page":"297","DOI":"10.1007\/s00244-005-1095-3","volume":"50","author":"OAH Jones","year":"2006","unstructured":"Jones OAH, Voulvoulis N, Lester JN (2006) Partitioning behavior of five pharmaceutical compounds to activated sludge and river sediment. Arch Environ Contam Toxicol 50:297\u2013305. https:\/\/doi.org\/10.1007\/s00244-005-1095-3","journal-title":"Arch Environ Contam Toxicol"},{"key":"23832_CR26","doi-asserted-by":"publisher","first-page":"2730","DOI":"10.1021\/jp962747a","volume":"101","author":"S Kelly","year":"1997","unstructured":"Kelly S, Pollak FH, Tomkiewicz M (1997) Raman spectroscopy as a morphological probe for TiO2 aerogels. J Phys Chem B 101:2730\u20132734. https:\/\/doi.org\/10.1021\/jp962747a","journal-title":"J Phys Chem B"},{"key":"23832_CR27","first-page":"11","volume":"9","author":"N Klueb-arb","year":"2018","unstructured":"Klueb-arb N, Chuangchote S, Roongraung K, Laosiripojana N, Sagawa T (2018) Fabrication of several metal-doped TiO2 nanoparticles and their physical properties for photocatalysis in energy and environmental applications. J Sustain Energy Environ 9:11\u201316","journal-title":"J Sustain Energy Environ"},{"key":"23832_CR28","doi-asserted-by":"publisher","first-page":"7438","DOI":"10.1007\/s10854-016-4720-1","volume":"27","author":"V Krishnakumar","year":"2016","unstructured":"Krishnakumar V, Boobas S, Jayaprakash J, Rajaboopathi M, Han B, Louhi-Kultanen M (2016) Effect of Cu doping on TiO2 nanoparticles and its photocatalytic activity under visible light. J. Mater. Sci.: Mater. Electron 27:7438\u20137447. https:\/\/doi.org\/10.1007\/s10854-016-4720-1","journal-title":"Electron"},{"key":"23832_CR29","doi-asserted-by":"publisher","first-page":"914","DOI":"10.1039\/c0ee00285b","volume":"4","author":"Y Lee","year":"2011","unstructured":"Lee Y, Choi JH, Jeon HJ et al (2011) Titanium-embedded layered double hydroxides as highly efficient water oxidation photocatalysts under visible light. Energy Environ Sci 4:914. https:\/\/doi.org\/10.1039\/c0ee00285b","journal-title":"Energy Environ Sci"},{"key":"23832_CR30","doi-asserted-by":"publisher","first-page":"432","DOI":"10.1016\/j.jhazmat.2009.07.031","volume":"172","author":"J Li","year":"2009","unstructured":"Li J, Jin Z (2009) Effect of hypersaline aniline-containing pharmaceutical wastewater on the structure of activated sludge-derived bacterial community. J Hazard Mater 172:432\u2013438. https:\/\/doi.org\/10.1016\/j.jhazmat.2009.07.031","journal-title":"J Hazard Mater"},{"key":"23832_CR31","doi-asserted-by":"publisher","first-page":"1610","DOI":"10.1021\/ja040162l","volume":"127","author":"W Lin","year":"2005","unstructured":"Lin W, Frei H (2005a) Photochemical CO 2 Splitting by metal-to-metal charge-transfer excitation in mesoporous ZrCu(I)-MCM-41 silicate sieve. J Am Chem Soc 127:1610\u20131611. https:\/\/doi.org\/10.1021\/ja040162l","journal-title":"J Am Chem Soc"},{"key":"23832_CR32","doi-asserted-by":"publisher","first-page":"4929","DOI":"10.1021\/jp040677z","volume":"109","author":"W Lin","year":"2005","unstructured":"Lin W, Frei H (2005b) Anchored metal-to-metal charge-transfer chromophores in a mesoporous silicate sieve for visible-light activation of titanium centers. J Phys Chem B 109:4929\u20134935. https:\/\/doi.org\/10.1021\/jp040677z","journal-title":"J