{"status":"ok","message-type":"work","message-version":"1.0.0","message":{"indexed":{"date-parts":[[2026,2,8]],"date-time":"2026-02-08T02:44:45Z","timestamp":1770518685663,"version":"3.49.0"},"reference-count":243,"publisher":"Springer Science and Business Media LLC","issue":"3","license":[{"start":{"date-parts":[[2020,6,1]],"date-time":"2020-06-01T00:00:00Z","timestamp":1590969600000},"content-version":"tdm","delay-in-days":0,"URL":"https:\/\/www.springer.com\/tdm"},{"start":{"date-parts":[[2020,6,1]],"date-time":"2020-06-01T00:00:00Z","timestamp":1590969600000},"content-version":"vor","delay-in-days":0,"URL":"https:\/\/www.springer.com\/tdm"}],"funder":[{"name":"Raazi Environmental Protection Foundation","award":["9097SS27\/12"],"award-info":[{"award-number":["9097SS27\/12"]}]}],"content-domain":{"domain":["link.springer.com"],"crossmark-restriction":false},"short-container-title":["Top Curr Chem (Z)"],"published-print":{"date-parts":[[2020,6]]},"DOI":"10.1007\/s41061-020-00304-8","type":"journal-article","created":{"date-parts":[[2020,5,4]],"date-time":"2020-05-04T15:03:31Z","timestamp":1588604611000},"update-policy":"https:\/\/doi.org\/10.1007\/springer_crossmark_policy","source":"Crossref","is-referenced-by-count":2,"title":["RETRACTED ARTICLE: Mononuclear Cu Complexes Based on Nitrogen Heterocyclic Carbene: A Comprehensive Review"],"prefix":"10.1007","volume":"378","author":[{"ORCID":"https:\/\/orcid.org\/0000-0001-5159-3932","authenticated-orcid":false,"given":"Sina","family":"Matavos-Aramyan","sequence":"first","affiliation":[],"role":[{"role":"author","vocabulary":"crossref"}]},{"given":"Sadaf","family":"Soukhakian","sequence":"additional","affiliation":[],"role":[{"role":"author","vocabulary":"crossref"}]},{"given":"Mohammad Hossein","family":"Jazebizadeh","sequence":"additional","affiliation":[],"role":[{"role":"author","vocabulary":"crossref"}]}],"member":"297","published-online":{"date-parts":[[2020,8,27]]},"reference":[{"issue":"1\u20133","key":"304_CR1","doi-asserted-by":"crossref","first-page":"185","DOI":"10.1016\/0022-328X(88)87079-7","volume":"358","author":"MF Lappert","year":"1988","unstructured":"Lappert MF (1988) The coordination chemistry of electron-rich alkenes (enetetramines). J Organomet Chem 358(1\u20133):185\u2013213","journal-title":"J Organomet Chem"},{"issue":"26","key":"304_CR2","doi-asserted-by":"crossref","first-page":"4666","DOI":"10.1021\/jp9639051","volume":"101","author":"VWW Yam","year":"1997","unstructured":"Yam VWW, Lo KKW, Wang CR, Cheung KK (1997) Synthesis, photophysics, and transient absorption spectroscopic studies of luminescent copper(I) chalcogenide complexes. Crystal structure of [Cu4(\u03bc-dtpm)4(\u03bc4-S)](PF6)2{dtpm = Bis[bis(4-methylphenyl)phosphino]methane}. J Phys Chem A 101(26):4666\u20134672","journal-title":"J Phys Chem A"},{"issue":"10","key":"304_CR3","doi-asserted-by":"crossref","first-page":"4391","DOI":"10.1021\/ja00089a029","volume":"116","author":"AJ Arduengo","year":"1994","unstructured":"Arduengo AJ, Gamper SF, Calabrese JC, Davidson F (1994) Low-coordinate carbene complexes of nickel(0) and platinum(0). J Am Chem Soc 116(10):4391\u20134394","journal-title":"J Am Chem Soc"},{"issue":"3","key":"304_CR4","doi-asserted-by":"crossref","first-page":"310","DOI":"10.1002\/anie.199603101","volume":"35","author":"U Kernbach","year":"1996","unstructured":"Kernbach U, Ramm M, Luger P, Fehlhammer WP (1996) A chelating triscarbene ligand and its hexacarbene iron complex. Angew Chem Int Ed Engl 35(3):310\u2013312","journal-title":"Angew Chem Int Ed Engl"},{"issue":"5","key":"304_CR5","first-page":"972","volume":"17","author":"HMJ Wang","year":"1998","unstructured":"Wang HMJ, Lin IJB (1998) Facile synthesis of silver(I)\u2212Carbene complexes. Useful Carbene Transfer Agents Organometall 17(5):972\u2013975","journal-title":"Useful Carbene Transfer Agents Organometall"},{"key":"304_CR6","doi-asserted-by":"crossref","first-page":"514","DOI":"10.1016\/j.ccr.2018.05.010","volume":"375","author":"Y Liu","year":"2018","unstructured":"Liu Y, Yiu S-C, Ho C-L, Wong W-Y (2018) Recent advances in copper complexes for electrical\/light energy conversion. Coord Chem Rev 375:514\u2013557","journal-title":"Coord Chem Rev"},{"issue":"9","key":"304_CR7","doi-asserted-by":"crossref","first-page":"5433","DOI":"10.1021\/acs.inorgchem.9b00337","volume":"58","author":"A Liske","year":"2019","unstructured":"Liske A, Wallbaum L, H\u00f6lzel T, F\u00f6ller J, Gernert M, Hupp B, Ganter C, Marian CM, Steffen A (2019) Cu\u2013F interactions between cationic linear N-heterocyclic carbene copper(I) pyridine complexes and their counterions greatly enhance blue luminescence efficiency. Inorg Chem 58(9):5433\u20135445","journal-title":"Inorg Chem"},{"key":"304_CR8","doi-asserted-by":"crossref","first-page":"112104","DOI":"10.1016\/j.jphotochem.2019.112104","volume":"387","author":"J Wang","year":"2020","unstructured":"Wang J, Chen H, Xu S, Su Q, Zhao F, He H (2020) Highly effective luminescence stemmed from thermally activated delayed fluorescence (TADF) and phosphorescence for the new four-coordinate copper(I) complexes containing N-heterocyclic carbene (NHC) ligands. J Photochem Photobiol A 387:112104","journal-title":"J Photochem Photobiol A"},{"key":"304_CR9","doi-asserted-by":"crossref","first-page":"114240","DOI":"10.1016\/j.poly.2019.114240","volume":"175","author":"B Yang","year":"2020","unstructured":"Yang B, Wang J, Xu S, Chen H, Zhao F, Wang Y (2020) Four-coordinate N-heterocyclic carbene (NHC) copper(I) complexes bearing functionalized 3-benzyl-1-(pyridyl)-1H-imidazolylidene ligands: synthesis, photophysical properties and computational study. Polyhedron 175:114240","journal-title":"Polyhedron"},{"key":"304_CR10","doi-asserted-by":"crossref","first-page":"121196","DOI":"10.1016\/j.jorganchem.2020.121196","volume":"913","author":"N Pentela","year":"2020","unstructured":"Pentela N, Gayathri V, Samanta D (2020) N-Heterocyclic carbene bearing thermoresponsive poly(NIPAM) supported palladium (II) complex: synthetic strategy and application. J Organomet Chem 913:121196","journal-title":"J Organomet Chem"},{"key":"304_CR11","doi-asserted-by":"crossref","first-page":"114381","DOI":"10.1016\/j.poly.2020.114381","volume":"180","author":"R Hamze","year":"2020","unstructured":"Hamze R, Kapper SC, Sylvinson Muthiah Ravinson D, Haiges R, Djurovich PI, Thompson ME (2020) Molecular dynamics of four-coordinate carbene-Cu(I) complexes employing tris(pyrazolyl)borate ligands. Polyhedron 180:114381","journal-title":"Polyhedron"},{"key":"304_CR12","doi-asserted-by":"crossref","first-page":"121195","DOI":"10.1016\/j.jorganchem.2020.121195","volume":"913","author":"C Cao","year":"2020","unstructured":"Cao C, Mao G, Cheng J, Leng X, Deng L (2020) Reactions of a bis(vinyltrimethylsilane)nickel(0) N-heterocyclic carbene complex with organic azides. J Organomet Chem 913:121195","journal-title":"J Organomet Chem"},{"key":"304_CR13","doi-asserted-by":"crossref","first-page":"121062","DOI":"10.1016\/j.jorganchem.2019.121062","volume":"907","author":"RM Lord","year":"2020","unstructured":"Lord RM, Holmes J, Singer FN, Frith A, Willans CE (2020) Precious metal N-heterocyclic carbene\u2013carbaboranyl complexes: cytotoxic and selective compounds for the treatment of cancer. J Organomet Chem 907:121062","journal-title":"J Organomet Chem"},{"issue":"9","key":"304_CR14","doi-asserted-by":"crossref","first-page":"3405","DOI":"10.1021\/om00033a009","volume":"12","author":"AJ Arduengo","year":"1993","unstructured":"Arduengo AJ, Dias HVR, Calabrese JC, Davidson F (1993) Homoleptic carbene\u2013silver(I) and carbene\u2013copper(I) complexes. Organometallics 12(9):3405\u20133409","journal-title":"Organometallics"},{"issue":"10","key":"304_CR15","doi-asserted-by":"crossref","first-page":"2027","DOI":"10.1021\/om010014t","volume":"20","author":"AAD Tulloch","year":"2001","unstructured":"Tulloch AAD, Danopoulos AA, Kleinhenz S, Light ME, Hursthouse MB, Eastham G (2001) Structural diversity in pyridine-N-functionalized carbene copper(I) complexes. Organometallics 20(10):2027\u20132031","journal-title":"Organometallics"},{"issue":"12","key":"304_CR16","doi-asserted-by":"crossref","first-page":"3302","DOI":"10.1021\/om200033m","volume":"30","author":"X Liu","year":"2011","unstructured":"Liu X, Pattacini R, Deglmann P, Braunstein P (2011) Do short C\u2013H\u2013M (M = Cu(I), Ag(I)) distances represent agostic interactions in Pincer-type complexes? Unusual NHC transmetalation from Cu(I) to Ag(I). Organometallics 30(12):3302\u20133310","journal-title":"Organometallics"},{"key":"304_CR17","doi-asserted-by":"crossref","first-page":"313","DOI":"10.1039\/dt9950000313","volume":"2","author":"HG Raubenheimer","year":"1995","unstructured":"Raubenheimer HG, Cronje S, Olivier PJ (1995) Synthesis and characterization of mono(carbene) complexes of copper and crystal structure of a linear thiazolinylidene compound. J Chem Soc Dalton Trans 2:313","journal-title":"J Chem Soc Dalton Trans"},{"issue":"10","key":"304_CR18","doi-asserted-by":"crossref","first-page":"5215","DOI":"10.1021\/cr4006439","volume":"114","author":"K Riener","year":"2014","unstructured":"Riener K, Haslinger S, Raba A, H\u00f6gerl MP, Cokoja M, Herrmann WA, K\u00fchn FE (2014) Chemistry of iron N-heterocyclic carbene complexes: syntheses, structures, reactivities, and catalytic applications. Chem Rev 114(10):5215\u20135272","journal-title":"Chem Rev"},{"issue":"8","key":"304_CR19","doi-asserted-by":"crossref","first-page":"3561","DOI":"10.1021\/cr8005153","volume":"109","author":"JCY Lin","year":"2009","unstructured":"Lin JCY, Huang RTW, Lee CS, Bhattacharyya A, Hwang WS, Lin IJB (2009) Coinage metal\u2212N-heterocyclic carbene complexes. Chem Rev 109(8):3561\u20133598","journal-title":"Chem Rev"},{"issue":"15","key":"304_CR20","doi-asserted-by":"crossref","first-page":"8318","DOI":"10.1021\/acs.chemrev.6b00366","volume":"116","author":"AJ Jordan","year":"2016","unstructured":"Jordan AJ, Lalic G, Sadighi JP (2016) Coinage metal hydrides: synthesis, characterization, and reactivity. Chem Rev 116(15):8318\u20138372","journal-title":"Chem Rev"},{"issue":"4","key":"304_CR21","doi-asserted-by":"crossref","first-page":"912","DOI":"10.1039\/c2cy20816d","volume":"3","author":"JD Egbert","year":"2013","unstructured":"Egbert JD, Cazin CSJ, Nolan SP (2013) Copper N-heterocyclic carbene complexes in catalysis. Catal Sci Technol 3(4):912","journal-title":"Catal Sci Technol"},{"key":"304_CR22","doi-asserted-by":"crossref","first-page":"380","DOI":"10.1016\/j.ccr.2017.10.013","volume":"355","author":"M Trose","year":"2018","unstructured":"Trose M, Nahra F, Cazin CSJ (2018) Dinuclear N-heterocyclic carbene copper(I) complexes. Coord Chem Rev 355:380\u2013403","journal-title":"Coord Chem Rev"},{"issue":"3","key":"304_CR23","doi-asserted-by":"crossref","first-page":"628","DOI":"10.1039\/C6DT03687B","volume":"46","author":"F Nahra","year":"2017","unstructured":"Nahra F, G\u00f3mez-Herrera A, Cazin CSJ (2017) Copper(I)\u2013NHC complexes as NHC transfer agents. Dalton Trans 46(3):628\u2013631","journal-title":"Dalton Trans"},{"issue":"19","key":"304_CR24","doi-asserted-by":"crossref","first-page":"9988","DOI":"10.1021\/acs.chemrev.6b00695","volume":"118","author":"E Peris","year":"2017","unstructured":"Peris E (2017) Smart N-heterocyclic carbene ligands in catalysis. Chem Rev 118(19):9988\u201310031","journal-title":"Chem Rev"},{"issue":"5\u20136","key":"304_CR25","doi-asserted-by":"crossref","first-page":"610","DOI":"10.1016\/j.ccr.2006.08.001","volume":"251","author":"D Pugh","year":"2007","unstructured":"Pugh D, Danopoulos AA (2007) Metal complexes with \u2018pincer\u2019-type ligands incorporating N-heterocyclic carbene functionalities. Coord Chem Rev 251(5\u20136):610\u2013641","journal-title":"Coord Chem Rev"},{"key":"304_CR26","doi-asserted-by":"crossref","first-page":"53","DOI":"10.1016\/j.ccr.2017.03.007","volume":"341","author":"V Charra","year":"2017","unstructured":"Charra V, de Fr\u00e9mont P, Braunstein P (2017) Multidentate N-heterocyclic carbene complexes of the 3d metals: synthesis, structure, reactivity and catalysis. Coord Chem Rev 341:53\u2013176","journal-title":"Coord Chem Rev"},{"issue":"3","key":"304_CR27","doi-asserted-by":"crossref","first-page":"632","DOI":"10.1039\/C6CS00499G","volume":"46","author":"S Hameury","year":"2017","unstructured":"Hameury S, de Fr\u00e9mont P, Braunstein P (2017) Metal complexes with oxygen-functionalized NHC ligands: synthesis and applications. Chem Soc Rev 46(3):632\u2013733","journal-title":"Chem Soc Rev"},{"issue":"3","key":"304_CR28","doi-asserted-by":"crossref","first-page":"357","DOI":"10.1021\/acs.accounts.5b00381","volume":"49","author":"S Roy","year":"2016","unstructured":"Roy S, Mondal KC, Roesky HW (2016) Cyclic alkyl(amino) carbene stabilized complexes with low coordinate metals of enduring nature. Acc Chem Res 49(3):357\u2013369","journal-title":"Acc