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Herein, we design an electrically insulating rigid electrolyte container to immobilize a liquid halogen-ion electrolyte for separator-free Zn-halogen batteries with customizable electron transfer. Robust hydrogen bonding of hydroxyl groups in SiO\n                    <jats:sub>2<\/jats:sub>\n                    with fluorinated moieties in PVDF-\n                    <jats:italic>hfp<\/jats:italic>\n                    regulates Zn\n                    <jats:sup>2+<\/jats:sup>\n                    solvation and suppresses H\n                    <jats:sub>2<\/jats:sub>\n                    O activity, while multi-channels formed by microcracks and interparticle gaps not only enhance mass transfer but also buffer interfacial electric field, jointly enabling a durable Zn plating\/stripping. Effective confinement of intermediates also ensures the high reversibility across single-(I\n                    <jats:sup>\u2212<\/jats:sup>\n                    \/I\n                    <jats:sup>0<\/jats:sup>\n                    ), double-(I\n                    <jats:sup>\u2212<\/jats:sup>\n                    \/I\n                    <jats:sup>0<\/jats:sup>\n                    \/I\u207a), and triple-(I\n                    <jats:sup>\u2212<\/jats:sup>\n                    \/I\n                    <jats:sup>0<\/jats:sup>\n                    \/I\u207a, Cl\n                    <jats:sup>\u2212<\/jats:sup>\n                    \/Cl\n                    <jats:sup>0<\/jats:sup>\n                    ) electron transfer mechanisms at cathode, as evidenced by the double-electron transfer systems exhibiting a low capacity decay rate of 0.02\u2030 over 4500 cycles at 10 mA cm\n                    <jats:sup>\u22122<\/jats:sup>\n                    and a high areal capacity of 11.9 mAh cm\n                    <jats:sup>\u22122<\/jats:sup>\n                    at 2 mA cm\n                    <jats:sup>\u22122<\/jats:sup>\n                    . This work presents a novel \u201ccontainer engineering\u201d approach to halogen-ion electrolyte design and provides fundamental insights into the relationships between redox reversibility and reaction kinetics.\n                  <\/jats:p>","DOI":"10.1007\/s40820-025-02007-5","type":"journal-article","created":{"date-parts":[[2026,1,5]],"date-time":"2026-01-05T02:01:32Z","timestamp":1767578492000},"update-policy":"https:\/\/doi.org\/10.1007\/springer_crossmark_policy","source":"Crossref","is-referenced-by-count":11,"title":["Electrically Insulating Rigid Multi-Channel Electrolyte Container for Customizable Electron Transfer in Zn-Halogen Batteries"],"prefix":"10.1007","volume":"18","author":[{"given":"Yifan","family":"Zhou","sequence":"first","affiliation":[],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Yicai","family":"Pan","sequence":"additional","affiliation":[],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Yongqiang","family":"Yang","sequence":"additional","affiliation":[],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Taghreed F.","family":"Altamimi","sequence":"additional","affiliation":[],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Yunpeng","family":"Zhong","sequence":"additional","affiliation":[],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Dalal A.","family":"Alshammari","sequence":"additional","affiliation":[],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Zeinhom M.","family":"El-Bahy","sequence":"additional","affiliation":[],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Shuquan","family":"Liang","sequence":"additional","affiliation":[],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Jiang","family":"Zhou","sequence":"additional","affiliation":[],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Xinxin","family":"Cao","sequence":"additional","affiliation":[],"role":[{"vocabulary":"crossref","role":"author"}]}],"member":"297","published-online":{"date-parts":[[2026,1,5]]},"reference":[{"issue":"11","key":"2007_CR1","doi-asserted-by":"publisher","first-page":"3288","DOI":"10.1039\/c9ee02526j","volume":"12","author":"B Tang","year":"2019","unstructured":"B. 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