{"status":"ok","message-type":"work","message-version":"1.0.0","message":{"indexed":{"date-parts":[[2026,4,5]],"date-time":"2026-04-05T16:21:18Z","timestamp":1775406078318,"version":"3.50.1"},"reference-count":115,"publisher":"Springer Science and Business Media LLC","issue":"3","license":[{"start":{"date-parts":[[2016,5,30]],"date-time":"2016-05-30T00:00:00Z","timestamp":1464566400000},"content-version":"tdm","delay-in-days":0,"URL":"http:\/\/www.springer.com\/tdm"},{"start":{"date-parts":[[2016,5,30]],"date-time":"2016-05-30T00:00:00Z","timestamp":1464566400000},"content-version":"vor","delay-in-days":0,"URL":"http:\/\/www.springer.com\/tdm"}],"funder":[{"DOI":"10.13039\/100000928","name":"Welch Foundation","doi-asserted-by":"publisher","award":["F-0038"],"award-info":[{"award-number":["F-0038"]}],"id":[{"id":"10.13039\/100000928","id-type":"DOI","asserted-by":"publisher"}]},{"DOI":"10.13039\/100000057","name":"National Institute of General Medical Sciences","doi-asserted-by":"publisher","award":["069445"],"award-info":[{"award-number":["069445"]}],"id":[{"id":"10.13039\/100000057","id-type":"DOI","asserted-by":"publisher"}]}],"content-domain":{"domain":["link.springer.com"],"crossmark-restriction":false},"short-container-title":["Top Curr Chem (Z)"],"published-print":{"date-parts":[[2016,6]]},"DOI":"10.1007\/s41061-016-0028-0","type":"journal-article","created":{"date-parts":[[2016,5,30]],"date-time":"2016-05-30T07:55:07Z","timestamp":1464594907000},"update-policy":"https:\/\/doi.org\/10.1007\/springer_crossmark_policy","source":"Crossref","is-referenced-by-count":17,"title":["Ruthenium-Catalyzed Transfer Hydrogenation for C\u2013C Bond Formation: Hydrohydroxyalkylation and Hydroaminoalkylation via Reactant Redox Pairs"],"prefix":"10.1007","volume":"374","author":[{"given":"Felix","family":"Perez","sequence":"first","affiliation":[],"role":[{"role":"author","vocabulary":"crossref"}]},{"given":"Susumu","family":"Oda","sequence":"additional","affiliation":[],"role":[{"role":"author","vocabulary":"crossref"}]},{"given":"Laina M.","family":"Geary","sequence":"additional","affiliation":[],"role":[{"role":"author","vocabulary":"crossref"}]},{"given":"Michael J.","family":"Krische","sequence":"additional","affiliation":[],"role":[{"role":"author","vocabulary":"crossref"}]}],"member":"297","published-online":{"date-parts":[[2016,5,30]]},"reference":[{"key":"28_CR1","unstructured":"James F. Boyce is credited with the hydrogenation of vegetable oils prior to Sabatier\u2019s seminal work. To our knowledge, the earliest written record of Boyce\u2019s work is a patent filed in 1911: Boyce, J \u201cProcess of producing an edible compound.\u201d US1061254 A, May 6, 1913"},{"key":"28_CR2","first-page":"1358","volume":"124","author":"P Sabatier","year":"1897","unstructured":"Sabatier P, Senderens J-B (1897) Action du Nickel sur l\u2019\u00c9thyl\u00e9ne. Synth\u00e9ses de l\u2019\u00c9thane. C R Acad Sci Paris 124:1358\u20131360","journal-title":"C R Acad Sci Paris"},{"key":"28_CR3","doi-asserted-by":"publisher","first-page":"7376","DOI":"10.1002\/anie.201201849","volume":"51","author":"HB Kagan","year":"2012","unstructured":"Kagan HB (2012) Victor Grignard and Paul Sabatier: two showcase laureates of the Nobel Prize for Chemistry. Angew Chem Int Ed 51:7376\u20137382","journal-title":"Angew Chem Int Ed"},{"key":"28_CR4","doi-asserted-by":"publisher","first-page":"1397","DOI":"10.1021\/ja01427a021","volume":"44","author":"V Voorhees","year":"1922","unstructured":"Voorhees V, Adams R (1922) The use of the oxides of platinum for the catalytic reduction of organic compounds. J Am Chem Soc 44:1397\u20131405","journal-title":"J Am Chem Soc"},{"key":"28_CR5","doi-asserted-by":"publisher","first-page":"1181","DOI":"10.1039\/tf9383401181","volume":"34","author":"M Calvin","year":"1938","unstructured":"Calvin M, Polyani M (1938) Homogeneous catalytic hydrogenation. Trans Faraday Soc 34:1181\u20131191","journal-title":"Trans Faraday Soc"},{"key":"28_CR6","doi-asserted-by":"publisher","first-page":"753","DOI":"10.1021\/ja01464a055","volume":"83","author":"J Halpern","year":"1961","unstructured":"Halpern J, Harrod JF, James BR (1961) Homogeneous catalytic hydrogenation of olefinic compounds. J Am Chem Soc 83:753\u2013754","journal-title":"J Am Chem Soc"},{"key":"28_CR7","doi-asserted-by":"publisher","first-page":"679","DOI":"10.1021\/ja00863a040","volume":"84","author":"L Vaska","year":"1962","unstructured":"Vaska L, DiLuzio JW (1962) Activation of hydrogen by a transition metal complex at normal conditions leading to a stable molecular dihydride. J Am Chem Soc 84:679\u2013680","journal-title":"J Am Chem Soc"},{"key":"28_CR8","unstructured":"Jardine FH, Osborn JA, Wilkinson G, Young JF (1965) Homogeneous catalytic hydrogenation and hydroformylation of acetylenic compounds. Chem Ind 560\u2013561"},{"key":"28_CR9","doi-asserted-by":"crossref","unstructured":"Young JF, Osborn JA, Jardine FH, Wilkinson G (1965) Hydride intermediates in homogeneous hydrogenation reactions of olefins and acetylenes using rhodium catalysts. Chem Commun 131\u2013132","DOI":"10.1039\/c19650000131"},{"key":"28_CR10","unstructured":"Knowles WS, Sabacky MJ (1968) Catalytic asymmetric hydrogenation employing a soluble, optically active, rhodium complex. Chem Commun 1445\u20131446"},{"key":"28_CR11","doi-asserted-by":"publisher","first-page":"161","DOI":"10.1016\/S0040-4039(01)84058-2","volume":"2","author":"L Horner","year":"1961","unstructured":"Horner L, Winkler H, Rapp A, Mentrup A, Hoffmann H, Beck P (1961) Phosphororganische verbindungen optisch aktive tertiare phosphine aus optisch aktiven quartaren phosphoniumsalzen. Tetrahedron Lett 2:161\u2013166","journal-title":"Tetrahedron Lett"},{"key":"28_CR12","doi-asserted-by":"publisher","first-page":"4784","DOI":"10.1021\/ja00994a037","volume":"89","author":"O