{"status":"ok","message-type":"work","message-version":"1.0.0","message":{"indexed":{"date-parts":[[2026,4,1]],"date-time":"2026-04-01T13:31:35Z","timestamp":1775050295693,"version":"3.50.1"},"reference-count":41,"publisher":"Springer Science and Business Media LLC","issue":"3","license":[{"start":{"date-parts":[[2016,9,29]],"date-time":"2016-09-29T00:00:00Z","timestamp":1475107200000},"content-version":"unspecified","delay-in-days":0,"URL":"http:\/\/www.springer.com\/tdm"}],"funder":[{"DOI":"10.13039\/501100001871","name":"Funda\u00e7\u00e3o para a Ci\u00eancia e a Tecnologia","doi-asserted-by":"publisher","award":["SFRH\/BPD\/99982\/2014"],"award-info":[{"award-number":["SFRH\/BPD\/99982\/2014"]}],"id":[{"id":"10.13039\/501100001871","id-type":"DOI","asserted-by":"publisher"}]}],"content-domain":{"domain":["link.springer.com"],"crossmark-restriction":false},"short-container-title":["J Mater Sci"],"published-print":{"date-parts":[[2017,2]]},"DOI":"10.1007\/s10853-016-0422-6","type":"journal-article","created":{"date-parts":[[2016,9,29]],"date-time":"2016-09-29T11:38:15Z","timestamp":1475149095000},"page":"1272-1284","update-policy":"https:\/\/doi.org\/10.1007\/springer_crossmark_policy","source":"Crossref","is-referenced-by-count":12,"title":["The impact of a designed lactic acid-based crosslinker in the thermochemical properties of unsaturated polyester resins\/nanoprecipitated calcium carbonate composites"],"prefix":"10.1007","volume":"52","author":[{"ORCID":"https:\/\/orcid.org\/0000-0002-7145-2472","authenticated-orcid":false,"given":"Ana C.","family":"Fonseca","sequence":"first","affiliation":[]},{"given":"C\u00e1tia S. M. F.","family":"Costa","sequence":"additional","affiliation":[]},{"given":"Teresa M. P.","family":"Marques","sequence":"additional","affiliation":[]},{"given":"Jorge F. J.","family":"Coelho","sequence":"additional","affiliation":[]},{"given":"Arm\u00e9nio C.","family":"Serra","sequence":"additional","affiliation":[]}],"member":"297","published-online":{"date-parts":[[2016,9,29]]},"reference":[{"issue":"2","key":"422_CR1","doi-asserted-by":"publisher","first-page":"233","DOI":"10.1007\/s13204-013-0193-1","volume":"4","author":"Y Jaya Vinse Ruban","year":"2014","unstructured":"Jaya Vinse Ruban Y, Ginil Mon S, Vetha Roy D (2014) Chemical resistance\/thermal and mechanical properties of unsaturated polyester-based nanocomposites. Appl Nanosci 4(2):233\u2013240. doi: 10.1007\/s13204-013-0193-1","journal-title":"Appl Nanosci"},{"issue":"5","key":"422_CR2","doi-asserted-by":"publisher","first-page":"629","DOI":"10.1002\/pc.20597","volume":"30","author":"MH Beheshty","year":"2009","unstructured":"Beheshty MH, Vafayan M, Poorabdollah M (2009) Low profile unsaturated polyester resin\u2013clay nanocomposite properties. Polym Compos 30(5):629\u2013638. doi: 10.1002\/pc.20597","journal-title":"Polym Compos"},{"issue":"2","key":"422_CR3","doi-asserted-by":"publisher","first-page":"510","DOI":"10.1016\/j.msec.2008.09.020","volume":"29","author":"MA Farias de","year":"2009","unstructured":"de Farias MA, Farina MZ, Pezzin APT, Silva DAK (2009) Unsaturated polyester composites reinforced with fiber and powder of peach palm: mechanical characterization and water absorption profile. Mater Sci Eng, C 29(2):510\u2013513. doi: 10.1016\/j.msec.2008.09.020","journal-title":"Mater Sci Eng, C"},{"issue":"3","key":"422_CR4","doi-asserted-by":"crossref","first-page":"035024","DOI":"10.1088\/1758-5082\/6\/3\/035024","volume":"6","author":"FAMM Gon\u00e7alves","year":"2014","unstructured":"Gon\u00e7alves FAMM, Costa CSMF, Fabela IGP, Farinha D, Faneca H, Sim\u00f5es PN et al (2014) 3D printing of new biobased unsaturated polyesters by microstereo-thermal-lithography. Biofabrication. 