{"status":"ok","message-type":"work","message-version":"1.0.0","message":{"indexed":{"date-parts":[[2026,8,25]],"date-time":"2026-08-25T00:37:55Z","timestamp":1787618275248,"version":"build-2736575974"},"reference-count":70,"publisher":"Springer Science and Business Media LLC","issue":"5","license":[{"start":{"date-parts":[[2021,10,6]],"date-time":"2021-10-06T00:00:00Z","timestamp":1633478400000},"content-version":"tdm","delay-in-days":0,"URL":"https:\/\/creativecommons.org\/licenses\/by\/4.0"},{"start":{"date-parts":[[2021,10,6]],"date-time":"2021-10-06T00:00:00Z","timestamp":1633478400000},"content-version":"vor","delay-in-days":0,"URL":"https:\/\/creativecommons.org\/licenses\/by\/4.0"}],"funder":[{"DOI":"10.13039\/501100004769","name":"Universit\u00e0 degli Studi di Pavia","doi-asserted-by":"crossref","id":[{"id":"10.13039\/501100004769","id-type":"DOI","asserted-by":"crossref"}]}],"content-domain":{"domain":["link.springer.com"],"crossmark-restriction":false},"short-container-title":["Photochem Photobiol Sci"],"published-print":{"date-parts":[[2022,5]]},"abstract":"<jats:title>Abstract<\/jats:title><jats:p>Lead halide perovskite nanocrystals were prepared and used as photocatalysts for the in situ <jats:sup>1<\/jats:sup>O<jats:sub>2<\/jats:sub> generation to perform hetero Diels\u2013Alder, ene and oxidation reactions with suitable dienes and alkenes. The methodology has been reasonably standardized and made applicable to a variety of olefinic substrates. The scope of the method is finely illustrated by the results in all the tested reactions, which allowed to obtain desymmetrized hydroxy-ketone derivatives, unsaturated ketones and epoxides. Some limitations were also observed especially in the case of the alkene oxidations as well as poor chemoselectivity was somewhere observed.<\/jats:p>\n                <jats:p><jats:bold>Graphic abstract<\/jats:bold><\/jats:p>\n                <jats:p><jats:sup>1<\/jats:sup>O<jats:sub>2<\/jats:sub> generated by lead halide perovskite nanocrystals as photocatalyst in organic reactions.<\/jats:p>","DOI":"10.1007\/s43630-021-00106-x","type":"journal-article","created":{"date-parts":[[2021,10,7]],"date-time":"2021-10-07T05:16:11Z","timestamp":1633583771000},"page":"613-624","update-policy":"https:\/\/doi.org\/10.1007\/springer_crossmark_policy","source":"Crossref","is-referenced-by-count":7,"title":["Nanocrystals perovskites photocatalyzed singlet oxygen generation for light-driven organic reactions"],"prefix":"10.1007","volume":"21","author":[{"ORCID":"https:\/\/orcid.org\/0000-0002-4290-2454","authenticated-orcid":false,"given":"Marco","family":"Corti","sequence":"first","affiliation":[],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Rossella","family":"Chiara","sequence":"additional","affiliation":[],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Lidia","family":"Romani","sequence":"additional","affiliation":[],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0002-7371-7243","authenticated-orcid":false,"given":"Barbara","family":"Mannucci","sequence":"additional","affiliation":[],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0003-4724-2376","authenticated-orcid":false,"given":"Lorenzo","family":"Malavasi","sequence":"additional","affiliation":[],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0001-5369-9140","authenticated-orcid":false,"given":"Paolo","family":"Quadrelli","sequence":"additional","affiliation":[],"role":[{"vocabulary":"crossref","role":"author"}]}],"member":"297","published-online":{"date-parts":[[2021,10,6]]},"reference":[{"key":"106_CR1","doi-asserted-by":"publisher","first-page":"5322","DOI":"10.1021\/cr300503r","volume":"113","author":"CK Prier","year":"2013","unstructured":"Prier, C. K., Rankic, D. A., & MacMillan, D. W. C. (2013). Visible light photoredox catalysis with transition metal complexes: Applications in organic synthesis. Chemical Reviews, 113, 5322\u20135363.","journal-title":"Chemical Reviews"},{"key":"106_CR2","doi-asserted-by":"publisher","first-page":"52","DOI":"10.1038\/s41570-017-0052","volume":"1","author":"J Twilton","year":"2017","unstructured":"Twilton, J., Le, C., Zhang, P., Shaw, M. H., Evans, R. W., & MacMillan, D. W. C. (2017). The merger of transition metal and photocatalysis. Nature Reviews Chemistry, 1, 52.","journal-title":"Nature