Korpiun","year":"1967","unstructured":"Korpiun O, Mislow K (1967) New route to the preparation and configurational correlation of optically active phosphine oxides. J Am Chem Soc 89:4784\u20134786","journal-title":"J Am Chem Soc"},{"key":"28_CR13","unstructured":"Dang TP, Kagan HB (1971) The asymmetric synthesis of hydratropic acid and amino-acids by homogeneous hydrogenation. J Chem Soc D Chem Commun 481\u2013481"},{"key":"28_CR14","doi-asserted-by":"publisher","first-page":"7932","DOI":"10.1021\/ja00547a020","volume":"102","author":"A Miyashita","year":"1980","unstructured":"Miyashita A, Yasuda A, Takaya H, Toriumi K, Ito T, Souchi T, Noyori R (1980) Synthesis of 2,2\u2032-bis(diphenylphosphino)-1,1-binapthyl (BINAP), an atropisomeric chiral bis(triaryl)phosphine, and its use in the rhodium(I)-catalyzed asymmetric hydrogenation of \u03b1-(acylamino)acrylic acids. J Am Chem Soc 102:7932\u20137934","journal-title":"J Am Chem Soc"},{"key":"28_CR15","doi-asserted-by":"publisher","first-page":"345","DOI":"10.1021\/ar00178a005","volume":"23","author":"R Noyori","year":"1990","unstructured":"Noyori R, Takaya H (1990) BINAP: an efficient chiral element for asymmetric catalysis. Acc Chem Res 23:345\u2013350","journal-title":"Acc Chem Res"},{"key":"28_CR16","doi-asserted-by":"publisher","first-page":"1102","DOI":"10.1246\/cl.2008.1102","volume":"37","author":"F Shibahara","year":"2008","unstructured":"Shibahara F, Krische MJ (2008) Formation of C\u2013C bonds via ruthenium-catalyzed transfer hydrogenation: carbonyl addition from the alcohol or aldehyde oxidation level. Chem Lett 37:1102\u20131107","journal-title":"Chem Lett"},{"key":"28_CR17","doi-asserted-by":"publisher","first-page":"107","DOI":"10.1007\/978-3-642-15334-1_5","volume":"34","author":"JF Bower","year":"2011","unstructured":"Bower JF, Krische MJ (2011) Formation of C\u2013C bonds via iridium-catalyzed hydrogenation and transfer hydrogenation. Top Organomet Chem 34:107\u2013138","journal-title":"Top Organomet Chem"},{"key":"28_CR18","doi-asserted-by":"publisher","first-page":"1236","DOI":"10.1021\/op200195m","volume":"15","author":"A Hassan","year":"2011","unstructured":"Hassan A, Krische MJ (2011) Unlocking hydrogenation for C\u2013C bond formation: a brief overview of enantioselective methods. Org Process Res Dev 15:1236\u20131242","journal-title":"Org Process Res Dev"},{"key":"28_CR19","doi-asserted-by":"publisher","first-page":"1729","DOI":"10.1351\/PAC-CON-11-10-18","volume":"84","author":"J Moran","year":"2012","unstructured":"Moran J, Krische MJ (2012) Formation of C\u2013C bonds via ruthenium-catalyzed transfer hydrogenation. Pure Appl Chem 84:1729\u20131739","journal-title":"Pure Appl Chem"},{"key":"28_CR20","doi-asserted-by":"publisher","first-page":"9142","DOI":"10.1002\/anie.201403873","volume":"53","author":"JM Ketcham","year":"2014","unstructured":"Ketcham JM, Shin I, Montgomery TP, Krische MJ (2014) Catalytic enantioselective C\u2013H functionalization of alcohols by redox-triggered carbonyl addition: borrowing hydrogen, returning carbon. Angew Chem Int Ed 53:9142\u20139150","journal-title":"Angew Chem Int Ed"},{"key":"28_CR21","doi-asserted-by":"publisher","first-page":"2167","DOI":"10.1016\/S0040-4039(01)96811-X","volume":"12","author":"Y Sasson","year":"1971","unstructured":"Sasson Y, Blum J (1971) Homogenous catalytic transfer-hydrogenation of \u03b1, \u03b2-unsaturated carbonyl compounds by dichlorotris(triphenylphosphine)ruthenium(II). Tetrahedron Lett 12:2167\u20132170","journal-title":"Tetrahedron Lett"},{"key":"28_CR22","doi-asserted-by":"publisher","first-page":"137","DOI":"10.1021\/ic50167a029","volume":"16","author":"A Dobson","year":"1977","unstructured":"Dobson A, Robinson SD (1977) Complexes of the platinum metals. 7. homogeneous ruthenium and osmium catalysts for the dehydrogenation of primary and secondary alcohols. Inorg Chem 16:137\u2013142","journal-title":"Inorg Chem"},{"key":"28_CR23","doi-asserted-by":"publisher","first-page":"1541","DOI":"10.1016\/S0040-4039(01)90372-7","volume":"22","author":"Y Blum","year":"1981","unstructured":"Blum Y, Reshef D, Shvo Y (1981) H-Transfer catalysis with Ru3(CO)12. Tetrahedron Lett 22:1541\u20131544","journal-title":"Tetrahedron Lett"},{"key":"28_CR24","doi-asserted-by":"publisher","first-page":"C21","DOI":"10.1016\/S0022-328X(00)83402-6","volume":"226","author":"Y Shvo","year":"1982","unstructured":"Shvo Y, Blum Y, Reshef D, Menzin M (1982) Catalytic oxidative coupling of diols by Ru3(CO)12. J Organomet Chem 226:C21\u2013C24","journal-title":"J Organomet Chem"},{"key":"28_CR25","doi-asserted-by":"publisher","first-page":"7117","DOI":"10.1021\/ja00282a054","volume":"108","author":"R Noyori","year":"1986","unstructured":"Noyori R, Ohta M, Hsiao Y, Kitamura M, Ohta T, Takaya H (1986) Asymmetric synthesis of isoquinoline alkaloids by homogeneous catalysis. J Am Chem Soc 108:7117\u20137119","journal-title":"J Am Chem Soc"},{"key":"28_CR26","doi-asserted-by":"publisher","first-page":"7562","DOI":"10.1021\/ja00133a037","volume":"117","author":"S Hashiguchi","year":"1995","unstructured":"Hashiguchi S, Fujii A, Takehara J, Ikariya T, Noyori R (1995) Asymmetric transfer hydrogenation of aromatic ketones catalyzed by chiral ruthenium(II) complexes. J Am Chem Soc 117:7562\u20137563","journal-title":"J Am Chem Soc"},{"key":"28_CR27","doi-asserted-by":"publisher","first-page":"15156","DOI":"10.1021\/ja021163l","volume":"124","author":"H-Y Jang","year":"2002","unstructured":"Jang H-Y, Huddleston RR, Krische MJ (2002) Reductive generation of enolates from enones using elemental hydrogen: catalytic C\u2013C bond formation under hydrogenative conditions. J Am Chem Soc 124:15156\u201315157","journal-title":"J Am Chem Soc"},{"key":"28_CR28","doi-asserted-by":"publisher","first-page":"77","DOI":"10.1007\/128_2007_122","volume":"279","author":"H