Chem Res"},{"issue":"34","key":"304_CR29","doi-asserted-by":"crossref","first-page":"10046","DOI":"10.1002\/anie.201702148","volume":"56","author":"M Melaimi","year":"2017","unstructured":"Melaimi M, Jazzar R, Soleilhavoup M, Bertrand G (2017) Cyclic (alkyl)(amino)carbenes (CAACs): recent developments. Angew Chem Int Ed 56(34):10046\u201310068","journal-title":"Angew Chem Int Ed"},{"issue":"8","key":"304_CR30","doi-asserted-by":"crossref","first-page":"3445","DOI":"10.1021\/cr8005087","volume":"109","author":"O Schuster","year":"2009","unstructured":"Schuster O, Yang L, Raubenheimer HG, Albrecht M (2009) Beyond conventional N-heterocyclic carbenes: abnormal, remote, and other classes of NHC ligands with reduced heteroatom stabilization. Chem Rev 109(8):3445\u20133478","journal-title":"Chem Rev"},{"issue":"14","key":"304_CR31","doi-asserted-by":"crossref","first-page":"2417","DOI":"10.1021\/ol034560p","volume":"5","author":"V Jurkauskas","year":"2003","unstructured":"Jurkauskas V, Sadighi JP, Buchwald SL (2003) Conjugate reduction of \u03b1, \u03b2-unsaturated carbonyl compounds catalyzed by a copper carbene complex. Org Lett 5(14):2417\u20132420","journal-title":"Org Lett"},{"issue":"6","key":"304_CR32","doi-asserted-by":"crossref","first-page":"1191","DOI":"10.1021\/om034368r","volume":"23","author":"NP Mankad","year":"2004","unstructured":"Mankad NP, Gray TG, Laitar DS, Sadighi JP (2004) Synthesis, structure, and CO2 reactivity of a two-coordinate (carbene)copper(I) methyl complex. Organometallics 23(6):1191\u20131193","journal-title":"Organometallics"},{"issue":"5","key":"304_CR33","doi-asserted-by":"crossref","first-page":"1157","DOI":"10.1021\/om034285a","volume":"23","author":"H Kaur","year":"2004","unstructured":"Kaur H, Zinn FK, Stevens ED, Nolan SP (2004) (NHC)CuI(NHC = N-heterocyclic carbene) complexes as efficient catalysts for the reduction of carbonyl compounds. Organometallics 23(5):1157\u20131160","journal-title":"Organometallics"},{"issue":"32","key":"304_CR34","doi-asserted-by":"crossref","first-page":"7595","DOI":"10.1039\/c0dt00218f","volume":"39","author":"S D\u00edez-Gonz\u00e1lez","year":"2010","unstructured":"D\u00edez-Gonz\u00e1lez S, Escudero-Ad\u00e1n EC, Benet-Buchholz J, Stevens ED, Slawin AMZ, Nolan SP (2010) [(NHC)CuX] complexes: synthesis, characterization and catalytic activities in reduction reactions and Click Chemistry. On the advantage of using well-defined catalytic systems. Dalton Trans 39(32):7595","journal-title":"Dalton Trans"},{"issue":"20","key":"304_CR35","doi-asserted-by":"crossref","first-page":"5463","DOI":"10.1021\/om200705y","volume":"30","author":"A G\u00f3mez-Su\u00e1rez","year":"2011","unstructured":"G\u00f3mez-Su\u00e1rez A, Ram\u00f3n RS, Songis O, Slawin AMZ, Cazin CSJ, Nolan SP (2011) Influence of a very bulky N-heterocyclic carbene in gold-mediated catalysis. Organometallics 30(20):5463\u20135470","journal-title":"Organometallics"},{"issue":"89","key":"304_CR36","doi-asserted-by":"crossref","first-page":"10483","DOI":"10.1039\/c3cc45488f","volume":"49","author":"O Santoro","year":"2013","unstructured":"Santoro O, Collado A, Slawin AMZ, Nolan SP, Cazin CSJ (2013) A general synthetic route to [Cu(X)(NHC)] (NHC = N-heterocyclic carbene, X = Cl, Br, I) complexes. Chem Commun 49(89):10483","journal-title":"Chem Commun"},{"issue":"15","key":"304_CR37","doi-asserted-by":"crossref","first-page":"4279","DOI":"10.1021\/om400440b","volume":"32","author":"C Gibard","year":"2013","unstructured":"Gibard C, Ibrahim H, Gautier A, Cisnetti F (2013) Simplified preparation of copper(I) NHCs using aqueous ammonia. Organometallics 32(15):4279\u20134283","journal-title":"Organometallics"},{"issue":"23","key":"304_CR38","doi-asserted-by":"crossref","first-page":"4778","DOI":"10.1039\/C4CC10375K","volume":"51","author":"YD Bidal","year":"2015","unstructured":"Bidal YD, Lesieur M, Melaimi M, Cordes DB, Slawin AMZ, Bertrand G, Cazin CSJ (2015) A simple access to transition metal cyclopropenylidene complexes. Chem Commun 51(23):4778\u20134781","journal-title":"Chem Commun"},{"issue":"14\u201315","key":"304_CR39","doi-asserted-by":"crossref","first-page":"3155","DOI":"10.1002\/adsc.201500453","volume":"357","author":"YD Bidal","year":"2015","unstructured":"Bidal YD, Lesieur M, Melaimi M, Nahra F, Cordes DB, AthukoralaArachchige KS, Slawin AMZ, Bertrand G, Cazin CSJ (2015) Copper(I) complexes bearing carbenes beyond classical N-heterocyclic carbenes: synthesis and catalytic activity in \u201cclick chemistry\u201d. Adv Synth Catal 357(14\u201315):3155\u20133161","journal-title":"Adv Synth Catal"},{"issue":"3","key":"304_CR40","doi-asserted-by":"crossref","first-page":"677","DOI":"10.1021\/om4008955","volume":"33","author":"S Dierick","year":"2014","unstructured":"Dierick S, Dewez DF, Mark\u00f3 IE (2014) IPr*(2-Np)\u2014an exceedingly bulky N-heterocyclic carbene. Organometallics 33(3):677\u2013683","journal-title":"Organometallics"},{"issue":"47","key":"304_CR41","doi-asserted-by":"crossref","first-page":"11249","DOI":"10.1002\/chem.201703215","volume":"23","author":"MMD Roy","year":"2017","unstructured":"Roy MMD, Lummis PA, Ferguson MJ, McDonald R, Rivard E (2017) Accessing low-valent inorganic cations by using an extremely bulky N-heterocyclic carbene. Chem Eur J 23(47):11249\u201311252","journal-title":"Chem Eur J"},{"issue":"31","key":"304_CR42","doi-asserted-by":"crossref","first-page":"10997","DOI":"10.1002\/chem.201500840","volume":"21","author":"M Teci","year":"2015","unstructured":"Teci M, Brenner E, Matt D, Gourlaouen C, Toupet L (2015) \u201cHummingbird\u201d behaviour of N-heterocyclic carbenes stabilises out-of-plane bonding of AuCl and CuCl units. Chem A Eur J 21(31):10997\u201311000","journal-title":"Chem A Eur J"},{"key":"304_CR43","doi-asserted-by":"crossref","first-page":"1","DOI":"10.1016\/j.jorganchem.2016.07.023","volume":"820","author":"Y Kim","year":"2016","unstructured":"Kim Y, Kim Y, Hur MY, Lee E (2016) Efficient synthesis of bulky N-heterocyclic carbene ligands for coinage metal complexes. J Organomet Chem 820:1\u20137","journal-title":"J Organomet Chem"},{"issue":"20","key":"304_CR44","doi-asserted-by":"crossref","first-page":"3067","DOI":"10.1002\/ejic.201100363","volume":"2011","author":"S Hohloch","year":"2011","unstructured":"Hohloch S, Su C-Y, Sarkar B (2011) Copper(I) complexes of normal and abnormal carbenes and their use as catalysts for the Huisgen [3+2] cycloaddition between azides and alkynes. Eur J Inorg Chem 2011(20):3067\u20133075","journal-title":"Eur J Inorg Chem"},{"issue":"4","key":"304_CR45","doi-asserted-by":"crossref","first-page":"620","DOI":"10.1021\/ol102858u","volume":"13","author":"T Nakamura","year":"2011","unstructured":"Nakamura T, Terashima T, Ogata K, Fukuzawa S-I (2011) Copper(I) 1,2,3-triazol-5-ylidene complexes as efficient catalysts for click reactions of azides with alkynes. Org Lett 13(4):620\u2013623","journal-title":"Org Lett"},{"issue":"15","key":"304_CR46","doi-asserted-by":"crossref","first-page":"2454","DOI":"10.1016\/j.jorganchem.2009.03.014","volume":"694","author":"EL Kolychev","year":"2009","unstructured":"Kolychev EL, Portnyagin IA, Shuntikov VV, Khrustalev VN, Nechaev MS (2009) Six- and seven-membered ring carbenes: Rational synthesis of amidinium salts, generation of carbenes, synthesis of Ag(I) and Cu(I) complexes. J Organomet Chem 694(15):2454\u20132462","journal-title":"J Organomet Chem"},{"issue":"5","key":"304_CR47","doi-asserted-by":"crossref","first-page":"613","DOI":"10.1021\/acs.organomet.6b00025","volume":"35","author":"AJ Jordan","year":"2016","unstructured":"Jordan AJ, Wyss CM, Bacsa J, Sadighi JP (2016) Synthesis and reactivity of new copper(I) hydride dimers. Organometallics 35(5):613\u2013616","journal-title":"Organometallics"},{"issue":"2","key":"304_CR48","doi-asserted-by":"crossref","first-page":"402","DOI":"10.1002\/asia.201000576","volume":"6","author":"GD Frey","year":"2011","unstructured":"Frey GD, Donnadieu B, Soleilhavoup M, Bertrand G (2011) Synthesis of a room-temperature-stable dimeric copper(I) hydride. Chem Asian J 6(2):402\u2013405","journal-title":"Chem Asian J"},{"issue":"35","key":"304_CR49","doi-asserted-by":"crossref","first-page":"12347","DOI":"10.1002\/chem.201500788","volume":"21","author":"H Braunschweig","year":"2015","unstructured":"Braunschweig H, Ewing WC, Kramer T, Mattock JD, Vargas A, Werner C (2015) Organometallic probe for the electronics of base-stabilized group 11 metal cations. Chem Eur J 21(35):12347\u201312356","journal-title":"Chem Eur J"},{"issue":"19","key":"304_CR50","doi-asserted-by":"crossref","first-page":"4625","DOI":"10.1002\/chem.201605891","volume":"23","author":"AS Romanov","year":"2017","unstructured":"Romanov AS, Becker CR, James CE, Di D, Credgington D, Linnolahti M, Bochmann M (2017) Copper and gold cyclic (alkyl)(amino)carbene complexes with sub-microsecond photoemissions: structure and substituent effects on redox and luminescent properties. Chem Eur J 23(19):4625\u20134637","journal-title":"Chem Eur J"},{"issue":"38","key":"304_CR51","doi-asserted-by":"crossref","first-page":"6379","DOI":"10.1039\/C6CC02349E","volume":"52","author":"AS Romanov","year":"2016","unstructured":"Romanov AS, Di D, Yang L, Fernandez-Cestau J, Becker CR, James CE, Zhu B, Linnolahti M, Credgington D, Bochmann M (2016) Highly photoluminescent copper carbene complexes based on prompt rather than delayed fluorescence. Chem Commun 52(38):6379\u20136382","journal-title":"Chem Commun"},{"issue":"22","key":"304_CR52","doi-asserted-by":"crossref","first-page":"7902","DOI":"10.1021\/om3005355","volume":"31","author":"C Gibard","year":"2012","unstructured":"Gibard C, Avignant D, Cisnetti F, Gautier A (2012) CuAAC functionalization of azide-tagged copper(I)-NHCs acting as catalyst and substrate. Organometallics 31(22):7902\u20137908","journal-title":"Organometallics"},{"issue":"19","key":"304_CR53","doi-asserted-by":"crossref","first-page":"6981","DOI":"10.1039\/C4DT00429A","volume":"43","author":"H Ibrahim","year":"2014","unstructured":"Ibrahim H, Gibard C, Hesling C, Guillot R, Morel L, Gautier A, Cisnetti F (2014) \u2018Auto-click\u2019 functionalization for diversified copper(i) and gold(i) NHCs. Dalton Trans 43(19):6981\u20136989","journal-title":"Dalton Trans"},{"issue":"27","key":"304_CR54","doi-asserted-by":"crossref","first-page":"7665","DOI":"10.1002\/anie.201600999","volume":"55","author":"W Wang","year":"2016","unstructured":"Wang W, Zhao L, Lv H, Zhang G, Xia C, Hahn FE, Li F (2016) Modular \u201cClick\u201d preparation of bifunctional polymeric heterometallic catalysts. Angew Chem Int Ed 55(27):7665\u20137670","journal-title":"Angew Chem Int Ed"},{"issue":"28","key":"304_CR55","doi-asserted-by":"crossref","first-page":"4074","DOI":"10.1002\/ejoc.201700523","volume":"2017","author":"A Szadkowska","year":"2017","unstructured":"Szadkowska A, Zaorska E, Staszko S, Paw\u0142owski R, Trzybi\u0144ski D, Wo\u017aniak K (2017) Synthesis, structural characterization and catalytic activities of sulfur-functionalized NHC\u2013copper(I) complexes. Eur J Org Chem 2017(28):4074\u20134084","journal-title":"Eur J Org Chem"},{"issue":"33","key":"304_CR56","doi-asserted-by":"crossref","first-page":"4344","DOI":"10.1039\/C4CC00550C","volume":"50","author":"C-C Tai","year":"2014","unstructured":"Tai C-C, Yu M-S, Chen Y-L, Chuang W-H, Lin T-H, Yap GPA, Ong T-G (2014) Synthesis of a guanidine NHC complex and its application in borylation reactions. Chem Commun 50(33):4344\u20134346","journal-title":"Chem Commun"},{"issue":"25","key":"304_CR57","doi-asserted-by":"crossref","first-page":"7884","DOI":"10.1021\/jacs.6b05221","volume":"138","author":"J Chu","year":"2016","unstructured":"Chu J, Munz D, Jazzar R, Melaimi M, Bertrand G (2016) Synthesis of hemilabile cyclic (alkyl)(amino)carbenes (CAACs) and applications in organometallic chemistry. J Am Chem Soc 138(25):7884\u20137887","journal-title":"J Am Chem Soc"},{"issue":"26","key":"304_CR58","doi-asserted-by":"crossref","first-page":"5801","DOI":"10.1021\/om980394r","volume":"17","author":"C Boehme","year":"1998","unstructured":"Boehme C, Frenking G (1998) N-Heterocyclic carbene, silylene, and germylene complexes of MCl (M = Cu, Ag, Au). Theoret Study Organometall 17(26):5801\u20135809","journal-title":"Theoret Study Organometall"},{"issue":"15","key":"304_CR59","doi-asserted-by":"crossref","first-page":"3640","DOI":"10.1021\/om049802j","volume":"23","author":"D Nemcsok","year":"2004","unstructured":"Nemcsok D, Wichmann K, Frenking G (2004) The significance of \u03c0 interactions in group 11 complexes with N-heterocyclic carbenes\u2020. Organometallics 23(15):3640\u20133646","journal-title":"Organometallics"},{"issue":"12","key":"304_CR60","doi-asserted-by":"crossref","first-page":"1555","DOI":"10.1002\/asia.200700235","volume":"2","author":"R Tonner","year":"2007","unstructured":"Tonner R, Heydenrych G, Frenking G (2007) Bonding analysis of