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Although it has been approved as a promising carbon capture and utilisation (CCU) method, its effect on the leachability of heavy metals from cementitious compounds has not yet been studied. This study focuses on the effect of in situ CO\n                    <jats:sub>2<\/jats:sub>\n                    mixing of cement paste on the leaching of hexavalent chromium (Cr(VI)). The tank leaching test of the CO\n                    <jats:sub>2<\/jats:sub>\n                    mixing cement specimen resulted in a Cr(VI) cumulative leaching of 0.614\u00a0mg\/m\n                    <jats:sup>2<\/jats:sup>\n                    in 28 d, which is ten times lower than that of the control mixing specimens. The results in thermogravimetric analysis indicated that a relatively significant amount of CrO\n                    <jats:sub>4<\/jats:sub>\n                    <jats:sup>2\u2212<\/jats:sup>\n                    is immobilised as CaCrO\n                    <jats:sub>4<\/jats:sub>\n                    during the CO\n                    <jats:sub>2<\/jats:sub>\n                    -mixing, and a higher Cr\u2013O extension is observed in the Fourier transform infrared spectra. Furthermore, a portion of the monocarboaluminate is inferred from microstructural analyses to incorporate CrO\n                    <jats:sub>4<\/jats:sub>\n                    <jats:sup>2\u2212<\/jats:sup>\n                    ions. These results demonstrate that in situ CO\n                    <jats:sub>2<\/jats:sub>\n                    mixing is beneficial not only in reducing CO\n                    <jats:sub>2<\/jats:sub>\n                    emissions, but also in controlling the leaching of toxic substances.\n                  <\/jats:p>","DOI":"10.1007\/s11356-024-34582-2","type":"journal-article","created":{"date-parts":[[2024,8,8]],"date-time":"2024-08-08T11:02:23Z","timestamp":1723114943000},"page":"51582-51592","update-policy":"https:\/\/doi.org\/10.1007\/springer_crossmark_policy","source":"Crossref","is-referenced-by-count":3,"title":["Effect of in situ CO2 mixing of cement paste on the leachability of hexavalent chromium (Cr(VI))"],"prefix":"10.1007","volume":"31","author":[{"given":"Kian","family":"Cho","sequence":"first","affiliation":[],"role":[{"role":"author","vocabulary":"crossref"}]},{"given":"Won Kyung","family":"Kim","sequence":"additional","affiliation":[],"role":[{"role":"author","vocabulary":"crossref"}]},{"given":"Juhyuk","family":"Moon","sequence":"additional","affiliation":[],"role":[{"role":"author","vocabulary":"crossref"}]},{"given":"Daniel","family":"Cha","sequence":"additional","affiliation":[],"role":[{"role":"author","vocabulary":"crossref"}]},{"ORCID":"https:\/\/orcid.org\/0000-0003-4954-8010","authenticated-orcid":false,"given":"Junboum","family":"Park","sequence":"additional","affiliation":[],"role":[{"role":"author","vocabulary":"crossref"}]}],"member":"297","published-online":{"date-parts":[[2024,8,8]]},"reference":[{"key":"34582_CR1","doi-asserted-by":"publisher","first-page":"20829","DOI":"10.1007\/s11356-019-05301-z","volume":"26","author":"N Bakhshi","year":"2019","unstructured":"Bakhshi N, Sarrafi A, Ramezanianpour AA (2019) Immobilization of hexavalent chromium in cement mortar: leaching properties and microstructures. 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