{"status":"ok","message-type":"work","message-version":"1.0.0","message":{"indexed":{"date-parts":[[2026,9,10]],"date-time":"2026-09-10T14:25:17Z","timestamp":1789050317464,"version":"build-2803163510"},"reference-count":66,"publisher":"Springer Science and Business Media LLC","issue":"59","license":[{"start":{"date-parts":[[2023,11,22]],"date-time":"2023-11-22T00:00:00Z","timestamp":1700611200000},"content-version":"tdm","delay-in-days":0,"URL":"https:\/\/creativecommons.org\/licenses\/by\/4.0"},{"start":{"date-parts":[[2023,11,22]],"date-time":"2023-11-22T00:00:00Z","timestamp":1700611200000},"content-version":"vor","delay-in-days":0,"URL":"https:\/\/creativecommons.org\/licenses\/by\/4.0"}],"funder":[{"DOI":"10.13039\/100020075","name":"Uniremington","doi-asserted-by":"crossref","award":["\u201cRemoci\u00f3n de f\u00e1rmacos usando un carb\u00f3n activado de cascarilla de arroz como adsorbente y activador de agentes oxidantes\u201d."],"award-info":[{"award-number":["\u201cRemoci\u00f3n de f\u00e1rmacos usando un carb\u00f3n activado de cascarilla de arroz como adsorbente y activador de agentes oxidantes\u201d."]}],"id":[{"id":"10.13039\/100020075","id-type":"DOI","asserted-by":"crossref"}]},{"name":"MINCIENCIAS COLOMBIA","award":["No. 1115-852-69594"],"award-info":[{"award-number":["No. 1115-852-69594"]}]},{"name":"MINCIENCIAS COLOMBIA","award":["Becas de Excelencia Doctoral del Bicentenario \u2013 Primer Corte"],"award-info":[{"award-number":["Becas de Excelencia Doctoral del Bicentenario \u2013 Primer Corte"]}]},{"name":"Universidad de Medellin","award":["Remoci\u00f3n de f\u00e1rmacos usando un carb\u00f3n activado de cascarilla de arroz como adsorbente y activador de agentes oxidantes"],"award-info":[{"award-number":["Remoci\u00f3n de f\u00e1rmacos usando un carb\u00f3n activado de cascarilla de arroz como adsorbente y activador de agentes oxidantes"]}]},{"DOI":"10.13039\/501100005278","name":"University of Antioquia","doi-asserted-by":"crossref","id":[{"id":"10.13039\/501100005278","id-type":"DOI","asserted-by":"crossref"}]}],"content-domain":{"domain":["link.springer.com"],"crossmark-restriction":false},"short-container-title":["Environ Sci Pollut Res"],"abstract":"<jats:title>Abstract<\/jats:title><jats:p>Pristine pyrogenic carbonaceous material (BRH) obtained from rice husk and modified with FeCl<jats:sub>3<\/jats:sub> (BRH-FeCl<jats:sub>3<\/jats:sub>) were prepared and explored as carbocatalysts for the activation of peroxymonosulfate (PMS) to degrade a model pharmaceutical (acetaminophen, ACE) in water. The BRH-FeCl<jats:sub>3<\/jats:sub>\/PMS system removed the pharmaceutical faster than the BRH\/PMS. This is explained because in BRH-FeCl<jats:sub>3<\/jats:sub>, compared to BRH, the modification (iron played a role as a structuring agent mainly) increased the average pore diameter and the presence of functional groups such as -COO<jats:sup>\u2212<\/jats:sup>, -Si\u2013O<jats:sup>\u2212<\/jats:sup>, or oxygen vacancies, which allowed to remove the pollutant through an adsorption process and significant carbocatalytic degradation. BRH-FeCl<jats:sub>3<\/jats:sub> was reusable during four cycles and had a higher efficiency for activating PMS than another inorganic peroxide (peroxydisulfate, PDS). The effects of BRH-FeCl<jats:sub>3<\/jats:sub> and PMS concentrations were evaluated and optimized through an experimental design, maximizing the ACE degradation. In the optimized system, a non-radical pathway (i.e., the action of singlet oxygen, from the interaction of PMS with defects and\/or -COO<jats:sup>\u2212<\/jats:sup>\/-Si\u2013O<jats:sup>\u2212<\/jats:sup> moieties on the BRH-FeCl<jats:sub>3<\/jats:sub>) was found. The BRH-FeCl<jats:sub>3<\/jats:sub>\/PMS system generated only one primary degradation product that was more susceptible to biodegradation and less active against living organisms than ACE. Also, the BRH-FeCl<jats:sub>3<\/jats:sub>\/PMS system induced partial removals of chemical oxygen demand and dissolved organic carbon. Furthermore, the carbocatalytic system eliminated ACE in a wide pH range and in simulated urine, having a low-moderate electric energy consumption, indicating the feasibility of the carbocatalytic process to treat water polluted with pharmaceuticals.