Iida","year":"2007","unstructured":"Iida H, Krische MJ (2007) Catalytic reductive coupling of alkenes and alkynes to carbonyl compounds and imines mediated by hydrogen. Top Curr Chem 279:77\u2013104","journal-title":"Top Curr Chem"},{"key":"28_CR29","doi-asserted-by":"publisher","first-page":"1394","DOI":"10.1021\/ar7001123","volume":"40","author":"E Skucas","year":"2007","unstructured":"Skucas E, Ngai M-Y, Komanduri V, Krische MJ (2007) Enantiomerically enriched allylic alcohols and allylic amines via C\u2013C bond forming hydrogenation: asymmetric carbonyl and imine vinylation. Acc Chem Res 40:1394\u20131401","journal-title":"Acc Chem Res"},{"key":"28_CR30","doi-asserted-by":"publisher","first-page":"15134","DOI":"10.1021\/ja077389b","volume":"129","author":"JF Bower","year":"2007","unstructured":"Bower JF, Skucas E, Patman RL, Krische MJ (2007) Catalytic C\u2013C coupling via transfer hydrogenation: reverse prenylation, crotylation and allylation from the alcohol or aldehyde oxidation level. J Am Chem Soc 129:15134\u201315135","journal-title":"J Am Chem Soc"},{"key":"28_CR31","doi-asserted-by":"publisher","first-page":"6338","DOI":"10.1021\/ja801213x","volume":"130","author":"F Shibahara","year":"2008","unstructured":"Shibahara F, Bower JF, Krische MJ (2008) Ruthenium-catalyzed C\u2013C bond forming transfer hydrogenation: carbonyl allylation from the alcohol or aldehyde oxidation level employing acyclic 1,3-dienes as surrogates to preformed allyl metal reagents. J Am Chem Soc 130:6338\u20136339","journal-title":"J Am Chem Soc"},{"key":"28_CR32","doi-asserted-by":"publisher","first-page":"14120","DOI":"10.1021\/ja805356j","volume":"130","author":"F Shibahara","year":"2008","unstructured":"Shibahara F, Bower JF, Krische MJ (2008) Diene hydroacylation from the alcohol or aldehyde oxidation level via ruthenium-catalyzed C\u2013C bond-forming transfer hydrogenation: synthesis of \u03b2, \u03b3-unsaturated ketones. J Am Chem Soc 130:14120\u201314122","journal-title":"J Am Chem Soc"},{"key":"28_CR33","doi-asserted-by":"publisher","first-page":"10582","DOI":"10.1021\/ja2046028","volume":"133","author":"JR Zbieg","year":"2011","unstructured":"Zbieg JR, Moran J, Krische MJ (2011) Diastereo- and enantioselective ruthenium-catalyzed hydrohydroxyalkylation of 2-Silyl-butadienes: carbonyl syn-crotylation from the alcohol oxidation level. J Am Chem Soc 133:10582\u201310586","journal-title":"J Am Chem Soc"},{"key":"28_CR34","unstructured":"Sato F, Kusakabe M, Kobayashi Y (1984) Highly diastereofacial selective addition of nucleophiles to 2-alkyl-3-trimethylsilylalk-3-enyl carbonyl compounds. Stereoselective preparation of \u03b2-methylhomoallyl alcohols and \u03b2-hydroxy-\u03b1-methyl ketones. J Chem Soc Chem Commun 1130\u20131132"},{"key":"28_CR35","doi-asserted-by":"crossref","unstructured":"Helm MD, Mayer P, Knochel P (2008) Preparation of silyl substituted crotylzinc reagents and their highly diastereoselective addition to carbonyl compounds. Chem Commun 1916\u20131917","DOI":"10.1039\/b802157k"},{"key":"28_CR36","doi-asserted-by":"publisher","first-page":"8838","DOI":"10.1021\/jacs.5b04844","volume":"137","author":"MN Grayson","year":"2015","unstructured":"Grayson MN, Krische MJ, Houk KN (2015) Ruthenium-catalyzed asymmetric hydrohydroxyalkylation of butadiene: the role of the formyl hydrogen bond in stereochemical control. J Am Chem Soc 137:8838\u20138850","journal-title":"J Am Chem Soc"},{"key":"28_CR37","doi-asserted-by":"publisher","first-page":"324","DOI":"10.1126\/science.1219274","volume":"336","author":"JR Zbieg","year":"2012","unstructured":"Zbieg JR, Yamaguchi E, McInturff EL, Krische MJ (2012) Enantioselective C\u2013H crotylation of primary alcohols via hydrohydroxyalkylation of butadiene. Science 336:324\u2013327","journal-title":"Science"},{"key":"28_CR38","doi-asserted-by":"publisher","first-page":"20628","DOI":"10.1021\/ja311208a","volume":"134","author":"EL McInturff","year":"2012","unstructured":"McInturff EL, Yamaguchi E, Krische MJ (2012) Chiral anion dependent inversion of diastereo- and enantioselectivity in carbonyl crotylation via ruthenium-catalyzed butadiene hydrohydroxyalkylation. J Am Chem Soc 134:20628\u201320631","journal-title":"J Am Chem Soc"},{"key":"28_CR39","doi-asserted-by":"publisher","first-page":"10366","DOI":"10.1021\/ja904124b","volume":"131","author":"T Smejkal","year":"2009","unstructured":"Smejkal T, Han H, Breit B, Krische MJ (2009) All carbon quaternary centers via ruthenium-catalyzed hydroxymethylation of 2-substituted butadienes mediated by formaldehyde: beyond hydroformylation. J Am Chem Soc 131:10366\u201310367","journal-title":"J Am Chem Soc"},{"key":"28_CR40","doi-asserted-by":"publisher","first-page":"1876","DOI":"10.1039\/c3sc22051f","volume":"4","author":"A K\u00f6pfer","year":"2013","unstructured":"K\u00f6pfer A, Sam B, Breit B, Krische MJ (2013) Regiodivergent reductive coupling of 2-substituted dienes to formaldehyde employing ruthenium or nickel catalysts: hydrohydroxymethylation via transfer hydrogenation. Chem Sci 4:1876\u20131880","journal-title":"Chem Sci"},{"key":"28_CR41","doi-asserted-by":"publisher","first-page":"3267","DOI":"10.1002\/anie.201407888","volume":"54","author":"B Sam","year":"2015","unstructured":"Sam B, Breit B, Krische MJ (2015) Paraformaldehyde and methanol as C1-feedstocks in metal-catalyzed C\u2013C couplings of \u03c0-unsaturated reactants: beyond hydroformylation. Angew Chem Int Ed 54:3267\u20133274","journal-title":"Angew Chem Int Ed"},{"key":"28_CR42","doi-asserted-by":"publisher","first-page":"2844","DOI":"10.1021\/ol101077v","volume":"12","author":"H Han","year":"2010","unstructured":"Han H, Krische MJ (2010) Direct ruthenium-catalyzed C\u2013C coupling of ethanol: diene hydro-hydroxyethylation to form all carbon quaternary