Reviews Chemistry"},{"key":"106_CR3","doi-asserted-by":"publisher","first-page":"31377","DOI":"10.1039\/C7RA05444K","volume":"7","author":"V Srivastava","year":"2017","unstructured":"Srivastava, V., & Singh, P. P. (2017). Eosin Y catalysed photoredox synthesis: A review. RSC Advances, 7, 31377\u201331392.","journal-title":"RSC Advances"},{"key":"106_CR4","doi-asserted-by":"publisher","first-page":"9977","DOI":"10.1039\/C9OB01739A","volume":"17","author":"HJ Cheng","year":"2019","unstructured":"Cheng, H. J., & Xu, W. T. (2019). Recent advances in modified TiO2 for photo-induced organic synthesis. Organic and Biomolecular Chemistry, 17, 9977\u20139989.","journal-title":"Organic and Biomolecular Chemistry"},{"key":"106_CR5","doi-asserted-by":"publisher","first-page":"1378","DOI":"10.1002\/cctc.201801773","volume":"11","author":"HM Hao","year":"2019","unstructured":"Hao, H. M., & Lang, X. J. (2019). Metal sulfide photocatalysis: Visible-lightinducedorganic transformations. ChemCatChem, 11, 1378\u20131393.","journal-title":"ChemCatChem"},{"key":"106_CR6","doi-asserted-by":"publisher","first-page":"100390","DOI":"10.1016\/j.cogsc.2020.100390","volume":"27","author":"M Zhang","year":"2021","unstructured":"Zhang, M., Sun, W., Lv, H., & Zhang, Z.-H. (2021). Syntheses and applications of perovskite-based photocatalysts in light-driven organic reactions. Current Opinion in Green and Sustainable Chemistry, 27, 100390.","journal-title":"Current Opinion in Green and Sustainable Chemistry"},{"key":"106_CR7","doi-asserted-by":"publisher","first-page":"404","DOI":"10.1002\/9781444300017","volume-title":"Photochemistry of organic compounds","author":"P Klan","year":"2009","unstructured":"Klan, P., & Wirz, J. (2009). Photochemistry of organic compounds (pp. 404\u2013451). Wiley."},{"key":"106_CR8","doi-asserted-by":"publisher","first-page":"19","DOI":"10.1039\/cs9952400019","volume":"24","author":"R Bonnett","year":"1995","unstructured":"Bonnett, R. (1995). Photosensitizers of the porphyrin and phthalocyanine series for photodynamic therapy. Chemical Society Reviews, 24, 19\u201333.","journal-title":"Chemical Society Reviews"},{"key":"106_CR9","volume-title":"Singlet oxygen","author":"AA Frimer","year":"1985","unstructured":"Frimer, A. A. (1985). Singlet oxygen (Vol. I). CRC Press."},{"key":"106_CR10","doi-asserted-by":"publisher","first-page":"133","DOI":"10.1002\/0471264180.or020.02","volume-title":"Organic reactions","author":"RW Denny","year":"2011","unstructured":"Denny, R. W., & Nickon, A. (2011). Sensitized photooxygenation of olefins. Organic reactions (Vol. 20, pp. 133\u2013336). Wiley."},{"key":"106_CR11","doi-asserted-by":"publisher","first-page":"105","DOI":"10.1007\/978-94-007-0874-7_4","volume-title":"Active oxygen in chemistry","year":"1995","unstructured":"Foote, C. S., Valentine, J. S., Greenberg, A., & Liebman, J. F. (Eds.). (1995). Active oxygen in chemistry (p. 105). Chapman & Hall."},{"key":"106_CR12","doi-asserted-by":"publisher","first-page":"3181","DOI":"10.1039\/b926014p","volume":"39","author":"PR Ogilby","year":"2010","unstructured":"Ogilby, P. R. (2010). Singlet oxygen: There is indeed something new under the sun. Chemical Society Reviews, 39, 3181\u20133209.","journal-title":"Chemical Society Reviews"},{"key":"106_CR13","doi-asserted-by":"publisher","first-page":"8814","DOI":"10.1021\/ja026815k","volume":"124","author":"W Adam","year":"2002","unstructured":"Adam, W., Bosio, S. G., & Turro, N. J. (2002). Highly diastereoselective dioxetane formation in the photooxygenation of enecarbamates with an oxazolidinone chiral auxiliary: Steric control in the [2 + 2] cycloaddition of singlet oxygen through conformational alignment. Journal of the American Chemical Society, 124, 8814\u20138815.","journal-title":"Journal of the American Chemical Society"},{"key":"106_CR14","doi-asserted-by":"publisher","first-page":"6665","DOI":"10.1016\/j.tet.2005.04.017","volume":"61","author":"EL Clennan","year":"2005","unstructured":"Clennan, E. L., & Pace, A. (2005). Advances in singlet oxygen chemistry. Tetrahedron, 61, 6665\u20136691.","journal-title":"Tetrahedron"},{"key":"106_CR15","doi-asserted-by":"publisher","first-page":"9414","DOI":"10.1002\/chem.201000752","volume":"16","author":"MN