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However, the requirement of highly pure H\n                    <jats:sub>2<\/jats:sub>\n                    for re-hydrogenation limits its wide application. Here, amorphous Al\n                    <jats:sub>2<\/jats:sub>\n                    O\n                    <jats:sub>3<\/jats:sub>\n                    shells (10\u00a0nm) were deposited on the surface of highly active hydrogen storage material particles (MgH\n                    <jats:sub>2<\/jats:sub>\n                    \u2013ZrTi) by atomic layer deposition to obtain MgH\n                    <jats:sub>2<\/jats:sub>\n                    \u2013ZrTi@Al\n                    <jats:sub>2<\/jats:sub>\n                    O\n                    <jats:sub>3<\/jats:sub>\n                    , which have been demonstrated to be air stable with selective adsorption of H\n                    <jats:sub>2<\/jats:sub>\n                    under a hydrogen atmosphere with different impurities (CH\n                    <jats:sub>4<\/jats:sub>\n                    , O\n                    <jats:sub>2<\/jats:sub>\n                    , N\n                    <jats:sub>2<\/jats:sub>\n                    , and CO\n                    <jats:sub>2<\/jats:sub>\n                    ). About 4.79\u00a0wt% H\n                    <jats:sub>2<\/jats:sub>\n                    was adsorbed by MgH\n                    <jats:sub>2<\/jats:sub>\n                    \u2013ZrTi@10nmAl\n                    <jats:sub>2<\/jats:sub>\n                    O\n                    <jats:sub>3<\/jats:sub>\n                    at 75\u00a0\u00b0C under 10%CH\n                    <jats:sub>4<\/jats:sub>\n                    \u2009+\u200990%H\n                    <jats:sub>2<\/jats:sub>\n                    atmosphere within 3\u00a0h with no kinetic or density decay after 5 cycles (~\u2009100% capacity retention). Furthermore, about 4\u00a0wt% of H\n                    <jats:sub>2<\/jats:sub>\n                    was absorbed by MgH\n                    <jats:sub>2<\/jats:sub>\n                    \u2013ZrTi@10nmAl\n                    <jats:sub>2<\/jats:sub>\n                    O\n                    <jats:sub>3<\/jats:sub>\n                    under 0.1%O\n                    <jats:sub>2<\/jats:sub>\n                    \u2009+\u20090.4%N\n                    <jats:sub>2<\/jats:sub>\n                    \u2009+\u200999.5%H\n                    <jats:sub>2<\/jats:sub>\n                    and 0.1%CO\n                    <jats:sub>2<\/jats:sub>\n                    \u2009+\u20090.4%N\n                    <jats:sub>2<\/jats:sub>\n                    \u2009+\u200999.5%H\n                    <jats:sub>2<\/jats:sub>\n                    atmospheres at 100\u00a0\u00b0C within 0.5\u00a0h, respectively, demonstrating the selective hydrogen absorption of MgH\n                    <jats:sub>2<\/jats:sub>\n                    \u2013ZrTi@10nmAl\n                    <jats:sub>2<\/jats:sub>\n                    O\n                    <jats:sub>3<\/jats:sub>\n                    in both oxygen-containing and carbon dioxide-containing atmospheres hydrogen atmosphere. The absorption and desorption curves of MgH\n                    <jats:sub>2<\/jats:sub>\n                    \u2013ZrTi@10nmAl\n                    <jats:sub>2<\/jats:sub>\n                    O\n                    <jats:sub>3<\/jats:sub>\n                    with and without absorption in pure hydrogen and then in 21%O\n                    <jats:sub>2<\/jats:sub>\n                    \u2009+\u200979%N\n                    <jats:sub>2<\/jats:sub>\n                    for 1\u00a0h were found to overlap, further confirming the successful shielding effect of Al\n                    <jats:sub>2<\/jats:sub>\n                    O\n                    <jats:sub>3<\/jats:sub>\n                    shells against O\n                    <jats:sub>2<\/jats:sub>\n                    and N\n                    <jats:sub>2<\/jats:sub>\n                    . The MgH\n                    <jats:sub>2<\/jats:sub>\n                    \u2013ZrTi@10nmAl\n                    <jats:sub>2<\/jats:sub>\n                    O\n                    <jats:sub>3<\/jats:sub>\n                    has been demonstrated to be air stable and have excellent selective hydrogen absorption performance under the atmosphere with CH\n                    <jats:sub>4<\/jats:sub>\n                    , O\n                    <jats:sub>2<\/jats:sub>\n                    , N\n                    <jats:sub>2<\/jats:sub>\n                    , and CO\n                    <jats:sub>2<\/jats:sub>\n                    .\n                  <\/jats:p>","DOI":"10.1007\/s40820-025-01934-7","type":"journal-article","created":{"date-parts":[[2025,10,24]],"date-time":"2025-10-24T00:02:31Z","timestamp":1761264151000},"update-policy":"https:\/\/doi.org\/10.1007\/springer_crossmark_policy","source":"Crossref","is-referenced-by-count":6,"title":["Solid\u2013State Hydrogen Storage Materials with Excellent Selective Hydrogen Adsorption in the Presence of Alkanes, Oxygen, and Carbon Dioxide by Atomic Layer Amorphous Al2O3 Encapsulation"],"prefix":"10.1007","volume":"18","author":[{"given":"Fanqi","family":"Bu","sequence":"first","affiliation":[],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Zhenyu","family":"Wang","sequence":"additional","affiliation":[],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Ali","family":"Wajid","sequence":"additional","affiliation":[],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Rui","family":"Zhai","sequence":"additional","affiliation":[],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Ting","family":"Liu","sequence":"additional","affiliation":[],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Yaohua","family":"Li","sequence":"additional","affiliation":[],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Xin","family":"Ji","sequence":"additional","affiliation":[],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Xin","family":"Liu","sequence":"additional","affiliation":[],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Shujiang","family":"Ding","sequence":"additional","affiliation":[],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Yonghong","family":"Cheng","sequence":"additional","affiliation":[],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Jinying","family":"Zhang","sequence":"additional","affiliation":[],"role":[{"vocabulary":"crossref","role":"author"}]}],"member":"297","published-online":{"date-parts":[[2025,10,24]]},"reference":[{"key":"1934_CR1","doi-asserted-by":"publisher","first-page":"168","DOI":"10.1016\/j.ensm.2017.01.010","volume":"10","author":"Y Sun","year":"2018","unstructured":"Y. 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