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The introduction of supporting scaffolds usually causes a reduction in the total hydrogen storage capacity due to \u201cdead weight.\u201d Here, we synthesize an optimized N-doped porous carbon (rN-pC) without heavy metal as supporting scaffold to confine Mg\/MgH\n                    <jats:sub>2<\/jats:sub>\n                    nanoparticles (Mg\/MgH\n                    <jats:sub>2<\/jats:sub>\n                    @rN-pC). rN-pC with 60 wt% loading capacity of Mg (denoted as 60\u00a0Mg@rN-pC) can adsorb and desorb 0.62 wt% H\n                    <jats:sub>2<\/jats:sub>\n                    on the rN-pC scaffold. The nanoconfined MgH\n                    <jats:sub>2<\/jats:sub>\n                    can be chemically dehydrided at 175\u00a0\u00b0C, providing\u2009~\u20093.59 wt% H\n                    <jats:sub>2<\/jats:sub>\n                    with fast kinetics (fully dehydrogenated at 300\u00a0\u00b0C within 15\u00a0min). This study presents the first realization of nanoconfined Mg-based system with adsorption-active scaffolds. Besides, the nanoconfined MgH\n                    <jats:sub>2<\/jats:sub>\n                    formation enthalpy is reduced to\u2009~\u200968\u00a0kJ\u00a0mol\n                    <jats:sup>\u22121<\/jats:sup>\n                    H\n                    <jats:sub>2<\/jats:sub>\n                    from\u2009~\u200975\u00a0kJ\u00a0mol\n                    <jats:sup>\u22121<\/jats:sup>\n                    H\n                    <jats:sub>2<\/jats:sub>\n                    for pure MgH\n                    <jats:sub>2<\/jats:sub>\n                    . The composite can be also compressed to nanostructured pellets, with volumetric H\n                    <jats:sub>2<\/jats:sub>\n                    density reaching 33.4\u00a0g L\n                    <jats:sup>\u22121<\/jats:sup>\n                    after 500\u00a0MPa compression pressure, which surpasses the 24\u00a0g L\n                    <jats:sup>\u22121<\/jats:sup>\n                    volumetric capacity of 350\u00a0bar compressed H\n                    <jats:sub>2<\/jats:sub>\n                    . Our approach can be implemented to the design of hybrid H\n                    <jats:sub>2<\/jats:sub>\n                    storage materials with enhanced capacity and desorption rate.\n                  <\/jats:p>","DOI":"10.1007\/s40820-025-01931-w","type":"journal-article","created":{"date-parts":[[2026,1,2]],"date-time":"2026-01-02T03:42:57Z","timestamp":1767325377000},"update-policy":"https:\/\/doi.org\/10.1007\/springer_crossmark_policy","source":"Crossref","is-referenced-by-count":10,"title":["Achieving Wide-Temperature-Range Physical and Chemical Hydrogen Sorption in a Structural Optimized Mg\/N-Doped Porous Carbon Nanocomposite"],"prefix":"10.1007","volume":"18","author":[{"given":"Yinghui","family":"Li","sequence":"first","affiliation":[],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Li","family":"Ren","sequence":"additional","affiliation":[],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Zi","family":"Li","sequence":"additional","affiliation":[],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Yingying","family":"Yao","sequence":"additional","affiliation":[],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Xi","family":"Lin","sequence":"additional","affiliation":[],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Wenjiang","family":"Ding","sequence":"additional","affiliation":[],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Andrea C.","family":"Ferrari","sequence":"additional","affiliation":[],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Jianxin","family":"Zou","sequence":"additional","affiliation":[],"role":[{"vocabulary":"crossref","role":"author"}]}],"member":"297","published-online":{"date-parts":[[2026,1,2]]},"reference":[{"issue":"11","key":"1931_CR1","doi-asserted-by":"publisher","first-page":"1214","DOI":"10.1038\/s41557-022-01056-2","volume":"14","author":"MD Allendorf","year":"2022","unstructured":"M.D. Allendorf, V. 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