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Herein, loose selective interface (LSI) is in situ constructed by self-assembly of porous organic cages (POCs) for practical Ah-level aqueous zinc metal batteries. The delicate balance between hydrogen-bonding interactions of POC-POC and coordination interactions of POC\u2013anion\/cation endows LSI with loose porous structure, selective Zn\n                    <jats:sup>2+<\/jats:sup>\n                    -conducting channels and dynamic self-repairing capability. LSI obtains the high Zn\n                    <jats:sup>2+<\/jats:sup>\n                    transfer number of 0.8, fast desolvation kinetics and homogeneous electric field distribution, which induces the dendrite-free Zn deposition along the Zn (002) plane. Meanwhile, LSI effectively confines the activity of interfacial water and enhances interfacial hydrophobicity, thus inhibiting the water-induced side reactions. Notably, Zn\/\/Zn cells deliver the cycling life over 3200 cycles at 50\u00a0mA\u00a0cm\n                    <jats:sup>\u22122<\/jats:sup>\n                    and Zn\/\/NVO full cells stably perform over 10,000 cycles at 10\u00a0A\u00a0g\n                    <jats:sup>\u22121<\/jats:sup>\n                    . Moreover, Ah-level pouch cell with high cathode areal capacity of 7.25\u00a0mAh\u00a0cm\n                    <jats:sup>\u22122<\/jats:sup>\n                    and limited\n                    <jats:italic>N<\/jats:italic>\n                    \/\n                    <jats:italic>P<\/jats:italic>\n                    of 2.65 delivers the initial discharge capacity of 1\u00a0Ah and cycling stability for over 237\u00a0cycles. This study offers a novel methodology for constructing stable highly conductive interfaces with porous materials.\n                  <\/jats:p>","DOI":"10.1007\/s40820-026-02264-y","type":"journal-article","created":{"date-parts":[[2026,7,8]],"date-time":"2026-07-08T08:34:57Z","timestamp":1783499697000},"update-policy":"https:\/\/doi.org\/10.1007\/springer_crossmark_policy","source":"Crossref","is-referenced-by-count":1,"title":["Engineering In Situ Loose Selective Interface with Conducting Channels for Practical Ah-Level Aqueous Zinc Metal Batteries"],"prefix":"10.1007","volume":"18","author":[{"given":"Dongdong","family":"Wang","sequence":"first","affiliation":[],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Shuo","family":"Dou","sequence":"additional","affiliation":[],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Qiongying","family":"Huang","sequence":"additional","affiliation":[],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Jiaying","family":"Li","sequence":"additional","affiliation":[],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Mi","family":"Xu","sequence":"additional","affiliation":[],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Jingshuai","family":"Li","sequence":"additional","affiliation":[],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Zhendong","family":"Guo","sequence":"additional","affiliation":[],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Siqi","family":"Qin","sequence":"additional","affiliation":[],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Tieyan","family":"Wang","sequence":"additional","affiliation":[],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Haipeng","family":"Yu","sequence":"additional","affiliation":[],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Haozhen","family":"Dou","sequence":"additional","affiliation":[],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Zhongwei","family":"Chen","sequence":"additional","affiliation":[],"role":[{"vocabulary":"crossref","role":"author"}]}],"member":"297","published-online":{"date-parts":[[2026,7,8]]},"reference":[{"key":"2264_CR1","doi-asserted-by":"publisher","DOI":"10.1038\/s41467-024-48444-5","volume":"15","author":"Q Nian","year":"2024","unstructured":"Q. 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