6(3):035024","journal-title":"Biofabrication."},{"key":"422_CR5","doi-asserted-by":"publisher","first-page":"1","DOI":"10.1016\/j.reactfunctpolym.2015.10.002","volume":"97","author":"AC Fonseca","year":"2015","unstructured":"Fonseca AC, Lopes IM, Coelho JFJ, Serra AC (2015) Synthesis of unsaturated polyesters based on renewable monomers: structure\/properties relationship and crosslinking with 2-hydroxyethyl methacrylate. React Funct Polym 97:1\u201311. doi: 10.1016\/j.reactfunctpolym.2015.10.002","journal-title":"React Funct Polym"},{"issue":"5","key":"422_CR6","doi-asserted-by":"publisher","first-page":"1049","DOI":"10.1039\/C5PY01702E","volume":"7","author":"AF Sousa","year":"2016","unstructured":"Sousa AF, Fonseca AC, Serra AC, Freire CSR, Silvestre AJD, Coelho JFJ (2016) New unsaturated copolyesters based on 2,5-furandicarboxylic acid and their crosslinked derivatives. Polym Chem 7(5):1049\u20131058. doi: 10.1039\/C5PY01702E","journal-title":"Polym Chem"},{"issue":"5","key":"422_CR7","doi-asserted-by":"publisher","first-page":"709","DOI":"10.1002\/pi.4443","volume":"62","author":"O Goerz","year":"2013","unstructured":"Goerz O, Ritter H (2013) Polymers with shape memory effect from renewable resources: crosslinking of polyesters based on isosorbide, itaconic acid and succinic acid. Polym Int 62(5):709\u2013712. doi: 10.1002\/pi.4443","journal-title":"Polym Int"},{"issue":"23","key":"422_CR8","doi-asserted-by":"publisher","first-page":"9660","DOI":"10.1021\/ma1015424","volume":"43","author":"DG Barrett","year":"2010","unstructured":"Barrett DG, Merkel TJ, Luft JC, Yousaf MN (2010) One-step syntheses of photocurable polyesters based on a renewable resource. Macromolecules 43(23):9660\u20139667. doi: 10.1021\/ma1015424","journal-title":"Macromolecules"},{"issue":"8","key":"422_CR9","doi-asserted-by":"publisher","first-page":"43052","DOI":"10.1002\/app.43052","volume":"133","author":"Y Wu","year":"2016","unstructured":"Wu Y, Li K (2016) Replacement of styrene with acrylated epoxidized soybean oil in an unsaturated polyester resin from propylene glycol, isophthalic acid, and maleic anhydride. J Appl Polym Sci 133(8):43052. doi: 10.1002\/app.43052","journal-title":"J Appl Polym Sci"},{"issue":"4","key":"422_CR10","doi-asserted-by":"publisher","first-page":"2383","DOI":"10.1039\/C4GC02057J","volume":"17","author":"J Dai","year":"2015","unstructured":"Dai J, Ma S, Wu Y, Han L, Zhang L, Zhu J et al (2015) Polyesters derived from itaconic acid for the properties and bio-based content enhancement of soybean oil-based thermosets. Green Chem 17(4):2383\u20132392. doi: 10.1039\/C4GC02057J","journal-title":"Green Chem"},{"issue":"22","key":"422_CR11","doi-asserted-by":"publisher","first-page":"7729","DOI":"10.1016\/j.polymer.2004.08.056","volume":"45","author":"JJ Scala La","year":"2004","unstructured":"La Scala JJ, Sands JM, Orlicki JA, Robinette EJ, Palmese GR (2004) Fatty acid-based monomers as styrene replacements for liquid molding resins. Polymer 45(22):7729\u20137737. doi: 