centers. Org Lett 12:2844\u20132846","journal-title":"Org Lett"},{"key":"28_CR43","doi-asserted-by":"publisher","first-page":"2705","DOI":"10.1021\/ol800836v","volume":"10","author":"M-Y Ngai","year":"2008","unstructured":"Ngai M-Y, Skucas E, Krische MJ (2008) Ruthenium-catalyzed C\u2013C bond formation via transfer hydrogenation: branch-selective reductive coupling of allenes to paraformaldehyde and higher aldehydes. Org Lett 10:2705\u20132708","journal-title":"Org Lett"},{"key":"28_CR44","doi-asserted-by":"publisher","first-page":"5054","DOI":"10.1021\/ja900827p","volume":"131","author":"E Skucas","year":"2009","unstructured":"Skucas E, Zbieg JR, Krische MJ (2009) anti-aminoallylation of aldehydes via ruthenium-catalyzed transfer hydrogenative coupling of sulfonamido-allenes: 1,2-aminoalcohols. J Am Chem Soc 131:5054\u20135055","journal-title":"J Am Chem Soc"},{"key":"28_CR45","doi-asserted-by":"publisher","first-page":"2514","DOI":"10.1021\/ol1007235","volume":"12","author":"JR Zbieg","year":"2010","unstructured":"Zbieg JR, McInturff EL, Krische MJ (2010) Allenamide hydro-hydroxyalkylation: 1,2-aminoalcohols via ruthenium-catalyzed carbonyl anti-aminoallylation. Org Lett 12:2514\u20132516","journal-title":"Org Lett"},{"key":"28_CR46","doi-asserted-by":"publisher","first-page":"1141","DOI":"10.1021\/ja1104156","volume":"133","author":"JR Zbieg","year":"2011","unstructured":"Zbieg JR, McInturff EL, Leung JC, Krische MJ (2011) Amplification of anti-diastereoselectivity via Curtin\u2013Hammett effects in ruthenium-catalyzed hydrohydroxyalkylation of 1,1-disubstituted allenes: diastereoselective formation of all-carbon quaternary centers. J Am Chem Soc 133:1141\u20131144","journal-title":"J Am Chem Soc"},{"key":"28_CR47","doi-asserted-by":"publisher","first-page":"5465","DOI":"10.1002\/anie.201500238","volume":"54","author":"B Sam","year":"2015","unstructured":"Sam B, Luong T, Krische MJ (2015) Ruthenium-catalyzed C\u2013C coupling of fluorinated alcohols with allenes: dehydrogenation at the energetic limit of \u03b2-hydride elimination. Angew Chem Int Ed 54:5465\u20135469","journal-title":"Angew Chem Int Ed"},{"key":"28_CR48","doi-asserted-by":"publisher","first-page":"11902","DOI":"10.1021\/ja505962w","volume":"136","author":"BY Park","year":"2014","unstructured":"Park BY, Nguyen KD, Chaulagain MR, Komanduri V, Krische MJ (2014) Alkynes as allylmetal equivalents in redox-triggered C\u2013C couplings to primary alcohols: (Z)-homoallylic alcohols via ruthenium-catalyzed propargyl C\u2013H oxidative addition. J Am Chem Soc 136:11902\u201311905","journal-title":"J Am Chem Soc"},{"key":"28_CR49","doi-asserted-by":"publisher","first-page":"3161","DOI":"10.1021\/jacs.5b00747","volume":"137","author":"T Liang","year":"2015","unstructured":"Liang T, Nguyen KD, Zhang W, Krische MJ (2015) Enantioselective ruthenium-catalyzed carbonyl allylation via alkyne-alcohol C\u2013C bond forming transfer hydrogenation: allene hydrometallation vs. oxidative coupling. J Am Chem Soc 137:3161\u20133164","journal-title":"J Am Chem Soc"},{"key":"28_CR50","first-page":"23","volume":"35","author":"PV Ramachandran","year":"2002","unstructured":"Ramachandran PV (2002) Pinane-based versatile allyl boranes. Aldrichimica Acta 35:23\u201335","journal-title":"Aldrichimica Acta"},{"key":"28_CR51","doi-asserted-by":"publisher","first-page":"4732","DOI":"10.1002\/anie.200301632","volume":"42","author":"JWJ Kennedy","year":"2003","unstructured":"Kennedy JWJ, Hall DG (2003) Recent advances in the activation of boron and silicon reagents for stereocontrolled allylation reactions. Angew Chem Int Ed 42:4732\u20134739","journal-title":"Angew Chem Int Ed"},{"key":"28_CR52","doi-asserted-by":"publisher","first-page":"2763","DOI":"10.1021\/cr020050h","volume":"103","author":"SE Denmark","year":"2003","unstructured":"Denmark SE, Fu J (2003) Catalytic enantioselective addition of allylic organometallic reagents to aldehydes and ketones. Chem Rev 103:2763\u20132794","journal-title":"Chem Rev"},{"key":"28_CR53","doi-asserted-by":"publisher","first-page":"463","DOI":"10.5012\/bkcs.2006.27.4.463","volume":"27","author":"C-M Yu","year":"2006","unstructured":"Yu C-M, Youn J, Jung H-K (2006) Regulation of stereoselectivity and reactivity in the inter- and intramolecular allylic transfer reactions. Bull Korean Chem Soc 27:463\u2013472","journal-title":"Bull Korean Chem Soc"},{"key":"28_CR54","doi-asserted-by":"crossref","unstructured":"Marek I, Sklute G (2007) Creation of quaternary stereocenters in carbonyl allylation reactions. Chem Commun 1683\u20131691","DOI":"10.1039\/B615042J"},{"key":"28_CR55","doi-asserted-by":"crossref","unstructured":"Hall DG (2007) Lewis and Br\u00f8nsted acid-catalyzed allylboration of carbonyl compounds: from discovery to mechanism and applications. Synlett 1644\u20131655","DOI":"10.1055\/s-2007-980384"},{"key":"28_CR56","first-page":"1","volume":"73","author":"H Lachance","year":"2008","unstructured":"Lachance H, Hall DG (2008) Allylboration of carbonyl compounds. Org React 73:1\u2013573","journal-title":"Org React"},{"key":"28_CR57","doi-asserted-by":"publisher","first-page":"7774","DOI":"10.1021\/cr1004474","volume":"111","author":"M Yus","year":"2011","unstructured":"Yus M, Gonz\u00e1lez-G\u00f3mez JC, Foubelo F (2011) Catalytic enantioselective allylation of carbonyl compounds and imines. Chem Rev 111:7774\u20137854","journal-title":"Chem Rev"},{"key":"28_CR58","doi-asserted-by":"publisher","first-page":"13066","DOI":"10.1021\/jacs.5b08019","volume":"137","author":"T Liang","year":"2015","unstructured":"Liang T, Zhang W, Chen T-Y, Nguyen KD, Krische MJ (2015) Ruthenium-catalyzed diastereo- and enantioselective coupling of propargyl ethers with alcohols: siloxy-crotylation via hydride shift enabled conversion of alkynes to \u03c0-allyls. J Am Chem Soc 