Phys Chem B"},{"key":"23832_CR33","doi-asserted-by":"publisher","unstructured":"Liu H, Zou M, Viliam Hakala B, et al (2017) Synthesis, characterization of Cu, N co-doped TiO2 microspheres with enhanced photocatalytic activities. Adv Mater Sci 2:. https:\/\/doi.org\/10.15761\/AMS.1000114","DOI":"10.15761\/AMS.1000114"},{"key":"23832_CR34","doi-asserted-by":"publisher","first-page":"8886","DOI":"10.1002\/slct.201801420","volume":"3","author":"Z Liu","year":"2018","unstructured":"Liu Z, Teng F (2018) Understanding the correlation of crystal atoms with photochemistry property: Zn5 (OH)6 (CO3)2 vs. ZnCO3. Chem Select 3:8886\u20138894. https:\/\/doi.org\/10.1002\/slct.201801420","journal-title":"Chem Select"},{"key":"23832_CR35","doi-asserted-by":"publisher","first-page":"2067","DOI":"10.3390\/app8112067","volume":"8","author":"S Mathew","year":"2018","unstructured":"Mathew S, Ganguly P, Rhatigan S et al (2018) Cu-doped TiO2: visible light assisted photocatalytic antimicrobial activity. Appl Sci 8:2067. https:\/\/doi.org\/10.3390\/app8112067","journal-title":"Appl Sci"},{"key":"23832_CR36","doi-asserted-by":"publisher","first-page":"105","DOI":"10.1016\/j.jphotochem.2016.04.024","volume":"328","author":"R Meribout","year":"2016","unstructured":"Meribout R, Zuo Y, Khodja AA et al (2016) Photocatalytic degradation of antiepileptic drug carbamazepine with bismuth oxychlorides (BiOCl and BiOCl\/AgCl composite) in water: efficiency evaluation and elucidation degradation pathways. J Photochem Photobiol, A 328:105\u2013113. https:\/\/doi.org\/10.1016\/j.jphotochem.2016.04.024","journal-title":"J Photochem Photobiol, A"},{"key":"23832_CR37","doi-asserted-by":"publisher","first-page":"568","DOI":"10.1016\/j.jhazmat.2008.07.005","volume":"163","author":"A Mittal","year":"2009","unstructured":"Mittal A, Kaur D, Mittal J (2009) Batch and bulk removal of a triarylmethane dye, fast green FCF, from wastewater by adsorption over waste materials. J Hazard Mater 163:568\u2013577. https:\/\/doi.org\/10.1016\/j.jhazmat.2008.07.005","journal-title":"J Hazard Mater"},{"key":"23832_CR38","doi-asserted-by":"publisher","first-page":"613","DOI":"10.1046\/j.1365-2125.2000.00206.x","volume":"49","author":"JC Mucklow","year":"2000","unstructured":"Mucklow JC (2000) Martindale: the complete drug reference: Book review. Br J Clin Pharmacol 49:613\u2013613. https:\/\/doi.org\/10.1046\/j.1365-2125.2000.00206.x","journal-title":"Br J Clin Pharmacol"},{"key":"23832_CR39","doi-asserted-by":"publisher","first-page":"10668","DOI":"10.1021\/ja0625632","volume":"128","author":"R Nakamura","year":"2006","unstructured":"Nakamura R, Frei H (2006) Visible light-driven water oxidation by Ir oxide clusters coupled to single Cr centers in mesoporous silica. J Am Chem Soc 128:10668\u201310669. https:\/\/doi.org\/10.1021\/ja0625632","journal-title":"J Am Chem Soc"},{"key":"23832_CR40","doi-asserted-by":"publisher","first-page":"19468","DOI":"10.1016\/j.ijhydene.2018.08.209","volume":"43","author":"JO Olowoyo","year":"2018","unstructured":"Olowoyo JO, Kumar M, Dash T et al (2018) Self-organized copper impregnation and doping in TiO2 with enhanced photocatalytic conversion of H2O and CO2 to fuel. Int J Hydrogen Energy 43:19468\u201319480. https:\/\/doi.org\/10.1016\/j.ijhydene.2018.08.209","journal-title":"Int J