10.1016\/j.polymer.2004.08.056","journal-title":"Polymer"},{"key":"422_CR12","doi-asserted-by":"publisher","first-page":"539","DOI":"10.1016\/j.eurpolymj.2015.02.016","volume":"67","author":"S Cousinet","year":"2015","unstructured":"Cousinet S, Ghadban A, Fleury E, Lortie F, Pascault J-P, Portinha D (2015) Toward replacement of styrene by bio-based methacrylates in unsaturated polyester resins. Eur Polym J 67:539\u2013550. doi: 10.1016\/j.eurpolymj.2015.02.016","journal-title":"Eur Polym J"},{"issue":"2","key":"422_CR13","doi-asserted-by":"publisher","first-page":"362","DOI":"10.1080\/15583724.2015.1108334","volume":"56","author":"CSMF Costa","year":"2016","unstructured":"Costa CSMF, Fonseca AC, Serra AC, Coelho JFJ (2016) Dynamic mechanical thermal analysis of polymer composites reinforced with natural fibers. Polym Rev 56(2):362\u2013383. doi: 10.1080\/15583724.2015.1108334","journal-title":"Polym Rev"},{"issue":"24","key":"422_CR14","doi-asserted-by":"publisher","first-page":"8557","DOI":"10.1016\/S0032-3861(00)00216-0","volume":"41","author":"DJ Suh","year":"2000","unstructured":"Suh DJ, Lim YT, Park OO (2000) The property and formation mechanism of unsaturated polyester\u2013layered silicate nanocomposite depending on the fabrication methods. Polymer 41(24):8557\u20138563. doi: 10.1016\/S0032-3861(00)00216-0","journal-title":"Polymer"},{"issue":"10","key":"422_CR15","doi-asserted-by":"publisher","first-page":"3146","DOI":"10.1016\/j.eurpolymj.2008.07.027","volume":"44","author":"V Morote-Mart\u00ednez","year":"2008","unstructured":"Morote-Mart\u00ednez V, Pascual-S\u00e1nchez V, Mart\u00edn-Mart\u00ednez JM (2008) Improvement in mechanical and structural integrity of natural stone by applying unsaturated polyester resin-nanosilica hybrid thin coating. Eur Polym J 44(10):3146\u20133155. doi: 10.1016\/j.eurpolymj.2008.07.027","journal-title":"Eur Polym J"},{"issue":"6","key":"422_CR16","doi-asserted-by":"publisher","first-page":"3432","DOI":"10.1002\/app.39068","volume":"129","author":"C Bora","year":"2013","unstructured":"Bora C, Gogoi P, Baglari S, Dolui SK (2013) Preparation of polyester resin\/graphene oxide nanocomposite with improved mechanical strength. J Appl Polym Sci 129(6):3432\u20133438. doi: 10.1002\/app.39068","journal-title":"J Appl Polym Sci"},{"issue":"10","key":"422_CR17","doi-asserted-by":"publisher","first-page":"611","DOI":"10.3144\/expresspolymlett.2010.76","volume":"4","author":"MYA Fuad","year":"2010","unstructured":"Fuad MYA, Hanim H, Zarina R, Ishak ZAM, Hassan A (2010) Polypropylene\/calcium carbonate nanocomposites\u2014effects of processing techniques and maleated polypropylene compatibiliser. EXPRESS Polym Lett 4(10):611\u2013620. doi: 10.3144\/expresspolymlett.2010.76","journal-title":"EXPRESS Polym Lett"},{"issue":"2","key":"422_CR18","doi-asserted-by":"publisher","first-page":"123","DOI":"10.1177\/0892705707083634","volume":"21","author":"H Hanim","year":"2008","unstructured":"Hanim H, Fuad MYA, Zarina R, Ishak ZAM, Hassan A (2008) Properties and structure of polypropylene\/polyethylene-octene elastomer\/nano CaCO3 composites. J Thermoplast Compos Mater 21(2):123\u2013140. doi: 10.1177\/0892705707083634","journal-title":"J Thermoplast Compos Mater"},{"issue":"16","key":"422_CR19","doi-asserted-by":"publisher","first-page":"4066","DOI":"10.1016\/j.polymer.2009.06.028","volume":"50","author":"I Kemal","year":"2009","unstructured":"Kemal I, Whittle A, Burford R, Vodenitcharova T, Hoffman M (2009) Toughening of unmodified