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The CO<jats:sub>2<\/jats:sub>RR approach suffers from kinetic-sluggish oxygen evolution reaction at the anode. To this end, an electrochemical system combining cathodic CO<jats:sub>2<\/jats:sub>RR with anodic FOR was developed, which enables the formate electrosynthesis at ultra-low voltage. Cathodic CO<jats:sub>2<\/jats:sub>RR employing the BiOCl electrode in H-cell exhibited formate Faradaic efficiency (FE) higher than 90% within a wide potential range from \u2212\u20090.48 to \u2212\u20091.32 <jats:italic>V<\/jats:italic><jats:sub>RHE<\/jats:sub>. In flow cell, the current density of 100\u00a0mA\u00a0cm<jats:sup>\u22122<\/jats:sup> was achieved at \u2212\u20090.67 <jats:italic>V<\/jats:italic><jats:sub>RHE<\/jats:sub>. The anodic FOR using the Cu<jats:sub>2<\/jats:sub>O electrode displayed a low onset potential of \u2212\u20090.13 <jats:italic>V<\/jats:italic><jats:sub>RHE<\/jats:sub> and nearly 100% formate and H<jats:sub>2<\/jats:sub> selectivity from 0.05 to 0.35 <jats:italic>V<\/jats:italic><jats:sub>RHE<\/jats:sub>. The CO<jats:sub>2<\/jats:sub>RR and FOR were constructed in a flow cell through membrane electrode assembly for the electrosynthesis of formate, where the CO<jats:sub>2<\/jats:sub>RR\/\/FOR delivered an enhanced current density of 100\u00a0mA\u00a0cm<jats:sup>\u22122<\/jats:sup> at 0.86\u00a0V. This work provides a promising pair-electrosynthesis of value-added chemicals with high FE and low energy consumption.<\/jats:p>","DOI":"10.1007\/s40820-022-00953-y","type":"journal-article","created":{"date-parts":[[2022,11,1]],"date-time":"2022-11-01T18:03:00Z","timestamp":1667325780000},"update-policy":"https:\/\/doi.org\/10.1007\/springer_crossmark_policy","source":"Crossref","is-referenced-by-count":80,"title":["A Pair-Electrosynthesis for Formate at Ultra-Low Voltage Via Coupling of CO2 Reduction and Formaldehyde Oxidation"],"prefix":"10.1007","volume":"14","author":[{"given":"Mengyu","family":"Li","sequence":"first","affiliation":[],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Tehua","family":"Wang","sequence":"additional","affiliation":[],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Weixing","family":"Zhao","sequence":"additional","affiliation":[],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Shuangyin","family":"Wang","sequence":"additional","affiliation":[],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Yuqin","family":"Zou","sequence":"additional","affiliation":[],"role":[{"vocabulary":"crossref","role":"author"}]}],"member":"297","published-online":{"date-parts":[[2022,11,1]]},"reference":[{"issue":"8","key":"953_CR1","doi-asserted-by":"publisher","first-page":"5071","DOI":"10.1021\/acscatal.7b00707","volume":"7","author":"JH Koh","year":"2017","unstructured":"J.H. 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