{"status":"ok","message-type":"work","message-version":"1.0.0","message":{"indexed":{"date-parts":[[2026,1,10]],"date-time":"2026-01-10T08:26:23Z","timestamp":1768033583675,"version":"3.49.0"},"reference-count":64,"publisher":"Springer Science and Business Media LLC","issue":"5","license":[{"start":{"date-parts":[[2016,12,12]],"date-time":"2016-12-12T00:00:00Z","timestamp":1481500800000},"content-version":"unspecified","delay-in-days":0,"URL":"http:\/\/www.springer.com\/tdm"}],"funder":[{"DOI":"10.13039\/501100001871","name":"Funda\u00e7\u00e3o para a Ci\u00eancia e a Tecnologia","doi-asserted-by":"publisher","award":["SFRH\/BD\/22413\/2005"],"award-info":[{"award-number":["SFRH\/BD\/22413\/2005"]}],"id":[{"id":"10.13039\/501100001871","id-type":"DOI","asserted-by":"publisher"}]}],"content-domain":{"domain":["link.springer.com"],"crossmark-restriction":false},"short-container-title":["Environ Sci Pollut Res"],"published-print":{"date-parts":[[2017,2]]},"DOI":"10.1007\/s11356-016-8161-4","type":"journal-article","created":{"date-parts":[[2016,12,12]],"date-time":"2016-12-12T07:29:02Z","timestamp":1481527742000},"page":"4562-4576","update-policy":"https:\/\/doi.org\/10.1007\/springer_crossmark_policy","source":"Crossref","is-referenced-by-count":29,"title":["Speciation and precipitation of heavy metals in high-metal and high-acid mine waters from the Iberian Pyrite Belt (Portugal)"],"prefix":"10.1007","volume":"24","author":[{"ORCID":"https:\/\/orcid.org\/0000-0003-2834-043X","authenticated-orcid":false,"given":"Nuno","family":"Dur\u00e3es","sequence":"first","affiliation":[]},{"given":"Iuliu","family":"Bobos","sequence":"additional","affiliation":[]},{"given":"Eduardo Ferreira","family":"da Silva","sequence":"additional","affiliation":[]}],"member":"297","published-online":{"date-parts":[[2016,12,12]]},"reference":[{"key":"8161_CR1","series-title":"Rev Econ Geol Vol. 6A","first-page":"289","volume-title":"The environmental geochemistry of mineral deposits, part a: processes, methods, and health issues","author":"CN Alpers","year":"1999","unstructured":"Alpers CN, Nordstrom DK (1999) Geochemical modelling of water-rock interactions in mining environments. In: Plumlee GS, Logsdon MJ (eds) The environmental geochemistry of mineral deposits, part a: processes, methods, and health issues, Rev Econ Geol Vol. 6A. Society of Economic Geology, Littleton, CO, pp. 289\u2013323"},{"key":"8161_CR2","series-title":"ACS Symp Ser. 550","first-page":"324","volume-title":"Environmental geochemistry of sulfide oxidation","author":"CN Alpers","year":"1994","unstructured":"Alpers CN, Nordstrom DK, Thompson JM (1994) Seasonal variations of Zn\/Cu ratios in acid mine water from Iron Mountain, California. In: Alpers CN, Blowes DW (eds) Environmental geochemistry of sulfide oxidation, ACS Symp Ser. 550. American Chemical Society, Washington DC, pp. 324\u2013344"},{"key":"8161_CR3","first-page":"32","volume-title":"Aljustrel e Gavi\u00e3o. I Congresso Hispano-Luso-Americano de Geologia Econ\u00f3mica, Livro-Guia n\u00b04","author":"RFD Andrade","year":"1971","unstructured":"Andrade RFD, Schermerhorn LJG (1971) Aljustrel e Gavi\u00e3o. I Congresso Hispano-Luso-Americano de Geologia Econ\u00f3mica, Livro-Guia n\u00b04. Direc\u00e7\u00e3o-Geral de Minas e Servi\u00e7os Geol\u00f3gicos, Lisboa, pp. 32\u201359"},{"key":"8161_CR4","doi-asserted-by":"crossref","unstructured":"Ball JW, Nordstro, DK (1991) WATEQ4F-User\u2019s manual with revised thermodynamic data base and test cases for calculating speciation of major, trace and redox elements in natural waters. U.S. Geological Survey, Open-File Report 90\u2013129, 185\u00a0pp.","DOI":"10.3133\/ofr90129"},{"key":"8161_CR5","unstructured":"Barriga, FJAS (1983) Hydrothermal metamorphism and ore genesis at Aljustrel, Iberian Pyrite Belt. University of Ontario, Canada, Ph.D. Thesis, 368p"},{"key":"8161_CR6","unstructured":"Barriga FJAS, Carvalho D, Ribeiro A (1997) Introduction to the Iberian Pyrite Belt. In: Barriga FJAS, Carvalho D (eds). Geology and VMS deposits of the Iberian Pyrite Belt. Neves Corvo Field Conference, Guidebook Series, Society of Economic Geologists 27:1\u201320"},{"issue":"3\u20134","key":"8161_CR7","doi-asserted-by":"publisher","first-page":"331","DOI":"10.1016\/0009-2541(88)90044-7","volume":"69","author":"FJAS Barriga","year":"1988","unstructured":"Barriga FJAS, Fyfe WS (1988) Giant pyritic base-metal deposits: the example of Feitais (Aljustrel, Portugal). Chem Geol 69(3\u20134):331\u2013343. doi: 10.1016\/0009-2541(88)90044-7","journal-title":"Chem Geol"},{"key":"8161_CR8","doi-asserted-by":"publisher","first-page":"88","DOI":"10.1007\/s001260050140","volume":"33","author":"FJAS Barriga","year":"1998","unstructured":"Barriga FJAS, Fyfe WS (1998) Multi-phase water-rhyolite interaction and ore fluid generation at Aljustrel, Portugal. Mineral Deposita 33:88\u2013207. doi: 10.1007\/s001260050140","journal-title":"Mineral Deposita"},{"key":"8161_CR9","series-title":"Rev Mineral Geochem Vol. 40","first-page":"351","volume-title":"Sulfate minerals\u2014crystallography, geochemistry, and environmental significance","author":"JM Bigham","year":"2000","unstructured":"Bigham JM, Nordstrom DK (2000) Iron and aluminium hydroxysulfates from acid sulfate waters. In: Alpers CN, Jambor JL, Nordstrom DK (eds) Sulfate minerals\u2014crystallography, geochemistry, and environmental significance, Rev Mineral Geochem Vol. 40. The Mineralogical Society of America and Geochemical Society, Washington, DC, pp. 351\u2013403"},{"key":"8161_CR10","doi-asserted-by":"publisher","first-page":"2111","DOI":"10.1016\/0016-7037(96)00091-9","volume":"60","author":"JM Bigham","year":"1996","unstructured":"Bigham JM, Schwertmann U, Traina SJ, Winland RL, Wolf M (1996) Schwertmannite and the chemical modeling of iron in acid sulfate waters. Geochim Cosmochim Ac 60:2111\u20132121. doi: 10.1016\/0016-7037(96)00091-9","journal-title":"Geochim Cosmochim Ac"},{"key":"8161_CR11","first-page":"337","volume-title":"Mineral spectroscopy: a tribute to Roger G. Burns, special publication","author":"JL Bishop","year":"1996","unstructured":"Bishop JL, Murad E (1996) Schwertmannite on Mars? Spectroscopic analyses of schwertmannite, its relationship to other ferric minerals, and its possible presence in the surface material of Mars. In: Dyar MD, McCammon C, Schaefer MW (eds) Mineral spectroscopy: a tribute to Roger G. Burns, special publication, vol Vol. 5. Geochemical Society, New York, pp. 337\u2013358"},{"key":"8161_CR12","doi-asserted-by":"publisher","first-page":"1","DOI":"10.1016\/j.gexplo.2005.08.004","volume":"88","author":"I Bobos","year":"2006","unstructured":"Bobos I, Dur\u00e3es N, Noronha F (2006) Mineralogy and geochemistry of mill tailings impoundments from Algares (Aljustrel), Portugal: implications for acid sulphate mine waters formation. J Geochem Explor 88:1\u20135. doi: 10.1016\/j.gexplo.2005.08.004","journal-title":"J Geochem Explor"},{"key":"8161_CR13","first-page":"59","volume-title":"Mina de S. Domingos. I Congresso Hispano-Luso-Americano de Geologia Econ\u00f3mica, Livro-Guia n\u00b04","author":"D Carvalho","year":"1971","unstructured":"Carvalho D (1971) Mina de S. Domingos. I Congresso Hispano-Luso-Americano de Geologia Econ\u00f3mica, Livro-Guia n\u00b04. Direc\u00e7\u00e3o-Geral de Minas e Servi\u00e7os Geol\u00f3gicos, Lisboa, pp. 