polyvinylchloride through the addition of nanoparticulate calcium carbonate. Polymer 50(16):4066\u20134079. doi: 10.1016\/j.polymer.2009.06.028","journal-title":"Polymer"},{"key":"422_CR20","doi-asserted-by":"publisher","first-page":"11","DOI":"10.1155\/2015\/905210","volume":"2015","author":"X Shi","year":"2015","unstructured":"Shi X, Zhang G, Siligardi C, Ori G, Lazzeri A (2015) Comparison of precipitated calcium carbonate\/polylactic acid and halloysite\/polylactic acid nanocomposites. J Nanomater 2015:11. doi: 10.1155\/2015\/905210","journal-title":"J Nanomater"},{"issue":"5","key":"422_CR21","doi-asserted-by":"publisher","first-page":"3087","DOI":"10.1002\/app.28229","volume":"109","author":"H-S Kim","year":"2008","unstructured":"Kim H-S, Park BH, Choi JH, Yoon J-S (2008) Mechanical properties and thermal stability of poly(l-lactide)\/calcium carbonate composites. J Appl Polym Sci 109(5):3087\u20133092. doi: 10.1002\/app.28229","journal-title":"J Appl Polym Sci"},{"issue":"6","key":"422_CR22","doi-asserted-by":"publisher","first-page":"503","DOI":"10.3144\/expresspolymlett.2012.53","volume":"6","author":"WS Chow","year":"2012","unstructured":"Chow WS, Leu YY, Ishak ZAM (2012) Effects of SEBS-g-MAH on the properties of injection moulded poly(lactic acid)\/nano-calcium carbonate composites. EXPRESS Polym Lett 6(6):503\u2013510. doi: 10.3144\/expresspolymlett.2012.53","journal-title":"EXPRESS Polym Lett"},{"issue":"5","key":"422_CR23","doi-asserted-by":"publisher","first-page":"736","DOI":"10.1002\/pi.4356","volume":"62","author":"AC Fonseca","year":"2013","unstructured":"Fonseca AC, Serra AC, Coelho JFJ, Gil MH, Sim\u00f5es PN (2013) Novel poly(ester amide)s from glycine and l-lactic acid by an easy and cost-effective synthesis. Polym Int 62(5):736\u2013743. doi: 10.1002\/pi.4356","journal-title":"Polym Int"},{"issue":"12","key":"422_CR24","doi-asserted-by":"publisher","first-page":"3085","DOI":"10.1007\/s00289-014-1239-6","volume":"71","author":"AC Fonseca","year":"2014","unstructured":"Fonseca AC, Coelho JFJ, Gil MH, Sim\u00f5es PN (2014) Poly(ester amide)s based on l-lactic acid oligomers and glycine: the role of the central unit of the l-lactic acid oligomers and their molecular weight in the poly(ester amide)s properties. Polym Bull 71(12):3085\u20133109. doi: 10.1007\/s00289-014-1239-6","journal-title":"Polym Bull"},{"issue":"2","key":"422_CR25","doi-asserted-by":"publisher","first-page":"422","DOI":"10.1016\/j.polymer.2007.11.038","volume":"49","author":"AJ Ro","year":"2008","unstructured":"Ro AJ, Huang SJ, Weiss RA (2008) Synthesis and thermal properties of telechelic poly(lactic acid) ionomers. Polymer 49(2):422\u2013431. doi: 10.1016\/j.polymer.2007.11.038","journal-title":"Polymer"},{"issue":"6","key":"422_CR26","doi-asserted-by":"publisher","first-page":"573","DOI":"10.1080\/03602559.2010.543740","volume":"50","author":"AH Mahmoud","year":"2011","unstructured":"Mahmoud AH, Tay GS, Rozman HD (2011) A preliminary study on ultraviolet radiation-cured unsaturated polyester resin based on palm oil. Polym Plast Technol Eng 50(6):573\u2013580. doi: 10.1080\/03602559.2010.543740","journal-title":"Polym Plast Technol Eng"},{"issue":"3","key":"422_CR27","doi-asserted-by":"publisher","first-page":"306","DOI":"10.1002\/bbb.1468","volume":"8","author":"PFH Harmsen","year":"2014","unstructured":"Harmsen PFH, Hackmann MM, Bos HL (2014) Green building blocks for bio-based