<\/jats:p>","DOI":"10.1007\/s11356-023-30785-1","type":"journal-article","created":{"date-parts":[[2023,11,22]],"date-time":"2023-11-22T07:02:13Z","timestamp":1700636533000},"page":"123616-123632","update-policy":"https:\/\/doi.org\/10.1007\/springer_crossmark_policy","source":"Crossref","is-referenced-by-count":7,"title":["Rice husk\u2013based pyrogenic carbonaceous material efficiently promoted peroxymonosulfate activation toward the non-radical pathway for the degradation of pharmaceuticals in water"],"prefix":"10.1007","volume":"30","author":[{"given":"Marcela","family":"Paredes-Laverde","sequence":"first","affiliation":[],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Jazm\u00edn","family":"Porras","sequence":"additional","affiliation":[],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Nancy","family":"Acelas","sequence":"additional","affiliation":[],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Jhonnaifer J.","family":"Romero-Hern\u00e1ndez","sequence":"additional","affiliation":[],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Sindy D.","family":"Jojoa-Sierra","sequence":"additional","affiliation":[],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"L\u00e1zaro","family":"Huerta","sequence":"additional","affiliation":[],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Efra\u00edm A.","family":"Serna-Galvis","sequence":"additional","affiliation":[],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0003-4583-9849","authenticated-orcid":false,"given":"Ricardo A.","family":"Torres-Palma","sequence":"additional","affiliation":[],"role":[{"vocabulary":"crossref","role":"author"}]}],"member":"297","published-online":{"date-parts":[[2023,11,22]]},"reference":[{"key":"30785_CR1","doi-asserted-by":"publisher","first-page":"588","DOI":"10.1016\/j.joen.2015.01.024","volume":"41","author":"A Aminoshariae","year":"2015","unstructured":"Aminoshariae A, Khan A (2015) Acetaminophen: old drug, new issues. J Endod 41:588\u2013593. https:\/\/doi.org\/10.1016\/j.joen.2015.01.024","journal-title":"J Endod"},{"key":"30785_CR2","doi-asserted-by":"publisher","first-page":"1","DOI":"10.3390\/catal11111303","volume":"11","author":"E Avramiotis","year":"2021","unstructured":"Avramiotis E, Frontistis Z, Manariotis ID et al (2021a) On the performance of a sustainable rice husk biochar for the activation of persulfate and the degradation of antibiotics. Catalysts 11:1\u201316. https:\/\/doi.org\/10.3390\/catal11111303","journal-title":"Catalysts"},{"key":"30785_CR3","doi-asserted-by":"publisher","unstructured":"Avramiotis E, Frontistis Z, Manariotis ID et al (2021b) Oxidation of sulfamethoxazole by rice husk biochar-activated persulfate. Catalysts 11:1\u201319. https:\/\/doi.org\/10.3390\/catal11070850","DOI":"10.3390\/catal11070850"},{"key":"30785_CR4","doi-asserted-by":"publisher","first-page":"842","DOI":"10.1016\/j.scitotenv.2018.06.088","volume":"642","author":"AM Botero-Coy","year":"2018","unstructured":"Botero-Coy AM, Mart\u00ednez-Pach\u00f3n D, Boix C et al (2018) An investigation into the occurrence and removal of pharmaceuticals in Colombian wastewater. Sci Total Environ 642:842\u2013853. https:\/\/doi.org\/10.1016\/j.scitotenv.2018.06.088","journal-title":"Sci Total Environ"},{"key":"30785_CR5","doi-asserted-by":"publisher","first-page":"1095","DOI":"10.1007\/s00128-022-03603-6","volume":"109","author":"M Bo\u017cym","year":"2022","unstructured":"Bo\u017cym M (2022) Assessment of phytotoxicity of landfilled waste and foundry dust based on the direct test. Bull Environ Contam Toxicol 109:1095\u20131105. https:\/\/doi.org\/10.1007\/s00128-022-03603-6","journal-title":"Bull Environ Contam Toxicol"},{"issue":"12","key":"30785_CR6","doi-asserted-by":"publisher","first-page":"1048","DOI":"10.1080\/1536383X.2020.1794851","volume":"28","author":"X Chen","year":"2020","unstructured":"Chen X, Wang X, Fang D (2020) A review on C1s XPS-spectra for some kinds of carbon materials. Fullerenes Nanotub Carbon Nanostructures 28(12):1048\u20131058. https:\/\/doi.org\/10.1080\/1536383X.2020.1794851","journal-title":"Fullerenes Nanotub Carbon Nanostructures"},{"key":"30785_CR7","doi-asserted-by":"publisher","first-page":"123219","DOI":"10.1016\/j.conbuildmat.2021.123219","volume":"292","author":"R Chen","year":"2021","unstructured":"Chen R, Congress SSC, Cai G et al (2021a) Sustainable utilization of biomass waste-rice husk ash as a new solidified material of soil in geotechnical engineering: a review. Constr Build Mater 292:123219. https:\/\/doi.org\/10.1016\/j.conbuildmat.2021.123219","journal-title":"Constr Build Mater"},{"key":"30785_CR8","doi-asserted-by":"publisher","first-page":"129830","DOI":"10.1016\/j.chemosphere.2021.129830","volume":"271","author":"S Chen","year":"2021","unstructured":"Chen S, He P, Zhou P et al (2021b) Development of a novel graphitic carbon nitride and