N-heterocyclic carbene tautomers and phosphine ligands in transition-metal complexes. Theoret Stud Chem Asian J 2(12):1555\u20131567","journal-title":"Theoret Stud Chem Asian J"},{"issue":"49","key":"304_CR61","doi-asserted-by":"crossref","first-page":"16486","DOI":"10.1021\/ja8070804","volume":"130","author":"JR Herron","year":"2008","unstructured":"Herron JR, Ball ZT (2008) Synthesis and reactivity of functionalized arylcopper compounds by transmetalation of organosilanes. J Am Chem Soc 130(49):16486\u201316487","journal-title":"J Am Chem Soc"},{"issue":"2","key":"304_CR62","doi-asserted-by":"crossref","first-page":"523","DOI":"10.1002\/anie.201006292","volume":"50","author":"T Fujihara","year":"2011","unstructured":"Fujihara T, Xu T, Semba K, Terao J, Tsuji Y (2011) Copper-catalyzed hydrocarboxylation of alkynes using carbon dioxide and hydrosilanes. Angew Chem Int Ed 50(2):523\u2013527","journal-title":"Angew Chem Int Ed"},{"key":"304_CR63","doi-asserted-by":"crossref","first-page":"87","DOI":"10.1016\/j.poly.2014.06.039","volume":"84","author":"CM Wyss","year":"2014","unstructured":"Wyss CM, Tate BK, Bacsa J, Wieliczko M, Sadighi JP (2014) Dinuclear \u03bc-fluoro cations of copper, silver and gold. Polyhedron 84:87\u201395","journal-title":"Polyhedron"},{"issue":"35","key":"304_CR64","doi-asserted-by":"crossref","first-page":"8713","DOI":"10.1002\/chem.200901438","volume":"15","author":"JR Herron","year":"2009","unstructured":"Herron JR, Russo V, Valente EJ, Ball ZT (2009) Catalytic organocopper chemistry from organosiloxane reagents. Chem Eur J 15(35):8713\u20138716","journal-title":"Chem Eur J"},{"issue":"25","key":"304_CR65","doi-asserted-by":"crossref","first-page":"6473","DOI":"10.1002\/anie.201402238","volume":"53","author":"H Dang","year":"2014","unstructured":"Dang H, Mailig M, Lalic G (2014) Mild copper-catalyzed fluorination of alkyl triflates with potassium fluoride. Angew Chem Int Ed 53(25):6473\u20136476","journal-title":"Angew Chem Int Ed"},{"issue":"3","key":"304_CR66","doi-asserted-by":"crossref","first-page":"793","DOI":"10.1002\/chem.201102655","volume":"18","author":"T Vergote","year":"2012","unstructured":"Vergote T, Nahra F, Welle A, Luhmer M, Wouters J, Mager N, Riant O, Leyssens T (2012) Unprecedented copper(I) bifluoride complexes: synthesis, characterization and reactivity. Chem Eur J 18(3):793\u2013798","journal-title":"Chem Eur J"},{"issue":"24","key":"304_CR67","doi-asserted-by":"crossref","first-page":"7747","DOI":"10.1021\/jacs.5b03086","volume":"137","author":"AM Suess","year":"2015","unstructured":"Suess AM, Uehling MR, Kaminsky W, Lalic G (2015) Mechanism of copper-catalyzed hydroalkylation of alkynes: an unexpected role of dinuclear copper complexes. J Am Chem Soc 137(24):7747\u20137753","journal-title":"J Am Chem Soc"},{"issue":"14","key":"304_CR68","doi-asserted-by":"crossref","first-page":"3369","DOI":"10.1021\/om0496380","volume":"23","author":"NP Mankad","year":"2004","unstructured":"Mankad NP, Laitar DS, Sadighi JP (2004) Synthesis, structure, and alkyne reactivity of a dimeric (carbene)copper(I) hydride. Organometallics 23(14):3369\u20133371","journal-title":"Organometallics"},{"issue":"34","key":"304_CR69","doi-asserted-by":"crossref","first-page":"11036","DOI":"10.1021\/ja064019z","volume":"128","author":"DS Laitar","year":"2006","unstructured":"Laitar DS, Tsui EY, Sadighi JP (2006) Catalytic diboration of aldehydes via insertion into the copper\u2212boron bond. J Am Chem Soc 128(34):11036\u201311037","journal-title":"J Am Chem Soc"},{"issue":"22","key":"304_CR70","doi-asserted-by":"crossref","first-page":"7125","DOI":"10.1002\/chem.201300443","volume":"19","author":"K Semba","year":"2013","unstructured":"Semba K, Shinomiya M, Fujihara T, Terao J, Tsuji Y (2013) Highly selective copper-catalyzed hydroboration of allenes and 1,3-dienes. Chem Eur J 19(22):7125\u20137132","journal-title":"Chem Eur J"},{"issue":"24","key":"304_CR71","doi-asserted-by":"crossref","first-page":"8647","DOI":"10.1021\/ic0517624","volume":"44","author":"LA Goj","year":"2005","unstructured":"Goj LA, Blue ED, Munro-Leighton C, Gunnoe TB, Petersen JL (2005) Cleavage of X\u2212H bonds (X = N, O, or C) by copper(I) alkyl complexes to form monomeric two-coordinate copper(I) systems. Inorg Chem 44(24):8647\u20138649","journal-title":"Inorg Chem"},{"issue":"22","key":"304_CR72","doi-asserted-by":"crossref","first-page":"9032","DOI":"10.1021\/ic0611995","volume":"45","author":"LA Goj","year":"2006","unstructured":"Goj LA, Blue ED, Delp SA, Gunnoe TB, Cundari TR, Pierpont AW, Petersen JL, Boyle PD (2006) Chemistry surrounding monomeric copper(I) methyl, phenyl, anilido, ethoxide, and phenoxide complexes supported by N-heterocyclic carbene ligands: reactivity consistent with both early and late transition metal systems. Inorg Chem 45(22):9032\u20139045","journal-title":"Inorg Chem"},{"issue":"17","key":"304_CR73","doi-asserted-by":"crossref","first-page":"3966","DOI":"10.1021\/om100733n","volume":"29","author":"GC Fortman","year":"2010","unstructured":"Fortman GC, Slawin AMZ, Nolan SP (2010) A Versatile cuprous synthon: [Cu(IPr)(OH)] (IPr = 1,3 bis(diisopropylphenyl)imidazol-2-ylidene). Organometallics 29(17):3966\u20133972","journal-title":"Organometallics"},{"issue":"10","key":"304_CR74","doi-asserted-by":"crossref","first-page":"4813","DOI":"10.1021\/acs.inorgchem.6b00210","volume":"55","author":"J Plotzitzka","year":"2016","unstructured":"Plotzitzka J, Kleeberg C (2016) [(NHC)CuI\u2013ER3] complexes (ER3= SiMe2Ph, SiPh3, SnMe3): from linear, mononuclear complexes to polynuclear complexes with ultrashort CuI\u00b7\u00b7\u00b7CuI distances. Inorg Chem 55(10):4813\u20134823","journal-title":"Inorg Chem"},{"issue":"40","key":"304_CR75","doi-asserted-by":"crossref","first-page":"14075","DOI":"10.1002\/chem.201502476","volume":"21","author":"LR Collins","year":"2015","unstructured":"Collins LR, Riddlestone IM, Mahon MF, Whittlesey MK (2015) A comparison of the stability and reactivity of diamido- and diaminocarbene copper alkoxide and hydride complexes. Chem Eur J 21(40):14075\u201314084","journal-title":"Chem Eur J"},{"issue":"3","key":"304_CR76","doi-asserted-by":"crossref","first-page":"745","DOI":"10.1039\/C6DT04016K","volume":"46","author":"S Shi","year":"2017","unstructured":"Shi S, Collins LR, Mahon MF, Djurovich PI, Thompson ME, Whittlesey MK (2017) Synthesis and characterization of phosphorescent two-coordinate copper(i) complexes bearing diamidocarbene ligands. Dalton Trans 46(3):745\u2013752","journal-title":"Dalton Trans"},{"issue":"49","key":"304_CR77","doi-asserted-by":"crossref","first-page":"17196","DOI":"10.1021\/ja0566679","volume":"127","author":"DS Laitar","year":"2005","unstructured":"Laitar DS, M\u00fcller P, Sadighi JP (2005) Efficient homogeneous catalysis in the reduction of CO2 to CO. J Am Chem Soc 127(49):17196\u201317197","journal-title":"J Am Chem Soc"},{"key":"304_CR78","first-page":"100499","volume":"20","author":"S Matavos-Aramyan","year":"2019","unstructured":"Matavos-Aramyan S, Soukhakian S, Jazebizadeh MH, Moussavi M, Hojjati MR (2019) On engineering strategies for photoselective CO2 reduction\u2014a thorough review. Appl Mater Today 20:100499","journal-title":"Appl Mater Today"},{"issue":"31","key":"304_CR79","doi-asserted-by":"crossref","first-page":"5792","DOI":"10.1002\/anie.200801857","volume":"47","author":"T Ohishi","year":"2008","unstructured":"Ohishi T, Nishiura M, Hou Z (2008) Carboxylation of organoboronic esters catalyzed by N-heterocyclic carbene copper(I) complexes. Angew Chem Int Ed 47(31):5792\u20135795","journal-title":"Angew Chem Int Ed"},{"issue":"14","key":"304_CR80","doi-asserted-by":"crossref","first-page":"3216","DOI":"10.1021\/ol101171v","volume":"12","author":"AM Whittaker","year":"2010","unstructured":"Whittaker AM, Rucker RP, Lalic G (2010) Catalytic SN2\u2032-selective substitution of allylic chlorides with arylboronic esters. Org Lett 12(14):3216\u20133218","journal-title":"Org Lett"},{"issue":"30","key":"304_CR81","doi-asserted-by":"crossref","first-page":"9400","DOI":"10.1002\/chem.201402017","volume":"20","author":"G Tan","year":"2014","unstructured":"Tan G, Blom B, Gallego D, Irran E, Driess M (2014) Elucidating the effect of the nucleophilicity of the silyl group in the reduction of CO2 to CO mediated by silyl-copper(I) complexes. Chem Eur J 20(30):9400\u20139408","journal-title":"Chem Eur J"},{"issue":"38","key":"304_CR82","doi-asserted-by":"crossref","first-page":"12605","DOI":"10.1021\/jacs.6b07486","volume":"138","author":"W Xie","year":"2016","unstructured":"Xie W, Yoon JH, Chang S (2016) (NHC)Cu-catalyzed mild C\u2013H amidation of (hetero)arenes with deprotectable carbamates: scope and mechanistic studies. J Am Chem Soc 138(38):12605\u201312614","journal-title":"J Am Chem Soc"},{"issue":"12","key":"304_CR83","doi-asserted-by":"crossref","first-page":"2682","DOI":"10.1021\/om8001729","volume":"27","author":"KX Bhattacharyya","year":"2008","unstructured":"Bhattacharyya KX, Akana JA, Laitar DS, Berlin JM, Sadighi JP (2008) Carbon\u2212carbon bond formation on reaction of a copper(I) stannyl complex with carbon dioxide. Organometallics 27(12):2682\u20132684","journal-title":"Organometallics"},{"issue":"47","key":"304_CR84","doi-asserted-by":"crossref","first-page":"19060","DOI":"10.1021\/ja208969d","volume":"133","author":"C Kleeberg","year":"2011","unstructured":"Kleeberg C, Cheung MS, Lin Z, Marder TB (2011) Copper-mediated reduction of CO2 with pinB-SiMe2Ph via CO2 insertion into a copper-silicon bond. J Am Chem Soc 133(47):19060\u201319063","journal-title":"J Am Chem Soc"},{"issue":"9","key":"304_CR85","doi-asserted-by":"crossref","first-page":"2898","DOI":"10.1021\/ja910989n","volume":"132","author":"K-S Lee","year":"2010","unstructured":"Lee K-S, Hoveyda AH (2010) Enantioselective conjugate silyl additions to cyclic and acyclic unsaturated carbonyls catalyzed by cu complexes of chiral N-heterocyclic carbenes. J Am Chem Soc 132(9):2898\u20132900","journal-title":"J Am Chem Soc"},{"issue":"27","key":"304_CR86","doi-asserted-by":"crossref","first-page":"8600","DOI":"10.1021\/ja802946s","volume":"130","author":"GG Dubinina","year":"2008","unstructured":"Dubinina GG, Furutachi H, Vicic DA (2008) Active trifluoromethylating agents from well-defined copper(I)\u2212CF3 complexes. J Am Chem Soc 130(27):8600\u20138601","journal-title":"J Am Chem Soc"},{"issue":"5","key":"304_CR87","doi-asserted-by":"crossref","first-page":"1446","DOI":"10.1021\/ja057622a","volume":"128","author":"C Munro-Leighton","year":"2006","unstructured":"Munro-Leighton C, Blue ED, Gunnoe TB (2006) Anti-Markovnikov N\u2212H and O\u2212H additions to electron-deficient olefins catalyzed by well-defined Cu(I) anilido, ethoxide, and phenoxide systems. J Am Chem Soc 128(5):1446\u20131447","journal-title":"J Am Chem Soc"},{"issue":"6","key":"304_CR88","doi-asserted-by":"crossref","first-page":"1483","DOI":"10.1021\/om061133h","volume":"26","author":"C Munro-Leighton","year":"2007","unstructured":"Munro-Leighton C, Delp SA, Blue ED, Gunnoe TB (2007) Addition of N\u2212H and O\u2212H bonds of amines and alcohols to electron-deficient olefins catalyzed by monomeric copper(I) systems: reaction scope, mechanistic details, and comparison of catalyst, efficiency. Organometallics 26(6):1483\u20131493","journal-title":"Organometallics"},{"issue":"10","key":"304_CR89","doi-asserted-by":"crossref","first-page":"2182","DOI":"10.1021\/cs300544w","volume":"2","author":"MJ Pouy","year":"2012","unstructured":"Pouy MJ, Delp SA, Uddin J, Ramdeen VM, Cochrane NA, Fortman GC, Gunnoe TB, Cundari TR, Sabat M, Myers WH (2012) Intramolecular hydroalkoxylation and hydroamination of alkynes catalyzed by Cu(I) complexes supported by N-heterocyclic carbene ligands. ACS Catal 2(10):2182\u20132193","journal-title":"ACS Catal"},{"issue":"64","key":"304_CR90","doi-asserted-by":"crossref","first-page":"8927","DOI":"10.1039\/C4CC03201B","volume":"50","author":"M Lesieur","year":"2014","unstructured":"Lesieur M, Lazreg F, Cazin CSJ (2014) A cooperative Pd\u2013Cu system for direct C\u2013H bond arylation. Chem Commun 50(64):8927\u20138929","journal-title":"Chem Commun"},{"issue":"23","key":"304_CR91","doi-asserted-by":"crossref","first-page":"6915","DOI":"10.1021\/om500989w","volume":"33","author":"J Plotzitzka","year":"2014","unstructured":"Plotzitzka J, Kleeberg C (2014) CuI-catalyzed conjugate addition of silyl boronic esters: retracing catalytic cycles using isolated copper and boron enolate intermediates. Organometallics 33(23):6915\u20136926","journal-title":"Organometallics"},{"issue":"1","key":"304_CR92","doi-asserted-by":"crossref","first-page":"349","DOI":"10.1002\/ange.201508266","volume":"128","author":"R Doi","year":"2016","unstructured":"Doi R, Ohashi M, Ogoshi S (2016) Copper-catalyzed reaction of trifluoromethylketones with aldehydes via a copper difluoroenolate. Angew Chem 128(1):349\u2013352","journal-title":"Angew