plastics. Biofuel Bioprod Biorefin 8(3):306\u2013324. doi: 10.1002\/bbb.1468","journal-title":"Biofuel Bioprod Biorefin"},{"key":"422_CR28","unstructured":"Jong Ed, Walsh P, Wellisch M (2012) Bio-based chemicals: value added products from biorefineries. Report produced on behalf of IEA Bioenergy - Task42 Biorefinery"},{"issue":"16","key":"422_CR29","doi-asserted-by":"publisher","first-page":"2549","DOI":"10.1002\/pola.10797","volume":"41","author":"N Bicak","year":"2003","unstructured":"Bicak N, Karagoz B, Tunca U (2003) Self-curable polyester by a reaction of glycidol with maleic anhydride. J Polym Sci Part A Polym Chem 41(16):2549\u20132555. doi: 10.1002\/pola.10797","journal-title":"J Polym Sci Part A Polym Chem"},{"issue":"9","key":"422_CR30","doi-asserted-by":"publisher","first-page":"3119","DOI":"10.1039\/C3PY01213A","volume":"5","author":"C Vilela","year":"2014","unstructured":"Vilela C, Sousa AF, Fonseca AC, Serra AC, Coelho JFJ, Freire CSR et al (2014) The quest for sustainable polyesters\u2014insights into the future. Polym Chem 5(9):3119\u20133141. doi: 10.1039\/C3PY01213A","journal-title":"Polym Chem"},{"issue":"7","key":"422_CR31","doi-asserted-by":"publisher","first-page":"14912","DOI":"10.3390\/ijms160714912","volume":"16","author":"TJ Farmer","year":"2015","unstructured":"Farmer TJ, Castle RL, Clark JH, Macquarrie DJ (2015) Synthesis of unsaturated polyester resins from various bio-derived platform molecules. Int J Mol Sci 16(7):14912\u201314932. doi: 10.3390\/ijms160714912","journal-title":"Int J Mol Sci"},{"issue":"3","key":"422_CR32","doi-asserted-by":"publisher","first-page":"246","DOI":"10.1002\/pi.4980090315","volume":"9","author":"JMG Cowie","year":"1977","unstructured":"Cowie JMG, Haq Z (1977) Some aspects of the thermal stability of poly(alkyl itaconic acid esters). Br Polym J 9(3):246\u2013250. doi: 10.1002\/pi.4980090315","journal-title":"Br Polym J"},{"issue":"14","key":"422_CR33","doi-asserted-by":"publisher","first-page":"3119","DOI":"10.1016\/j.polymer.2009.05.012","volume":"50","author":"S Shang","year":"2009","unstructured":"Shang S, Huang SJ, Weiss RA (2009) Synthesis and characterization of itaconic anhydride and stearyl methacrylate copolymers. Polymer 50(14):3119\u20133127. doi: 10.1016\/j.polymer.2009.05.012","journal-title":"Polymer"},{"issue":"13","key":"422_CR34","doi-asserted-by":"publisher","first-page":"2885","DOI":"10.1002\/pola.24067","volume":"48","author":"L Jasinska","year":"2010","unstructured":"Jasinska L, Koning CE (2010) Unsaturated, biobased polyesters and their cross-linking via radical copolymerization. J Polym Sci Part A Polym Chem 48(13):2885\u20132895. doi: 10.1002\/pola.24067","journal-title":"J Polym Sci Part A Polym Chem"},{"issue":"4","key":"422_CR35","doi-asserted-by":"publisher","first-page":"790","DOI":"10.1016\/j.porgcoat.2014.01.005","volume":"77","author":"I Barata","year":"2014","unstructured":"Barata I, Fonseca AC, Costa CSMF, Ferreira L, J\u00falio E, Coelho JFJ (2014) Insights into the thermo-mechanical properties of films cast from emulsion terpolymers. Prog Org Coat 77(4):790\u2013797. doi: 10.1016\/j.porgcoat.2014.01.005","journal-title":"Prog Org Coat"},{"issue":"3\u20134","key":"422_CR36","first-page":"69","volume":"34","author":"IM Kalogeras","year":"2012","unstructured":"Kalogeras IM, Lobland HEH (2012) The nature of the glassy state: structure and glass transitions. J Mater Educ 