Hydrogen Energy"},{"key":"23832_CR41","doi-asserted-by":"publisher","first-page":"284","DOI":"10.1021\/cm00027a009","volume":"5","author":"J Papp","year":"1993","unstructured":"Papp J, Shen HS, Kershaw R et al (1993) Titanium(IV) oxide photocatalysts with palladium. Chem Mater 5:284\u2013288. https:\/\/doi.org\/10.1021\/cm00027a009","journal-title":"Chem Mater"},{"key":"23832_CR42","doi-asserted-by":"publisher","first-page":"695","DOI":"10.1016\/j.solener.2021.03.071","volume":"220","author":"B Pava-G\u00f3mez","year":"2021","unstructured":"Pava-G\u00f3mez B, Vargas-Ram\u00edrez X, D\u00edaz-Uribe C et al (2021) Evaluation of copper-doped TiO2 film supported on glass and LDPE with the design of a pilot-scale solar photoreactor. Sol Energy 220:695\u2013705. https:\/\/doi.org\/10.1016\/j.solener.2021.03.071","journal-title":"Sol Energy"},{"key":"23832_CR43","doi-asserted-by":"publisher","first-page":"8300","DOI":"10.1021\/es050794n","volume":"39","author":"LA P\u00e9rez-Estrada","year":"2005","unstructured":"P\u00e9rez-Estrada LA, Malato S, Gernjak W et al (2005) Photo-Fenton degradation of Diclofenac: identification of main intermediates and degradation pathway. Environ Sci Technol 39:8300\u20138306. https:\/\/doi.org\/10.1021\/es050794n","journal-title":"Environ Sci Technol"},{"key":"23832_CR44","doi-asserted-by":"publisher","first-page":"1239","DOI":"10.1590\/S0100-40422009000500030","volume":"32","author":"S Pirillo","year":"2009","unstructured":"Pirillo S, Pedroni V, Rueda E, Luj\u00e1n Ferreira M (2009) Elimination of dyes from aqueous solutions using iron oxides and chitosan as adsorbents: a comparative study. Qu\u00edm Nova 32:1239\u20131244. https:\/\/doi.org\/10.1590\/S0100-40422009000500030","journal-title":"Qu\u00edm Nova"},{"key":"23832_CR45","doi-asserted-by":"publisher","first-page":"1","DOI":"10.1016\/j.jphotochem.2015.10.003","volume":"316","author":"S Rafqah","year":"2016","unstructured":"Rafqah S, Sarakha M (2016) Photochemical transformation of flufenamic acid by artificial sunlight in aqueous solutions. J Photochem Photobiol, A 316:1\u20136. https:\/\/doi.org\/10.1016\/j.jphotochem.2015.10.003","journal-title":"J Photochem Photobiol, A"},{"key":"23832_CR46","doi-asserted-by":"publisher","first-page":"119","DOI":"10.1016\/j.apcatb.2006.03.004","volume":"66","author":"S Rafqah","year":"2006","unstructured":"Rafqah S, Wong-Wah-Chung P, Nelieu S et al (2006) Phototransformation of triclosan in the presence of TiO2 in aqueous suspension: mechanistic approach. Appl Catal B 66:119\u2013125. https:\/\/doi.org\/10.1016\/j.apcatb.2006.03.004","journal-title":"Appl Catal B"},{"key":"23832_CR47","doi-asserted-by":"publisher","first-page":"298","DOI":"10.1002\/jms.3521","volume":"50","author":"S Rafqah","year":"2015","unstructured":"Rafqah S, Seddigi ZS, Ahmed SA et al (2015) Use of quadrupole time of flight mass spectrometry for the characterization of transformation products of the antibiotic sulfamethazine upon photocatalysis with Pd-doped ceria-ZnO nanocomposite: Hydroxylation sites of sulfamethazine. J Mass Spectrom 50:298\u2013307. https:\/\/doi.org\/10.1002\/jms.3521","journal-title":"J Mass Spectrom"},{"key":"23832_CR48","doi-asserted-by":"publisher","first-page":"1301","DOI":"10.1039\/C8PP00156A","volume":"17","author":"M Rathod","year":"2018","unstructured":"Rathod