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The Arrhenius function\u2014diffusion activation energy and preexponential factor\u2014has also been determined from the data:<jats:inline-formula><jats:alternatives><jats:tex-math>$$D_{B44} = 35.2\\;{\\text{cm}}^{2} \\;{\\text{s}}^{ - 1} \\exp \\left( { - 25\\;{\\text{kJ mol}}^{ - 1} \/{\\text{RT}}} \\right)$$<\/jats:tex-math><mml:math xmlns:mml=\"http:\/\/www.w3.org\/1998\/Math\/MathML\"><mml:mrow><mml:msub><mml:mi>D<\/mml:mi><mml:mrow><mml:mi>B<\/mml:mi><mml:mn>44<\/mml:mn><\/mml:mrow><\/mml:msub><mml:mo>=<\/mml:mo><mml:mn>35.2<\/mml:mn><mml:mspace\/><mml:msup><mml:mrow><mml:mtext>cm<\/mml:mtext><\/mml:mrow><mml:mn>2<\/mml:mn><\/mml:msup><mml:mspace\/><mml:msup><mml:mrow><mml:mtext>s<\/mml:mtext><\/mml:mrow><mml:mrow><mml:mo>-<\/mml:mo><mml:mn>1<\/mml:mn><\/mml:mrow><\/mml:msup><mml:mo>exp<\/mml:mo><mml:mfenced><mml:mrow><mml:mo>-<\/mml:mo><mml:mn>25<\/mml:mn><mml:mspace\/><mml:msup><mml:mrow><mml:mtext>kJ mol<\/mml:mtext><\/mml:mrow><mml:mrow><mml:mo>-<\/mml:mo><mml:mn>1<\/mml:mn><\/mml:mrow><\/mml:msup><mml:mo>\/<\/mml:mo><mml:mtext>RT<\/mml:mtext><\/mml:mrow><\/mml:mfenced><\/mml:mrow><\/mml:math><\/jats:alternatives><\/jats:inline-formula>;<jats:inline-formula><jats:alternatives><jats:tex-math>$$D_{B72} = 9.5\\;{\\text{cm}}^{2} \\;{\\text{s}}^{ - 1} \\exp \\left( { - 23\\;{\\text{kJ mol}}^{ - 1} \/{\\text{RT}}} \\right)$$<\/jats:tex-math><mml:math xmlns:mml=\"http:\/\/www.w3.org\/1998\/Math\/MathML\"><mml:mrow><mml:msub><mml:mi>D<\/mml:mi><mml:mrow><mml:mi>B<\/mml:mi><mml:mn>72<\/mml:mn><\/mml:mrow><\/mml:msub><mml:mo>=<\/mml:mo><mml:mn>9.5<\/mml:mn><mml:mspace\/><mml:msup><mml:mrow><mml:mtext>cm<\/mml:mtext><\/mml:mrow><mml:mn>2<\/mml:mn><\/mml:msup><mml:mspace\/><mml:msup><mml:mrow><mml:mtext>s<\/mml:mtext><\/mml:mrow><mml:mrow><mml:mo>-<\/mml:mo><mml:mn>1<\/mml:mn><\/mml:mrow><\/mml:msup><mml:mo>exp<\/mml:mo><mml:mfenced><mml:mrow><mml:mo>-<\/mml:mo><mml:mn>23<\/mml:mn><mml:mspace\/><mml:msup><mml:mrow><mml:mtext>kJ mol<\/mml:mtext><\/mml:mrow><mml:mrow><mml:mo>-<\/mml:mo><mml:mn>1<\/mml:mn><\/mml:mrow><\/mml:msup><mml:mo>\/<\/mml:mo><mml:mtext>RT<\/mml:mtext><\/mml:mrow><\/mml:mfenced><\/mml:mrow><\/mml:math><\/jats:alternatives><\/jats:inline-formula>;<jats:inline-formula><jats:alternatives><jats:tex-math>$$D_{\\text{Incralac}} = 622.8\\;{\\text{cm}}^{2} \\;{\\text{s}}^{ - 1} { \\exp }\\left( { - 28\\;{\\text{kJ mol}}^{ - 1} \/{\\text{RT}}} \\right)$$<\/jats:tex-math><mml:math xmlns:mml=\"http:\/\/www.w3.org\/1998\/Math\/MathML\"><mml:mrow><mml:msub><mml:mi>D<\/mml:mi><mml:mtext>Incralac<\/mml:mtext><\/mml:msub><mml:mo>=<\/mml:mo><mml:mn>622.8<\/mml:mn><mml:mspace\/><mml:msup><mml:mrow><mml:mtext>cm<\/mml:mtext><\/mml:mrow><mml:mn>2<\/mml:mn><\/mml:msup><mml:mspace\/><mml:msup><mml:mrow><mml:mtext>s<\/mml:mtext><\/mml:mrow><mml:mrow><mml:mo>-<\/mml:mo><mml:mn>1<\/mml:mn><\/mml:mrow><\/mml:msup><mml:mo>exp<\/mml:mo><mml:mfenced><mml:mrow><mml:mo>-<\/mml:mo><mml:mn>28<\/mml:mn><mml:mspace\/><mml:msup><mml:mrow><mml:mtext>kJ mol<\/mml:mtext><\/mml:mrow><mml:mrow><mml:mo>-<\/mml:mo><mml:mn>1<\/mml:mn><\/mml:mrow><\/mml:msup><mml:mo>\/<\/mml:mo><mml:mtext>RT<\/mml:mtext><\/mml:mrow><\/mml:mfenced><\/mml:mrow><\/mml:math><\/jats:alternatives><\/jats:inline-formula>. These