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Herein, we report efficient electrocatalytic oxidations of saturated alcohols (C\n                    <jats:sub>1<\/jats:sub>\n                    -C\n                    <jats:sub>6<\/jats:sub>\n                    ) to selectively form formate using NiCo hydroxide (NiCo\u2013OH) derived NiCo\n                    <jats:sub>2<\/jats:sub>\n                    O\n                    <jats:sub>4<\/jats:sub>\n                    solid-acid electrocatalysts with balanced Lewis acid (LASs) and Br\u00f8nsted acid sites (BASs). Thermal treatment transforms BASs-rich (89.6%) NiCo\u2013OH into NiCo\n                    <jats:sub>2<\/jats:sub>\n                    O\n                    <jats:sub>4<\/jats:sub>\n                    with nearly equal distribution of LASs (53.1%) and BASs (46.9%) which synergistically promote adsorption and activation of OH\n                    <jats:sup>\u2212<\/jats:sup>\n                    and alcohol molecules for enhanced oxidation activity. In contrast, BASs-enriched NiCo\u2013OH facilitates formation of higher valence metal sites, beneficial for water oxidation. The combined experimental studies and theoretical calculation imply the oxidation ability of C\n                    <jats:sub>1<\/jats:sub>\n                    -C\n                    <jats:sub>6<\/jats:sub>\n                    alcohols increases as increased number of hydroxyl groups and decreased HOMO\u2013LUMO gaps: methanol (C\n                    <jats:sub>1<\/jats:sub>\n                    )\u2009&lt;\u2009ethylene glycol (C\n                    <jats:sub>2<\/jats:sub>\n                    )\u2009&lt;\u2009glycerol (C\n                    <jats:sub>3<\/jats:sub>\n                    )\u2009&lt;\u2009meso-erythritol (C\n                    <jats:sub>4<\/jats:sub>\n                    )\u2009&lt;\u2009xylitol (C\n                    <jats:sub>5<\/jats:sub>\n                    )\u2009&lt;\u2009sorbitol (C\n                    <jats:sub>6<\/jats:sub>\n                    ), while the formate selectivity shows the opposite trend from 100 to 80%. This study unveils synergistic roles of LASs and BASs, as well as hydroxyl group effect in electro-upgrading of alcohols using solid-acid electrocatalysts.\n                  <\/jats:p>","DOI":"10.1007\/s40820-025-01893-z","type":"journal-article","created":{"date-parts":[[2025,8,25]],"date-time":"2025-08-25T03:20:48Z","timestamp":1756092048000},"update-policy":"https:\/\/doi.org\/10.1007\/springer_crossmark_policy","source":"Crossref","is-referenced-by-count":4,"title":["Saturated Alcohols Electrocatalytic Oxidations on Ni-Co Bimetal Oxide Featuring Balanced B- and L-Acidic Active Sites"],"prefix":"10.1007","volume":"18","author":[{"given":"Junqing","family":"Ma","sequence":"first","affiliation":[],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Wenshu","family":"Luo","sequence":"additional","affiliation":[],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Xunlu","family":"Wang","sequence":"additional","affiliation":[],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Xu","family":"Yu","sequence":"additional","affiliation":[],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Jiacheng Jayden","family":"Wang","sequence":"additional","affiliation":[],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Huashuai","family":"Hu","sequence":"additional","affiliation":[],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Hanxiao","family":"Du","sequence":"additional","affiliation":[],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Jianrong","family":"Zeng","sequence":"additional","affiliation":[],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Wei","family":"Chen","sequence":"additional","affiliation":[],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Minghui","family":"Yang","sequence":"additional","affiliation":[],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Jiacheng","family":"Wang","sequence":"additional","affiliation":[],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Xiangzhi","family":"Cui","sequence":"additional","affiliation":[],"role":[{"vocabulary":"crossref","role":"author"}]}],"member":"297","published-online":{"date-parts":[[2025,8,25]]},"reference":[{"issue":"7612","key":"1893_CR1","doi-asserted-by":"publisher","first-page":"406","DOI":"10.1038\/nature18008","volume":"535","author":"A Badalyan","year":"2016","unstructured":"A. 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