Alberti","year":"2010","unstructured":"Alberti, M. N., & Orfanopoulos, M. (2010). Unraveling the mechanism of the singlet oxygen ene reaction: Recent computational and experimental approaches. Chemistry: A European Journal, 16, 9414\u20139421.","journal-title":"Chemistry: A European Journal"},{"key":"106_CR16","doi-asserted-by":"publisher","first-page":"7574","DOI":"10.1021\/acs.joc.8b01307","volume":"83","author":"JM de Souza","year":"2018","unstructured":"de Souza, J. M., Brocksom, T. J., McQuade, D. T., & de Oliveira, K. T. (2018). Continuous endoperoxidation of conjugated dienes and subsequent rearrangements leading to C\u2013H oxidized synthons. Journal of Organic Chemistry, 83, 7574\u20137585.","journal-title":"Journal of Organic Chemistry"},{"key":"106_CR17","doi-asserted-by":"publisher","first-page":"12602","DOI":"10.1038\/srep12602","volume":"5","author":"Z Wang","year":"2015","unstructured":"Wang, Z., Hong, X., Zong, S., Tang, C., Cui, Y., & Zheng, Q. (2015). BODIPY-doped silica nanoparticles with reduced dye leakage and enhanced singlet oxygen generation. Science and Reports, 5, 12602. https:\/\/doi.org\/10.1038\/srep12602","journal-title":"Science and Reports"},{"key":"106_CR18","doi-asserted-by":"publisher","first-page":"72","DOI":"10.1039\/C6CS00532B","volume":"46","author":"KS Lakhi","year":"2017","unstructured":"Lakhi, K. S., Park, D. H., Al-Bahily, K., Cha, W., Viswanathan, B., Choy, J. H., & Vinu, A. (2017). Mesoporous carbon nitrides: Synthesis, functionalization, and applications. Chemical Society Reviews, 46, 72\u2013101.","journal-title":"Chemical Society Reviews"},{"key":"106_CR19","doi-asserted-by":"publisher","first-page":"8176","DOI":"10.1021\/acssuschemeng.8b06164","volume":"7","author":"I Camussi","year":"2019","unstructured":"Camussi, I., Mannucci, B., Speltini, A., Profumo, A., Milanese, C., Malavasi, L., & Quadrelli, P. (2019). g-C3N4\u2014Singlet oxygen made easy for organic synthesis: Scope and limitations. ACS Sustainable Chemistry and Engineering, 7, 8176\u20138182.","journal-title":"ACS Sustainable Chemistry and Engineering"},{"key":"106_CR20","doi-asserted-by":"publisher","first-page":"2292","DOI":"10.1039\/D0CY02352C","volume":"11","author":"M Corti","year":"2021","unstructured":"Corti, M., Chiara, R., Romani, L., Mannucci, B., Malavasi, L., & Quadrelli, P. (2021). g-C3N4\/metal halide perovskite composites as photocatalysts for singlet oxygen generation processes for the preparation of variable oxidized synthons. Catalysis Science and Technology, 11, 2292\u20132298.","journal-title":"Catalysis Science and Technology"},{"key":"106_CR21","doi-asserted-by":"publisher","first-page":"3692","DOI":"10.1021\/nl5048779","volume":"15","author":"L Protesescu","year":"2015","unstructured":"Protesescu, L., Yakunin, S., Bodnarchuk, M. I., Krieg, F., Caputo, R., Hendon, C. H., Yang, R. X., Walsh, A., & Kovalenko, M. V. (2015). Nanocrystals of cesium lead halide perovskites (CsPbX3, X = Cl, Br, and I): Novel optoelectronic materials showing bright emission with wide color gamut. Nano Letters, 15, 3692\u20133696.","journal-title":"Nano Letters"},{"key":"106_CR22","doi-asserted-by":"publisher","first-page":"2765","DOI":"10.1021\/acs.nanolett.6b04781","volume":"17","author":"I Levchuk","year":"2017","unstructured":"Levchuk, I., Osvet, A., Tang, X., Brandl, M., Perea, J. D., Hoegl, F., Matt, G. J., Hock, R., Batentschuk, M., & Brabec, C. J. (2017). Brightly luminescent and color-tunable formamidinium lead halide perovskite FAPbX3 (X = Cl, Br, I) colloidal nanocrystals. Nano Letters, 17, 2765\u20132770.","journal-title":"Nano Letters"},{"key":"106_CR23","doi-asserted-by":"publisher","first-page":"9151","DOI":"10.1016\/S0040-4020(00)00794-8","volume":"56","author":"EL Clennan","year":"2000","unstructured":"Clennan, E. L. (2000). New mechanistic and synthetic aspects of singlet oxygen chemistry. Tetrahedron, 56, 9151\u20139179.","journal-title":"Tetrahedron"},{"key":"106_CR24","doi-asserted-by":"publisher","first-page":"1319","DOI":"10.1021\/ja027225p","volume":"125","author":"DA Singleton","year":"2003","unstructured":"Singleton, D. A., Hang, C., Szymanski, M. J., Meyer, M. P., Leach, A. G., Kuwata, K. T., Chgen, J. S., Greer, A., Foote, C. S., & Houk, K. N. (2003). Mechanism of ene reactions of singlet oxygen. A two-step no-intermediate mechanism. Journal of the