multiwall carbon nanotube co-doped Ti\/PbO2 anode for electrocatalytic degradation of acetaminophen. Chemosphere 271:129830. https:\/\/doi.org\/10.1016\/j.chemosphere.2021.129830","journal-title":"Chemosphere"},{"key":"30785_CR9","doi-asserted-by":"publisher","first-page":"13","DOI":"10.1016\/j.watres.2007.07.025","volume":"42","author":"M Deborde","year":"2008","unstructured":"Deborde M, von Gunten U (2008) Reactions of chlorine with inorganic and organic compounds during water treatment\u2014kinetics and mechanisms: a critical review. Water Res 42:13\u201351. https:\/\/doi.org\/10.1016\/j.watres.2007.07.025","journal-title":"Water Res"},{"key":"30785_CR10","doi-asserted-by":"publisher","first-page":"33781","DOI":"10.1007\/s11356-018-2423-2","volume":"26","author":"CD Dong","year":"2019","unstructured":"Dong CD, Chen CW, Hung CM (2019) Persulfate activation with rice husk-based magnetic biochar for degrading PAEs in marine sediments. Environ Sci Pollut Res 26:33781\u201333790. https:\/\/doi.org\/10.1007\/s11356-018-2423-2","journal-title":"Environ Sci Pollut Res"},{"key":"30785_CR11","doi-asserted-by":"publisher","DOI":"10.1007\/s11356-020-07612-y","author":"J Du Faheem,","year":"2020","unstructured":"Du Faheem, J, Kim SH et al (2020) Application of biochar in advanced oxidation processes\u202f: supportive, adsorptive, and catalytic role. Environ Sci Pollut Res. https:\/\/doi.org\/10.1007\/s11356-020-07612-y","journal-title":"Environ Sci Pollut Res"},{"key":"30785_CR12","doi-asserted-by":"publisher","first-page":"2982","DOI":"10.1039\/d0en00848f","volume":"7","author":"W Duan","year":"2020","unstructured":"Duan W, He J, Wei Z et al (2020) A unique Si-doped carbon nanocatalyst for peroxymonosulfate (PMS) activation: insights into the singlet oxygen generation mechanism and the abnormal salt effect. Environ Sci Nano 7:2982\u20132994. https:\/\/doi.org\/10.1039\/d0en00848f","journal-title":"Environ Sci Nano"},{"key":"30785_CR13","unstructured":"EAWAG (2022) Biocatalysis\/Biodegradation database. In: Pathw Predict Syst. https:\/\/eawag-bbd.ethz.ch\/predict\/. Accessed 1 Oct 2023"},{"key":"30785_CR14","doi-asserted-by":"crossref","unstructured":"Fisher ES, Curry SC (2019) Chapter ten - evaluation and treatment of acetaminophen toxicity. In: Ramachandran A, Jaeschke HBT-A in P (eds.) Druginduced Liver Injury. Academic Press, pp 263\u2013272","DOI":"10.1016\/bs.apha.2018.12.004"},{"key":"30785_CR15","doi-asserted-by":"publisher","first-page":"123936","DOI":"10.1016\/j.cej.2019.123936","volume":"394","author":"Y Gao","year":"2020","unstructured":"Gao Y, Zhu Y, Chen Z et al (2020) Insights into the difference in metal-free activation of peroxymonosulfate and peroxydisulfate. Chem Eng J 394:123936. https:\/\/doi.org\/10.1016\/j.cej.2019.123936","journal-title":"Chem Eng J"},{"key":"30785_CR16","doi-asserted-by":"publisher","first-page":"121857","DOI":"10.1016\/j.seppur.2022.121857","volume":"300","author":"Y Gao","year":"2022","unstructured":"Gao Y, Chen Y, Song T et al (2022) Activated peroxymonosulfate with ferric chloride-modified biochar to degrade bisphenol A: characteristics, influencing factors, reaction mechanism and reuse performance. Sep Purif Technol 300:121857. https:\/\/doi.org\/10.1016\/j.seppur.2022.121857","journal-title":"Sep Purif Technol"},{"key":"30785_CR17","doi-asserted-by":"publisher","first-page":"116148","DOI":"10.1016\/j.jenvman.2022.116148","volume":"323","author":"CM Grisales-Cifuentes","year":"2022","unstructured":"Grisales-Cifuentes CM, Serna-Galvis EA, Acelas N et al (2022) Biochar from palm fiber wastes as an activator of different oxidants for the elimination of pharmaceuticals from diverse classes in aqueous samples. J Environ Manage 323:116148. https:\/\/doi.org\/10.1016\/j.jenvman.2022.116148","journal-title":"J Environ Manage"},{"key":"30785_CR18","doi-asserted-by":"publisher","first-page":"10270","DOI":"10.1080\/19443994.2015.1035338","volume":"57","author":"E-K Guechi","year":"2015","unstructured":"Guechi E-K, Hamdaoui O (2015) Biosorption of methylene blue from aqueous solution by potato (Solanum tuberosum) peel: equilibrium modelling, kinetic, and thermodynamic studies. Desalin Water Treat 57:10270\u201310285. https:\/\/doi.org\/10.1080\/19443994.2015.1035338","journal-title":"Desalin Water Treat"},{"key":"30785_CR19","doi-asserted-by":"publisher","first-page":"1","DOI":"10.3390\/w10020182","volume":"10","author":"N Hagemann","year":"2018","unstructured":"Hagemann N, Spokas K, Schmidt HP et al (2018) Activated carbon, biochar and charcoal: Linkages and