M, Moradeeya PG, Haldar S, Basha S (2018) Nanocellulose\/TiO2 composites: preparation, characterization and application in the photocatalytic degradation of a potential endocrine disruptor, mefenamic acid, in aqueous media. Photochem Photobiol Sci 17:1301\u20131309. https:\/\/doi.org\/10.1039\/C8PP00156A","journal-title":"Photochem Photobiol Sci"},{"key":"23832_CR49","doi-asserted-by":"publisher","DOI":"10.1016\/j.watres.2021.116833","volume":"192","author":"JJ Rueda-M\u00e1rquez","year":"2021","unstructured":"Rueda-M\u00e1rquez JJ, Moreno-Andr\u00e9s J, Rey A et al (2021) Post-treatment of real municipal wastewater effluents by means of granular activated carbon (GAC) based catalytic processes: a focus on abatement of pharmaceutically active compounds. Water Res 192:116833. https:\/\/doi.org\/10.1016\/j.watres.2021.116833","journal-title":"Water Res"},{"key":"23832_CR50","doi-asserted-by":"publisher","first-page":"519","DOI":"10.1016\/j.cej.2011.01.016","volume":"168","author":"M Shao","year":"2011","unstructured":"Shao M, Han J, Wei M et al (2011) The synthesis of hierarchical Zn\u2013Ti layered double hydroxide for efficient visible-light photocatalysis. Chem Eng J 168:519\u2013524. https:\/\/doi.org\/10.1016\/j.cej.2011.01.016","journal-title":"Chem Eng J"},{"key":"23832_CR51","doi-asserted-by":"publisher","DOI":"10.1016\/j.chemosphere.2022.133846","volume":"295","author":"T Shen","year":"2022","unstructured":"Shen T, Han T, Zhao Q et al (2022) Efficient removal of mefenamic acid and ibuprofen on organo-Vts with a quinoline-containing gemini surfactant: adsorption studies and model calculations. Chemosphere 295:133846. https:\/\/doi.org\/10.1016\/j.chemosphere.2022.133846","journal-title":"Chemosphere"},{"key":"23832_CR52","doi-asserted-by":"publisher","first-page":"222","DOI":"10.1016\/j.molcata.2015.10.027","volume":"411","author":"A Shirzadi","year":"2016","unstructured":"Shirzadi A, Nezamzadeh-Ejhieh A (2016) Enhanced photocatalytic activity of supported CuO\u2013ZnO semiconductors towards the photodegradation of mefenamic acid aqueous solution as a semi real sample. J Mol Catal a: Chem 411:222\u2013229. https:\/\/doi.org\/10.1016\/j.molcata.2015.10.027","journal-title":"J Mol Catal a: Chem"},{"key":"23832_CR53","doi-asserted-by":"publisher","first-page":"1938","DOI":"10.1016\/j.envpol.2009.10.036","volume":"158","author":"W-J Sim","year":"2010","unstructured":"Sim W-J, Lee J-W, Oh J-E (2010) Occurrence and fate of pharmaceuticals in wastewater treatment plants and rivers in Korea. Environ Pollut 158:1938\u20131947. https:\/\/doi.org\/10.1016\/j.envpol.2009.10.036","journal-title":"Environ Pollut"},{"key":"23832_CR54","doi-asserted-by":"publisher","first-page":"659","DOI":"10.1080\/0306731021000075384","volume":"82","author":"B Soulet","year":"2002","unstructured":"Soulet B, Tauxe A, Tarradellas J (2002) Analysis of acidic drugs in Swiss wastewaters. Int J Environ Anal Chem 82:659\u2013667. https:\/\/doi.org\/10.1080\/0306731021000075384","journal-title":"Int J Environ Anal Chem"},{"key":"23832_CR55","doi-asserted-by":"publisher","first-page":"661","DOI":"10.1016\/j.catcom.2005.06.004","volume":"6","author":"T Sreethawong","year":"2005","unstructured":"Sreethawong T, Yoshikawa S (2005) Comparative investigation on photocatalytic