59\u201364"},{"key":"8161_CR14","first-page":"271","volume":"60","author":"D Carvalho","year":"1976","unstructured":"Carvalho D, Conde L, Enrile JH, Oliveira V, Schermerhorn LJGS (1976) Livro\u2013Guia das excurs\u00f5es geol\u00f3gicas na Faixa Piritosa Ib\u00e9rica. Comum Serv Geol Port Tomo 60:271\u2013315","journal-title":"Comum Serv Geol Port Tomo"},{"issue":"2","key":"8161_CR15","doi-asserted-by":"publisher","first-page":"203","DOI":"10.1016\/j.apgeochem.2007.10.003","volume":"23","author":"CA Cravotta","year":"2008","unstructured":"Cravotta CA (2008) Dissolved metals and associated constituents in abandoned coalmine discharges, Pennsylvania, USA. Part 2: geochemical controls on constituent concentrations. Appl Geochem 23(2):203\u2013226. doi: 10.1016\/j.apgeochem.2007.10.003","journal-title":"Appl Geochem"},{"key":"8161_CR16","volume-title":"The geochemistry of natural waters: surface and groundwater environments","author":"JI Drever","year":"1997","unstructured":"Drever JI (1997) The geochemistry of natural waters: surface and groundwater environments, 3rd edn. Prentice-Hall, Upper Saddle River","edition":"3"},{"key":"8161_CR17","unstructured":"Dur\u00e3es N (2011) Geoqu\u00edmica dos metais bivalentes t\u00f3xicos no sistema solos - sedimentos - \u00e1guas - plantas em zonas contaminadas \u00e1ridas e semi-\u00e1ridas. Ph.D. Thesis, Faculdade de Ci\u00eancias da Universidade do Porto, 289\u00a0pp."},{"key":"8161_CR18","volume-title":"Surface complexation modelling: hydrous ferric oxide","author":"DA Dzombak","year":"1990","unstructured":"Dzombak DA, Morel FMM (1990) Surface complexation modelling: hydrous ferric oxide. John Wiley & Sons, New York"},{"key":"8161_CR19","doi-asserted-by":"publisher","first-page":"213","DOI":"10.1002\/ldr.659","volume":"16","author":"E Ferreira da Silva","year":"2005","unstructured":"Ferreira da Silva E, Cardoso Fonseca E, Matos JX, Patinha C, Reis P, Santos Oliveira JM (2005) The effect of unconfined mine tailings on the geochemistry of soils, sediments and surface waters of the Lousal area (Iberian Pyrite Belt, southern Portugal). Land Degrad Dev 16:213\u2013228. doi: 10.1002\/ldr.659","journal-title":"Land Degrad Dev"},{"key":"8161_CR20","doi-asserted-by":"publisher","first-page":"1001","DOI":"10.1007\/s00254-006-0273-6","volume":"50","author":"E Ferreira da Silva","year":"2006","unstructured":"Ferreira da Silva E, Patinha C, Reis P, Cardoso Fonseca E, Matos JX, Barrosinho J, Santos Oliveira JM (2006) Interaction of acid mine drainage with waters and sediments at the corona stream, Lousal mine (Iberian Pyrite Belt, southern Portugal). Environ Geol 50:1001\u20131013. doi: 10.1007\/s00254-006-0273-6","journal-title":"Environ Geol"},{"key":"8161_CR21","doi-asserted-by":"publisher","first-page":"383","DOI":"10.1016\/apgeochem.2008.12.001","volume":"24","author":"E Ferreira da Silva","year":"2009","unstructured":"Ferreira da Silva E, Bobos I, Matos JX, Patinha C, Reis PA, Cardoso Fonseca E (2009) Mineralogy and geochemistry of trace metals and REE in volcanic massive sulfide host rocks, stream sediments, stream waters and acid mine drainage from the Lousal mine area (Iberian Pyrite Belt, Portugal). Appl Geochem 24:383\u2013401. doi: 10.1016\/apgeochem.2008.12.001","journal-title":"Appl Geochem"},{"key":"8161_CR22","unstructured":"Ficklin WH, Plumlee GS, Smith KS, McHugh JB (1992) Geochemical classification of mine drainages and natural drainages in mineralized areas. Proceedings of the 7th International Symposium on Water-Rock Interaction, Balkema, Rotterdam, pp 381\u2013384"},{"key":"8161_CR23","first-page":"3","volume":"38","author":"O Gaspar","year":"1996","unstructured":"Gaspar O (1996) Microscopia