137:13066\u201313071","journal-title":"J Am Chem Soc"},{"key":"28_CR59","doi-asserted-by":"publisher","first-page":"2066","DOI":"10.1021\/ja809456u","volume":"131","author":"RL Patman","year":"2009","unstructured":"Patman RL, Chaulagain MR, Williams VM, Krische MJ (2009) Direct vinylation of alcohols or aldehydes employing alkynes as vinyl donors: a ruthenium-catalyzed C\u2013C bond forming transfer hydrogenation. J Am Chem Soc 131:2066\u20132067","journal-title":"J Am Chem Soc"},{"key":"28_CR60","doi-asserted-by":"publisher","first-page":"5024","DOI":"10.1016\/j.tet.2009.03.068","volume":"65","author":"VM Williams","year":"2009","unstructured":"Williams VM, Leung JC, Patman RL, Krische MJ (2009) Hydroacylation of 2-butyne from the alcohol or aldehyde oxidation level via ruthenium-catalyzed C\u2013C bond forming transfer hydrogenation. Tetrahedron 65:5024\u20135029","journal-title":"Tetrahedron"},{"key":"28_CR61","doi-asserted-by":"publisher","first-page":"5220","DOI":"10.1002\/anie.200801359","volume":"47","author":"RL Patman","year":"2008","unstructured":"Patman RL, Williams VM, Bower JF, Krische MJ (2008) Carbonyl propargylation from the alcohol or aldehyde oxidation level employing 1,3-enynes as surrogates to preformed allenylmetal reagents: a ruthenium-catalyzed C\u2013C bond forming transfer hydrogenation. Angew Chem Int Ed 47:5220\u20135223","journal-title":"Angew Chem Int Ed"},{"key":"28_CR62","doi-asserted-by":"publisher","first-page":"16823","DOI":"10.1002\/chem.201202446","volume":"18","author":"LM Geary","year":"2012","unstructured":"Geary LM, Leung JC, Krische MJ (2012) Ruthenium-catalyzed reductive coupling of 1,3-enynes and aldehydes via transfer hydrogenation: anti-diastereoselective carbonyl propargylation. Chem Eur J 18:16823\u201316827","journal-title":"Chem Eur J"},{"key":"28_CR63","doi-asserted-by":"publisher","first-page":"5238","DOI":"10.1021\/jacs.6b02279","volume":"138","author":"KD Nguyen","year":"2016","unstructured":"Nguyen KD, Herkommer D, Krische MJ (2016) Ruthenium-BINAP-catalyzed alcohol C-H tert-prenylation via 1,3-enyne transfer hydrogenation: beyond stoichiometric carbanions in enantioselective carbonyl propargylation. J Am Chem Soc 138:5238\u20135241","journal-title":"J Am Chem Soc"},{"key":"28_CR64","doi-asserted-by":"publisher","first-page":"1914","DOI":"10.1021\/cr100284m","volume":"111","author":"C-H Ding","year":"2011","unstructured":"Ding C-H, Lou X-L (2011) Catalytic asymmetric propargylation. Chem Rev 111:1914\u20131937","journal-title":"Chem Rev"},{"key":"28_CR65","doi-asserted-by":"publisher","first-page":"11629","DOI":"10.1021\/jo4019107","volume":"78","author":"HM Wisniewska","year":"2013","unstructured":"Wisniewska HM, Jarvo ER (2013) Enantioselective propargylation and allenylation reactions of ketones and imines. J Org Chem 78:11629\u201311636","journal-title":"J Org Chem"},{"key":"28_CR66","doi-asserted-by":"publisher","first-page":"15700","DOI":"10.1021\/ja3075049","volume":"134","author":"JC Leung","year":"2012","unstructured":"Leung JC, Geary LM, Chen T-Y, Zbieg JR, Krische MJ (2012) Direct, redox neutral prenylation and geranylation of secondary carbinol C\u2013H bonds: C4 regioselectivity in ruthenium-catalyzed C\u2013C couplings of dienes to \u03b1-hydroxy esters. J Am Chem Soc 134:15700\u201315703","journal-title":"J Am Chem Soc"},{"key":"28_CR67","doi-asserted-by":"publisher","first-page":"2994","DOI":"10.1021\/ol401184k","volume":"15","author":"T-Y Chen","year":"2013","unstructured":"Chen T-Y, Krische MJ (2013) Regioselective ruthenium-catalyzed hydrohydroxyalkylation of dienes with 3-hydroxy-2-oxindoles: prenylation, geranylation and beyond. Org Lett 15:2994\u20132997","journal-title":"Org Lett"},{"key":"28_CR68","doi-asserted-by":"publisher","first-page":"16320","DOI":"10.1021\/ja4087193","volume":"135","author":"BY Park","year":"2013","unstructured":"Park BY, Montgomery TP, Garza VJ, Krische MJ (2013) Ruthenium-catalyzed hydrohydroxyalkylation of isoprene with heteroaromatic secondary alcohols: isolation and reversible formation of the putative metallacycle intermediate. J Am Chem Soc 135:16320\u201316323","journal-title":"J Am Chem Soc"},{"key":"28_CR69","doi-asserted-by":"publisher","first-page":"173","DOI":"10.1007\/128_2007_121","volume":"279","author":"M Kimura","year":"2007","unstructured":"Kimura M, Tamaru Y (2007) Nickel-catalyzed reductive coupling of dienes and carbonyl compounds. Top Curr Chem 279:173\u2013207","journal-title":"Top Curr Chem"},{"key":"28_CR70","doi-asserted-by":"publisher","first-page":"3232","DOI":"10.1002\/anie.201311130","volume":"53","author":"EL McInturff","year":"2014","unstructured":"McInturff EL, Nguyen KD, Krische MJ (2014) Redox-triggered C\u2013C coupling of diols and alkynes: synthesis of \u03b2, \u03b3-unsaturated \u03b1-hydroxyketones and furans by ruthenium-catalyzed hydrohydroxyalkylation. Angew Chem Int Ed 53:3232\u20133235","journal-title":"Angew Chem Int Ed"},{"key":"28_CR71","doi-asserted-by":"crossref","unstructured":"Ru3(CO)12 reacts with dppe in benzene solvent to provide Ru(CO)3(dppe): Sanchez-Delgado RA, Bradley JS, Wilkinson G (1976) Further studies on the homogeneous hydroformylation of alkenes by use of ruthenium complex catalysts. J Chem Soc Dalton Trans 399\u2013404","DOI":"10.1039\/dt9760000399"},{"key":"28_CR72","doi-asserted-by":"publisher","first-page":"7160","DOI":"10.1021\/ja991223w","volume":"121","author":"N Chatani","year":"1999","unstructured":"Chatani N, Tobisu M, Asaumi T, Fukumoto Y, Murai S (1999) Ruthenium carbonyl-catalyzed [2+2+1]-cycloaddition of ketones, olefins, and carbon monoxide, leading to functionalized \u03b3-butyrolactones. J Am Chem Soc 121:7160\u20137161","journal-title":"J Am Chem Soc"},{"key":"28_CR73","doi-asserted-by":"publisher","first-page":"12663","DOI":"10.1021\/ja003018i","volume":"122","author":"M