American Chemical Society, 125, 1319\u20131328.","journal-title":"Journal of the American Chemical Society"},{"key":"106_CR25","doi-asserted-by":"crossref","unstructured":"Leach, A. G., & Houk, K. N. (2002). Diels\u2013Alder and ene reactions of singlet oxygen, nitroso compounds and triazolinediones: transition states and mechanisms from contemporary theory. Chemical Communications, 1243\u20131255.","DOI":"10.1039\/b111251c"},{"key":"106_CR26","doi-asserted-by":"publisher","first-page":"14820","DOI":"10.1021\/ja012757b","volume":"124","author":"AG Leach","year":"2002","unstructured":"Leach, A. G., & Houk, K. N. (2002). The ene reactions of nitroso compounds involve polarized diradical intermediates. Journal of the American Chemical Society, 124, 14820\u201314821.","journal-title":"Journal of the American Chemical Society"},{"key":"106_CR27","doi-asserted-by":"publisher","first-page":"1093","DOI":"10.1007\/BF00905697","volume":"94","author":"H Koch","year":"1963","unstructured":"Koch, H., Pirsch, J., & Benedikt, A. (1963). Notiz zur Darstellung von cyclopenten-3,4-und-3,5-diol. Monatshefte f\u00fcr Chemie und verwandte Teile anderer Wissenschaften, 94, 1093\u20131097.","journal-title":"Monatshefte f\u00fcr Chemie und verwandte Teile anderer Wissenschaften"},{"key":"106_CR28","doi-asserted-by":"publisher","first-page":"15676","DOI":"10.1039\/C7TA01792H","volume":"5","author":"C-C Chang","year":"2017","unstructured":"Chang, C.-C., Lee, J.-F., & Cheng, S. (2017). Highly catalytically active micro\/meso-porous Ti-MCM-36 prepared by a grafting method. Journal of Materials Chemistry A, 5, 15676\u201315687.","journal-title":"Journal of Materials Chemistry A"},{"key":"106_CR29","doi-asserted-by":"publisher","first-page":"2132","DOI":"10.1016\/j.tet.2007.01.001","volume":"63","author":"C Alvarez","year":"2007","unstructured":"Alvarez, C., Pelaez, R., & Medarde, M. (2007). New dicyclopentadiene-based scaffolds. Tetrahedron, 63, 2132\u20132141.","journal-title":"Tetrahedron"},{"key":"106_CR30","doi-asserted-by":"publisher","first-page":"481","DOI":"10.1002\/prac.19833250318","volume":"325","author":"D Schnurpfeil","year":"1983","unstructured":"Schnurpfeil, D. (1983). Dicyclopentadienoxidation. I, Unkatalysierte Fl\u00fcssigphasenoxidation von Dicyclopentadien. Journal fuer Praktische Chemie\/Chemiker-Zeitung, 325, 481\u2013488.","journal-title":"Journal fuer Praktische Chemie\/Chemiker-Zeitung"},{"key":"106_CR31","doi-asserted-by":"publisher","first-page":"1001","DOI":"10.1016\/S0040-4039(01)92813-8","volume":"18","author":"S Terashima","year":"1977","unstructured":"Terashima, S., & Yamada, S. (1977). Novel use of meso-compound for the preparation of optically active compounds: synthesis of optically active prostaglandin intermediates from\u00a0CIS-2-cyclopentene-1,4-diol. Tetrahedron Letters, 18, 1001\u20131004.","journal-title":"Tetrahedron Letters"},{"key":"106_CR32","doi-asserted-by":"publisher","first-page":"5117","DOI":"10.1016\/0040-4020(95)98708-P","volume":"51","author":"J Zhu","year":"1995","unstructured":"Zhu, J., Klunder, A. J. H., & Zwanenburg, B. (1995). A facile approach to norbornene-annulated cyclopentenones, a novel class of tricyclodecadienones. Tetrahedron, 51, 5117\u20135132.","journal-title":"Tetrahedron"},{"key":"106_CR33","doi-asserted-by":"publisher","first-page":"3473","DOI":"10.1016\/S0040-4020(01)87027-7","volume":"50","author":"PPMA Dolls","year":"1994","unstructured":"Dolls, P. P. M. A., Arnouts, E. G., Rohaan, J., Klunder, A. J. H., & Zwanenburg, B. (1994). Nucleophilic additions to tricyclodecadienone epoxides. The Payne rearrangement of \u03b1,\u03b2-epoxycyclopentanols contained in a rigid tricyclic system. Tetrahedron, 50, 3473\u20133490.","journal-title":"Tetrahedron"},{"key":"106_CR34","doi-asserted-by":"crossref","unstructured":"Wiel, J.-B., & Rouessac, F. (1976). A new approach to the synthesis of the prostanoids. Journal of the Chemical Society, Chemical Communications, 446\u2013447.","DOI":"10.1039\/c3976000446b"},{"key":"106_CR35","unstructured":"Ingelbrecht, H., Kumar, A., Menon, A. R., Nadkarni, P., & Pawar, R. (2007). US 2007\/0049767."