synergies across pyrogenic carbon\u2019s ABCs. Water 10:1\u201319. https:\/\/doi.org\/10.3390\/w10020182","journal-title":"Water"},{"key":"30785_CR20","doi-asserted-by":"publisher","first-page":"126895","DOI":"10.1016\/j.cej.2020.126895","volume":"405","author":"L He","year":"2021","unstructured":"He L, Liu Z, Hu J et al (2021) Sugarcane biochar as novel catalyst for highly efficient oxidative removal of organic compounds in water. Chem Eng J 405:126895. https:\/\/doi.org\/10.1016\/j.cej.2020.126895","journal-title":"Chem Eng J"},{"key":"30785_CR21","doi-asserted-by":"publisher","first-page":"189","DOI":"10.1016\/S0167-8809(01)00348-6","volume":"93","author":"NJ Hoekstra","year":"2002","unstructured":"Hoekstra NJ, Bosker T, Lantinga EA (2002) Effects of cattle dung from farms with different feeding strategies on germination and initial root growth of cress (Lepidium sativum L.). Agric Ecosyst Environ 93:189\u2013196. https:\/\/doi.org\/10.1016\/S0167-8809(01)00348-6","journal-title":"Agric Ecosyst Environ"},{"key":"30785_CR22","doi-asserted-by":"publisher","DOI":"10.1016\/j.jpcs.2020.109846","volume":"150","author":"MS Hosseini","year":"2021","unstructured":"Hosseini MS, Masteri-Farahani M, Ghahremani M, Forouzeshfar N (2021) New approach for sulfonation of carbonaceous materials: highly efficient solid acid catalysts for benzaldehyde acetalization with ethylene glycol. J Phys Chem Solids 150:109846. https:\/\/doi.org\/10.1016\/j.jpcs.2020.109846","journal-title":"J Phys Chem Solids"},{"key":"30785_CR23","doi-asserted-by":"publisher","first-page":"127066","DOI":"10.1016\/j.cej.2020.127066","volume":"404","author":"C Huang","year":"2021","unstructured":"Huang C, Zhang C, Huang D et al (2021a) Influence of surface functionalities of pyrogenic carbonaceous materials on the generation of reactive species towards organic contaminants: A review. Chem Eng J 404:127066. https:\/\/doi.org\/10.1016\/j.cej.2020.127066","journal-title":"Chem Eng J"},{"key":"30785_CR24","doi-asserted-by":"publisher","first-page":"143957","DOI":"10.1016\/j.scitotenv.2020.143957","volume":"758","author":"H Huang","year":"2021","unstructured":"Huang H, Guo T, Wang K et al (2021b) Efficient activation of persulfate by a magnetic recyclable rape straw biochar catalyst for the degradation of tetracycline hydrochloride in water. Sci Total Environ 758:143957. https:\/\/doi.org\/10.1016\/j.scitotenv.2020.143957","journal-title":"Sci Total Environ"},{"key":"30785_CR25","doi-asserted-by":"publisher","first-page":"163","DOI":"10.1016\/j.cej.2016.11.085","volume":"311","author":"I Hussain","year":"2017","unstructured":"Hussain I, Li M, Zhang Y et al (2017) Insights into the mechanism of persulfate activation with nZVI\/BC nanocomposite for the degradation of nonylphenol. Chem Eng J 311:163\u2013172. https:\/\/doi.org\/10.1016\/j.cej.2016.11.085","journal-title":"Chem Eng J"},{"key":"30785_CR26","doi-asserted-by":"publisher","first-page":"127957","DOI":"10.1016\/j.cej.2020.127957","volume":"411","author":"M Kohantorabi","year":"2021","unstructured":"Kohantorabi M, Moussavi G, Giannakis S (2021) A review of the innovations in metal- and carbon-based catalysts explored for heterogeneous peroxymonosulfate (PMS) activation, with focus on radical vs. non-radical degradation pathways of organic contaminants. Chem Eng J 411:127957. https:\/\/doi.org\/10.1016\/j.cej.2020.127957","journal-title":"Chem Eng J"},{"key":"30785_CR27","doi-asserted-by":"publisher","first-page":"3064","DOI":"10.1021\/acs.est.9b07082","volume":"54","author":"J Lee","year":"2020","unstructured":"Lee J, Von Gunten U, Kim JH (2020) Persulfate-based advanced oxidation: critical assessment of opportunities and roadblocks. Environ Sci Technol 54:3064\u20133081. https:\/\/doi.org\/10.1021\/acs.est.9b07082","journal-title":"Environ Sci Technol"},{"key":"30785_CR28","doi-asserted-by":"publisher","unstructured":"Lehmann J, Joseph S (2015) Biochar for environmental management: science, technology and implementation, Second Edi. London and New York. https:\/\/doi.org\/10.4324\/9780203762264","DOI":"10.4324\/9780203762264"},{"key":"30785_CR29","doi-asserted-by":"publisher","first-page":"18358","DOI":"10.1021\/ja906190t","volume":"131","author":"K Leung","year":"2009","unstructured":"Leung K, Nielsen IMB, Criscenti LJ (2009) Elucidating the bimodal acid-base behavior of the water-silica interface from first principles. J Am Chem Soc 131:18358\u201318365. https:\/\/doi.org\/10.1021\/ja906190t","journal-title":"J Am Chem