Chem"},{"issue":"1","key":"304_CR93","doi-asserted-by":"crossref","first-page":"589","DOI":"10.1039\/C5SC03258J","volume":"7","author":"J Zhai","year":"2016","unstructured":"Zhai J, Filatov AS, Hillhouse GL, Hopkins MD (2016) Synthesis, structure, and reactions of a copper\u2013sulfido cluster comprised of the parent Cu2S unit: {(NHC)Cu}2(\u03bc-S). Chem Sci 7(1):589\u2013595","journal-title":"Chem Sci"},{"issue":"7","key":"304_CR94","doi-asserted-by":"crossref","first-page":"2365","DOI":"10.1021\/ic070268s","volume":"46","author":"SA Delp","year":"2007","unstructured":"Delp SA, Munro-Leighton C, Goj LA, Ram\u00edrez MA, Gunnoe TB, Petersen JL, Boyle PD (2007) Addition of S\u2212H bonds across electron-deficient olefins catalyzed by well-defined copper(I) thiolate complexes. Inorg Chem 46(7):2365\u20132367","journal-title":"Inorg Chem"},{"issue":"2","key":"304_CR95","doi-asserted-by":"crossref","first-page":"621","DOI":"10.1021\/ic801836k","volume":"48","author":"S Groysman","year":"2009","unstructured":"Groysman S, Holm RH (2009) A series of mononuclear quasi-two-coordinate copper(I) complexes employing a sterically demanding thiolate ligand. Inorg Chem 48(2):621\u2013627","journal-title":"Inorg Chem"},{"key":"304_CR96","doi-asserted-by":"crossref","first-page":"5847","DOI":"10.1039\/b911643e","volume":"39","author":"MM Melzer","year":"2009","unstructured":"Melzer MM, Li E, Warren TH (2009) Reversible RS\u2013NO bond cleavage and formation at copper(I) thiolates. Chem Commun 39:5847","journal-title":"Chem Commun"},{"issue":"12","key":"304_CR97","doi-asserted-by":"crossref","first-page":"6567","DOI":"10.1021\/ic300124n","volume":"51","author":"SJ Ferrara","year":"2012","unstructured":"Ferrara SJ, Mague JT, Donahue JP (2012) Synthesis and structures of cuprous triptycylthiolate complexes. Inorg Chem 51(12):6567\u20136576","journal-title":"Inorg Chem"},{"issue":"19","key":"304_CR98","doi-asserted-by":"crossref","first-page":"4637","DOI":"10.1021\/acs.organomet.5b00421","volume":"34","author":"J Zhai","year":"2015","unstructured":"Zhai J, Hopkins MD, Hillhouse GL (2015) Synthesis and structure of a CuI3S cluster unsupported by other bridging ligands. Organometallics 34(19):4637\u20134640","journal-title":"Organometallics"},{"issue":"18","key":"304_CR99","doi-asserted-by":"crossref","first-page":"9173","DOI":"10.1021\/acs.inorgchem.5b02811","volume":"55","author":"SJ Ferrara","year":"2016","unstructured":"Ferrara SJ, Wang B, Haas E, Wright LeBlanc K, Mague JT, Donahue JP (2016) Synthesis and structures of [LCu(I)(SSiiPr3)] (L = triphos, carbene) and related compounds. Inorg Chem 55(18):9173\u20139177","journal-title":"Inorg Chem"},{"key":"304_CR100","doi-asserted-by":"crossref","first-page":"161","DOI":"10.1016\/j.jorganchem.2017.10.039","volume":"867","author":"M Shieh","year":"2018","unstructured":"Shieh M, Liu Y-H, Li Y-H, Lin C-N, Wang C-C (2018) Functionalized NHC-incorporated Te\u2212Fe\u2212Cu clusters: facile synthesis, electrochemistry, and catalytic reaction. J Organomet Chem 867:161\u2013169","journal-title":"J Organomet Chem"},{"issue":"1","key":"304_CR101","doi-asserted-by":"crossref","first-page":"55","DOI":"10.1021\/om101084e","volume":"30","author":"SA Delp","year":"2011","unstructured":"Delp SA, Goj LA, Pouy MJ, Munro-Leighton C, Lee JP, Gunnoe TB, Cundari TR, Petersen JL (2011) Well-defined copper(I) amido complex and aryl iodides reacting to form aryl amines. Organometallics 30(1):55\u201357","journal-title":"Organometallics"},{"issue":"15","key":"304_CR102","doi-asserted-by":"crossref","first-page":"1523","DOI":"10.1016\/j.tetlet.2017.03.011","volume":"58","author":"T Bai","year":"2017","unstructured":"Bai T, Yang Y, Han C (2017) Isolation and characterization of hydrocarbon soluble NHC copper(I) phosphoranimide complex and catalytic application for alkyne hydroboration reaction. Tetrahedron Lett 58(15):1523\u20131527","journal-title":"Tetrahedron Lett"},{"issue":"15","key":"304_CR103","doi-asserted-by":"crossref","first-page":"2800","DOI":"10.1021\/acs.organomet.7b00292","volume":"36","author":"JP Coyle","year":"2017","unstructured":"Coyle JP, Sirianni ER, Korobkov I, Yap GPA, Dey G, Barry ST (2017) Study of monomeric copper complexes supported by N-heterocyclic and acyclic diamino carbenes. Organometallics 36(15):2800\u20132810","journal-title":"Organometallics"},{"issue":"32","key":"304_CR104","doi-asserted-by":"crossref","first-page":"14235","DOI":"10.1039\/C5DT02040A","volume":"44","author":"B Khalili Najafabadi","year":"2015","unstructured":"Khalili Najafabadi B, Corrigan JF (2015) Enhanced thermal stability of Cu\u2013silylphosphido complexes via NHC ligation. Dalton Trans 44(32):14235\u201314241","journal-title":"Dalton Trans"},{"issue":"2","key":"304_CR105","doi-asserted-by":"crossref","first-page":"455","DOI":"10.1021\/acs.organomet.6b00854","volume":"36","author":"J Yuan","year":"2017","unstructured":"Yuan J, Zhu L, Zhang J, Li J, Cui C (2017) Sequential addition of phosphine to alkynes for the selective synthesis of 1,2-diphosphinoethanes under catalysis. Well-defined NHC-copper phosphides vs in situ CuCl2\/NHC catalyst. Organometallics 36(2):455\u2013459","journal-title":"Organometallics"},{"issue":"1","key":"304_CR106","doi-asserted-by":"crossref","first-page":"112","DOI":"10.1039\/C7DT04110A","volume":"47","author":"M Blum","year":"2018","unstructured":"Blum M, Kappler J, Schlindwein SH, Nieger M, Gudat D (2018) Synthesis, spectroscopic characterisation and transmetalation of lithium and potassium diaminophosphanide-boranes. Dalton Trans 47(1):112\u2013119","journal-title":"Dalton Trans"},{"issue":"52","key":"304_CR107","doi-asserted-by":"crossref","first-page":"16968","DOI":"10.1002\/anie.201803888","volume":"57","author":"JM Goicoechea","year":"2018","unstructured":"Goicoechea JM, Gr\u00fctzmacher H (2018) The chemistry of the 2-phosphaethynolate anion. Angew Chem Int Ed 57(52):16968\u201316994","journal-title":"Angew Chem Int Ed"},{"issue":"3","key":"304_CR108","doi-asserted-by":"crossref","first-page":"2335","DOI":"10.1039\/C5SC04504E","volume":"7","author":"L Liu","year":"2016","unstructured":"Liu L, Ruiz DA, Dahcheh F, Bertrand G, Suter R, Tondreau AM, Gr\u00fctzmacher H (2016) Isolation of Au-, Co-\u03b71PCO and Cu-\u03b72PCO complexes, conversion of an Ir\u2013\u03b71PCO complex into a dimetalladiphosphene, and an interaction-free PCO anion. Chem Sci 7(3):2335\u20132341","journal-title":"Chem Sci"},{"issue":"17","key":"304_CR109","doi-asserted-by":"crossref","first-page":"4097","DOI":"10.1021\/om060409i","volume":"25","author":"LA Goj","year":"2006","unstructured":"Goj LA, Blue ED, Delp SA, Gunnoe TB, Cundari TR, Petersen JL (2006) Single-electron oxidation of monomeric copper(I) alkyl complexes: evidence for reductive elimination through bimolecular formation of alkanes. Organometallics 25(17):4097\u20134104","journal-title":"Organometallics"},{"issue":"4","key":"304_CR110","doi-asserted-by":"crossref","first-page":"1010","DOI":"10.1002\/asia.201403247","volume":"10","author":"A Ueno","year":"2015","unstructured":"Ueno A, Takimoto M, Nishiura WWNOM, Ikariya T, Hou Z (2015) Copper-catalyzed formal C\u2013H carboxylation of aromatic compounds with carbon dioxide through arylaluminum intermediates. Chem Asian J 10(4):1010\u20131016","journal-title":"Chem Asian J"},{"issue":"1","key":"304_CR111","doi-asserted-by":"crossref","first-page":"362","DOI":"10.1021\/ol2031119","volume":"14","author":"MR Uehling","year":"2011","unstructured":"Uehling MR, Marionni ST, Lalic G (2011) Asymmetric synthesis of trisubstituted allenes: copper-catalyzed alkylation and arylation of propargylic phosphates. Org Lett 14(1):362\u2013365","journal-title":"Org Lett"},{"issue":"15","key":"304_CR112","doi-asserted-by":"crossref","first-page":"6571","DOI":"10.1021\/ja3023829","volume":"134","author":"RP Rucker","year":"2012","unstructured":"Rucker RP, Whittaker AM, Dang H, Lalic G (2012) Synthesis of tertiary alkyl amines from terminal alkenes: copper-catalyzed amination of alkyl boranes. J Am Chem Soc 134(15):6571\u20136574","journal-title":"J Am Chem Soc"},{"key":"304_CR113","doi-asserted-by":"crossref","first-page":"106","DOI":"10.1016\/j.jorganchem.2016.07.006","volume":"821","author":"M Stollenz","year":"2016","unstructured":"Stollenz M, Fischer S, Gehring H, Resch SG, Dechert S, Gro\u00dfe C, Meyer F (2016) Molecular dicopper(I) oxalate stabilized by two N-heterocyclic carbenes: a potential precursor for copper deposition. J Organomet Chem 821:106\u2013111","journal-title":"J Organomet Chem"},{"issue":"9","key":"304_CR114","doi-asserted-by":"crossref","first-page":"1535","DOI":"10.1002\/zaac.200300104","volume":"629","author":"M Niemeyer","year":"2003","unstructured":"Niemeyer M (2003) Reaktion von Kupferarylen mit Imidazol-2-ylidenen oder Triphenylphosphan\u2014Bildung von 1:1-Addukten mit zweifach koordinierten Kupferatomen. Z Anorg Allg Chem 629(9):1535\u20131540","journal-title":"Z Anorg Allg Chem"},{"issue":"28","key":"304_CR115","doi-asserted-by":"crossref","first-page":"4506","DOI":"10.1002\/ejic.201000433","volume":"2010","author":"D An","year":"2010","unstructured":"An D, Wang J, Dong T, Yang Y, Wen T, Zhu H, Lu X, Wang Y (2010) Mononuclear bis(imino)arylcopper(I) N-heterocyclic carbene complex: synthesis, structure, and reaction with organic azide. Eur J Inorg Chem 2010(28):4506\u20134512","journal-title":"Eur J Inorg Chem"},{"issue":"46","key":"304_CR116","doi-asserted-by":"crossref","first-page":"8670","DOI":"10.1002\/anie.201003995","volume":"49","author":"L Zhang","year":"2010","unstructured":"Zhang L, Cheng J, Ohishi T, Hou Z (2010) Copper-catalyzed direct carboxylation of C\u2013H bonds with carbon dioxide. Angew Chem Int Ed 49(46):8670\u20138673","journal-title":"Angew Chem Int Ed"},{"issue":"12","key":"304_CR117","doi-asserted-by":"crossref","first-page":"2101","DOI":"10.1002\/anie.200604444","volume":"46","author":"C Nolte","year":"2007","unstructured":"Nolte C, Mayer P, Straub BF (2007) Isolation of a copper(I) triazolide: a \u201cclick\u201d intermediate. Angew Chem Int Ed 46(12):2101\u20132103","journal-title":"Angew Chem Int Ed"},{"issue":"6131","key":"304_CR118","doi-asserted-by":"crossref","first-page":"457","DOI":"10.1126\/science.1229506","volume":"340","author":"BT Worrell","year":"2013","unstructured":"Worrell BT, Malik JA, Fokin VV (2013) Direct evidence of a dinuclear copper intermediate in Cu(I)-catalyzed azide-alkyne cycloadditions. Science 340(6131):457\u2013460","journal-title":"Science"},{"issue":"5","key":"304_CR119","doi-asserted-by":"crossref","first-page":"e1500304","DOI":"10.1126\/sciadv.1500304","volume":"1","author":"L Jin","year":"2015","unstructured":"Jin L, Tolentino DR, Melaimi M, Bertrand G (2015) Isolation of bis(copper) key intermediates in Cu-catalyzed azide-alkyne \u201cclick reaction\u201d. Sci Adv 1(5):e1500304","journal-title":"Sci Adv"},{"issue":"5","key":"304_CR120","doi-asserted-by":"crossref","first-page":"1112","DOI":"10.1021\/ol4001679","volume":"15","author":"AM Whittaker","year":"2013","unstructured":"Whittaker AM, Lalic G (2013) Monophasic catalytic system for the selective semireduction of alkynes. Org Lett 15(5):1112\u20131115","journal-title":"Org Lett"},{"issue":"24","key":"304_CR121","doi-asserted-by":"crossref","first-page":"8799","DOI":"10.1021\/ja503944n","volume":"136","author":"MR Uehling","year":"2014","unstructured":"Uehling MR, Rucker RP, Lalic G (2014) Catalytic anti-Markovnikov hydrobromination of alkynes. J Am Chem Soc 136(24):8799\u20138803","journal-title":"J Am Chem Soc"},{"issue":"4","key":"304_CR122","doi-asserted-by":"crossref","first-page":"1424","DOI":"10.1021\/ja5124368","volume":"137","author":"MR Uehling","year":"2015","unstructured":"Uehling MR, Suess AM, Lalic G (2015) Copper-catalyzed hydroalkylation of terminal alkynes. J Am Chem Soc 137(4):1424\u20131427","journal-title":"J Am Chem Soc"},{"issue":"1","key":"304_CR123","doi-asserted-by":"crossref","first-page":"158","DOI":"10.1002\/chem.200701013","volume":"14","author":"S D\u00edez-Gonz\u00e1lez","year":"2008","unstructured":"D\u00edez-Gonz\u00e1lez S, Stevens ED, Scott NM, Petersen JL, Nolan SP (2008) Synthesis and characterization of [Cu(NHC)2]X complexes: catalytic and mechanistic studies of hydrosilylation reactions. Chem Eur J 14(1):158\u2013168","journal-title":"Chem Eur J"},{"issue":"29","key":"304_CR124","doi-asserted-by":"crossref","first-page":"4124","DOI":"10.1039\/C7CC00891K","volume":"53","author":"L Jin","year":"2017","unstructured":"Jin L, Hao W, Xu J, Sun N, Hu B, Shen Z, Mo W, Hu X (2017) N-Heterocyclic carbene copper-catalyzed direct alkylation of terminal alkynes with non-activated alkyl triflates. Chem Commun 53(29):4124\u20134127","journal-title":"Chem Commun"},{"issue":"6","key":"304_CR125","doi-asserted-by":"crossref","first-page":"1451","DOI":"10.1021\/om901122z","volume":"29","author":"I Kieltsch","year":"2010","unstructured":"Kieltsch