e petrologia de min\u00e9rios, aplicada \u00e0 g\u00e9nese, explora\u00e7\u00e3o e mineralurgia dos sulfuretos maci\u00e7os dos jazigos de Aljustrel e Neves Corvo. Est. Notas Trab Inst Geol Min Tomo 38:3\u2013195","journal-title":"Notas Trab Inst Geol Min Tomo"},{"key":"8161_CR24","doi-asserted-by":"publisher","first-page":"407","DOI":"10.1016\/j.chemgeo.2004.06.053","volume":"215","author":"JM Hammarstrom","year":"2005","unstructured":"Hammarstrom JM, Seal RR II, Meier AL, Kornfeld JM (2005) Secondary sulfate minerals associated with acid mine drainage in the eastern US: recycling of metals and acidity in surficial environments. Chem Geol 215:407\u2013431. doi: 10.1016\/j.chemgeo.2004.06.053","journal-title":"Chem Geol"},{"key":"8161_CR25","doi-asserted-by":"publisher","first-page":"415","DOI":"10.1006\/jcis.1996.4755","volume":"188","author":"SJ Hug","year":"1997","unstructured":"Hug SJ (1997) In situ Fourier transform infrared measurements of sulfate adsorption on hematite in aqueous solutions. J Colloid Interf Sci 188:415\u2013422. doi: 10.1006\/jcis.1996.4755","journal-title":"J Colloid Interf Sci"},{"key":"8161_CR26","unstructured":"Jambor JL, Blowes DW (1998) Theory and applications of mineralogy in environmental studies of sulphide-bearing mine wastes. In: Cabril LJ, Vaughan DJ (eds). Modern approaches to ore and environmental mineralogy, Short Courses Series Vol. 27, Mineralogical Association of Canada, pp 367\u2013401"},{"key":"8161_CR27","series-title":"Rev Min Geochem Vol. 40","first-page":"303","volume-title":"Sulfate minerals\u2014crystallography, geochemistry, and environmental significance","author":"JL Jambor","year":"2000","unstructured":"Jambor JL, Nordstrom DK, Alpers CN (2000) Metal-sulfate salts from sulphide mineral oxidation. In: Alpers CN, Jambor JL, Nordstrom DK (eds) Sulfate minerals\u2014crystallography, geochemistry, and environmental significance, Rev Min Geochem Vol. 40. The Mineralogical Society of America and Geochemical Society, Washington, DC, pp. 303\u2013350"},{"key":"8161_CR28","doi-asserted-by":"publisher","first-page":"1511","DOI":"10.1016\/S0016-7037(99)00421-4","volume":"64","author":"MP Janzen","year":"2000","unstructured":"Janzen MP, Nicholson RV, Scharer JM (2000) Pyrrhotite reaction kinetics: reaction rates for oxidation by oxygen, ferric iron, and for nonoxidative dissolution. Geochim Cosmochim Ac 64:1511\u20131522. doi: 10.1016\/S0016-7037(99)00421-4","journal-title":"Geochim Cosmochim Ac"},{"key":"8161_CR29","doi-asserted-by":"publisher","first-page":"235","DOI":"10.1016\/S0883-2927(99)00041-4","volume":"15","author":"SR Jennings","year":"2000","unstructured":"Jennings SR, Dollhopf DJ, Inskeep WP (2000) Acid production from sulphide minerals using hydrogen peroxide weathering. Appl Geochem 15:235\u2013243. doi: 10.1016\/S0883-2927(99)00041-4","journal-title":"Appl Geochem"},{"key":"8161_CR30","doi-asserted-by":"crossref","first-page":"1919","DOI":"10.2138\/am-2003-11-1235","volume":"88","author":"JK Jerz","year":"2003","unstructured":"Jerz JK, Rimstidt JD (2003) Efflorescent iron sulfate minerals: Paragenesis, relative stability, and environmental impact. Am Mineral 88:1919\u20131932","journal-title":"Am Mineral"},{"key":"8161_CR31","series-title":"Rev Econ Geol Vol. 6B","first-page":"467","volume-title":"The environmental geochemistry of mineral deposits, part B: case studies and research topics","author":"BA Kimball","year":"1994","unstructured":"Kimball BA (1994) Seasonal variation in metal concentrations in a stream affected by acid mine drainage, St. Kevin Gulch, Colorado. In: Filipek LH, Plumlee GS (eds) The environmental geochemistry of mineral deposits, part B: case studies