Soc"},{"key":"30785_CR30","doi-asserted-by":"publisher","first-page":"110653","DOI":"10.1016\/j.ecoenv.2020.110653","volume":"198","author":"F Li","year":"2020","unstructured":"Li F, Duan F, Ji W, Gui X (2020) Biochar-activated persulfate for organic contaminants removal: efficiency, mechanisms and influencing factors. Ecotoxicol Environ Saf 198:110653. https:\/\/doi.org\/10.1016\/j.ecoenv.2020.110653","journal-title":"Ecotoxicol Environ Saf"},{"key":"30785_CR31","doi-asserted-by":"publisher","first-page":"129766","DOI":"10.1016\/j.chemosphere.2021.129766","volume":"274","author":"X Li","year":"2021","unstructured":"Li X, Qin Y, Jia Y et al (2021) Preparation and application of Fe\/biochar (Fe-BC) catalysts in wastewater treatment: a review. Chemosphere 274:129766. https:\/\/doi.org\/10.1016\/j.chemosphere.2021.129766","journal-title":"Chemosphere"},{"key":"30785_CR32","doi-asserted-by":"publisher","first-page":"135897","DOI":"10.1016\/j.cej.2022.135897","volume":"440","author":"R Li","year":"2022","unstructured":"Li R, Lu X, Yan B et al (2022) Sludge-derived biochar toward sustainable peroxymonosulfate activation: regulation of active sites and synergistic production of reaction oxygen species. Chem Eng J 440:135897. https:\/\/doi.org\/10.1016\/j.cej.2022.135897","journal-title":"Chem Eng J"},{"key":"30785_CR33","doi-asserted-by":"publisher","first-page":"40022","DOI":"10.1039\/d1ra07891g","volume":"11","author":"Y Lin","year":"2021","unstructured":"Lin Y, Mo X, Zhang Y et al (2021) Selective degradation of acetaminophen from hydrolyzed urine by peroxymonosulfate alone: performances and mechanisms. RSC Adv 11:40022\u201340032. https:\/\/doi.org\/10.1039\/d1ra07891g","journal-title":"RSC Adv"},{"key":"30785_CR34","doi-asserted-by":"publisher","first-page":"131188","DOI":"10.1016\/j.chemosphere.2021.131188","volume":"283","author":"T Liu","year":"2021","unstructured":"Liu T, Cui K, Chen Y et al (2021) Removal of chlorophenols in the aquatic environment by activation of peroxymonosulfate with nMnOx@biochar hybrid composites: Performance and mechanism. Chemosphere 283:131188. https:\/\/doi.org\/10.1016\/j.chemosphere.2021.131188","journal-title":"Chemosphere"},{"key":"30785_CR35","doi-asserted-by":"publisher","first-page":"596","DOI":"10.1016\/j.chemosphere.2019.06.092","volume":"234","author":"S Mandal","year":"2019","unstructured":"Mandal S, Adhikari S, Pu S et al (2019) Interactive Fe2O3\/porous SiO2 nanospheres for photocatalytic degradation of organic pollutants: kinetic and mechanistic approach. Chemosphere 234:596\u2013607. https:\/\/doi.org\/10.1016\/j.chemosphere.2019.06.092","journal-title":"Chemosphere"},{"key":"30785_CR36","doi-asserted-by":"publisher","first-page":"138073","DOI":"10.1016\/j.electacta.2021.138073","volume":"377","author":"F Miao","year":"2021","unstructured":"Miao F, Liu Z, Kang X et al (2021) Electro-enhanced heterogeneous activation of peroxymonosulfate via acceleration of Fe(III)\/Fe(II) redox cycle on Fe-B catalyst. Electrochim Acta 377:138073. https:\/\/doi.org\/10.1016\/j.electacta.2021.138073","journal-title":"Electrochim Acta"},{"key":"30785_CR37","doi-asserted-by":"publisher","first-page":"118","DOI":"10.1016\/j.watres.2018.03.042","volume":"139","author":"DB Miklos","year":"2018","unstructured":"Miklos DB, Remy C, Jekel M et al (2018) Evaluation of advanced oxidation processes for water and wastewater treatment \u2013 a critical review. Water Res 139:118\u2013131. https:\/\/doi.org\/10.1016\/j.watres.2018.03.042","journal-title":"Water Res"},{"key":"30785_CR38","doi-asserted-by":"publisher","DOI":"10.1016\/j.cej.2020.124856","author":"TD Minh","year":"2020","unstructured":"Minh TD, Song J, Deb A et al (2020) Biochar based catalysts for the abatement of emerging pollutants: a review. Chem Eng J. https:\/\/doi.org\/10.1016\/j.cej.2020.124856","journal-title":"Chem Eng J"},{"key":"30785_CR39","doi-asserted-by":"publisher","first-page":"130569","DOI":"10.1016\/j.chemosphere.2021.130569","volume":"279","author":"HT Nguyen","year":"2021","unstructured":"Nguyen HT, Lee J, Kwon E et al (2021) Bamboo-like N-doped carbon nanotube\u2013confined cobalt as an efficient and robust catalyst for activating monopersulfate to degrade bisphenol A. Chemosphere 279:130569. https:\/\/doi.org\/10.1016\/j.chemosphere.2021.130569","journal-title":"Chemosphere"},{"key":"30785_CR40","doi-asserted-by":"publisher","first-page":"183","DOI":"10.14447\/jnmes.v16i3.9","volume":"16","author":"MA Oliver-Tolentino","year":"2013","unstructured":"Oliver-Tolentino MA, Cabrera-Sierra R, Lartundo-Rojas L et al (2013) Understanding the surface state and