Tobisu","year":"2000","unstructured":"Tobisu M, Chatani N, Asaumi T, Amako K, Ie Y, Fukumoto Y, Murai S (2000) Ru3(CO)12-catalyzed intermolecular cyclocoupling of ketones, alkenes or alkynes, and carbon monoxide. [2+2+1] cycloaddition strategy for the synthesis of functionalized \u03b3-butyrolactones. J Am Chem Soc 122:12663\u201312674","journal-title":"J Am Chem Soc"},{"key":"28_CR74","doi-asserted-by":"publisher","first-page":"1065","DOI":"10.1016\/j.tet.2003.11.082","volume":"60","author":"RH Meijer","year":"2004","unstructured":"Meijer RH, Ligthart GBWL, Meuldijk J, Vekemans JAJM, Hulshof LA, Mills AM, Kooijman H, Spek AL (2004) Triruthenium dodecacarbonyl\/triphenylphosphine-catalyzed dehydrogenation of primary and secondary alcohols. Tetrahedron 60:1065\u20131072","journal-title":"Tetrahedron"},{"key":"28_CR75","doi-asserted-by":"publisher","first-page":"6787","DOI":"10.1021\/ja00130a022","volume":"117","author":"WE Crowe","year":"1995","unstructured":"Crowe WE, Rachita MJ (1995) Titanium-catalyzed reductive cyclization of \u03b4, \u03b5-unsaturated ketones and aldehydes. J Am Chem Soc 117:6787\u20136788","journal-title":"J Am Chem Soc"},{"key":"28_CR76","doi-asserted-by":"publisher","first-page":"3182","DOI":"10.1021\/ja954192n","volume":"118","author":"NM Kablaoui","year":"1996","unstructured":"Kablaoui NM, Buchwald SL (1996) Development of a method for the reductive cyclization of enones by a titanium catalyst. J Am Chem Soc 118:3182\u20133191","journal-title":"J Am Chem Soc"},{"key":"28_CR77","doi-asserted-by":"publisher","first-page":"6785","DOI":"10.1021\/ja00130a021","volume":"117","author":"NM Kablaoui","year":"1995","unstructured":"Kablaoui NM, Buchwald SL (1995) Reductive cyclization of enones by a titanium catalyst. J Am Chem Soc 117:6785\u20136786","journal-title":"J Am Chem Soc"},{"key":"28_CR78","doi-asserted-by":"publisher","first-page":"8428","DOI":"10.1002\/anie.201303552","volume":"52","author":"E Yamaguchi","year":"2013","unstructured":"Yamaguchi E, Mowat J, Luong T, Krische MJ (2013) Regio- and diastereoselective C\u2013C coupling of \u03b1-olefins and styrenes to 3-hydroxy-2-oxindoles by Ru-catalyzed hydrohydroxyalkylation. Angew Chem Int Ed 52:8428\u20138431","journal-title":"Angew Chem Int Ed"},{"key":"28_CR79","doi-asserted-by":"publisher","first-page":"49","DOI":"10.1021\/cr950016l","volume":"96","author":"M Lautens","year":"1996","unstructured":"Lautens M, Klute W, Tam W (1996) Transition metal-mediated cycloaddition reactions. Chem Rev 96:49\u201392","journal-title":"Chem Rev"},{"key":"28_CR80","doi-asserted-by":"publisher","first-page":"11022","DOI":"10.1002\/anie.201503247","volume":"54","author":"A Nandakumar","year":"2015","unstructured":"Nandakumar A, Midya SP, Landge VG, Balaraman E (2015) Transition-metal-catalyzed hydrogen-transfer annulations: access to heterocyclic scaffolds. Angew Chem Int Ed 54:11022\u201311034","journal-title":"Angew Chem Int Ed"},{"key":"28_CR81","doi-asserted-by":"publisher","first-page":"17230","DOI":"10.1021\/ja410533y","volume":"135","author":"EL McInturff","year":"2013","unstructured":"McInturff EL, Mowat J, Waldeck AR, Krische MJ (2013) Ruthenium-catalyzed hydrohydroxyalkylation of acrylates with diols and \u03b1-hydroxycarbonyl compounds to form spiro- and \u03b1-methylene-\u03b3-butyrolactones. J Am Chem Soc 135:17230\u201317235","journal-title":"J Am Chem Soc"},{"key":"28_CR82","doi-asserted-by":"publisher","first-page":"3796","DOI":"10.1021\/ja400691t","volume":"135","author":"LM Geary","year":"2013","unstructured":"Geary LM, Glasspoole BW, Kim MM, Krische MJ (2013) Successive C\u2013C coupling of dienes to vicinally dioxygenated hydrocarbons: ruthenium-catalyzed [4+2] cycloaddition across the diol, Hydroxycarbonyl or dione oxidation levels. J Am Chem Soc 135:3796\u20133799","journal-title":"J Am Chem Soc"},{"key":"28_CR83","doi-asserted-by":"publisher","first-page":"7545","DOI":"10.1039\/c4cc03983a","volume":"50","author":"ZA Kasun","year":"2014","unstructured":"Kasun ZA, Geary LM, Krische MJ (2014) Ring expansion of cyclic 1,2-diols to form medium sized rings via ruthenium-catalyzed transfer hydrogenative [4+2] cycloaddition. Chem Commun 50:7545\u20137547","journal-title":"Chem Commun"},{"key":"28_CR84","doi-asserted-by":"publisher","first-page":"5920","DOI":"10.1021\/ja502659t","volume":"136","author":"LM Geary","year":"2014","unstructured":"Geary LM, Chen TY, Montgomery TP, Krische MJ (2014) Benzannulation via ruthenium-catalyzed diol-diene [4+2] cycloaddition: one- and two-directional syntheses of fluoranthenes and acenes. J Am Chem Soc 136:5920\u20135922","journal-title":"J Am Chem Soc"},{"key":"28_CR85","doi-asserted-by":"publisher","first-page":"5883","DOI":"10.1021\/jacs.5b02755","volume":"137","author":"A Saxena","year":"2015","unstructured":"Saxena A, Perez F, Krische MJ (2015) Ruthenium(0)-catalyzed endiyne-\u03b1-ketol [4+2] cycloaddition: convergent assembly of type II polyketide substructures. J Am Chem Soc 137:5883\u20135886","journal-title":"J Am Chem Soc"},{"key":"28_CR86","doi-asserted-by":"publisher","first-page":"1493","DOI":"10.1002\/anie.201509646","volume":"55","author":"A Saxena","year":"2016","unstructured":"Saxena A, Perez F, Krische MJ (2016) Ruthenium(0)-catalyzed [4+2] cycloaddition of acetylenic aldehydes with \u03b1-ketols: convergent construction of angucycline ring systems. Angew Chem Int Ed 55:1493\u20131497","journal-title":"Angew Chem Int Ed"},{"key":"28_CR87","doi-asserted-by":"publisher","first-page":"127","DOI":"10.1007\/BFb0119236","volume":"188","author":"K Krohn","year":"1997","unstructured":"Krohn K, Rohr J (1997) Angucyclines: total syntheses, new structures, and biosynthetic studies of an emerging new class of antibiotics. Top Curr Chem 188:127\u2013195","journal-title":"Top Curr