and research topics, Rev Econ Geol Vol. 6B. Society of Economic Geology, Littleton, CO, pp. 467\u2013477"},{"key":"8161_CR32","doi-asserted-by":"publisher","unstructured":"Lambert DC, McDonough KM, Dzombak DA (2004) Long-term changes in quality of discharge water from abandoned underground coal mines in Uniontown Syncline, Fayette County, PA, USA. Water Res 38(2):277\u2013288. doi: 10.1016\/j.watres.2003.09.017","DOI":"10.1016\/j.watres.2003.09.017"},{"key":"8161_CR33","volume-title":"Mine wastes. Characterization, treatment, environmental impacts","author":"BG Lottermoser","year":"2007","unstructured":"Lottermoser BG (2007) Mine wastes. Characterization, treatment, environmental impacts, 2nd edn. Springer-Verlag, Berlin","edition":"2"},{"key":"8161_CR34","first-page":"25","volume-title":"Mina do Lousal. Livro-Guia n\u00b04. I Congresso Hispano-Luso-Americano de Geologia Econ\u00f3mica","author":"K Matzke","year":"1971","unstructured":"Matzke K (1971) Mina do Lousal. Livro-Guia n\u00b04. I Congresso Hispano-Luso-Americano de Geologia Econ\u00f3mica. Direc\u00e7\u00e3o-Geral de Minas e Servi\u00e7os Geol\u00f3gicos, Lisboa, pp. 25\u201332"},{"key":"8161_CR35","doi-asserted-by":"publisher","first-page":"9874","DOI":"10.1021\/es402188r","volume":"47","author":"RB McCleskey","year":"2013","unstructured":"McCleskey RB (2013) New method for electrical conductivity temperature compensation. Environ Sci Technol 47:9874\u20139881. doi: 10.1021\/es402188r","journal-title":"Environ Sci Technol"},{"key":"8161_CR36","doi-asserted-by":"publisher","first-page":"121","DOI":"10.1016\/j.apgeochem.2007.10.009","volume":"23","author":"MA McKibben","year":"2008","unstructured":"McKibben MA, Tallant BA, del Angel JK (2008) Kinetics of inorganic arsenopyrite oxidation in acidic aqueous solutions. Appl Geochem 23:121\u2013135. doi: 10.1016\/j.apgeochem.2007.10.009","journal-title":"Appl Geochem"},{"key":"8161_CR37","doi-asserted-by":"publisher","first-page":"56","DOI":"10.1039\/b104809k","volume":"2","author":"F Millero","year":"2001","unstructured":"Millero F (2001) Speciation of metals in natural waters. Geochem T 2:56\u201364. doi: 10.1039\/b104809k","journal-title":"Geochem T"},{"key":"8161_CR38","doi-asserted-by":"publisher","first-page":"31","DOI":"10.1016\/0048-9697(94)90042-6","volume":"158","author":"C Monterroso","year":"1994","unstructured":"Monterroso C, Alvarez E, Mac\u00edas F (1994) Speciation and solubility control of Al and Fe in minesoil solutions. Sci Total Environ 158:31\u201343. doi: 10.1016\/0048-9697(94)90042-6","journal-title":"Sci Total Environ"},{"key":"8161_CR39","first-page":"14","volume-title":"Environmental geochemistry of sulfide oxidation","author":"RV Nicholson","year":"1994","unstructured":"Nicholson RV, Scharer JM (1994) Laboratory studies of pyrrhotite oxidation kinetics. In: Alpers CN, Blowes DW (eds) Environmental geochemistry of sulfide oxidation. American Chemical Society Symposium Series, Washington, DC, pp. 14\u201330"},{"key":"8161_CR40","first-page":"37","volume-title":"Acid sulfate weathering","author":"DK Nordstrom","year":"1982","unstructured":"Nordstrom DK (1982) Aqueous pyrite oxidation and the consequent formation of secondary iron minerals. In: Kittrick JA, Fanning DS, Hossner LR (eds) Acid sulfate weathering. Soil Science Society of America, Special Publication 10, Madison, Wiscosin, pp. 37\u201356"},{"key":"8161_CR41","doi-asserted-by":"publisher","first-page":"97","DOI":"10.1016\/j.gexplo.2008.08.002","volume":"100","author":"DK Nordstrom","year":"2009","unstructured":"Nordstrom DK (2009) Acid rock drainage and climate change. J Geochem Explor 100:97\u2013104. doi: 10.1016\/j.gexplo.2008.08.002","journal-title":"J