I, Dubinina GG, Hamacher C, Kaiser A, Torres-Nieto J, Hutchison JM, Klein A, Budnikova Y, Vicic DA (2010) Magnitudes of electron-withdrawing effects of the trifluoromethyl ligand in organometallic complexes of copper and nickel. Organometallics 29(6):1451\u20131456","journal-title":"Organometallics"},{"issue":"23","key":"304_CR126","doi-asserted-by":"crossref","first-page":"6233","DOI":"10.1021\/om800794m","volume":"27","author":"GG Dubinina","year":"2008","unstructured":"Dubinina GG, Ogikubo J, Vicic DA (2008) Structure of bis(trifluoromethyl)cuprate and its role in trifluoromethylation reactions. Organometallics 27(23):6233\u20136235","journal-title":"Organometallics"},{"issue":"7","key":"304_CR127","doi-asserted-by":"crossref","first-page":"1220","DOI":"10.1021\/acs.organomet.7b00025","volume":"36","author":"JR Bour","year":"2017","unstructured":"Bour JR, Kariofillis SK, Sanford MS (2017) Synthesis, reactivity, and catalytic applications of isolable (NHC)Cu(CHF2) complexes. Organometallics 36(7):1220\u20131223","journal-title":"Organometallics"},{"issue":"17","key":"304_CR128","doi-asserted-by":"crossref","first-page":"5307","DOI":"10.1002\/ange.201500341","volume":"127","author":"LI Panferova","year":"2015","unstructured":"Panferova LI, Miloserdov FM, Lishchynskyi A, Mart\u00ednez Belmonte M, Benet-Buchholz J, Grushin VV (2015) Well-defined CuC2F5 complexes and pentafluoroethylation of acid chlorides. Angew Chem 127(17):5307\u20135311","journal-title":"Angew Chem"},{"issue":"36","key":"304_CR129","doi-asserted-by":"crossref","first-page":"12855","DOI":"10.1021\/jacs.7b08343","volume":"139","author":"H Sakaguchi","year":"2017","unstructured":"Sakaguchi H, Uetake Y, Ohashi M, Niwa T, Ogoshi S, Hosoya T (2017) Copper-catalyzed regioselective monodefluoroborylation of polyfluoroalkenes en route to diverse fluoroalkenes. J Am Chem Soc 139(36):12855\u201312862","journal-title":"J Am Chem Soc"},{"issue":"1","key":"304_CR130","doi-asserted-by":"crossref","first-page":"328","DOI":"10.1002\/anie.201710866","volume":"57","author":"H Sakaguchi","year":"2018","unstructured":"Sakaguchi H, Ohashi M, Ogoshi S (2018) Fluorinated vinylsilanes from the copper-catalyzed defluorosilylation of fluoroalkene feedstocks. Angew Chem Int Ed 57(1):328\u2013332","journal-title":"Angew Chem Int Ed"},{"issue":"4","key":"304_CR131","doi-asserted-by":"crossref","first-page":"755","DOI":"10.1021\/om0341855","volume":"23","author":"X Hu","year":"2004","unstructured":"Hu X, Castro-Rodriguez I, Olsen K, Meyer K (2004) Group 11 metal complexes of N-heterocyclic carbene ligands: nature of the metalcarbene bond. Organometallics 23(4):755\u2013764","journal-title":"Organometallics"},{"issue":"20","key":"304_CR132","doi-asserted-by":"crossref","first-page":"6135","DOI":"10.1021\/om900566k","volume":"28","author":"VM Iluc","year":"2009","unstructured":"Iluc VM, Laskowski CA, Hillhouse GL (2009) Synthesis of bis(phosphine) and N-heterocyclic carbene supported \u03b1-diazoalkyl complexes of copper(I). Organometallics 28(20):6135\u20136138","journal-title":"Organometallics"},{"issue":"8","key":"304_CR133","doi-asserted-by":"crossref","first-page":"3817","DOI":"10.1039\/C4DT03770G","volume":"44","author":"MJ Sgro","year":"2015","unstructured":"Sgro MJ, Piers WE, Romero PE (2015) Synthesis, structural characterization and thermal properties of copper and silver silyl complexes. Dalton Trans 44(8):3817\u20133828","journal-title":"Dalton Trans"},{"issue":"48","key":"304_CR134","doi-asserted-by":"crossref","first-page":"13538","DOI":"10.1002\/chem.201102367","volume":"17","author":"C Kleeberg","year":"2011","unstructured":"Kleeberg C, Feldmann E, Hartmann E, Vyas DJ, Oestreich M (2011) Copper-catalyzed 1,2-addition of nucleophilic silicon to aldehydes: mechanistic insight and catalytic systems. Chem Eur J 17(48):13538\u201313543","journal-title":"Chem Eur J"},{"issue":"6","key":"304_CR135","doi-asserted-by":"crossref","first-page":"1340","DOI":"10.1021\/om100730h","volume":"30","author":"A Ariafard","year":"2011","unstructured":"Ariafard A, Brookes NJ, Stranger R, Yates BF (2011) DFT Study on the mechanism of the activation and cleavage of CO2 by (NHC)CuEPh3(E = Si, Ge, Sn). Organometallics 30(6):1340\u20131349","journal-title":"Organometallics"},{"issue":"15","key":"304_CR136","doi-asserted-by":"crossref","first-page":"2486","DOI":"10.1002\/ejic.201402234","volume":"2014","author":"C Borner","year":"2014","unstructured":"Borner C, Kleeberg C (2014) Selective synthesis of unsymmetrical diboryl ptiiand diaminoboryl CuI complexes by B\u2013B activation of unsymmetrical diboranes(4) {pinB-B[(NR)2C6H4]}. Eur J Inorg Chem 2014(15):2486\u20132489","journal-title":"Eur J Inorg Chem"},{"issue":"50","key":"304_CR137","doi-asserted-by":"crossref","first-page":"11744","DOI":"10.1021\/ja992168u","volume":"121","author":"Y Kawano","year":"1999","unstructured":"Kawano Y, Yasue T, Shimoi M, Bond BH (1999) Activation of trimethylphosphineborane by transition metal complexes: synthesis of metal complexes bearing nonsubstituted boryl\u2212trimethylphosphine, Cp*M(CO)3(BH2\u00b7PMe3) (M = Mo, W). J Am Chem Soc 121(50):11744\u201311750","journal-title":"J Am Chem Soc"},{"issue":"14","key":"304_CR138","doi-asserted-by":"crossref","first-page":"3424","DOI":"10.1021\/om700345m","volume":"26","author":"SP Green","year":"2007","unstructured":"Green SP, Jones C, Mills DP, Stasch A (2007) Group 9 and 11 metal(I) gallyl complexes stabilized by N-heterocyclic carbene coordination: first structural characterization of Ga\u2212M (M = Cu or Ag) bonds. Organometallics 26(14):3424\u20133430","journal-title":"Organometallics"},{"issue":"22","key":"304_CR139","doi-asserted-by":"crossref","first-page":"2410","DOI":"10.1016\/j.jorganchem.2010.07.016","volume":"695","author":"C Jones","year":"2010","unstructured":"Jones C, Mills DP, Rose RP, Stasch A, Woodul WD (2010) Synthesis and further reactivity studies of some transition metal gallyl complexes. J Organomet Chem 695(22):2410\u20132417","journal-title":"J Organomet Chem"},{"issue":"8","key":"304_CR140","doi-asserted-by":"crossref","first-page":"1818","DOI":"10.1021\/ic50114a015","volume":"11","author":"MR Churchill","year":"1972","unstructured":"Churchill MR, Bezman SA, Osborn JA, Wormald J (1972) Synthesis and molecular geometry of hexameric triphenylphosphinocopper(I) hydride and the crystal structure of H6Cu6(PPh3)6. HCONMe2 [hexameric triphenylphosphino copper(I) hydride dimethylformamide]. Inorgan Chem 11(8):1818\u20131825","journal-title":"Inorgan Chem"},{"issue":"8","key":"304_CR141","doi-asserted-by":"crossref","first-page":"2916","DOI":"10.1021\/cr0684321","volume":"108","author":"C Deutsch","year":"2008","unstructured":"Deutsch C, Krause N, Lipshutz BH (2008) CuH-catalyzed reactions. Chem Rev 108(8):2916\u20132927","journal-title":"Chem Rev"},{"issue":"16","key":"304_CR142","doi-asserted-by":"crossref","first-page":"4164","DOI":"10.1021\/acs.organomet.5b00629","volume":"34","author":"SC Schmid","year":"2015","unstructured":"Schmid SC, Van Hoveln R, Rigoli JW, Schomaker JM (2015) Development of N-heterocyclic carbene-copper complexes for 1,3-halogen migration. Organometallics 34(16):4164\u20134173","journal-title":"Organometallics"},{"issue":"8","key":"304_CR143","doi-asserted-by":"crossref","first-page":"1953","DOI":"10.1021\/om401097q","volume":"33","author":"T Vergote","year":"2014","unstructured":"Vergote T, Nahra F, Merschaert A, Riant O, Peeters D, Leyssens T (2014) Mechanistic insight into the (NHC)copper(I)-catalyzed hydrosilylation of ketones. Organometallics 33(8):1953\u20131963","journal-title":"Organometallics"},{"issue":"14","key":"304_CR144","doi-asserted-by":"crossref","first-page":"4024","DOI":"10.1002\/anie.201700858","volume":"56","author":"EA Romero","year":"2017","unstructured":"Romero EA, Olsen PM, Jazzar R, Soleilhavoup M, Gembicky M, Bertrand G (2017) Spectroscopic evidence for a monomeric copper(I) hydride and crystallographic characterization of a monomeric silver(I) hydride. Angew Chem Int Ed 56(14):4024\u20134027","journal-title":"Angew Chem Int Ed"},{"key":"304_CR145","doi-asserted-by":"crossref","first-page":"121025","DOI":"10.1016\/j.jorganchem.2019.121025","volume":"906","author":"D Li","year":"2020","unstructured":"Li D, Ollevier T (2020) Mechanism studies of oxidation and hydrolysis of Cu(I)\u2013NHC and Ag\u2013NHC in solution under air. J Organomet Chem 906:121025","journal-title":"J Organomet Chem"},{"issue":"50","key":"304_CR146","doi-asserted-by":"crossref","first-page":"15539","DOI":"10.1002\/anie.201608081","volume":"55","author":"LR Collins","year":"2016","unstructured":"Collins LR, Rajabi NA, Macgregor SA, Mahon MF, Whittlesey MK (2016) Experimental and computational studies of the copper borate complexes [(NHC)Cu(HBEt3)] and [(NHC)Cu(HB(C6F5)3)]. Angew Chem Int Ed 55(50):15539\u201315543","journal-title":"Angew Chem Int Ed"},{"issue":"20","key":"304_CR147","doi-asserted-by":"crossref","first-page":"6008","DOI":"10.1002\/anie.201500224","volume":"54","author":"X Hu","year":"2015","unstructured":"Hu X, Soleilhavoup M, Melaimi M, Chu J, Bertrand G (2015) Air-stable (CAAC)CuCl and (CAAC)CuBH4 complexes as catalysts for the hydrolytic dehydrogenation of BH3NH3. Angew Chem Int Ed 54(20):6008\u20136011","journal-title":"Angew Chem Int Ed"},{"issue":"49","key":"304_CR148","doi-asserted-by":"crossref","first-page":"19680","DOI":"10.1021\/ja209187a","volume":"133","author":"A Albright","year":"2011","unstructured":"Albright A, Gawley RE (2011) Application of a C2-symmetric copper carbenoid in the enantioselective hydrosilylation of dialkyl and aryl-alkyl ketones. J Am Chem Soc 133(49):19680\u201319683","journal-title":"J Am Chem Soc"},{"issue":"19","key":"304_CR149","doi-asserted-by":"crossref","first-page":"3844","DOI":"10.1039\/C5CC09162D","volume":"52","author":"S Bagherzadeh","year":"2016","unstructured":"Bagherzadeh S, Mankad NP (2016) Extremely efficient hydroboration of ketones and aldehydes by copper carbene catalysis. Chem Commun 52(19):3844\u20133846","journal-title":"Chem Commun"},{"issue":"42","key":"304_CR150","doi-asserted-by":"crossref","first-page":"4782","DOI":"10.1039\/c3cc41838c","volume":"49","author":"L Zhang","year":"2013","unstructured":"Zhang L, Cheng J, Hou Z (2013) Highly efficient catalytic hydrosilylation of carbon dioxide by an N-heterocyclic carbene copper catalyst. Chem Commun 49(42):4782","journal-title":"Chem Commun"},{"issue":"35","key":"304_CR151","doi-asserted-by":"crossref","first-page":"14314","DOI":"10.1021\/ja3063474","volume":"134","author":"L Zhang","year":"2012","unstructured":"Zhang L, Cheng J, Carry B, Hou Z (2012) Catalytic boracarboxylation of alkynes with diborane and carbon dioxide by an N-heterocyclic carbene copper catalyst. J Am Chem Soc 134(35):14314\u201314317","journal-title":"J Am Chem Soc"},{"issue":"35","key":"304_CR152","doi-asserted-by":"crossref","first-page":"8114","DOI":"10.1002\/anie.201101769","volume":"50","author":"T Ohishi","year":"2011","unstructured":"Ohishi T, Zhang L, Nishiura M, Hou Z (2011) Carboxylation of alkylboranes by N-heterocyclic carbene copper catalysts: synthesis of carboxylic acids from terminal alkenes and carbon dioxide. Angew Chem Int Ed 50(35):8114\u20138117","journal-title":"Angew Chem Int Ed"},{"issue":"18","key":"304_CR153","doi-asserted-by":"crossref","first-page":"5224","DOI":"10.1021\/om4008532","volume":"32","author":"T Fan","year":"2013","unstructured":"Fan T, Sheong FK, Lin Z (2013) DFT studies on copper-catalyzed hydrocarboxylation of alkynes using CO2 and hydrosilanes. Organometallics 32(18):5224\u20135230","journal-title":"Organometallics"},{"key":"304_CR154","doi-asserted-by":"crossref","first-page":"21","DOI":"10.1016\/j.jorganchem.2019.04.003","volume":"893","author":"M Elie","year":"2019","unstructured":"Elie M, Mahoro GU, Duverger E, Renaud J-L, Daniellou R, Gaillard S (2019) Cytotoxicity of cationic NHC copper(I) complexes coordinated to 2,2'-bis-pyridyl ligands. J Organomet Chem 893:21\u201331","journal-title":"J Organomet Chem"},{"issue":"8","key":"304_CR155","doi-asserted-by":"crossref","first-page":"2459","DOI":"10.1021\/om400175h","volume":"32","author":"R Shintani","year":"2013","unstructured":"Shintani R, Nozaki K (2013) Copper-catalyzed hydroboration of carbon dioxide. Organometallics 32(8):2459\u20132462","journal-title":"Organometallics"},{"issue":"3","key":"304_CR156","doi-asserted-by":"crossref","first-page":"752","DOI":"10.1002\/anie.201307697","volume":"53","author":"H Dang","year":"2014","unstructured":"Dang H, Cox N, Lalic G (2014) Copper-catalyzed reduction of alkyl triflates and iodides: an efficient method for the deoxygenation of primary and secondary alcohols. Angew Chem Int Ed 53(3):752\u2013756","journal-title":"Angew Chem Int Ed"},{"issue":"8","key":"304_CR157","doi-asserted-by":"crossref","first-page":"1542","DOI":"10.1002\/adsc.201200200","volume":"354","author":"K Semba","year":"2012","unstructured":"Semba