34(3\u20134):69\u201394","journal-title":"J Mater Educ"},{"issue":"9","key":"422_CR37","doi-asserted-by":"publisher","first-page":"2422","DOI":"10.1557\/jmr.2006.0300","volume":"21","author":"W Brostow","year":"2006","unstructured":"Brostow W, Lobland HEH, Narkis M (2006) Sliding wear, viscoelasticity, and brittleness of polymers. J Mater Res 21(9):2422\u20132428. doi: 10.1557\/jmr.2006.0300","journal-title":"J Mater Res"},{"issue":"13","key":"422_CR38","doi-asserted-by":"publisher","first-page":"2187","DOI":"10.1016\/j.compscitech.2005.12.010","volume":"66","author":"L Petersson","year":"2006","unstructured":"Petersson L, Oksman K (2006) Biopolymer based nanocomposites: comparing layered silicates and microcrystalline cellulose as nanoreinforcement. Compos Sci Technol 66(13):2187\u20132196. doi: 10.1016\/j.compscitech.2005.12.010","journal-title":"Compos Sci Technol"},{"issue":"2","key":"422_CR39","doi-asserted-by":"publisher","first-page":"765","DOI":"10.1016\/S0032-3861(99)00184-6","volume":"41","author":"EMS Sanchez","year":"2000","unstructured":"Sanchez EMS, Zavaglia CAC, Felisberti MI (2000) Unsaturated polyester resins: influence of the styrene concentration on the miscibility and mechanical properties. Polymer 41(2):765\u2013769. doi: 10.1016\/S0032-3861(99)00184-6","journal-title":"Polymer"},{"key":"422_CR40","doi-asserted-by":"publisher","unstructured":"Melot D, Escaig B, Lefebvre JM, Eustache RP, Laupr\u00eatre F (1994) Mechanical properties of unsaturated polyester resins in relation to their chemical structure I. Secondary relaxations and local motions. J Polym Sci Part B Polym Phys. 32(2):249\u201360. doi: 10.1002\/polb.1994.090320206","DOI":"10.1002\/polb.1994.090320206"},{"issue":"1\u20132","key":"422_CR41","doi-asserted-by":"publisher","first-page":"129","DOI":"10.1016\/j.tca.2010.08.004","volume":"511","author":"GZ Papageorgiou","year":"2010","unstructured":"Papageorgiou GZ, Achilias DS, Nanaki S, Beslikas T, Bikiaris D (2010) PLA nanocomposites: effect of filler type on non-isothermal crystallization. Thermochim Acta 511(1\u20132):129\u2013139. doi: 10.1016\/j.tca.2010.08.004","journal-title":"Thermochim Acta"}],"container-title":["Journal of Materials Science"],"original-title":[],"language":"en","link":[{"URL":"http:\/\/link.springer.com\/content\/pdf\/10.1007\/s10853-016-0422-6.pdf","content-type":"application\/pdf","content-version":"vor","intended-application":"text-mining"},{"URL":"http:\/\/link.springer.com\/article\/10.1007\/s10853-016-0422-6\/fulltext.html","content-type":"text\/html","content-version":"vor","intended-application":"text-mining"},{"URL":"http:\/\/link.springer.com\/content\/pdf\/10.1007\/s10853-016-0422-6.pdf","content-type":"application\/pdf","content-version":"vor","intended-application":"similarity-checking"}],"deposited":{"date-parts":[[2017,6,24]],"date-time":"2017-06-24T19:58:39Z","timestamp":1498334319000},"score":1,"resource":{"primary":{"URL":"http:\/\/link.springer.com\/10.1007\/s10853-016-0422-6"}},"subtitle":[],"short-title":[],"issued":{"date-parts":[[2016,9,29]]},"references-count":41,"journal-issue":{"issue":"3","published-print":{"date-parts":[[2017,2]]}},"alternative-id":["422"],"URL":"https:\/\/doi.org\/10.1007\/s10853-016-0422-6","relation":{},"ISSN":["0022-2461","1573-4803"],"issn-type":[{"value":"0022-2461","type":"print"},{"value":"1573-4803","type":"electronic"}],"subject":[],"published":{"date-parts":[[2016,9,29]]}}}