hydrogen evolution over Cu-, Pd-, and Au-loaded mesoporous TiO2 photocatalysts. Catal Commun 6:661\u2013668. https:\/\/doi.org\/10.1016\/j.catcom.2005.06.004","journal-title":"Catal Commun"},{"key":"23832_CR56","doi-asserted-by":"publisher","first-page":"14","DOI":"10.1016\/j.emcon.2015.07.001","volume":"1","author":"Q Sui","year":"2015","unstructured":"Sui Q, Cao X, Lu S et al (2015) Occurrence, sources and fate of pharmaceuticals and personal care products in the groundwater: a review. Emerg Contaminants 1:14\u201324. https:\/\/doi.org\/10.1016\/j.emcon.2015.07.001","journal-title":"Emerg Contaminants"},{"key":"23832_CR57","doi-asserted-by":"publisher","first-page":"406","DOI":"10.1016\/j.biortech.2013.04.116","volume":"140","author":"L Sun","year":"2013","unstructured":"Sun L, Wan S, Luo W (2013) Biochars prepared from anaerobic digestion residue, palm bark, and eucalyptus for adsorption of cationic methylene blue dye: characterization, equilibrium, and kinetic studies. Biores Technol 140:406\u2013413. https:\/\/doi.org\/10.1016\/j.biortech.2013.04.116","journal-title":"Biores Technol"},{"key":"23832_CR58","doi-asserted-by":"publisher","first-page":"1761","DOI":"10.1016\/j.watres.2005.03.003","volume":"39","author":"A Tauxe-Wuersch","year":"2005","unstructured":"Tauxe-Wuersch A, De Alencastro LF, Grandjean D, Tarradellas J (2005) Occurrence of several acidic drugs in sewage treatment plants in Switzerland and risk assessment. Water Res 39:1761\u20131772. https:\/\/doi.org\/10.1016\/j.watres.2005.03.003","journal-title":"Water Res"},{"key":"23832_CR59","doi-asserted-by":"publisher","first-page":"3855","DOI":"10.1021\/es015757k","volume":"36","author":"TA Ternes","year":"2002","unstructured":"Ternes TA, Meisenheimer M, McDowell D et al (2002) Removal of pharmaceuticals during drinking water treatment. Environ Sci Technol 36:3855\u20133863. https:\/\/doi.org\/10.1021\/es015757k","journal-title":"Environ Sci Technol"},{"key":"23832_CR60","doi-asserted-by":"publisher","first-page":"2102","DOI":"10.1007\/s11270-014-2102-y","volume":"225","author":"JO Tijani","year":"2014","unstructured":"Tijani JO, Fatoba OO, Madzivire G, Petrik LF (2014) A review of combined advanced oxidation technologies for the removal of organic pollutants from water. Water Air Soil Pollut 225:2102. https:\/\/doi.org\/10.1007\/s11270-014-2102-y","journal-title":"Water Air Soil Pollut"},{"key":"23832_CR61","doi-asserted-by":"publisher","first-page":"328","DOI":"10.1016\/j.jcou.2016.08.007","volume":"16","author":"E Turianicov\u00e1","year":"2016","unstructured":"Turianicov\u00e1 E, Ka\u0148uchov\u00e1 M, Zorkovsk\u00e1 A et al (2016) CO2 utilization for fast preparation of nanocrystalline hydrozincite. J CO2 Utilization 16:328\u2013335","journal-title":"J CO2 Utilization"},{"key":"23832_CR62","doi-asserted-by":"publisher","first-page":"3428","DOI":"10.1002\/jctb.5928","volume":"94","author":"C Tzompantzi-Flores","year":"2019","unstructured":"Tzompantzi-Flores C, Castillo-Rodr\u00edguez JC, G\u00f3mez R et al (2019) Synthesis and characterization of ZnZr composites for the photocatalytic degradation of phenolic molecules: addition effect of ZrO 2 over hydrozincite Zn 5 (OH) 6 (CO 3) 2. J Chem Technol Biotechnol 94:3428\u20133439. https:\/\/doi.org\/10.1002\/jctb.5928","journal-title":"J