},{"key":"106_CR36","doi-asserted-by":"publisher","first-page":"3378","DOI":"10.1016\/j.tetlet.2013.04.061","volume":"54","author":"S Jeanmart","year":"2013","unstructured":"Jeanmart, S., Taylor, J. B., Parsons, R. W., Mathews, C. J., & Smith, S. (2013). Synthesis of novel heterocyclic acetyl coenzyme-A carboxylase inhibitors via a Claisen rearrangement. Tetrahedron Letters, 54, 3378\u20133383.","journal-title":"Tetrahedron Letters"},{"key":"106_CR37","doi-asserted-by":"publisher","first-page":"103","DOI":"10.1023\/A:1019053402854","volume":"69","author":"M Skumov","year":"2000","unstructured":"Skumov, M., & Balbolov, E. (2000). Oxidation of dicyclopentadiene catalyzed by palladium(II) acetate and p-benzoquinone in the presence of inorganic acid. Catalysis Letters, 69, 103\u2013107.","journal-title":"Catalysis Letters"},{"key":"106_CR38","doi-asserted-by":"publisher","first-page":"5096","DOI":"10.1021\/acs.inorgchem.7b00220","volume":"56","author":"M Sankaralingam","year":"2017","unstructured":"Sankaralingam, M., Lee, Y.-M., Nam, W., & Fukuzumi, S. (2017). Selective oxygenation of cyclohexene by dioxygen via an iron(V)-oxo complex-autocatalyzed reaction. Inorganic Chemistry, 56, 5096\u20135104.","journal-title":"Inorganic Chemistry"},{"key":"106_CR39","doi-asserted-by":"publisher","first-page":"4741","DOI":"10.1021\/jo00374a053","volume":"51","author":"AA Ponoras","year":"1986","unstructured":"Ponoras, A. A., & Zaim, O. (1986). Synthetic elaboration of diosphenols. Replacement of hydroxyl by halogen. Journal of Organic Chemistry, 51, 4741\u20134743.","journal-title":"Journal of Organic Chemistry"},{"key":"106_CR40","doi-asserted-by":"publisher","first-page":"4734","DOI":"10.1021\/acs.orglett.6b02405","volume":"18","author":"J Yu","year":"2016","unstructured":"Yu, J., Zhou, Y., Lin, Z., & Tong, R. (2016). Regioselective and stereospecific copper-catalyzed deoxygenation of epoxides to alkenes. Organic Letters, 18, 4734\u20134737.","journal-title":"Organic Letters"},{"key":"106_CR41","doi-asserted-by":"publisher","first-page":"3336","DOI":"10.1021\/acscatal.5b00066","volume":"5","author":"SR Amanchi","year":"2015","unstructured":"Amanchi, S. R., Khenkin, A. M., Diskin-Posner, Y., & Neumann, R. (2015). Bismuth-substituted \u201cSandwich\u201d type polyoxometalate catalyst for activation of peroxide: Umpolung of the peroxo intermediate and change of chemoselectivity. ACS Catalysis, 5, 3336\u20133341.","journal-title":"ACS Catalysis"},{"key":"106_CR42","doi-asserted-by":"publisher","first-page":"15138","DOI":"10.1021\/acs.inorgchem.7b02463","volume":"56","author":"J Zhang","year":"2017","unstructured":"Zhang, J., Wei, W.-J., Lu, X., Yang, H., Chen, Z., Liao, R.-Z., & Yin, G. (2017). Nonredox metal ions promoted olefin epoxidation by iron(II) complexes with H2O2: DFT calculations reveal multiple channels for oxygen transfer. Inorganic Chemistry, 56, 15138\u201315149.","journal-title":"Inorganic Chemistry"},{"key":"106_CR43","doi-asserted-by":"publisher","first-page":"1887","DOI":"10.1016\/S0040-4039(00)87212-3","volume":"23","author":"JP Dulcere","year":"1982","unstructured":"Dulcere, J. P., & Rodriguez, J. (1982). Epoxidation with H2O2\/Vilsmeier reagent system. Tetrahedron Letters, 23, 1887\u20131888.","journal-title":"Tetrahedron Letters"},{"key":"106_CR44","doi-asserted-by":"publisher","first-page":"6021","DOI":"10.1016\/S0040-4039(00)61116-4","volume":"33","author":"S Raina","year":"1992","unstructured":"Raina, S., Bhuniya, D., & Singh, V. K. (1992). A mild method for conversion of epoxides into \u03b1-chloro ketones. Tetrahedron Letters, 33, 6021\u20136022.","journal-title":"Tetrahedron Letters"},{"key":"106_CR45","doi-asserted-by":"publisher","first-page":"7644","DOI":"10.1021\/acs.inorgchem.8b00611","volume":"57","author":"GA Bhat","year":"2018","unstructured":"Bhat, G. A., Verma, S., Rajendran, A., & Murugavel, R. (2018). Thermolabile organotitanium monoalkyl phosphates: Synthesis, structures, and utility as epoxidation catalysts and single-source precursors for TiP2O7. Inorganic Chemistry, 57, 7644\u20137654.","journal-title":"Inorganic Chemistry"},{"key":"106_CR46","doi-asserted-by":"publisher","first-page":"5736","DOI":"10.1021\/ja01530a051","volume":"81","author":"J Allinger","year":"1959","unstructured":"Allinger, J., & Allinger, M. N. L. (1959). Conformational analysis. V. 2-bromocyclooctanone. Journal of the American Chemical Society, 81, 5736\u20135740.","journal-title":"Journal of the American