resins are important coating materials, for example, for conservators to protect metallic artifacts, such as statues, against corrosion. Despite Paraloid B44 and B72 resins being\u00a0considered as reference materials in conservation practice, that is, new coating materials (either water vapor retarders or transmitters) are often compared to them, there are no comprehensive data for the quantities describing the vapor permeability (<jats:italic>P, S, D<\/jats:italic>) of these materials. The measurements are based on the ISO cup-method using substrate\/coating composite samples. The strength of this technique is that it can also be used when the coating is non-self-supporting; nevertheless,<jats:italic>P<\/jats:italic>,<jats:italic>S,<\/jats:italic>and<jats:italic>D<\/jats:italic>can be deduced for the coating layer itself, and it seems to be a standardizable procedure for comparative performance testing of coating materials. Paraloid B72 layers exhibited higher WVTRs\u2014from 39 to 315\u00a0g\u00a0m<jats:sup>\u22122<\/jats:sup>day<jats:sup>\u22121<\/jats:sup>as the temperature increased from 5 to 35\u00b0C\u2014compared to Paraloid B44 and Incralac coatings\u2014from 17 to 190\u00a0g\u00a0m<jats:sup>\u22122<\/jats:sup>\u00a0day<jats:sup>\u22121<\/jats:sup>, respectively. The transmission rate parameters were also compared to the results of corrosion tests. Incralac was the most effective corrosion inhibitor, and\u00a0the performance of the B44 was better than the B72, which is in good agreement with the transmission rate tests.<\/jats:p>","DOI":"10.1007\/s11998-020-00421-5","type":"journal-article","created":{"date-parts":[[2020,12,22]],"date-time":"2020-12-22T16:03:20Z","timestamp":1608653000000},"page":"523-534","update-policy":"https:\/\/doi.org\/10.1007\/springer_crossmark_policy","source":"Crossref","is-referenced-by-count":13,"title":["Water vapor transmission properties of acrylic organic coatings"],"prefix":"10.1007","volume":"18","author":[{"given":"R\u00e9ka Lilla","family":"Kov\u00e1cs","sequence":"first","affiliation":[],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Lajos","family":"Dar\u00f3czi","sequence":"additional","affiliation":[],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"P\u00e9ter","family":"Bark\u00f3czy","sequence":"additional","affiliation":[],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Eszter","family":"Barad\u00e1cs","sequence":"additional","affiliation":[],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Eszter","family":"Bakonyi","sequence":"additional","affiliation":[],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Szilvia","family":"Kov\u00e1cs","sequence":"additional","affiliation":[],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Zolt\u00e1n","family":"Erd\u00e9lyi","sequence":"additional","affiliation":[],"role":[{"vocabulary":"crossref","role":"author"}]}],"member":"297","published-online":{"date-parts":[[2020,12,22]]},"reference":[{"issue":"1\u20132","key":"421_CR1","doi-asserted-by":"publisher","first-page":"5","DOI":"10.1016\/S0300-9440(97)00013-1","volume":"31","author":"W Funke","year":"1997","unstructured":"Funke, W, \u201cProblems and Progress in Organic Coatings Science and Technology.\u201d Prog. 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