Geochem Explor"},{"key":"8161_CR42","doi-asserted-by":"publisher","first-page":"1777","DOI":"10.1016\/j.apgeochem.2011.06.002","volume":"26","author":"DK Nordstrom","year":"2011","unstructured":"Nordstrom DK (2011) Hydrogeochemical processes governing the origin, transport and fate of major and trace elements from mine wastes and mineralized rock to surface waters. Appl Geochem 26:1777\u20131791. doi: 10.1016\/j.apgeochem.2011.06.002","journal-title":"Appl Geochem"},{"key":"8161_CR43","series-title":"Rev Econ Geol Vol. 6A","first-page":"133","volume-title":"The environmental geochemistry of mineral deposits, part a: processes, methods, and health issues","author":"DK Nordstrom","year":"1999","unstructured":"Nordstrom DK, Alpers CN (1999) Geochemistry of acid mine waters. In: Plumlee GS, Logsdon MJ (eds) The environmental geochemistry of mineral deposits, part a: processes, methods, and health issues, Rev Econ Geol Vol. 6A. Society of Economic Geology, Littleton, CO, pp. 133\u2013160"},{"key":"8161_CR44","first-page":"269","volume":"42","author":"DK Nordstrom","year":"1989","unstructured":"Nordstrom DK, Ball JW (1989) Mineral saturation states in natural waters and their sensitivity to thermodynamic and analytical errors. Sci G\u00e9ol Bull 42:269\u2013280","journal-title":"Sci G\u00e9ol Bull"},{"key":"8161_CR45","doi-asserted-by":"publisher","first-page":"422","DOI":"10.1007\/s00126-004-0415-2","volume":"39","author":"JT Oliveira","year":"2004","unstructured":"Oliveira JT, Pereira Z, Carvalho P, Pacheco N, Korn D (2004) Stratigraphy of the tectonically imbricated lithological succession of the Neves Corvo mine area, Iberian Pyrite Belt, Portugal. Mineral Deposita 39:422\u2013436. doi: 10.1007\/s00126-004-0415-2","journal-title":"Mineral Deposita"},{"key":"8161_CR46","unstructured":"Parkhurst DL, Appelo CAJ (2013) Description of input and examples for PHREEQC version 3--A computer program for speciation, batch-reaction, one-dimensional transport, and inverse geochemical calculations: U.S. Geological Survey Water-Resources Investigations. Chapter 43 of Section A, Groundwater Book 6, Modeling Techniques: Techniques and Methods 6\u2013A43."},{"key":"8161_CR47","doi-asserted-by":"publisher","first-page":"289","DOI":"10.1006\/jcis.1999.6405","volume":"218","author":"D Peak","year":"1999","unstructured":"Peak D, Ford RG, Sparks DL (1999) An in situ ATR-FTIR investigation of sulfate bonding mechanisms on goethite. J Colloid Interf Sci 218:289\u2013299. doi: 10.1006\/jcis.1999.6405","journal-title":"J Colloid Interf Sci"},{"key":"8161_CR48","doi-asserted-by":"publisher","first-page":"169","DOI":"10.1016\/j.chemgeo.2009.01.017","volume":"262","author":"T Peretyazhko","year":"2009","unstructured":"Peretyazhko T, Zachara JM, Boily J-F, Xia Y, Gassman PL, Arey BW, Burgos WD (2009) Mineralogical transformations controlling acid mine drainage chemistry. Chem Geol 262:169\u2013178. doi: 10.1016\/j.chemgeo.2009.01.017","journal-title":"Chem Geol"},{"key":"8161_CR49","series-title":"ACS Symposium Series 550","first-page":"2","volume-title":"Environmental geochemistry of sulfide oxidation","author":"JD Rimstidt","year":"1994","unstructured":"Rimstidt JD, Chermak JA, Gagen PM (1994) Rates of reaction of galena, sphalerite, chalcopyrite, and arsenopyrite with Fe(III) in acidic solutions. In: Alpers CN, Blowes DW (eds) Environmental geochemistry of sulfide oxidation, ACS Symposium Series 550. American Chemical Society, Washington DC, pp. 2\u201313"},{"key":"8161_CR50","doi-asserted-by":"publisher","first-page":"1431","DOI":"10.2113\/gscanmin.44.6.1431","volume":"44","author":"A Romero","year":"2006","unstructured":"Romero A, Gonz\u00e1lez