proton adsorption phenomena on ni-based alloys at the hydrogen evolution zone in alkaline medium by EIS-XPS. J New Mater Electrochem Syst 16:183\u2013188. https:\/\/doi.org\/10.14447\/jnmes.v16i3.9","journal-title":"J New Mater Electrochem Syst"},{"key":"30785_CR41","doi-asserted-by":"publisher","first-page":"103318","DOI":"10.1016\/j.jece.2019.103318","volume":"7","author":"M Paredes-Laverde","year":"2019","unstructured":"Paredes-Laverde M, Salamanca M, Silva-Agredo J et al (2019) Selective removal of acetaminophen in urine with activated carbons from rice (Oryza sativa) and coffee (Co ffea arabica) husk: effect of activating agent, activation temperature and analysis of physical-chemical interactions. J Environ Chem Eng 7:103318. https:\/\/doi.org\/10.1016\/j.jece.2019.103318","journal-title":"J Environ Chem Eng"},{"key":"30785_CR42","doi-asserted-by":"publisher","first-page":"3510","DOI":"10.1021\/acs.chemrev.8b00299","volume":"119","author":"M Patel","year":"2019","unstructured":"Patel M, Kumar R, Kishor K et al (2019) Pharmaceuticals of emerging concern in aquatic systems: chemistry, occurrence, effects, and removal methods. Chem Rev 119:3510\u20133673. https:\/\/doi.org\/10.1021\/acs.chemrev.8b00299","journal-title":"Chem Rev"},{"key":"30785_CR43","doi-asserted-by":"publisher","first-page":"111218","DOI":"10.1016\/j.envres.2021.111218","volume":"201","author":"M Patel","year":"2021","unstructured":"Patel M, Kumar R, Pittman CU, Mohan D (2021) Ciprofloxacin and acetaminophen sorption onto banana peel biochars: environmental and process parameter influences. Environ Res 201:111218. https:\/\/doi.org\/10.1016\/j.envres.2021.111218","journal-title":"Environ Res"},{"key":"30785_CR44","doi-asserted-by":"publisher","first-page":"124391","DOI":"10.1016\/j.chemosphere.2019.124391","volume":"236","author":"HN Phong Vo","year":"2019","unstructured":"Phong Vo HN, Le GK, Hong Nguyen TM et al (2019) Acetaminophen micropollutant: Historical and current occurrences, toxicity, removal strategies and transformation pathways in different environments. Chemosphere 236:124391. https:\/\/doi.org\/10.1016\/j.chemosphere.2019.124391","journal-title":"Chemosphere"},{"key":"30785_CR45","doi-asserted-by":"publisher","first-page":"125225","DOI":"10.1016\/j.jclepro.2020.125225","volume":"291","author":"X Ren","year":"2021","unstructured":"Ren X, Wang J, Yu J et al (2021) Waste valorization: transforming the fishbone biowaste into biochar as an efficient persulfate catalyst for degradation of organic pollutant. J Clean Prod 291:125225. https:\/\/doi.org\/10.1016\/j.jclepro.2020.125225","journal-title":"J Clean Prod"},{"key":"30785_CR46","doi-asserted-by":"publisher","first-page":"131319","DOI":"10.1016\/j.jclepro.2022.131319","volume":"350","author":"J Scaria","year":"2022","unstructured":"Scaria J, Gopinath A, Ranjith N et al (2022) Carbonaceous materials as effective adsorbents and catalysts for the removal of emerging contaminants from water. J Clean Prod 350:131319. https:\/\/doi.org\/10.1016\/j.jclepro.2022.131319","journal-title":"J Clean Prod"},{"key":"30785_CR47","unstructured":"Sehnal D (2022) Atomic charge calculator. In: WebChemistry. https:\/\/webchem.ncbr.muni.cz\/Platform\/ChargeCalculator\/. Accessed 15 Feb 2023"},{"key":"30785_CR48","doi-asserted-by":"publisher","first-page":"105814","DOI":"10.1016\/j.ultsonch.2021.105814","volume":"80","author":"EA Serna-Galvis","year":"2021","unstructured":"Serna-Galvis EA, Guateque-Londo\u00f1o JF, Silva-Agredo J et al (2021) Ultrasonics Sonochemistry Superior selectivity of high-frequency ultrasound toward chorine containing-pharmaceuticals elimination in urine: a comparative study with other oxidation processes through the elucidation of the degradation pathways. Ultrason Sonochem 80:105814. https:\/\/doi.org\/10.1016\/j.ultsonch.2021.105814","journal-title":"Ultrason Sonochem"},{"key":"30785_CR49","doi-asserted-by":"publisher","first-page":"121","DOI":"10.1016\/j.cherd.2023.03.015","volume":"193","author":"EA Serna-Galvis","year":"2023","unstructured":"Serna-Galvis EA, Mart\u00ednez-Mena YL, Arboleda-Echavarr\u00eda J et al (2023) Zeolite 4A activates peroxymonosulfate toward the production of singlet oxygen for the selective degradation of organic pollutants. Chem Eng Res Des 193:121\u2013131. https:\/\/doi.org\/10.1016\/j.cherd.2023.03.015","journal-title":"Chem Eng Res Des"},{"key":"30785_CR50","doi-asserted-by":"publisher","first-page":"1","DOI":"10.1039\/c8qo00004b","volume":"5","author":"X Su","year":"2018","unstructured":"Su X, Wu P, Liu W, Chen C (2018) A concise synthesis of indene-based polycyclic compounds: via FeCl3-catalyzed cascade cyclization. Org Chem Front 5:1\u20135. https:\/\/doi.org\/10.1039\/c8qo00004b","journal-title":"Org Chem Front"},{"key":"30785_CR51","doi-asserted-by":"publisher","first-page":"297","DOI":"10.1021\/es061440e","volume":"41","author":"RA Torres","year":"2007","unstructured":"Torres RA, P\u00e9trier C, Combet E et al (2007) Bisphenol A mineralization by integrated ultrasound-UV-iron (II) treatment. Environ Sci Technol 41:297\u2013302. https:\/\/doi.org\/10.1021\/es061440e","journal-title":"Environ Sci Technol"},{"key":"30785_CR52","doi-asserted-by":"publisher","first-page":"97","DOI":"10.1289\/ehp.866997","volume":"69","author":"EA Voudrias","year":"1986","unstructured":"Voudrias EA, Larson RA, Snoeyink VL (1986) Hypochlorous acid-activated carbon: an oxidizing agent capable of producing hydroxylated polychlorinated biphenyls. Environ Health Perspect 69:97\u2013100. https:\/\/doi.org\/10.1289\/ehp.866997","journal-title":"Environ Health Perspect"},{"key":"30785_CR53","unstructured":"W2D Team - PharmaExpert (2021) PASS online"},{"key":"30785_CR54","doi-asserted-by":"publisher","first-page":"129902","DOI":"10.1016\/j.cej.2021.129902","volume":"420","author":"M Xi","year":"2021","unstructured":"Xi M, Cui K, Cui M et al (2021) Enhanced norfloxacin degradation by iron and nitrogen co-doped biochar: revealing the radical and nonradical co-dominant mechanism of persulfate activation. Chem Eng J 420:129902. https:\/\/doi.org\/10.1016\/j.cej.2021.129902","journal-title":"Chem Eng J"},{"key":"30785_CR55","doi-asserted-by":"publisher","unstructured":"Xiao S, Cheng M, Zhong H et al (2020) Iron-mediated activation of persulfate and peroxymonosulfate in both homogeneous and heterogeneous ways: a review. Chem Eng J 384. https:\/\/doi.org\/10.1016\/j.cej.2019.123265","DOI":"10.1016\/j.cej.2019.123265"},{"key":"30785_CR56","doi-asserted-by":"publisher","first-page":"39467","DOI":"10.1039\/D1RA06914D","volume":"11","author":"K Xie","year":"2021","unstructured":"Xie K, Han R, Sun P et al (2021) Rice husk biochar modified-CuCo2O4 as an efficient peroxymonosulfate activator for non-radical degradation of organic pollutants from aqueous environment. RSC Adv 11:39467\u201339475","journal-title":"RSC Adv"},{"key":"30785_CR57","doi-asserted-by":"publisher","first-page":"16000","DOI":"10.1007\/s11356-019-04346-4","volume":"26","author":"J Xiong","year":"2019","unstructured":"Xiong J, Li Y, Pang C et al (2019) Removal of pollutants in banknote printing wastewater by mesoporous Fe\/SiO2 prepared from rice husk pyrolytic residues. Environ Sci Pollut Res 26:16000\u201316013. https:\/\/doi.org\/10.1007\/s11356-019-04346-4","journal-title":"Environ Sci Pollut Res"},{"key":"30785_CR58","doi-asserted-by":"publisher","first-page":"589","DOI":"10.1016\/j.cej.2018.09.184","volume":"357","author":"R Yin","year":"2019","unstructured":"Yin R, Guo W, Wang H et al (2019) Singlet oxygen-dominated peroxydisulfate activation by sludge-derived biochar for sulfamethoxazole degradation through a nonradical oxidation pathway: performance and mechanism. Chem Eng J 357:589\u2013599. https:\/\/doi.org\/10.1016\/j.cej.2018.09.184","journal-title":"Chem Eng J"},{"key":"30785_CR59","doi-asserted-by":"publisher","first-page":"141642","DOI":"10.1016\/j.cej.2023.141642","volume":"459","author":"Y Zeng","year":"2023","unstructured":"Zeng Y, Wang F, He D et al (2023) Role of superoxide radical and singlet oxygen in peroxymonosulfate activation by iron-doped bone char for efficient acetaminophen degradation. Chem Eng J 459:141642. https:\/\/doi.org\/10.1016\/j.cej.2023.141642","journal-title":"Chem Eng J"},{"key":"30785_CR60","doi-asserted-by":"publisher","first-page":"283","DOI":"10.1016\/j.watres.2016.07.037","volume":"103","author":"R Zhang","year":"2016","unstructured":"Zhang R, Yang Y, Huang CH et al (2016) Kinetics and modeling of sulfonamide antibiotic degradation in wastewater and human urine by UV\/H2 O2 and UV\/PDS. Water Res 103:283\u2013292. https:\/\/doi.org\/10.1016\/j.watres.2016.07.037","journal-title":"Water Res"},{"key":"30785_CR61","doi-asserted-by":"publisher","first-page":"136730","DOI":"10.1016\/j.scitotenv.2020.136730","volume":"715","author":"Q Zhang","year":"2020","unstructured":"Zhang Q, Wang BX, Yu YB et al (2020) Sulfur doped-graphene for enhanced acetaminophen degradation via electro-catalytic activation: efficiency and mechanism. Sci Total Environ 715:136730. https:\/\/doi.org\/10.1016\/j.scitotenv.2020.136730","journal-title":"Sci