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During the MW-AC production process, which involved two steps\u2014microwave treatment and muffle furnace heating\u2014we investigated the effects of various factors and achieved the highest iodine number of 1250\u00a0mg\/g. This was achieved under optimal operating conditions, which included a 100% impregnation ratio, CO2 as the gas in the microwave environment, a microwave power set at 500 W, a microwave duration of 10\u00a0min, an activation temperature of 500\u00a0\u00b0C and an activation time of 45\u00a0min. The structural and morphological properties of the optimized MW-AC were assessed through SEM, FTIR, and BET analysis. The dynamic adsorption process of benzene on the optimized MW-AC adsorbent, which has a significant BET surface area of 1204.90 m\n                    <jats:sup>2<\/jats:sup>\n                    \/g, was designed using the Box-Behnken approach within the response surface methodology. Under optimal experimental conditions, including a contact duration of 80\u00a0min, an inlet concentration of 18\u00a0ppm, and a temperature of 26\u00a0\u00b0C, the maximum adsorption capacity reached was 568.34\u00a0mg\/g. The experimental data are better described by the pseudo-second-order kinetic model, while it is concluded that the equilibrium data are better described by the Langmuir isotherm model. MW-AC exhibited a reuse efficiency of 86.54% for benzene vapor after five consecutive recycling processes. The motivation of the study highlights the high adsorption capacity and superior reuse efficiency of MW-AC adsorbent with high BET surface area against benzene pollutant. According to our results, the developed MW-AC presents itself as a promising adsorbent candidate for the treatment of VOCs in various industrial applications.\n                  <\/jats:p>","DOI":"10.1007\/s11356-024-32973-z","type":"journal-article","created":{"date-parts":[[2024,3,24]],"date-time":"2024-03-24T23:44:30Z","timestamp":1711323870000},"page":"27935-27948","update-policy":"https:\/\/doi.org\/10.1007\/springer_crossmark_policy","source":"Crossref","is-referenced-by-count":9,"title":["Enhanced benzene vapor adsorption through microwave-assisted fabrication of activated carbon from peanut shells using ZnCl2 as an activating agent"],"prefix":"10.1007","volume":"31","author":[{"given":"Sinan","family":"Kutluay","sequence":"first","affiliation":[],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"\u00d6mer","family":"\u015eahin","sequence":"additional","affiliation":[],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0002-2915-202X","authenticated-orcid":false,"given":"Orhan","family":"Baytar","sequence":"additional","affiliation":[],"role":[{"vocabulary":"crossref","role":"author"}]}],"member":"297","published-online":{"date-parts":[[2024,3,25]]},"reference":[{"key":"32973_CR1","doi-asserted-by":"publisher","first-page":"139636","DOI":"10.1016\/j.chemosphere.2023.139636","volume":"338","author":"R A\u00e7in Ok","year":"2023","unstructured":"A\u00e7in Ok R, Kutluay S (2023) Designing novel perlite-Fe3O4@SiO2@8-HQ-5-SA as a promising magnetic nanoadsorbent for competitive adsorption of multicomponent VOCs. 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