Chem"},{"issue":"1","key":"28_CR88","doi-asserted-by":"crossref","first-page":"1","DOI":"10.1055\/s-2004-834813","volume":"36","author":"MC Carre\u00f1o","year":"2005","unstructured":"Carre\u00f1o MC, Urbano A (2005) Recent advances in the synthesis of angucyclines. Synlett 36(1):1\u201325","journal-title":"Synlett"},{"key":"28_CR89","doi-asserted-by":"publisher","first-page":"264","DOI":"10.1039\/C1NP00068C","volume":"29","author":"MK Kharel","year":"2012","unstructured":"Kharel MK, Pahari P, Shepherd MD, Tibrewal N, Nybo SE, Shaaban KA, Rohr J (2012) Angucyclines: biosynthesis, mode-of-action, new natural products, and synthesis. Nat Prod Rep 29:264\u2013325","journal-title":"Nat Prod Rep"},{"key":"28_CR90","unstructured":"Clerici MG, Maspero F (1980) Catalytic C-alkylation of secondary amines with alkenes. Synthesis 305\u2013306"},{"key":"28_CR91","doi-asserted-by":"publisher","first-page":"161","DOI":"10.1021\/om00073a031","volume":"2","author":"WA Nugent","year":"1983","unstructured":"Nugent WA, Ovenall DW, Holmes SJ (1983) Catalytic C\u2013H activation in early transition-metal dialkylamides and alkoxides. Organometallics 2:161\u2013162","journal-title":"Organometallics"},{"key":"28_CR92","doi-asserted-by":"publisher","first-page":"1069","DOI":"10.1039\/B607547A","volume":"36","author":"KR Campos","year":"2007","unstructured":"Campos KR (2007) Direct sp3 C\u2013H bond activation adjacent to nitrogen in heterocycles. Chem Soc Rev 36:1069\u20131084","journal-title":"Chem Soc Rev"},{"key":"28_CR93","doi-asserted-by":"publisher","first-page":"4892","DOI":"10.1002\/anie.200900735","volume":"48","author":"PW Roesky","year":"2009","unstructured":"Roesky PW (2009) Catalytic hydroaminoalkylation. Angew Chem Int Ed 48:4892\u20134894","journal-title":"Angew Chem Int Ed"},{"key":"28_CR94","doi-asserted-by":"publisher","first-page":"2884","DOI":"10.1055\/s-0034-1379216","volume":"46","author":"E Chong","year":"2014","unstructured":"Chong E, Garcia P, Schafer LL (2014) Hydroaminoalkylation: early-transition-metal-catalyzed \u03b1-alkylation of amines. Synthesis 46:2884\u20132896","journal-title":"Synthesis"},{"key":"28_CR95","doi-asserted-by":"publisher","first-page":"1798","DOI":"10.1021\/ja5130258","volume":"137","author":"T-Y Chen","year":"2015","unstructured":"Chen T-Y, Tsutsumi R, Montgomery TP, Volchkov I, Krische MJ (2015) Ruthenium-catalyzed C\u2013C coupling of amino alcohols with dienes via transfer hydrogenation: redox-triggered imine addition and related hydroaminoalkylations. J Am Chem Soc 137:1798\u20131801","journal-title":"J Am Chem Soc"},{"key":"28_CR96","doi-asserted-by":"publisher","first-page":"8525","DOI":"10.1002\/anie.201503250","volume":"54","author":"S Oda","year":"2015","unstructured":"Oda S, Sam B, Krische MJ (2015) Hydroaminomethylation beyond carbonylation: allene-imine reductive coupling by ruthenium-catalyzed transfer hydrogenation. Angew Chem Int Ed 54:8525\u20138528","journal-title":"Angew Chem Int Ed"},{"key":"28_CR97","doi-asserted-by":"publisher","first-page":"136","DOI":"10.1039\/C5SC03854E","volume":"7","author":"S Oda","year":"2016","unstructured":"Oda S, Franke J, Krische MJ (2016) Diene hydroaminomethylation via ruthenium-catalyzed C\u2013C bond forming transfer hydrogenation: beyond carbonylation. Chem Sci 7:136\u2013141","journal-title":"Chem Sci"},{"key":"28_CR98","doi-asserted-by":"publisher","first-page":"1440","DOI":"10.1021\/ol4006079","volume":"15","author":"S Zhu","year":"2013","unstructured":"Zhu S, Lu X, Luo Y, Zhang W, Jiang H, Yan M, Zeng W (2013) Ruthenium(II)-catalyzed regioselective reductive coupling of \u03b1-imino esters with dienes. Org Lett 15:1440\u20131443","journal-title":"Org Lett"},{"key":"28_CR99","doi-asserted-by":"publisher","first-page":"6096","DOI":"10.1039\/c3cc43463j","volume":"49","author":"DC Schmitt","year":"2013","unstructured":"Schmitt DC, Lee J, Dechert-Schmitt A-MR, Yamaguchi E, Krische MJ (2013) Ruthenium-catalyzed hydroaminoalkylation of isoprene via transfer hydrogenation: byproduct-free prenylation of hydantoins. Chem Commun 49:6096\u20136098","journal-title":"Chem Commun"},{"key":"28_CR100","unstructured":"Jun C-H (1998) Chelation-assisted alkylation of benzylamine derivatives by Ru0 catalyst. Chem Commun 1405\u20131406"},{"key":"28_CR101","doi-asserted-by":"publisher","first-page":"10935","DOI":"10.1021\/ja011540e","volume":"123","author":"N Chatani","year":"2001","unstructured":"Chatani N, Asaumi T, Yorimitsu S, Ikeda T, Kakiuchi F, Murai S (2001) Ru3(CO)12-catalyzed coupling reaction of sp3 C\u2013H bonds adjacent to a nitrogen atom in alkylamines with alkenes. J Am Chem Soc 123:10935\u201310941","journal-title":"J Am Chem Soc"},{"key":"28_CR102","doi-asserted-by":"publisher","first-page":"10393","DOI":"10.1002\/chem.201201072","volume":"18","author":"SD Bergman","year":"2012","unstructured":"Bergman SD, Storr TE, Prokopcov\u00e1 H, Aelvoet K, Diels G, Meerpoel L, Maes BUW (2012) The role of the alcohol and carboxylic acid in directed ruthenium-catalyzed C(sp3)-H \u03b1-alkylation of cyclic amines. Chem Eur J 18:10393\u201310398","journal-title":"Chem Eur J"},{"key":"28_CR103","doi-asserted-by":"publisher","first-page":"1876","DOI":"10.1021\/ol500300w","volume":"16","author":"M Schinkel","year":"2014","unstructured":"Schinkel M, Wang L, Bielefeld K, Ackermann L (2014) Ruthenium(II)-catalyzed C(sp3)-H \u03b1-alkylation of pyrrolidines. Org Lett 16:1876\u20131879","journal-title":"Org Lett"},{"key":"28_CR104","doi-asserted-by":"publisher","first-page":"1610","DOI":"10.1002\/adsc.201400117","volume":"356","author":"AA Kulago","year":"2014","unstructured":"Kulago AA, Van Steijvoort BF, Mitchell EA, Meerpoel L, Maes BUW (2014) Directed ruthenium-catalyzed C(sp3)-H \u03b1-alkylation of cyclic amines using dioxolane-protected alkenones. Adv Synth Catal 356:1610\u20131618","journal-title":"Adv