K, Fujihara T, Xu T, Terao J, Tsuji Y (2012) Copper-catalyzed highly selective semihydrogenation of non-polar carbon\u2013carbon multiple bonds using a silane and an alcohol. Adv Synth Catal 354(8):1542\u20131550","journal-title":"Adv Synth Catal"},{"key":"304_CR158","doi-asserted-by":"crossref","first-page":"173","DOI":"10.1016\/j.ica.2018.09.042","volume":"485","author":"M Khajehzadeh","year":"2019","unstructured":"Khajehzadeh M, Moghadam M, Jamehbozorgi S (2019) Synthesis and characterization of a new poly(N-heterocyclic carbene Cu complex) immobilized on nano-silica, (CuII\u2013NHCs)n@nSiO2, and its application as an efficient and reusable catalyst in the synthesis of benzimidazoles, benzothiazoles, 1,2,3\u2013triazoles, bis-triazoles and Sonogashira-Hagihara reactions. Inorg Chim Acta 485:173\u2013189","journal-title":"Inorg Chim Acta"},{"issue":"11","key":"304_CR159","doi-asserted-by":"crossref","first-page":"1923","DOI":"10.1021\/acs.organomet.6b00246","volume":"35","author":"X Deng","year":"2016","unstructured":"Deng X, Dang Y, Wang Z-X, Wang X (2016) How Does an earth-abundant copper-based catalyst achieve anti-Markovnikov hydrobromination of alkynes? A DFT mechanistic study. Organometallics 35(11):1923\u20131930","journal-title":"Organometallics"},{"key":"304_CR160","doi-asserted-by":"crossref","first-page":"166","DOI":"10.1016\/j.jorganchem.2013.07.065","volume":"745\u2013746","author":"Y Zhao","year":"2013","unstructured":"Zhao Y, Liu Y, Bi S, Liu Y (2013) Theoretical study on copper-catalyzed reaction of hydrosilane, alkyne and carbon dioxide: a hydrocarboxylation or a hydrosilylation process? J Organomet Chem 745\u2013746:166\u2013172","journal-title":"J Organomet Chem"},{"issue":"36","key":"304_CR161","doi-asserted-by":"crossref","first-page":"4036","DOI":"10.1016\/j.tetlet.2016.07.056","volume":"57","author":"L Zhan","year":"2016","unstructured":"Zhan L, Pan R, Xing P, Jiang B (2016) An efficient method for the preparation of dialkoxymethanes from dichloromethane with alcohols catalyzed by a Cu-NHC complex. Tetrahedron Lett 57(36):4036\u20134038","journal-title":"Tetrahedron Lett"},{"key":"304_CR162","doi-asserted-by":"crossref","first-page":"114123","DOI":"10.1016\/j.poly.2019.114123","volume":"173","author":"B Santra","year":"2019","unstructured":"Santra B (2019) Trinuclear Cu(I)\u2013NHC as NHC transfer agent: synthesis of mono- and di-nuclear palladium and mercury complexes. Polyhedron 173:114123","journal-title":"Polyhedron"},{"issue":"45","key":"304_CR163","doi-asserted-by":"crossref","first-page":"15934","DOI":"10.1002\/chem.201501739","volume":"21","author":"F Pape","year":"2015","unstructured":"Pape F, Thiel NO, Teichert JF (2015) Z-selective copper(I)-catalyzed alkyne semihydrogenation with tethered Cu-alkoxide complexes. Chem Eur J 21(45):15934\u201315938","journal-title":"Chem Eur J"},{"issue":"10","key":"304_CR164","doi-asserted-by":"crossref","first-page":"1354","DOI":"10.1021\/acs.organomet.6b00126","volume":"35","author":"T Wakamatsu","year":"2016","unstructured":"Wakamatsu T, Nagao K, Ohmiya H, Sawamura M (2016) Copper-catalyzed semihydrogenation of internal alkynes with molecular hydrogen. Organometallics 35(10):1354\u20131357","journal-title":"Organometallics"},{"issue":"6","key":"304_CR165","doi-asserted-by":"crossref","first-page":"1390","DOI":"10.1021\/acs.orglett.6b00325","volume":"18","author":"WJ Jang","year":"2016","unstructured":"Jang WJ, Lee WL, Moon JH, Lee JY, Yun J (2016) Copper-catalyzed trans-hydroboration of terminal aryl alkynes: stereodivergent synthesis of alkenylboron compounds. Org Lett 18(6):1390\u20131393","journal-title":"Org Lett"},{"issue":"15","key":"304_CR166","doi-asserted-by":"crossref","first-page":"2183","DOI":"10.1016\/j.tet.2015.02.027","volume":"71","author":"K Semba","year":"2015","unstructured":"Semba K, Fujihara T, Terao J, Tsuji Y (2015) Copper-catalyzed borylative transformations of non-polar carbon\u2013carbon unsaturated compounds employing borylcopper as an active catalyst species. Tetrahedron 71(15):2183\u20132197","journal-title":"Tetrahedron"},{"issue":"9","key":"304_CR167","doi-asserted-by":"crossref","first-page":"3395","DOI":"10.1039\/c3sc51070k","volume":"4","author":"L Zhang","year":"2013","unstructured":"Zhang L, Hou Z (2013) N-Heterocyclic carbene (NHC)\u2013copper-catalysed transformations of carbon dioxide. Chem Sci 4(9):3395","journal-title":"Chem Sci"},{"issue":"16","key":"304_CR168","doi-asserted-by":"crossref","first-page":"9091","DOI":"10.1021\/acs.chemrev.6b00193","volume":"116","author":"EC Neeve","year":"2016","unstructured":"Neeve EC, Geier SJ, Mkhalid IAI, Westcott SA, Marder TB (2016) Diboron(4) compounds: from structural curiosity to synthetic workhorse. Chem Rev 116(16):9091\u20139161","journal-title":"Chem Rev"},{"issue":"10","key":"304_CR169","doi-asserted-by":"crossref","first-page":"2405","DOI":"10.1021\/om060131u","volume":"25","author":"DS Laitar","year":"2006","unstructured":"Laitar DS, Tsui EY, Sadighi JP (2006) Copper(I) \u03b2-boroalkyls from alkene insertion: isolation and rearrangement. Organometallics 25(10):2405\u20132408","journal-title":"Organometallics"},{"issue":"11","key":"304_CR170","doi-asserted-by":"crossref","first-page":"2824","DOI":"10.1021\/om070103r","volume":"26","author":"L Dang","year":"2007","unstructured":"Dang L, Zhao H, Lin Z, Marder TB (2007) DFT studies of alkene insertions into Cu\u2212B bonds in copper(I) boryl complexes. Organometallics 26(11):2824\u20132832","journal-title":"Organometallics"},{"issue":"16","key":"304_CR171","doi-asserted-by":"crossref","first-page":"5586","DOI":"10.1021\/ja710659y","volume":"130","author":"H Zhao","year":"2008","unstructured":"Zhao H, Dang L, Marder TB, Lin Z (2008) DFT Studies on the mechanism of the diboration of aldehydes catalyzed by copper(I) boryl complexes. J Am Chem Soc 130(16):5586\u20135594","journal-title":"J Am Chem Soc"},{"issue":"9","key":"304_CR172","doi-asserted-by":"crossref","first-page":"3160","DOI":"10.1021\/ja809382c","volume":"131","author":"Y Lee","year":"2009","unstructured":"Lee Y, Hoveyda AH (2009) Efficient boron\u2212copper additions to aryl-substituted alkenes promoted by NHC\u2212based catalysts. Enantioselective Cu-catalyzed hydroboration reactions. J Am Chem Soc 131(9):3160\u20133161","journal-title":"J Am Chem Soc"},{"issue":"20","key":"304_CR173","doi-asserted-by":"crossref","first-page":"7859","DOI":"10.1021\/ja2007643","volume":"133","author":"H Jang","year":"2011","unstructured":"Jang H, Zhugralin AR, Lee Y, Hoveyda AH (2011) Highly selective methods for synthesis of internal (\u03b1-) vinylboronates through efficient NHC\u2013Cu-catalyzed hydroboration of terminal alkynes. Utility in chemical synthesis and mechanistic basis for selectivity. J Am Chem Soc 133(20):7859\u20137871","journal-title":"J Am Chem Soc"},{"issue":"61","key":"304_CR174","doi-asserted-by":"crossref","first-page":"8299","DOI":"10.1039\/C4CC01757A","volume":"50","author":"H Yoshida","year":"2014","unstructured":"Yoshida H, Takemoto Y, Takaki K (2014) A masked diboron in Cu-catalysed borylation reaction: highly regioselective formal hydroboration of alkynes for synthesis of branched alkenylborons. Chem Commun 50(61):8299\u20138302","journal-title":"Chem Commun"},{"issue":"9","key":"304_CR175","doi-asserted-by":"crossref","first-page":"2614","DOI":"10.1002\/chem.200601146","volume":"13","author":"V Lillo","year":"2007","unstructured":"Lillo V, Fructos MR, Ram\u00edrez J, Braga AAC, Maseras F, D\u00edaz-Requejo MM, P\u00e9rez PJ, Fern\u00e1ndez E, Valuable A (2007) Inexpensive CuI\/N-heterocyclic carbene catalyst for the selective diboration of styrene. Chem Eur J 13(9):2614\u20132621","journal-title":"Chem Eur J"},{"issue":"6","key":"304_CR176","doi-asserted-by":"crossref","first-page":"1178","DOI":"10.1021\/om700999w","volume":"27","author":"L Dang","year":"2008","unstructured":"Dang L, Zhao H, Lin Z, Marder TB (2008) Understanding the higher reactivity of B2cat2versus B2pin2in copper(I)-catalyzed alkene diboration reactions. Organometallics 27(6):1178\u20131186","journal-title":"Organometallics"},{"issue":"4","key":"304_CR177","doi-asserted-by":"crossref","first-page":"952","DOI":"10.1021\/ol4001526","volume":"15","author":"H Yoshida","year":"2013","unstructured":"Yoshida H, Kageyuki I, Takaki K (2013) Copper-catalyzed three-component carboboration of alkynes and alkenes. Org Lett 15(4):952\u2013955","journal-title":"Org Lett"},{"issue":"13","key":"304_CR178","doi-asserted-by":"crossref","first-page":"3543","DOI":"10.1002\/ange.201310275","volume":"126","author":"Y Zhou","year":"2014","unstructured":"Zhou Y, You W, Smith KB, Brown MK (2014) Copper-catalyzed cross-coupling of boronic esters with aryl iodides and application to the carboboration of alkynes and allenes. Angew Chem 126(13):3543\u20133547","journal-title":"Angew Chem"},{"issue":"21","key":"304_CR179","doi-asserted-by":"crossref","first-page":"7567","DOI":"10.1021\/ja5029556","volume":"136","author":"K Semba","year":"2014","unstructured":"Semba K, Nakao Y (2014) Arylboration of alkenes by cooperative palladium\/copper catalysis. J Am Chem Soc 136(21):7567\u20137570","journal-title":"J Am Chem Soc"},{"issue":"41","key":"304_CR180","doi-asserted-by":"crossref","first-page":"1903470","DOI":"10.1002\/adma.201903470","volume":"31","author":"L Lin","year":"2019","unstructured":"Lin L, Li H, Yan C, Li H, Si R, Li M, Xiao J, Wang G, Bao X (2019) Synergistic catalysis over iron-nitrogen sites anchored with cobalt phthalocyanine for efficient CO2 electroreduction. Adv Mater 31(41):1903470","journal-title":"Adv Mater"},{"issue":"17","key":"304_CR181","doi-asserted-by":"crossref","first-page":"5228","DOI":"10.1002\/anie.201500396","volume":"54","author":"KM Logan","year":"2015","unstructured":"Logan KM, Smith KB, Brown MK (2015) Copper\/palladium synergistic catalysis for the syn-and anti-selective carboboration of alkenes. Angew Chem Int Ed 54(17):5228\u20135231","journal-title":"Angew Chem Int Ed"},{"issue":"1","key":"304_CR182","doi-asserted-by":"crossref","first-page":"146","DOI":"10.1021\/acscatal.6b02594","volume":"7","author":"TJ Mazzacano","year":"2016","unstructured":"Mazzacano TJ, Mankad NP (2016) Dehydrogenative borylation and silylation of styrenes catalyzed by copper-carbenes. ACS Catalysis 7(1):146\u2013149","journal-title":"ACS Catalysis"},{"issue":"4","key":"304_CR183","doi-asserted-by":"crossref","first-page":"917","DOI":"10.1021\/om901047e","volume":"29","author":"L Dang","year":"2010","unstructured":"Dang L, Lin Z, Marder TB (2010) DFT studies on the carboxylation of arylboronate esters with CO2 catalyzed by copper(I) complexes. Organometallics 29(4):917\u2013927","journal-title":"Organometallics"},{"issue":"22","key":"304_CR184","doi-asserted-by":"crossref","first-page":"6218","DOI":"10.1021\/om200744a","volume":"30","author":"A Ariafard","year":"2011","unstructured":"Ariafard A, Zarkoob F, Batebi H, Stranger R, Yates BF (2011) DFT studies on the carboxylation of the C\u2013H bond of heteroarenes by copper(I) complexes. Organometallics 30(22):6218\u20136224","journal-title":"Organometallics"},{"issue":"46","key":"304_CR185","doi-asserted-by":"crossref","first-page":"8674","DOI":"10.1002\/anie.201004153","volume":"49","author":"IIF Boogaerts","year":"2010","unstructured":"Boogaerts IIF, Fortman GC, Furst MRL, Cazin CSJ, Nolan SP (2010) Carboxylation of N\u2013H\/C\u2013H bonds using N-heterocyclic carbene copper(I) complexes. Angew Chem Int Ed 49(46):8674\u20138677","journal-title":"Angew Chem Int Ed"},{"key":"304_CR186","doi-asserted-by":"crossref","first-page":"69","DOI":"10.1016\/j.ccr.2015.01.010","volume":"288","author":"A Pinaka","year":"2015","unstructured":"Pinaka A, Vougioukalakis GC (2015) Using sustainable metals to carry out \u201cgreen\u201d transformations: Fe- and Cu-catalyzed CO2 monetization. Coord Chem Rev 288:69\u201397","journal-title":"Coord Chem Rev"},{"issue":"15","key":"304_CR187","doi-asserted-by":"crossref","first-page":"3666","DOI":"10.1039\/C6OB00199H","volume":"14","author":"S Wang","year":"2016","unstructured":"Wang S, Du G, Xi C (2016) Copper-catalyzed carboxylation reactions using carbon dioxide. Org Biomol Chem 14(15):3666\u20133676","journal-title":"Org Biomol Chem"},{"issue":"49","key":"304_CR188","doi-asserted-by":"crossref","first-page":"15637","DOI":"10.1021\/ja063671r","volume":"128","author":"H Zhao","year":"2006","unstructured":"Zhao H, Lin Z, Marder TB (2006) Density functional theory studies on the mechanism of the reduction of CO2 to CO catalyzed by copper(I) boryl complexes. J Am Chem Soc 128(49):15637\u201315643","journal-title":"J Am Chem Soc"},{"issue":"34","key":"304_CR189","doi-asserted-by":"crossref","first-page":"10898","DOI":"10.1021\/jacs.5b05692","volume":"137","author":"S Bagherzadeh","year":"2015","unstructured":"Bagherzadeh S, Mankad NP (2015) Catalyst control of selectivity in CO2 reduction using a tunable