Chemical Society"},{"key":"106_CR47","doi-asserted-by":"publisher","first-page":"142","DOI":"10.1016\/j.molcata.2013.06.013","volume":"378","author":"H G\u00f6ksu","year":"2013","unstructured":"G\u00f6ksu, H., Dalmizrak, D., Akbayrak, S., G\u00fcltekin, M. S., Ozkar, S., & Metin, O. (2013). One-pot synthesis of 1,2\/3-triols from the allylic hydroperoxides catalyzed by zeolite-confined osmium(0) nanoclusters. Journal of Molecular Catalysis A: Chemical, 378, 142\u2013147.","journal-title":"Journal of Molecular Catalysis A: Chemical"},{"key":"106_CR48","doi-asserted-by":"publisher","first-page":"1181","DOI":"10.1366\/0003702944027471","volume":"48","author":"TW Collette","year":"1994","unstructured":"Collette, T. W., Richardson, S. D., & Thruston, A. D., Jr. (1994). Identification of bromohydrins in ozonated waters. Applied Spectroscopy, 48, 1181\u20131192.","journal-title":"Applied Spectroscopy"},{"key":"106_CR49","doi-asserted-by":"publisher","first-page":"844","DOI":"10.1021\/acs.organomet.8b00834","volume":"38","author":"JP Camarena-D\u00edaz","year":"2019","unstructured":"Camarena-D\u00edaz, J. P., Iglesias, A. L., Ch\u00e1vez, D., Aguirre, G., Grotjahn, D. B., Rheingold, A. L., Parra-Hake, M., & Miranda-Soto, V. (2019). Rh(III)Cp* and Ir(III)Cp* complexes of 1-[(4-methyl)phenyl]-3-[(2-methyl-4\u2032-R)imidazol-1-yl]triazenide (R = t-Bu or H): Synthesis, structure, and catalytic activity. Organometallics, 38, 844\u2013851.","journal-title":"Organometallics"},{"key":"106_CR50","doi-asserted-by":"publisher","first-page":"3997","DOI":"10.1021\/ol0483394","volume":"6","author":"MF Oswald","year":"2004","unstructured":"Oswald, M. F., Raw, S. A., & Taylor, R. J. K. (2004). Tandem oxidation processes for the preparation of functionalized cyclopropanes. Organic Letters, 6, 3997\u20134000.","journal-title":"Organic Letters"},{"key":"106_CR51","doi-asserted-by":"publisher","first-page":"69","DOI":"10.1016\/j.apcata.2003.10.030","volume":"261","author":"UR Pillai","year":"2004","unstructured":"Pillai, U. R., & Sahle-Demessie, E. (2004). Epoxidation of olefins and \u03b1, \u03b2-unsaturated ketones over sonochemically prepared hydroxyapatites using hydrogen peroxide. Applied Catalysis A: General, 261, 69\u201376.","journal-title":"Applied Catalysis A: General"},{"key":"106_CR52","doi-asserted-by":"publisher","first-page":"6997","DOI":"10.1021\/ja901289r","volume":"131","author":"K Kamata","year":"2009","unstructured":"Kamata, K., Hirano, T., Kuzuya, S., & Mizuno, N. (2009). Hydrogen-bond-assisted epoxidation of homoallylic and allylic alcohols with hydrogen peroxide catalyzed by selenium-containing dinuclear peroxotungstate. Journal of the American Chemical Society, 131, 6997\u20137004.","journal-title":"Journal of the American Chemical Society"},{"key":"106_CR53","doi-asserted-by":"publisher","first-page":"196","DOI":"10.1007\/s11244-015-0428-3","volume":"59","author":"PJ Luggren","year":"2016","unstructured":"Luggren, P. J., Apesteguia, C. R., & Di Cosimo, J. I. (2016). Conversion of biomass-derived 2-hexanol to liquid transportation fuels: Study of the reaction mechanism on Cu\u2013Mg\u2013Al mixed oxides. Topics in Catalysis, 59, 196\u2013206.","journal-title":"Topics in Catalysis"},{"key":"106_CR54","doi-asserted-by":"publisher","first-page":"2697","DOI":"10.1021\/ja00789a055","volume":"95","author":"KB Sharpless","year":"1973","unstructured":"Sharpless, K. B., & Lauer, R. F. (1973). Mild procedure for the conversion of epoxides to allylic alcohols. First organoselenium reagent. Journal of the American Chemical Society, 95, 2697\u20132699.","journal-title":"Journal of the American Chemical Society"},{"key":"106_CR55","doi-asserted-by":"publisher","first-page":"1685","DOI":"10.1021\/tx7001433","volume":"20","author":"KV Petrova","year":"2007","unstructured":"Petrova, K. V., Jalluri, R. S., Kozekov, I. D., & Rizzo, C. J. (2007). Mechanism of 1, N2-etheno-2\u2032-deoxyguanosine formation from epoxyaldehydes. Chemical Research in Toxicology, 20, 1685\u20131692.","journal-title":"Chemical Research in Toxicology"},{"key":"106_CR56","doi-asserted-by":"publisher","first-page":"12108","DOI":"10.1021\/ja5060884","volume":"136","author":"CCH Atienza","year":"2014","unstructured":"Atienza, C. C. H., Diao, T., Weller, K. J., Nye, S. A., Lewis, K. M., Delis, J. G. P., Boyer, J. L., Roy, A. K., & Chirik, P. J. (2014). Bis(imino)pyridine