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Nevertheless, some challenges remained to be addressed in the latter devices, the most critical one being the poor solubility of PMMA in the ionic liquid used in the formulation of these materials. To avoid this drawback, in the present work we propose novel lanthanide-containing acrylate\/ionosilicas (AC\/IS-Ln, Ln\u2009=\u2009Tb<jats:sup>3+<\/jats:sup>, Eu<jats:sup>3+<\/jats:sup>). The transparent, homogeneous, and luminescent hybrid materials synthesized are characterized by Fourier transform infrared spectroscopy, X-ray diffraction, thermogravimetric analysis, atomic force microscopy, contact angle measurements, ionic conductivity, and photoluminescence spectroscopy. Optimized samples are successfully employed as electrolytes in luminescent ECD prototypes. The ECD device doped with AC\/IS-Eu shows good cycling stability with reproducible bleaching\/coloring over 50 chronoamperometry cycles, high coloration efficiency (CE) values CE<jats:sub>in<\/jats:sub>\/CE<jats:sub>out<\/jats:sub> in the visible (\u221289\/+98\u2009cm<jats:sup>2<\/jats:sup>\u2009C<jats:sup>\u22121<\/jats:sup>), and near-infrared (\u2212126\/138\u2009cm<jats:sup>2<\/jats:sup>\u2009C<jats:sup>\u22121<\/jats:sup>) spectral regions, and outstanding memory effect.<\/jats:p>\n          <jats:p>\n            <jats:bold>Graphical Abstract<\/jats:bold>\n          <\/jats:p>","DOI":"10.1007\/s10971-024-06342-8","type":"journal-article","created":{"date-parts":[[2024,2,27]],"date-time":"2024-02-27T10:02:13Z","timestamp":1709028133000},"page":"148-163","update-policy":"https:\/\/doi.org\/10.1007\/springer_crossmark_policy","source":"Crossref","is-referenced-by-count":2,"title":["Electrochromic windows based on luminescent acrylate\/ionosilicas"],"prefix":"10.1007","volume":"114","author":[{"given":"Daniela","family":"Pinheiro","sequence":"first","affiliation":[]},{"given":"Rui F. 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