Chem Technol Biotechnol"},{"key":"23832_CR63","doi-asserted-by":"publisher","first-page":"575","DOI":"10.1007\/s11244-020-01236-9","volume":"63","author":"C Tzompantzi-Flores","year":"2020","unstructured":"Tzompantzi-Flores C, Castillo-Rodr\u00edguez JC, G\u00f3mez R et al (2020) Photocatalytic evaluation of the ZrO2:Zn5(OH)6(CO3)2 composite for the H2 production via water splitting. Top Catal 63:575\u2013585. https:\/\/doi.org\/10.1007\/s11244-020-01236-9","journal-title":"Top Catal"},{"key":"23832_CR64","doi-asserted-by":"publisher","first-page":"414","DOI":"10.1016\/j.watres.2003.09.028","volume":"38","author":"D Vogna","year":"2004","unstructured":"Vogna D, Marotta R, Napolitano A et al (2004) Advanced oxidation of the pharmaceutical drug diclofenac with UV\/H2O2 and ozone. Water Res 38:414\u2013422. https:\/\/doi.org\/10.1016\/j.watres.2003.09.028","journal-title":"Water Res"},{"key":"23832_CR65","doi-asserted-by":"publisher","first-page":"394","DOI":"10.1016\/j.cclet.2016.09.002","volume":"28","author":"X-R Wang","year":"2017","unstructured":"Wang X-R, Li Y, Tang L-P et al (2017) Fabrication of Zn-Ti layered double hydroxide by varying cationic ratio of Ti 4+ and its application as UV absorbent. Chin Chem Lett 28:394\u2013399. https:\/\/doi.org\/10.1016\/j.cclet.2016.09.002","journal-title":"Chin Chem Lett"},{"key":"23832_CR66","doi-asserted-by":"publisher","first-page":"16716","DOI":"10.1016\/j.ceramint.2020.03.246","volume":"46","author":"M Wang","year":"2020","unstructured":"Wang M, Zhao Q, Yang H et al (2020) Photocatalytic antibacterial properties of copper doped TiO2 prepared by high-energy ball milling. Ceram Int 46:16716\u201316724. https:\/\/doi.org\/10.1016\/j.ceramint.2020.03.246","journal-title":"Ceram Int"},{"key":"23832_CR67","doi-asserted-by":"publisher","first-page":"124808","DOI":"10.1016\/j.cej.2020.124808","volume":"392","author":"X Wei","year":"2020","unstructured":"Wei X, Wang Y, Chen J et al (2020) Adsorption of pharmaceuticals and personal care products by deep eutectic solvents-regulated magnetic metal-organic framework adsorbents: performance and mechanism. Chem Eng J 392:124808. https:\/\/doi.org\/10.1016\/j.cej.2020.124808","journal-title":"Chem Eng J"},{"key":"23832_CR68","doi-asserted-by":"publisher","first-page":"35776","DOI":"10.1039\/C7RA05488B","volume":"7","author":"C Wu","year":"2017","unstructured":"Wu C, De Visscher A, Gates ID (2017) Reactions of hydroxyl radicals with benzoic acid and benzoate. RSC Adv 7:35776\u201335785. https:\/\/doi.org\/10.1039\/C7RA05488B","journal-title":"RSC Adv"},{"key":"23832_CR69","doi-asserted-by":"publisher","first-page":"172","DOI":"10.1016\/j.cis.2014.04.002","volume":"209","author":"MT Yagub","year":"2014","unstructured":"Yagub MT, Sen TK, Afroze S, Ang HM (2014) Dye and its removal from aqueous solution by adsorption: a review. Adv Coll Interface Sci 209:172\u2013184. https:\/\/doi.org\/10.1016\/j.cis.2014.04.002","journal-title":"Adv Coll Interface Sci"},{"key":"23832_CR70","doi-asserted-by":"publisher","first-page":"11076","DOI":"10.1021\/jp060357a","volume":"110","author":"C Yan","year":"2006","unstructured":"Yan C, Xue D (2006) Morphosynthesis of hierarchical hydrozincite with tunable surface architectures and hollow zinc oxide. J Phys Chem B 