I, Gal\u00e1n E (2006) The role of efflorescent sulfates in the storage of trace elements in stream waters polluted by acid mine-drainage: the case of Pe\u00f1a del Hierro, southwestern Spain. Can Mineral 44:1431\u20131446. doi: 10.2113\/gscanmin.44.6.1431","journal-title":"Can Mineral"},{"key":"8161_CR51","doi-asserted-by":"publisher","first-page":"1320","DOI":"10.1016\/j.apgeochem.2005.01.011","volume":"20","author":"J S\u00e1nchez Espa\u00f1a","year":"2005","unstructured":"S\u00e1nchez Espa\u00f1a J, L\u00f3pez Pamo E, Santofimia E, Aduvire O, Reyes J, Barettino D (2005) Acid mine drainage in the Iberian Pyrite Belt (Odiel river watershed, Huelva, SW Spain): geochemistry, mineralogy and environmental implications. Appl Geochem 20:1320\u20131356. doi: 10.1016\/j.apgeochem.2005.01.011","journal-title":"Appl Geochem"},{"key":"8161_CR52","doi-asserted-by":"publisher","first-page":"269","DOI":"10.1007\/s10498-005-6246-7","volume":"12","author":"J S\u00e1nchez Espa\u00f1a","year":"2006","unstructured":"S\u00e1nchez Espa\u00f1a J, L\u00f3pez Pamo E, Santofimia Pastor E, Reyes Andr\u00e9s J, Mart\u00edn Rub\u00ed JA (2006) The removal of dissolved metals by hydroxysulphate precipitates during oxidation and neutralization of acid mine waters, Iberian Pyrite Belt. Aquat Geochem 12:269\u2013298. doi: 10.1007\/s10498-005-6246-7","journal-title":"Aquat Geochem"},{"key":"8161_CR53","first-page":"15","volume-title":"A Faixa Piritosa do Sul de Portugal. I Congresso Hispano-Luso-Americano de Geologia Econ\u00f3mica, Livro-Guia n\u00b04","author":"LJG Schermerhorn","year":"1971","unstructured":"Schermerhorn LJG (1971) A Faixa Piritosa do Sul de Portugal. I Congresso Hispano-Luso-Americano de Geologia Econ\u00f3mica, Livro-Guia n\u00b04. Direc\u00e7\u00e3o-Geral de Minas e Servi\u00e7os Geol\u00f3gicos, Lisboa, pp. 15\u201325"},{"key":"8161_CR54","doi-asserted-by":"publisher","first-page":"172","DOI":"10.1016\/j.chemosphere.2013.11.059","volume":"103","author":"SL Simpson","year":"2014","unstructured":"Simpson SL, Vardanega CR, Jarolimek C, Jolley DF, Angel BM, Mosley LM (2014) Metal speciation and potential bioavailability changes during discharge and neutralization of acidic drainage water. Chemosphere 103:172\u2013180. doi: 10.1016\/j.chemosphere.2013.11.059","journal-title":"Chemosphere"},{"key":"8161_CR55","doi-asserted-by":"publisher","first-page":"1121","DOI":"10.1126\/science.167.3921.1121","volume":"167","author":"PC Singer","year":"1970","unstructured":"Singer PC, Stumm W (1970) Acid mine drainage: the rate-determining step. Science 167:1121\u20131123. doi: 10.1126\/science.167.3921.1121","journal-title":"Science"},{"key":"8161_CR56","doi-asserted-by":"publisher","first-page":"59","DOI":"10.1007\/s002540050401","volume":"38","author":"M Shum","year":"1999","unstructured":"Shum M, Lavkulich L (1999) Speciation and solubility relationships of Al, Cu and Fe in solutions associated with sulfuric acid leached mine waste rock. Environ Geol 38:59\u201368. doi: 10.1007\/s002540050401","journal-title":"Environ Geol"},{"key":"8161_CR57","volume-title":"Chemistry of the solid-water interface: processes at the mineral-water and particle-water interface in natural systems","author":"W Stumm","year":"1992","unstructured":"Stumm W (1992) Chemistry of the solid-water interface: processes at the mineral-water and particle-water interface in natural systems. John Wiley & Sons, New York"},{"key":"8161_CR58","volume-title":"Aquatic chemistry: chemical equilibria and rates in natural waters","author":"W Stumm","year":"1996","unstructured":"Stumm W, Morgan J (1996) Aquatic chemistry: chemical equilibria and rates in natural waters, 3rd edn. John Wiley