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Herein, a high-performance quinone-based polymer (H-PNADBQ) material is designed by introducing an intramolecular hydrogen bonding (HB) strategy. The intramolecular HB (C=O\u22efN\u2013H) is formed in the reaction of 1,4-benzoquinone and 1,5-naphthalene diamine, which efficiently reduces the H-PNADBQ solubility and enhances its charge transfer in theory. In situ ultraviolet\u2013visible analysis further reveals the insolubility of H-PNADBQ during the electrochemical cycles, enabling high durability at different current densities. Specifically, the H-PNADBQ electrode with high loading (10\u00a0mg\u00a0cm<jats:sup>\u22122<\/jats:sup>) performs a long cycling life at 125\u00a0mA\u00a0g<jats:sup>\u22121<\/jats:sup> (&gt;\u2009290 cycles). The H-PNADBQ also shows high rate capability (137.1\u00a0mAh\u00a0g<jats:sup>\u22121<\/jats:sup> at 25\u00a0A\u00a0g<jats:sup>\u22121<\/jats:sup>) due to significantly improved kinetics inducted by intramolecular HB. This work provides an efficient approach toward insoluble organic electrode materials.<\/jats:p>","DOI":"10.1007\/s40820-023-01263-7","type":"journal-article","created":{"date-parts":[[2023,12,8]],"date-time":"2023-12-08T16:02:18Z","timestamp":1702051338000},"update-policy":"https:\/\/doi.org\/10.1007\/springer_crossmark_policy","source":"Crossref","is-referenced-by-count":46,"title":["Intramolecular Hydrogen Bond Improved Durability and Kinetics for Zinc-Organic Batteries"],"prefix":"10.1007","volume":"16","author":[{"given":"Tianjiang","family":"Sun","sequence":"first","affiliation":[],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Jun","family":"Pan","sequence":"additional","affiliation":[],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Weijia","family":"Zhang","sequence":"additional","affiliation":[],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Xiaodi","family":"Jiang","sequence":"additional","affiliation":[],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Min","family":"Cheng","sequence":"additional","affiliation":[],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Zhengtai","family":"Zha","sequence":"additional","affiliation":[],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Hong Jin","family":"Fan","sequence":"additional","affiliation":[],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Zhanliang","family":"Tao","sequence":"additional","affiliation":[],"role":[{"vocabulary":"crossref","role":"author"}]}],"member":"297","published-online":{"date-parts":[[2023,12,8]]},"reference":[{"key":"1263_CR1","doi-asserted-by":"publisher","first-page":"841","DOI":"10.1038\/nmat4919","volume":"16","author":"Y Liang","year":"2017","unstructured":"Y. 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