110:11076\u201311080. https:\/\/doi.org\/10.1021\/jp060357a","journal-title":"J Phys Chem B"},{"key":"23832_CR71","doi-asserted-by":"publisher","first-page":"5074","DOI":"10.1039\/C5CE00933B","volume":"17","author":"Y Yu","year":"2015","unstructured":"Yu Y, Wang J, Li W et al (2015) Doping mechanism of Zn 2+ ions in Zn-doped TiO 2 prepared by a sol\u2013gel method. CrystEngComm 17:5074\u20135080. https:\/\/doi.org\/10.1039\/C5CE00933B","journal-title":"CrystEngComm"},{"key":"23832_CR72","doi-asserted-by":"publisher","first-page":"6794","DOI":"10.1007\/s10853-015-9237-0","volume":"50","author":"H Zheng","year":"2015","unstructured":"Zheng H, Li J, Zhang X et al (2015) Structural and electronic properties of Cu-doped Zn5(OH)6(CO3)2 from first principles. J Mater Sci 50:6794\u20136807. https:\/\/doi.org\/10.1007\/s10853-015-9237-0","journal-title":"J Mater Sci"}],"container-title":["Environmental Science and Pollution Research"],"original-title":[],"language":"en","link":[{"URL":"https:\/\/link.springer.com\/content\/pdf\/10.1007\/s11356-022-23832-w.pdf","content-type":"application\/pdf","content-version":"vor","intended-application":"text-mining"},{"URL":"https:\/\/link.springer.com\/article\/10.1007\/s11356-022-23832-w\/fulltext.html","content-type":"text\/html","content-version":"vor","intended-application":"text-mining"},{"URL":"https:\/\/link.springer.com\/content\/pdf\/10.1007\/s11356-022-23832-w.pdf","content-type":"application\/pdf","content-version":"vor","intended-application":"similarity-checking"}],"deposited":{"date-parts":[[2023,2,19]],"date-time":"2023-02-19T09:01:51Z","timestamp":1676797311000},"score":1,"resource":{"primary":{"URL":"https:\/\/link.springer.com\/10.1007\/s11356-022-23832-w"}},"subtitle":[],"short-title":[],"issued":{"date-parts":[[2022,11,7]]},"references-count":72,"journal-issue":{"issue":"9","published-online":{"date-parts":[[2023,2]]}},"alternative-id":["23832"],"URL":"https:\/\/doi.org\/10.1007\/s11356-022-23832-w","relation":{},"ISSN":["1614-7499"],"issn-type":[{"value":"1614-7499","type":"electronic"}],"subject":[],"published":{"date-parts":[[2022,11,7]]},"assertion":[{"value":"22 August 2022","order":1,"name":"received","label":"Received","group":{"name":"ArticleHistory","label":"Article History"}},{"value":"21 October 2022","order":2,"name":"accepted","label":"Accepted","group":{"name":"ArticleHistory","label":"Article History"}},{"value":"7 November 2022","order":3,"name":"first_online","label":"First Online","group":{"name":"ArticleHistory","label":"Article History"}},{"order":1,"name":"Ethics","group":{"name":"EthicsHeading","label":"Declarations"}},{"value":"The paper does not involve relevant ethical research.","order":2,"name":"Ethics","group":{"name":"EthicsHeading","label":"Ethical approval and consent to participate"}},{"value":"The manuscript is approved by all authors for publication. The work described was original research that has not been published previously, and not under consideration for publication elsewhere, in whole or in part. All the authors listed have approved the manuscript that is enclosed.","order":3,"name":"Ethics","group":{"name":"EthicsHeading","label":"Consent for publication"}},{"value":"The authors declare no competing interests.","order":4,"name":"Ethics","group":{"name":"EthicsHeading","label":"Competing interests"}}]}}