Total Environ"},{"key":"30785_CR62","doi-asserted-by":"publisher","first-page":"125294","DOI":"10.1016\/j.jhazmat.2021.125294","volume":"413","author":"K Zhang","year":"2021","unstructured":"Zhang K, Min X, Zhang T et al (2021) Selenium and nitrogen co-doped biochar as a new metal-free catalyst for adsorption of phenol and activation of peroxymonosulfate: elucidating the enhanced catalytic performance and stability. J Hazard Mater 413:125294. https:\/\/doi.org\/10.1016\/j.jhazmat.2021.125294","journal-title":"J Hazard Mater"},{"key":"30785_CR63","doi-asserted-by":"publisher","first-page":"136050","DOI":"10.1016\/j.cej.2022.136050","volume":"443","author":"P Zhang","year":"2022","unstructured":"Zhang P, Shu Y, Wang Y et al (2022) Enhanced catalytic oxidation of bisphenol A via persulfate oxidation by microwave-assisted preparation of ZnCoxFe2-xO4-loaded rice-husk-carbon. Chem Eng J 443:136050. https:\/\/doi.org\/10.1016\/j.cej.2022.136050","journal-title":"Chem Eng J"},{"key":"30785_CR64","doi-asserted-by":"publisher","first-page":"1301","DOI":"10.2175\/106143018X15289915807236","volume":"90","author":"Y Zhao","year":"2018","unstructured":"Zhao Y, Ye L, Zhang X-X (2018) Emerging pollutants\u2013part I: occurrence, fate and transport. Water Environ Res 90:1301\u20131322. https:\/\/doi.org\/10.2175\/106143018X15289915807236","journal-title":"Water Environ Res"},{"key":"30785_CR65","doi-asserted-by":"publisher","first-page":"124371","DOI":"10.1016\/j.cej.2020.124371","volume":"388","author":"Y Zhao","year":"2020","unstructured":"Zhao Y, An H, Dong G et al (2020) Oxygen vacancies induced heterogeneous catalysis of peroxymonosulfate by Ni-doped AgFeO2 materials: evolution of reactive oxygen species and mechanism. Chem Eng J 388:124371. https:\/\/doi.org\/10.1016\/j.cej.2020.124371","journal-title":"Chem Eng J"},{"key":"30785_CR66","doi-asserted-by":"publisher","first-page":"128337","DOI":"10.1016\/j.jelechem.2021.115319","volume":"410","author":"B Zhao","year":"2021","unstructured":"Zhao B, Yu H, Liu Y et al (2021) Enhanced photoelectrocatalytic degradation of tetracycline using a bifacial electrode of nickel-polyethylene glycol-PbO2\/\/Ti\/\/TiO2-nanotubes. Chem Eng J 410:128337. https:\/\/doi.org\/10.1016\/j.jelechem.2021.115319","journal-title":"Chem Eng J"}],"container-title":["Environmental Science and Pollution Research"],"original-title":[],"language":"en","link":[{"URL":"https:\/\/link.springer.com\/content\/pdf\/10.1007\/s11356-023-30785-1.pdf","content-type":"application\/pdf","content-version":"vor","intended-application":"text-mining"},{"URL":"https:\/\/link.springer.com\/article\/10.1007\/s11356-023-30785-1\/fulltext.html","content-type":"text\/html","content-version":"vor","intended-application":"text-mining"},{"URL":"https:\/\/link.springer.com\/content\/pdf\/10.1007\/s11356-023-30785-1.pdf","content-type":"application\/pdf","content-version":"vor","intended-application":"similarity-checking"}],"deposited":{"date-parts":[[2023,12,22]],"date-time":"2023-12-22T08:33:26Z","timestamp":1703234006000},"score":1,"resource":{"primary":{"URL":"https:\/\/link.springer.com\/10.1007\/s11356-023-30785-1"}},"subtitle":[],"short-title":[],"issued":{"date-parts":[[2023,11,22]]},"references-count":66,"journal-issue":{"issue":"59","published-online":{"date-parts":[[2023,12]]}},"alternative-id":["30785"],"URL":"https:\/\/doi.org\/10.1007\/s11356-023-30785-1","relation":{},"ISSN":["1614-7499"],"issn-type":[{"value":"1614-7499","type":"electronic"}],"subject":[],"published":{"date-parts":[[2023,11,22]]},"assertion":[{"value":"8 September 2023","order":1,"name":"received","label":"Received","group":{"name":"ArticleHistory","label":"Article History"}},{"value":"27 October 2023","order":2,"name":"accepted","label":"Accepted","group":{"name":"ArticleHistory","label":"Article History"}},{"value":"22 November 2023","order":3,"name":"first_online","label":"First Online","group":{"name":"ArticleHistory","label":"Article History"}},{"order":1,"name":"Ethics","group":{"name":"EthicsHeading","label":"Declarations"}},{"value":"Not applicable.","order":2,"name":"Ethics","group":{"name":"EthicsHeading","label":"Ethical approval"}},{"value":"Not applicable.","order":3,"name":"Ethics","group":{"name":"EthicsHeading","label":"Consent to participate"}},{"value":"Not applicable.","order":4,"name":"Ethics","group":{"name":"EthicsHeading","label":"Consent for publication"}},{"value":"The authors declare no competing interests.","order":5,"name":"Ethics","group":{"name":"EthicsHeading","label":"Competing interests"}}]}}