cobalt-catalyzed dehydrogenative silylation of alkenes: Scope, mechanism, and origins of selective allylsilane formation. Journal of the American Chemical Society, 136, 12108\u201312118.","journal-title":"Journal of the American Chemical Society"},{"key":"106_CR57","doi-asserted-by":"publisher","first-page":"3034","DOI":"10.1021\/acssuschemeng.8b04643","volume":"7","author":"R Lebeuf","year":"2019","unstructured":"Lebeuf, R., & Nardello-Rataj, V. (2019). Dual catalytic role of molybdate ions for direct conversion of photo-oxidized fatty acid methyl esters into keto or hydroxy derivatives. ACS Sustainable Chemistry and Engineering, 7, 3034\u20133041.","journal-title":"ACS Sustainable Chemistry and Engineering"},{"key":"106_CR58","doi-asserted-by":"publisher","first-page":"4501","DOI":"10.1021\/ol0358206","volume":"5","author":"GK Dewkar","year":"2003","unstructured":"Dewkar, G. K., Narina, S. V., & Sudalai, A. (2003). NaIO4-mediated selective oxidative halogenation of alkenes and aromatics using alkali metal halides. Organic Letters, 5, 4501\u20134504.","journal-title":"Organic Letters"},{"key":"106_CR59","doi-asserted-by":"publisher","first-page":"631","DOI":"10.1021\/acsearthspacechem.0c00023","volume":"4","author":"B You","year":"2020","unstructured":"You, B., Li, S., Tsona, N. T., Li, J., Xu, L., Yang, Z., Cheng, S., Chen, Q., George, C., Ge, M., & Du, L. (2020). Environmental processing of short-chain fatty alcohols induced by photosensitized chemistry of brown carbons. ACS Earth and Space Chemistry, 4, 631\u2013640.","journal-title":"ACS Earth and Space Chemistry"},{"key":"106_CR60","doi-asserted-by":"publisher","first-page":"1785","DOI":"10.1002\/cssc.201903549","volume":"13","author":"D Jiang","year":"2020","unstructured":"Jiang, D., Hu, W., Chen, M., Fu, Z., Su, A., Yang, B., Mao, F., Zhang, C., Liu, Y., & Yin, D. (2020). Visible-light-triggered quantitative oxidation of 9,10-dihydroanthracene to anthraquinone by O2 under mild conditions. Chemsuschem, 13, 1785\u20131792.","journal-title":"Chemsuschem"},{"key":"106_CR61","doi-asserted-by":"publisher","first-page":"7535","DOI":"10.1021\/acscatal.0c01515","volume":"10","author":"K Raghuvanshi","year":"2020","unstructured":"Raghuvanshi, K., Zhu, C., Ramezani, M., Menegatti, S., Santiso, E. E., Mason, D., Rodgers, J., Janka, M. E., & Abolhasani, M. (2020). Highly efficient 1-octene hydroformylation at low syngas pressure: From single-droplet screening to continuous flow synthesis. ACS Catalysis, 10, 7535\u20137542.","journal-title":"ACS Catalysis"},{"key":"106_CR62","doi-asserted-by":"publisher","first-page":"254","DOI":"10.1002\/aoc.3281","volume":"29","author":"A Wusimana","year":"2015","unstructured":"Wusimana, A., & Lu, C.-D. (2015). Selective oxidation of benzylic, allylic and propargylic alcohols using dirhodium(II) tetraamidinate as catalyst and aqueous tert-butyl hydroperoxide as oxidant. Applied Organometallic Chemistry, 29, 254\u2013258.","journal-title":"Applied Organometallic Chemistry"},{"key":"106_CR63","doi-asserted-by":"publisher","first-page":"8893","DOI":"10.1021\/acs.orglett.9b02987","volume":"21","author":"M Ju","year":"2019","unstructured":"Ju, M., Guan, W., Schomaker, J. M., & Harper, K. C. (2019). Sequential reduction of nitroalkanes mediated by CS2 and amidine\/guanidine bases: A controllable Nef reaction. Organic Letters, 21, 8893\u20138898.","journal-title":"Organic Letters"},{"key":"106_CR64","doi-asserted-by":"publisher","first-page":"12440","DOI":"10.1021\/ja0529687","volume":"127","author":"M-C Lacasse","year":"2005","unstructured":"Lacasse, M.