Synth Catal"},{"key":"28_CR105","doi-asserted-by":"publisher","first-page":"1821","DOI":"10.1021\/ol900404r","volume":"11","author":"K Tsuchikama","year":"2009","unstructured":"Tsuchikama K, Kasagawa M, Endo K, Shibata T (2009) Cationic Ir(I)-catalyzed sp3 C\u2013H bond alkenylation of amides with alkynes. Org Lett 11:1821\u20131823","journal-title":"Org Lett"},{"key":"28_CR106","doi-asserted-by":"publisher","first-page":"4692","DOI":"10.1021\/ol201907w","volume":"13","author":"S Pan","year":"2011","unstructured":"Pan S, Endo K, Shibata T (2011) Ir(I)-catalyzed enantioselective secondary sp3 C\u2013H bond activation of 2-(Alkylamino)pyridines with alkenes. Org Lett 13:4692\u20134695","journal-title":"Org Lett"},{"key":"28_CR107","doi-asserted-by":"publisher","first-page":"9009","DOI":"10.1016\/j.tet.2012.08.071","volume":"68","author":"S Pan","year":"2012","unstructured":"Pan S, Matsuo Y, Endo K, Shibata T (2012) Cationic iridium-catalyzed enantioselective activation of secondary sp3 C\u2013H bond adjacent to nitrogen atom. Tetrahedron 68:9009\u20139015","journal-title":"Tetrahedron"},{"key":"28_CR108","doi-asserted-by":"publisher","first-page":"4201","DOI":"10.1021\/ol501935d","volume":"16","author":"G Lahm","year":"2014","unstructured":"Lahm G, Opatz T (2014) Unique regioselectivity in the C(sp3)-H \u03b1-alkylation of amines: the benzoxazole moiety as a removable directing group. Org Lett 16:4201\u20134203","journal-title":"Org Lett"},{"key":"28_CR109","doi-asserted-by":"publisher","first-page":"3329","DOI":"10.1021\/cr970413r","volume":"99","author":"P Eilbracht","year":"1999","unstructured":"Eilbracht P, B\u00e4rfacker L, Buss C, Hollmann C, Kitsos-Rzychon BE, Kranemann CL, Rishe T, Roggenbuck R, Schmidt A (1999) Tandem reaction sequences under hydroformylation conditions: new synthetic applications of transition metal catalysis. Chem Rev 99:3329\u20133366","journal-title":"Chem Rev"},{"key":"28_CR110","doi-asserted-by":"crossref","unstructured":"Breit B, Seiche W (2001) Recent advances on chemo-, regio- and stereoselective hydroformylation. Synthesis 1\u201336","DOI":"10.1055\/s-2001-9739"},{"key":"28_CR111","doi-asserted-by":"publisher","first-page":"65","DOI":"10.1007\/3418_017","volume":"18","author":"P Eilbracht","year":"2006","unstructured":"Eilbracht P, Schmidt AM (2006) Synthetic applications of tandem reaction sequences involving hydroformylation. Top Organomet Chem 18:65\u201395","journal-title":"Top Organomet Chem"},{"key":"28_CR112","first-page":"1102","volume":"3","author":"D Crozet","year":"2011","unstructured":"Crozet D, Urrutigo\u00efty M, Kalck P (2011) Recent advances in amine synthesis by catalytic hydroaminomethylation of alkenes. Chem Cat Chem 3:1102\u20131118","journal-title":"Chem Cat Chem"},{"key":"28_CR113","doi-asserted-by":"publisher","first-page":"103","DOI":"10.1007\/978-3-642-28288-1_3","volume":"39","author":"A Behr","year":"2012","unstructured":"Behr A, Vorholt AJ (2012) Hydroformylation and related reactions of renewable resources. Top Organomet Chem 39:103\u2013128","journal-title":"Top Organomet Chem"},{"key":"28_CR114","doi-asserted-by":"publisher","first-page":"7179","DOI":"10.1039\/C4OB00620H","volume":"12","author":"S Raoufmoghaddam","year":"2014","unstructured":"Raoufmoghaddam S (2014) Recent advances in catalytic C\u2013N bond formation: a comparison of cascade hydroaminomethylation and reductive amination reactions with the corresponding hydroamidomethylation and reductive amidation reactions. Org Biomol Chem 12:7179\u20137193","journal-title":"Org Biomol Chem"},{"key":"28_CR115","doi-asserted-by":"publisher","first-page":"1041","DOI":"10.1021\/ar400222k","volume":"47","author":"X-F Wu","year":"2014","unstructured":"Wu X-F, Fang X, Wu L, Jackstell R, Neumann H, Beller M (2014) Transition-metal-catalyzed carbonylation reactions of olefins and alkynes: a personal account. Acc Chem Res 47:1041\u20131053","journal-title":"Acc Chem Res"}],"container-title":["Topics in Current Chemistry"],"original-title":[],"language":"en","link":[{"URL":"http:\/\/link.springer.com\/article\/10.1007\/s41061-016-0028-0\/fulltext.html","content-type":"text\/html","content-version":"vor","intended-application":"text-mining"},{"URL":"http:\/\/link.springer.com\/content\/pdf\/10.1007\/s41061-016-0028-0.pdf","content-type":"application\/pdf","content-version":"vor","intended-application":"text-mining"},{"URL":"http:\/\/link.springer.com\/content\/pdf\/10.1007\/s41061-016-0028-0","content-type":"unspecified","content-version":"vor","intended-application":"similarity-checking"},{"URL":"http:\/\/link.springer.com\/content\/pdf\/10.1007\/s41061-016-0028-0.pdf","content-type":"application\/pdf","content-version":"vor","intended-application":"similarity-checking"}],"deposited":{"date-parts":[[2020,5,17]],"date-time":"2020-05-17T00:35:08Z","timestamp":1589675708000},"score":1,"resource":{"primary":{"URL":"http:\/\/link.springer.com\/10.1007\/s41061-016-0028-0"}},"subtitle":[],"short-title":[],"issued":{"date-parts":[[2016,5,30]]},"references-count":115,"journal-issue":{"issue":"3","published-print":{"date-parts":[[2016,6]]}},"alternative-id":["28"],"URL":"https:\/\/doi.org\/10.1007\/s41061-016-0028-0","relation":{},"ISSN":["2365-0869","2364-8961"],"issn-type":[{"value":"2365-0869","type":"print"},{"value":"2364-8961","type":"electronic"}],"subject":[],"published":{"date-parts":[[2016,5,30]]},"assertion":[{"value":"5 March 2016","order":1,"name":"received","label":"Received","group":{"name":"ArticleHistory","label":"Article History"}},{"value":"20 April 2016","order":2,"name":"accepted","label":"Accepted","group":{"name":"ArticleHistory","label":"Article History"}},{"value":"30 May 2016","order":3,"name":"first_online","label":"First Online","group":{"name":"ArticleHistory","label":"Article History"}}],"article-number":"35"}}