heterobimetallic effect. J Am Chem Soc 137(34):10898\u201310901","journal-title":"J Am Chem Soc"},{"issue":"3","key":"304_CR190","doi-asserted-by":"crossref","first-page":"1584","DOI":"10.1021\/ic302455y","volume":"52","author":"C Dash","year":"2013","unstructured":"Dash C, Das A, Yousufuddin M, Dias HVR (2013) Isolable, copper(I) dicarbonyl complexes supported by N-heterocyclic carbenes. Inorg Chem 52(3):1584\u20131590","journal-title":"Inorg Chem"},{"issue":"22","key":"304_CR191","doi-asserted-by":"crossref","first-page":"7969","DOI":"10.1021\/om3006195","volume":"31","author":"F Lazreg","year":"2012","unstructured":"Lazreg F, Slawin AMZ, Cazin CSJ (2012) Heteroleptic bis(N-heterocyclic carbene)copper(I) complexes: highly efficient systems for the [3+2] cycloaddition of azides and alkynes. Organometallics 31(22):7969\u20137975","journal-title":"Organometallics"},{"issue":"23","key":"304_CR192","doi-asserted-by":"crossref","first-page":"7225","DOI":"10.1021\/om400911u","volume":"32","author":"S Guo","year":"2013","unstructured":"Guo S, Lim MH, Huynh HV (2013) Copper(I) heteroleptic bis(NHC) and mixed NHC\/phosphine complexes: syntheses and catalytic activities in the one-pot sequential CuAAC reaction of aromatic amines. Organometallics 32(23):7225\u20137233","journal-title":"Organometallics"},{"issue":"34","key":"304_CR193","doi-asserted-by":"crossref","first-page":"11933","DOI":"10.1021\/jacs.7b05834","volume":"139","author":"FS Geitner","year":"2017","unstructured":"Geitner FS, Dums JV, F\u00e4ssler TF (2017) Derivatization of phosphine ligands with bulky deltahedral zintl clusters\u2014synthesis of charge neutral zwitterionic tetrel cluster compounds [(Ge9{Si(TMS)3}2)tBu2P]M(NHCDipp) (M: Cu, Ag, Au). J Am Chem Soc 139(34):11933\u201311940","journal-title":"J Am Chem Soc"},{"key":"304_CR194","doi-asserted-by":"crossref","first-page":"116","DOI":"10.1016\/j.ccr.2017.07.018","volume":"355","author":"R Peloso","year":"2018","unstructured":"Peloso R, Carmona E (2018) Non-heteroatom-substituted alkylidene complexes of groups 10 and 11. Coord Chem Rev 355:116\u2013132","journal-title":"Coord Chem Rev"},{"issue":"35","key":"304_CR195","doi-asserted-by":"crossref","first-page":"10331","DOI":"10.1002\/anie.201504117","volume":"54","author":"MW Hussong","year":"2015","unstructured":"Hussong MW, Hoffmeister WT, Rominger F, Straub BF (2015) Copper and silver carbene complexes without heteroatom-stabilization: structure, spectroscopy, and relativistic effects. Angew Chem Int Ed 54(35):10331\u201310335","journal-title":"Angew Chem Int Ed"},{"key":"304_CR196","doi-asserted-by":"crossref","first-page":"46","DOI":"10.1016\/j.jcat.2018.03.015","volume":"362","author":"I Misztalewska-Turkowicz","year":"2018","unstructured":"Misztalewska-Turkowicz I, Markiewicz KH, Michalak M, Wilczewska AZ (2018) NHC-copper complexes immobilized on magnetic nanoparticles: synthesis and catalytic activity in the CuAAC reactions. J Catal 362:46\u201354","journal-title":"J Catal"},{"key":"304_CR197","doi-asserted-by":"crossref","first-page":"1","DOI":"10.1038\/s41467-016-0009-6","volume":"8","author":"J Wang","year":"2017","unstructured":"Wang J, Cao X, Lv S, Zhang C, Xu S, Shi M, Zhang J (2017) Synthesis and structures of gold and copper carbene intermediates in catalytic amination of alkynes. Nat Commun 8:1","journal-title":"Nat Commun"},{"issue":"9","key":"304_CR198","doi-asserted-by":"crossref","first-page":"2355","DOI":"10.1021\/om0600487","volume":"25","author":"S D\u00edez-Gonz\u00e1lez","year":"2006","unstructured":"D\u00edez-Gonz\u00e1lez S, Scott NM, Nolan SP (2006) Cationic copper(I) complexes as efficient precatalysts for the hydrosilylation of carbonyl compounds. Organometallics 25(9):2355\u20132358","journal-title":"Organometallics"},{"issue":"6","key":"304_CR199","doi-asserted-by":"crossref","first-page":"1537","DOI":"10.1021\/om301091p","volume":"32","author":"S Budagumpi","year":"2013","unstructured":"Budagumpi S, Endud S (2013) Group XII metal\u2013N-heterocyclic carbene complexes: synthesis, structural diversity, intramolecular interactions, and applications. Organometallics 32(6):1537\u20131562","journal-title":"Organometallics"},{"issue":"22\u201323","key":"304_CR200","doi-asserted-by":"crossref","first-page":"3956","DOI":"10.1002\/ejic.201300150","volume":"2013","author":"S Hohloch","year":"2013","unstructured":"Hohloch S, Scheiffele D, Sarkar B (2013) Activating azides and alkynes for the click reaction with [Cu(aNHC)2I] or [Cu(aNHC)2]+(aNHC = triazole-derived abnormal carbenes): structural characterization and catalytic properties. Eur J Inorg Chem 2013(22\u201323):3956\u20133965","journal-title":"Eur J Inorg Chem"},{"issue":"51","key":"304_CR201","doi-asserted-by":"crossref","first-page":"12145","DOI":"10.1016\/j.tet.2005.07.116","volume":"61","author":"B Bantu","year":"2005","unstructured":"Bantu B, Wang D, Wurst K, Buchmeiser MR (2005) Copper (I) 1,3-R2-3,4,5,6-tetrahydropyrimidin-2-ylidenes (R=mesityl, 2-propyl): synthesis, X-ray structures, immobilization and catalytic activity. Tetrahedron 61(51):12145\u201312152","journal-title":"Tetrahedron"},{"issue":"17","key":"304_CR202","doi-asserted-by":"crossref","first-page":"6235","DOI":"10.1021\/ja502521b","volume":"136","author":"DS Weinberger","year":"2014","unstructured":"Weinberger DS, Amin NSK, Mondal KC, Melaimi M, Bertrand G, St\u00fcckl AC, Roesky HW, Dittrich B, Demeshko S, Schwederski B, Kaim W, Jerabek P, Frenking G (2014) Isolation of neutral mononuclear copper complexes stabilized by two cyclic (alkyl)(amino)carbenes. J Am Chem Soc 136(17):6235\u20136238","journal-title":"J Am Chem Soc"},{"issue":"49","key":"304_CR203","doi-asserted-by":"crossref","first-page":"17123","DOI":"10.1021\/ja508887s","volume":"136","author":"P Jerabek","year":"2014","unstructured":"Jerabek P, Roesky HW, Bertrand G, Frenking G (2014) Coinage metals binding as main group elements: structure and bonding of the carbene complexes [TM(cAAC)2] and [TM(cAAC)2]+(TM = Cu, Ag, Au). J Am Chem Soc 136(49):17123\u201317135","journal-title":"J Am Chem Soc"},{"issue":"13","key":"304_CR204","doi-asserted-by":"crossref","first-page":"3442","DOI":"10.1021\/acs.organomet.5b00429","volume":"34","author":"CR Landis","year":"2015","unstructured":"Landis CR, Hughes RP, Weinhold F (2015) Bonding analysis of TM(cAAC)2 (TM = Cu, Ag, and Au) and the importance of reference state. Organometallics 34(13):3442\u20133449","journal-title":"Organometallics"},{"issue":"2","key":"304_CR205","doi-asserted-by":"crossref","first-page":"419","DOI":"10.1021\/om500882t","volume":"34","author":"F Lazreg","year":"2015","unstructured":"Lazreg F, Cordes DB, Slawin AMZ, Cazin CSJ (2015) Synthesis of homoleptic and heteroleptic bis-N-heterocylic carbene group 11 complexes. Organometallics 34(2):419\u2013425","journal-title":"Organometallics"},{"issue":"20","key":"304_CR206","doi-asserted-by":"crossref","first-page":"7373","DOI":"10.1039\/c3dt32919d","volume":"42","author":"V C\u00e9sar","year":"2013","unstructured":"C\u00e9sar V, Barthes C, Farr\u00e9 YC, Cuisiat SV, Vacher BY, Brousses R, Lugan N, Lavigne G (2013) Anionic and zwitterionic copper(i) complexes incorporating an anionic N-heterocyclic carbene decorated with a malonate backbone: synthesis, structure and catalytic applications. Dalton Trans 42(20):7373","journal-title":"Dalton Trans"},{"issue":"36","key":"304_CR207","doi-asserted-by":"crossref","first-page":"6696","DOI":"10.1039\/c0cc01864c","volume":"46","author":"VA Krylova","year":"2010","unstructured":"Krylova VA, Djurovich PI, Whited MT, Thompson ME (2010) Synthesis and characterization of phosphorescent three-coordinate Cu(i)\u2013NHC complexes. Chem Commun 46(36):6696","journal-title":"Chem Commun"},{"issue":"17","key":"304_CR208","doi-asserted-by":"crossref","first-page":"9181","DOI":"10.1021\/ic501230m","volume":"53","author":"R Marion","year":"2014","unstructured":"Marion R, Sguerra F, Di Meo F, Sauvageot E, Lohier J-F, Daniellou R, Renaud J-L, Linares M, Hamel M, Gaillard S (2014) NHC copper(I) complexes bearing dipyridylamine ligands: synthesis, structural, and photoluminescent studies. Inorgan Chem 53(17):9181\u20139191","journal-title":"Inorgan Chem"},{"key":"304_CR209","doi-asserted-by":"crossref","first-page":"12","DOI":"10.1016\/j.molstruc.2017.09.119","volume":"1153","author":"S Xu","year":"2018","unstructured":"Xu S, Wang J, Liu S, Zhao F, Xia H, Wang Y (2018) Synthesis, photophysical properties, and computational studies of four-coordinate copper(I) complexes based on benzimidazolylidene N-heterocyclic carbene (NHC) ligands bearing aryl substituents. J Mol Struct 1153:12\u201319","journal-title":"J Mol Struct"},{"issue":"23","key":"304_CR210","doi-asserted-by":"crossref","first-page":"14678","DOI":"10.1021\/acsami.6b04647","volume":"8","author":"M Elie","year":"2016","unstructured":"Elie M, Sguerra F, Di Meo F, Weber MD, Marion R, Grimault A, Lohier J-F, Stallivieri A, Brosseau A, Pansu RB, Renaud J-L, Linares M, Hamel M, Costa RD, Gaillard S (2016) Designing NHC\u2013copper(I) dipyridylamine complexes for blue light-emitting electrochemical cells. ACS Appl Mater Interfaces 8(23):14678\u201314691","journal-title":"ACS Appl Mater Interfaces"},{"issue":"9","key":"304_CR211","doi-asserted-by":"crossref","first-page":"2206","DOI":"10.1002\/chem.201605412","volume":"23","author":"M Gernert","year":"2017","unstructured":"Gernert M, M\u00fcller U, Haehnel M, Pflaum J, Steffen A (2017) A cyclic alkyl(amino)carbene as two-atom \u03c0-chromophore leading to the first phosphorescent linear cui complexes. Chem Eur J 23(9):2206\u20132216","journal-title":"Chem Eur J"},{"issue":"4","key":"304_CR212","doi-asserted-by":"crossref","first-page":"517","DOI":"10.1021\/acs.organomet.7b00838","volume":"37","author":"F Medici","year":"2018","unstructured":"Medici F, Gontard G, Derat E, Lemi\u00e8re G, Fensterbank L (2018) Synthesis of stable pentacoordinate silicon(IV)\u2013NHC adducts: an entry to anionic N-heterocyclic carbene ligands. Organometallics 37(4):517\u2013520","journal-title":"Organometallics"},{"issue":"26","key":"304_CR213","doi-asserted-by":"crossref","first-page":"7008","DOI":"10.1039\/c1dt10377f","volume":"40","author":"\u00d6 \u00d6ztopcu","year":"2011","unstructured":"\u00d6ztopcu \u00d6, Mereiter K, Puchberger M, Kirchner KA (2011) Tri- and tetracoordinate copper(i) complexes bearing bidentate soft\/hard SN and SeN ligands based on 2-aminopyridine. Dalton Trans 40(26):7008","journal-title":"Dalton Trans"},{"issue":"22","key":"304_CR214","doi-asserted-by":"crossref","first-page":"7983","DOI":"10.1021\/om300656v","volume":"31","author":"VA Krylova","year":"2012","unstructured":"Krylova VA, Djurovich PI, Aronson JW, Haiges R, Whited MT, Thompson ME (2012) Structural and photophysical studies of phosphorescent three-coordinate copper(I) complexes supported by an N-heterocyclic carbene ligand. Organometallics 31(22):7983\u20137993","journal-title":"Organometallics"},{"issue":"54","key":"304_CR215","doi-asserted-by":"crossref","first-page":"7176","DOI":"10.1039\/C4CC02037E","volume":"50","author":"VA Krylova","year":"2014","unstructured":"Krylova VA, Djurovich PI, Conley BL, Haiges R, Whited MT, Williams TJ, Thompson ME (2014) Control of emission colour with N-heterocyclic carbene (NHC) ligands in phosphorescent three-coordinate Cu(i) complexes. Chem Commun 50(54):7176\u20137179","journal-title":"Chem Commun"},{"issue":"5","key":"304_CR216","doi-asserted-by":"crossref","first-page":"629","DOI":"10.1021\/acs.organomet.5b00904","volume":"35","author":"R Molteni","year":"2016","unstructured":"Molteni R, Edkins K, Haehnel M, Steffen A (2016) C\u2013H activation of fluoroarenes: synthesis, structure, and luminescence properties of copper(I) and gold(I) complexes bearing 2-phenylpyridine ligands. Organometallics 35(5):629\u2013640","journal-title":"Organometallics"},{"issue":"25","key":"304_CR217","doi-asserted-by":"crossref","first-page":"5271","DOI":"10.1039\/C4CC08641D","volume":"51","author":"V C\u00e9sar","year":"2015","unstructured":"C\u00e9sar V, Mallardo V, Nano A, Dahm G, Lugan N, Lavigne G, Bellemin-Laponnaz S (2015) IMes-acac: hybrid combination of diaminocarbene and acetylacetonato sub-units into a new anionic ambidentate NHC ligand. Chem Commun 51(25):5271\u20135274","journal-title":"Chem Commun"},{"issue":"64","key":"304_CR218","doi-asserted-by":"crossref","first-page":"9008","DOI":"10.1039\/C7CC02638B","volume":"53","author":"R Hamze","year":"2017","unstructured":"Hamze R, Jazzar R, Soleilhavoup M, Djurovich PI, Bertrand G, Thompson ME (2017) Phosphorescent 2-, 3- and 4-coordinate cyclic (alkyl)(amino)carbene (CAAC) Cu(i) complexes. Chem Commun 53(64):9008\u20139011","journal-title":"Chem Commun"},{"key":"304_CR219","doi-asserted-by":"crossref","first-page":"5181","DOI":"10.1039\/b509964a","volume":"41","author":"J Yun","year":"2005","unstructured":"Yun J, Kim D, Yun H (2005) A new alternative to Stryker's reagent in