-C., Poulard, C., & Charette, A. B. (2005). Iodomethylzinc phosphates: powerful reagents for the cyclopropanation of alkenes. Journal of the American Chemical Society, 127, 12440\u201312441.","journal-title":"Journal of the American Chemical Society"},{"key":"106_CR65","doi-asserted-by":"publisher","first-page":"2313","DOI":"10.1080\/00397911.2020.1771370","volume":"50","author":"A Kumari","year":"2020","unstructured":"Kumari, A., Singh, S. K., Singh, R. B., Bhunia, S., & Ghosh, P. (2020). A concise synthesis of 2-benzoyl-1-indanones and 1-indanones from 2-aryl-1-tetralones. Synthetic Communications, 50, 2313\u20132318.","journal-title":"Synthetic Communications"},{"key":"106_CR66","doi-asserted-by":"publisher","first-page":"834","DOI":"10.1002\/1521-3773(20020301)41:5<834::AID-ANIE834>3.0.CO;2-V","volume":"41","author":"KC Nicolaou","year":"2002","unstructured":"Nicolaou, K. C., Huang, X., Snyder, S. A., Rao, P. B., Bella, M., & Reddy, M. V. (2002). A novel regio- and stereoselective synthesis of sulfamidates from 1,2-diols using burgess and related reagents: A facile entry into \u03b2-amino alcohols. Angewandte Chemie International Edition, 41, 834\u2013838.","journal-title":"Angewandte Chemie International Edition"},{"key":"106_CR67","doi-asserted-by":"publisher","first-page":"912","DOI":"10.1111\/php.12716","volume":"93","author":"MS Baptista","year":"2017","unstructured":"Baptista, M. S., Cadet, J., Di Mascio, P., Ghogare, A. A., Greer, A., Hamblin, M. R., Lorente, C., Nunez, S. C., Ribeiro, M. S., Thomas, A. H., Vignoni, M., & Yoshimura, T. M. (2017). Type I and type II photosensitized oxidation reactions: Guidelines and mechanistic pathways. Photochemistry and Photobiology, 93, 912\u2013919.","journal-title":"Photochemistry and Photobiology"},{"key":"106_CR68","doi-asserted-by":"publisher","first-page":"4339","DOI":"10.1021\/ja00820a056","volume":"96","author":"PA Burns","year":"1974","unstructured":"Burns, P. A., & Foote, C. S. (1974). Chemistry of singlet oxygen. XIX. Dioxetanes from indene derivatives. Journal of the American Chemical Society, 96, 4339\u20134340.","journal-title":"Journal of the American Chemical Society"},{"key":"106_CR69","doi-asserted-by":"publisher","first-page":"899","DOI":"10.1021\/jo00868a001","volume":"41","author":"PA Burns","year":"1976","unstructured":"Burns, P. A., Foote, C. S., & Mazur, S. (1976). Chemistry of singlet oxygen. XXIII. Low temperature photooxygenation of indene in aprotic solvent. Journal of Organic Chemistry, 41, 899\u2013907.","journal-title":"Journal of Organic Chemistry"},{"key":"106_CR70","doi-asserted-by":"publisher","first-page":"3945","DOI":"10.1021\/ja00819a035","volume":"96","author":"NR Easton Jr","year":"1974","unstructured":"Easton, N. R., Jr., Anet, F. A. L., Burns, P. A., & Foote, C. S. (1974). Carbon-13 nuclear magnetic resonance studies on polyepoxides derived from singlet oxygen addition to indene. Journal of the American Chemical Society, 96, 3945\u20133948.","journal-title":"Journal of the American Chemical Society"}],"container-title":["Photochemical &amp; Photobiological Sciences"],"original-title":[],"language":"en","link":[{"URL":"https:\/\/link.springer.com\/content\/pdf\/10.1007\/s43630-021-00106-x.pdf","content-type":"application\/pdf","content-version":"vor","intended-application":"text-mining"},{"URL":"https:\/\/link.springer.com\/article\/10.1007\/s43630-021-00106-x\/fulltext.html","content-type":"text\/html","content-version":"vor","intended-application":"text-mining"},{"URL":"https:\/\/link.springer.com\/content\/pdf\/10.1007\/s43630-021-00106-x.pdf","content-type":"application\/pdf","content-version":"vor","intended-application":"similarity-checking"}],"deposited":{"date-parts":[[2022,6,8]],"date-time":"2022-06-08T13:11:19Z","timestamp":1654693879000},"score":1,"resource":{"primary":{"URL":"https:\/\/link.springer.com\/10.1007\/s43630-021-00106-x"}},"subtitle":[],"short-title":[],"issued":{"date-parts":[[2021,10,6]]},"references-count":70,"journal-issue":{"issue":"5","published-print":{"date-parts":[[2022,5]]}},"alternative-id":["106"],"URL":"https:\/\/doi.org\/10.1007\/s43630-021-00106-x","relation":{},"ISSN":["1474-9092"],"issn-type":[{"value":"1474-9092","type":"electronic"}],"subject":[],"published":{"date-parts":[[2021,10,6]]},"assertion":[{"value":"12 July 2021","order":1,"name":"received","label":"Received","group":{"name":"ArticleHistory","label":"Article History"}},{"value":"16 September 2021","order":2,"name":"accepted","label":"Accepted","group":{"name":"ArticleHistory","label":"Article History"}},{"value":"6 October 2021","order":3,"name":"first_online","label":"First Online","group":{"name":"ArticleHistory","label":"Article History"}},{"order":1,"name":"Ethics","group":{"name":"EthicsHeading","label":"Declarations"}},{"value":"The authors declare no competing financial interest.","order":2,"name":"Ethics","group":{"name":"EthicsHeading","label":"Conflict of interest"}}]}}