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FeOOH powders were prepared as precipitates by mixing aqueous FeCl<jats:sub>3<\/jats:sub> and NaOH solutions (1:3\u00a0mol\/mol) in the presence of 2,2,6,6,-tetramethylpiperidine-1-oxyl radical (TEMPO)-oxidized cellulose nanofibrils (TOCNs), carboxymethylcellulose (CMC), or TEMPO-oxidized cellulose (TOC) fibers (without nanofibrillation), and subsequent drying and pulverizing. The FeOOH:TOCN, FeOOH:CMC, and FeOOH:TOC dry mass ratios were controlled at 87:13. The amount of F<jats:sup>\u2212<\/jats:sup> adsorbed by the FeOOH\/TOCN powder per FeOOH mass was higher than those adsorbed by FeOOH, FeOOH\/CMC, or FeOOH\/TOC. The F<jats:sup>\u2212<\/jats:sup> adsorption isotherms on the FeOOH-containing powders showed higher correlation coefficients with the Langmuir model than with the Freundlich model. This indicates that F<jats:sup>\u2212<\/jats:sup> adsorbed on FeOOH initially formed a monolayer, predominantly via physical adsorption. Pseudo-second-order kinetics fitted well to the time-dependent F<jats:sup>\u2212<\/jats:sup> adsorption behaviors on the FeOOH-containing powders. Thermodynamic analysis of F<jats:sup>\u2212<\/jats:sup> adsorption on the FeOOH-containing powders showed that the \u0394<jats:italic>G<\/jats:italic> values were negative, which indicates that F<jats:sup>\u2212<\/jats:sup> adsorption on the FeOOH-containing powders proceeded spontaneously in water. The negative \u0394<jats:italic>G<\/jats:italic> value for FeOOH\/TOCN was higher than those for FeOOH, FeOOH\/CMC, and FeOOH\/TOC at the same temperature. This shows that the FeOOH\/TOCN powder can be used as an excellent and efficient F<jats:sup>\u2212<\/jats:sup> adsorbent in water.<\/jats:p>\n                <jats:p><jats:bold>Graphical abstract<\/jats:bold><\/jats:p>","DOI":"10.1007\/s11356-023-25679-1","type":"journal-article","created":{"date-parts":[[2023,2,9]],"date-time":"2023-02-09T01:03:10Z","timestamp":1675904590000},"page":"48201-48210","update-policy":"https:\/\/doi.org\/10.1007\/springer_crossmark_policy","source":"Crossref","is-referenced-by-count":15,"title":["Fluoride ion adsorption isotherms, kinetics, and thermodynamics on iron(III) oxyhydroxide powders containing cellulose nanofibrils"],"prefix":"10.1007","volume":"30","author":[{"given":"Masahiro","family":"Umehara","sequence":"first","affiliation":[],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Yoshiaki","family":"Kumamoto","sequence":"additional","affiliation":[],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Kenta","family":"Mukai","sequence":"additional","affiliation":[],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Akira","family":"Isogai","sequence":"additional","affiliation":[],"role":[{"vocabulary":"crossref","role":"author"}]}],"member":"297","published-online":{"date-parts":[[2023,2,8]]},"reference":[{"key":"25679_CR1","doi-asserted-by":"publisher","first-page":"388","DOI":"10.1016\/j.micromeso.2006.12.007","volume":"101","author":"M Alkan","year":"2007","unstructured":"Alkan M, Demirbas O, Dogan M (2007) Adsorption kinetics and thermodynamics of an anionic dye onto sepiolite. 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