hydrosilylation: synthesis, structure, and reactivity of a well-defined carbene\u2013copper(ii) acetate complex. Chem Commun 41:5181","journal-title":"Chem Commun"},{"issue":"12","key":"304_CR220","doi-asserted-by":"crossref","first-page":"3074","DOI":"10.1039\/c0dt01630f","volume":"40","author":"EL Kolychev","year":"2011","unstructured":"Kolychev EL, Shuntikov VV, Khrustalev VN, Bush AA, Nechaev MS (2011) Dual reactivity of N-heterocyclic carbenes towards copper(ii) salts. Dalton Trans 40(12):3074","journal-title":"Dalton Trans"},{"issue":"49","key":"304_CR221","doi-asserted-by":"crossref","first-page":"16780","DOI":"10.1002\/chem.201301896","volume":"19","author":"BRM Lake","year":"2013","unstructured":"Lake BRM, Willans CE (2013) Structural diversity of copper(I)\u2013N-heterocyclic carbene complexes; ligand tuning facilitates isolation of the first structurally characterised copper(I)\u2013NHC containing a copper(I)\u2013alkene interaction. Chem Eur J 19(49):16780\u201316790","journal-title":"Chem Eur J"},{"issue":"14","key":"304_CR222","doi-asserted-by":"crossref","first-page":"3361","DOI":"10.1039\/c002234a","volume":"39","author":"AC Badaj","year":"2010","unstructured":"Badaj AC, Dastgir S, Lough AJ, Lavoie GG (2010) First aryl-substituted acyclic imino-N-heterocyclic carbene ligand precursor: synthesis, characterisation and coordination with silver(i) and copper(i). Dalton Trans 39(14):3361","journal-title":"Dalton Trans"},{"issue":"6","key":"304_CR223","doi-asserted-by":"crossref","first-page":"1034","DOI":"10.1002\/hlca.200800406","volume":"92","author":"G Venkatachalam","year":"2009","unstructured":"Venkatachalam G, Heckenroth M, Neels A, Albrecht M (2009) Synthesis, structural diversity, and ligand-transfer potential of (carbene)copper(I) complexes. Helv Chim Acta 92(6):1034\u20131045","journal-title":"Helv Chim Acta"},{"key":"304_CR224","doi-asserted-by":"crossref","first-page":"112","DOI":"10.1016\/j.jorganchem.2016.03.023","volume":"821","author":"C Thie","year":"2016","unstructured":"Thie C, Hitzel S, Wallbaum L, Bruhn C, Siemeling U (2016) Coinage metal complexes of the carbenic tautomer of nitron. J Organomet Chem 821:112\u2013121","journal-title":"J Organomet Chem"},{"issue":"26","key":"304_CR225","doi-asserted-by":"crossref","first-page":"6322","DOI":"10.1002\/chem.200900727","volume":"15","author":"M-L Teyssot","year":"2009","unstructured":"Teyssot M-L, Chevry A, Tra\u00efkia M, El-Ghozzi M, Avignant D, Gautier A (2009) Improved copper(I)-NHC catalytic efficiency on Huisgen reaction by addition of aromatic nitrogen donors. Chem Eur J 15(26):6322\u20136326","journal-title":"Chem Eur J"},{"issue":"19","key":"304_CR226","doi-asserted-by":"crossref","first-page":"4109","DOI":"10.1016\/j.jorganchem.2006.06.017","volume":"691","author":"H Ren","year":"2006","unstructured":"Ren H, Zhao X, Xu S, Song H, Wang B (2006) Synthesis and structures of cyclopentadienyl N-heterocyclic carbene copper(I) complexes. J Organomet Chem 691(19):4109\u20134113","journal-title":"J Organomet Chem"},{"issue":"12","key":"304_CR227","doi-asserted-by":"crossref","first-page":"2819","DOI":"10.1021\/acs.organomet.5b00103","volume":"34","author":"I Klawitter","year":"2015","unstructured":"Klawitter I, Anneser MR, Dechert S, Meyer S, Demeshko S, Haslinger S, P\u00f6thig A, K\u00fchn FE, Meyer F (2015) Iron complexes of a macrocyclic N-heterocyclic carbene\/pyridine hybrid ligand. Organometallics 34(12):2819\u20132825","journal-title":"Organometallics"},{"issue":"8","key":"304_CR228","doi-asserted-by":"crossref","first-page":"2027","DOI":"10.1021\/om500178e","volume":"33","author":"BRM Lake","year":"2014","unstructured":"Lake BRM, Willans CE (2014) Remarkable stability of copper(II)\u2013N-heterocyclic carbene complexes void of an anionic tether. Organometallics 33(8):2027\u20132038","journal-title":"Organometallics"},{"issue":"24\u201325","key":"304_CR229","doi-asserted-by":"crossref","first-page":"5556","DOI":"10.1016\/j.jorganchem.2005.06.044","volume":"690","author":"N Schneider","year":"2005","unstructured":"Schneider N, C\u00e9sar V, Bellemin-Laponnaz S, Gade LH (2005) Synthesis and structural chemistry of oxazolinyl-carbene copper(I) complexes. J Organomet Chem 690(24\u201325):5556\u20135561","journal-title":"J Organomet Chem"},{"issue":"5","key":"304_CR230","doi-asserted-by":"crossref","first-page":"2157","DOI":"10.1021\/acs.inorgchem.5b02546","volume":"55","author":"Z Wang","year":"2016","unstructured":"Wang Z, Zheng C, Wang W, Xu C, Ji B, Zhang X (2016) Synthesis, structure, and photophysical properties of two four-coordinate CuI\u2013NHC complexes with efficient delayed fluorescence. Inorg Chem 55(5):2157\u20132164","journal-title":"Inorg Chem"},{"key":"304_CR231","doi-asserted-by":"crossref","first-page":"351","DOI":"10.1016\/j.jorganchem.2017.07.016","volume":"846","author":"J Wang","year":"2017","unstructured":"Wang J, Liu S, Xu S, Zhao F, Xia H, Wang Y (2017) Four-coordinated copper(I) complexes containing variably substituted N-heterocyclic carbenes (NHCs): synthesis, photophysical properties and theoretical investigation. J Organomet Chem 846:351\u2013359","journal-title":"J Organomet Chem"},{"key":"304_CR232","doi-asserted-by":"crossref","first-page":"3826","DOI":"10.1039\/b506232b","volume":"30","author":"CY Legault","year":"2005","unstructured":"Legault CY, Kendall C, Charette AB (2005) Structure and reactivity of a new anionic N-heterocyclic carbene silver(i) complex. Chem Commun 30:3826","journal-title":"Chem Commun"},{"key":"304_CR233","doi-asserted-by":"crossref","first-page":"1612","DOI":"10.1039\/b404614e","volume":"14","author":"PL Arnold","year":"2004","unstructured":"Arnold PL, Rodden M, Davis KM, Scarisbrick AC, Blake AJ, Wilson C (2004) Asymmetric lithium(i) and copper(ii) alkoxy-N-heterocyclic carbene complexes; crystallographic characterisation and Lewis acid catalysis. Electronic supplementary information (ESI) available: full synthetic and structural details. Chem Commun 14:1612","journal-title":"Chem Commun"},{"issue":"21","key":"304_CR234","doi-asserted-by":"crossref","first-page":"8937","DOI":"10.1039\/C6DT01263A","volume":"45","author":"RE Andrew","year":"2016","unstructured":"Andrew RE, Storey CM, Chaplin AB (2016) Well-defined coinage metal transfer agents for the synthesis of NHC-based nickel, rhodium and palladium macrocycles. Dalton Trans 45(21):8937\u20138944","journal-title":"Dalton Trans"},{"issue":"22","key":"304_CR235","doi-asserted-by":"crossref","first-page":"11685","DOI":"10.1021\/acs.inorgchem.6b01646","volume":"55","author":"D Domyati","year":"2016","unstructured":"Domyati D, Hope SL, Latifi R, Hearns MD, Tahsini L (2016) Cu(I) complexes of pincer pyridine-based N-heterocyclic carbenes with small wingtip substituents: synthesis and structural and spectroscopic studies. Inorg Chem 55(22):11685\u201311693","journal-title":"Inorg Chem"},{"key":"304_CR236","doi-asserted-by":"crossref","first-page":"98","DOI":"10.1016\/j.jorganchem.2018.02.028","volume":"860","author":"D Domyati","year":"2018","unstructured":"Domyati D, Latifi R, Tahsini L (2018) Sonogashira-type cross-coupling reactions catalyzed by copper complexes of pincer N-heterocyclic carbenes. J Organomet Chem 860:98\u2013105","journal-title":"J Organomet Chem"},{"issue":"4","key":"304_CR237","doi-asserted-by":"crossref","first-page":"1836","DOI":"10.1039\/C4DT02986K","volume":"44","author":"B Liu","year":"2015","unstructured":"Liu B, Ma X, Wu F, Chen W (2015) Simple synthesis of neutral and cationic Cu\u2013NHC complexes. Dalton Trans 44(4):1836\u20131844","journal-title":"Dalton Trans"},{"issue":"13","key":"304_CR238","doi-asserted-by":"crossref","first-page":"5713","DOI":"10.1039\/C6DT00008H","volume":"45","author":"H Iwasaki","year":"2016","unstructured":"Iwasaki H, Teshima Y, Yamada Y, Ishikawa R, Koga Y, Matsubara K (2016) Bimetallic Cu(i) complex with a pyridine-bridged bis(1,2,3-triazole-5-ylidene) ligand. Dalton Trans 45(13):5713\u20135719","journal-title":"Dalton Trans"},{"issue":"17","key":"304_CR239","doi-asserted-by":"crossref","first-page":"3175","DOI":"10.1021\/acs.organomet.7b00489","volume":"36","author":"DJ O\u2019Hearn","year":"2017","unstructured":"O\u2019Hearn DJ, Singer RD (2017) Direct synthesis of a copper(II) N-heterocyclic carbene complex in air. Organometallics 36(17):3175\u20133177","journal-title":"Organometallics"},{"issue":"52","key":"304_CR240","doi-asserted-by":"crossref","first-page":"6511","DOI":"10.1039\/c2cc33036a","volume":"48","author":"PD Newman","year":"2012","unstructured":"Newman PD, Cavell KJ, Kariuki BM (2012) Monovalent chiral-at-copper complexes: halide-controlled diastereoselectivity. Chem Commun 48(52):6511","journal-title":"Chem Commun"},{"issue":"19","key":"304_CR241","doi-asserted-by":"crossref","first-page":"2431","DOI":"10.1039\/c3cc49385g","volume":"50","author":"DI Bezuidenhout","year":"2014","unstructured":"Bezuidenhout DI, Kleinhans G, Guisado-Barrios G, Liles DC, Ung G, Bertrand G (2014) Isolation of a potassium bis(1,2,3-triazol-5-ylidene)carbazolide: a stabilizing pincer ligand for reactive late transition metal complexes. Chem Commun 50(19):2431","journal-title":"Chem Commun"},{"issue":"40","key":"304_CR242","doi-asserted-by":"crossref","first-page":"12237","DOI":"10.1021\/ja036880+","volume":"125","author":"X Hu","year":"2003","unstructured":"Hu X, Castro-Rodriguez I, Meyer K (2003) Copper complexes of nitrogen-anchored tripodal N-heterocyclic carbene ligands. J Am Chem Soc 125(40):12237\u201312245","journal-title":"J Am Chem Soc"},{"issue":"23","key":"304_CR243","doi-asserted-by":"crossref","first-page":"11223","DOI":"10.1021\/ic1018407","volume":"49","author":"JM Smith","year":"2010","unstructured":"Smith JM, Long JR (2010) First-row transition metal complexes of the strongly donating pentadentate ligand PY4Im. Inorg Chem 49(23):11223\u201311230","journal-title":"Inorg Chem"}],"updated-by":[{"DOI":"10.1007\/s41061-020-00308-4","type":"retraction","label":"Retraction","source":"retraction-watch","updated":{"date-parts":[[2020,9,2]],"date-time":"2020-09-02T00:00:00Z","timestamp":1599004800000},"record-id":"24133"},{"DOI":"10.1007\/s41061-020-00308-4","type":"retraction","label":"Retraction","source":"publisher","updated":{"date-parts":[[2020,9,2]],"date-time":"2020-09-02T00:00:00Z","timestamp":1599004800000}}],"container-title":["Topics in Current Chemistry"],"original-title":[],"language":"en","link":[{"URL":"https:\/\/link.springer.com\/content\/pdf\/10.1007\/s41061-020-00304-8.pdf","content-type":"application\/pdf","content-version":"vor","intended-application":"text-mining"},{"URL":"https:\/\/link.springer.com\/article\/10.1007\/s41061-020-00304-8\/fulltext.html","content-type":"text\/html","content-version":"vor","intended-application":"text-mining"},{"URL":"https:\/\/link.springer.com\/content\/pdf\/10.1007\/s41061-020-00304-8.pdf","content-type":"application\/pdf","content-version":"vor","intended-application":"similarity-checking"}],"deposited":{"date-parts":[[2021,8,26]],"date-time":"2021-08-26T23:45:07Z","timestamp":1630021507000},"score":1,"resource":{"primary":{"URL":"https:\/\/link.springer.com\/10.1007\/s41061-020-00304-8"}},"subtitle":[],"short-title":[],"issued":{"date-parts":[[2020,6]]},"references-count":243,"journal-issue":{"issue":"3","published-print":{"date-parts":[[2020,6]]}},"alternative-id":["304"],"URL":"https:\/\/doi.org\/10.1007\/s41061-020-00304-8","relation":{"retraction":[{"id-type":"doi","id":"10.1007\/s41061-020-00308-4","asserted-by":"object"}]},"ISSN":["2365-0869","2364-8961"],"issn-type":[{"value":"2365-0869","type":"print"},{"value":"2364-8961","type":"electronic"}],"subject":[],"published":{"date-parts":[[2020,6]]},"assertion":[{"value":"6 February 2020","order":1,"name":"received","label":"Received","group":{"name":"ArticleHistory","label":"Article History"}},{"value":"16 April 2020","order":2,"name":"accepted","label":"Accepted","group":{"name":"ArticleHistory","label":"Article History"}},{"value":"27 August 2020","order":3,"name":"first_online","label":"First Online","group":{"name":"ArticleHistory","label":"Article History"}},{"value":"2 September 2020","order":4,"name":"change_date","label":"Change Date","group":{"name":"ArticleHistory","label":"Article History"}},{"value":"Correction","order":5,"name":"change_type","label":"Change Type","group":{"name":"ArticleHistory","label":"Article History"}},{"value":"None of the authors have responded to any correspondence from the publisher about this retraction.","order":6,"name":"change_details","label":"Change Details","group":{"name":"ArticleHistory","label":"Article History"}},{"order":1,"name":"Ethics","group":{"name":"EthicsHeading","label":"Compliance with Ethical Standards"}},{"value":"On behalf of all authors, Sina Matavos-Aramyan states that there is no conflict of interest.","order":2,"name":"Ethics","group":{"name":"EthicsHeading","label":"Conflict of interest"}}],"article-number":"39"}}