and Sons, New York","edition":"3"},{"key":"8161_CR59","doi-asserted-by":"publisher","first-page":"785","DOI":"10.1016\/S0883-2927(99)00097-9","volume":"15","author":"E Viollier","year":"2000","unstructured":"Viollier E, Inglett PW, Hunter K, Roychoudhury AN, Van Cappellen P (2000) The ferrozine method revisited: Fe(II)\/Fe(III) determination in natural waters. Appl Geochem 15:785\u2013790. doi: 10.1016\/S0883-2927(99)00097-9","journal-title":"Appl Geochem"},{"key":"8161_CR60","doi-asserted-by":"publisher","first-page":"1668","DOI":"10.1016\/j.gca.2005.12.010","volume":"70","author":"FP Walker","year":"2006","unstructured":"Walker FP, Schreibe ME, Rimstidt JD (2006) Kinetics of arsenopyrite oxidative dissolution by oxygen. Geochim Cosmochim Ac 70:1668\u20131676. doi: 10.1016\/j.gca.2005.12.010","journal-title":"Geochim Cosmochim Ac"},{"key":"8161_CR61","first-page":"129","volume":"42","author":"JS Webb","year":"1958","unstructured":"Webb JS (1958) Observations on the geology and origin of the San Domingos pyrite deposit, Portugal. Comun Serv Geol Port 42:129\u2013143","journal-title":"Comun Serv Geol Port"},{"key":"8161_CR62","doi-asserted-by":"publisher","first-page":"239","DOI":"10.1016\/S0016-7037(02)01276-0","volume":"74","author":"CG Weisener","year":"2004","unstructured":"Weisener CG, Smart RSC, Gerson AR (2004) A comparison of the kinetics and mechanism of acid leaching of sphalerite containing low and high concentrations of iron. Int J Miner Process 74:239\u2013249. doi: 10.1016\/S0016-7037(02)01276-0","journal-title":"Int J Miner Process"},{"key":"8161_CR63","doi-asserted-by":"publisher","first-page":"6460","DOI":"10.1021\/es070788m","volume":"41","author":"Y Yunmei","year":"2007","unstructured":"Yunmei Y, Yongxuan Z, Zheinmin G, Christopher HG, Denxian L (2007) Rates of arsenopyrite oxidation by oxygen and Fe(III) at pH 1.8 \u2013 12.6 and 15 \u2013 45 \u00b0C. Envir Sci Tech 41:6460\u20136464. doi: 10.1021\/es070788m","journal-title":"Envir Sci Tech"},{"key":"8161_CR64","doi-asserted-by":"publisher","first-page":"2158","DOI":"10.1016\/j.gca.2006.12.020","volume":"71","author":"GY Zhang","year":"2007","unstructured":"Zhang GY, Peak D (2007) Studies of Cd(II)-sulfate interactions at the goethite-water interface by ATR-FTIR spectroscopy. Geochim Cosmochim Ac 71:2158\u20132169. doi: 10.1016\/j.gca.2006.12.020","journal-title":"Geochim Cosmochim Ac"}],"container-title":["Environmental Science and Pollution Research"],"original-title":[],"language":"en","link":[{"URL":"http:\/\/link.springer.com\/content\/pdf\/10.1007\/s11356-016-8161-4.pdf","content-type":"application\/pdf","content-version":"vor","intended-application":"text-mining"},{"URL":"http:\/\/link.springer.com\/article\/10.1007\/s11356-016-8161-4\/fulltext.html","content-type":"text\/html","content-version":"vor","intended-application":"text-mining"},{"URL":"http:\/\/link.springer.com\/content\/pdf\/10.1007\/s11356-016-8161-4.pdf","content-type":"application\/pdf","content-version":"vor","intended-application":"similarity-checking"}],"deposited":{"date-parts":[[2019,9,16]],"date-time":"2019-09-16T08:22:50Z","timestamp":1568622170000},"score":1,"resource":{"primary":{"URL":"http:\/\/link.springer.com\/10.1007\/s11356-016-8161-4"}},"subtitle":[],"short-title":[],"issued":{"date-parts":[[2016,12,12]]},"references-count":64,"journal-issue":{"issue":"5","published-print":{"date-parts":[[2017,2]]}},"alternative-id":["8161"],"URL":"https:\/\/doi.org\/10.1007\/s11356-016-8161-4","relation":{},"ISSN":["0944-1344","1614-7499"],"issn-type":[{"value":"0944-1344","type":"print"},{"value":"1614-7499","type":"electronic"}],"subject":[],"published":{"date-parts":[[2016,12,12]]}}}