{"status":"ok","message-type":"work","message-version":"1.0.0","message":{"indexed":{"date-parts":[[2026,1,31]],"date-time":"2026-01-31T00:22:59Z","timestamp":1769818979132,"version":"3.49.0"},"reference-count":94,"publisher":"Springer Science and Business Media LLC","issue":"19","license":[{"start":{"date-parts":[[2020,5,30]],"date-time":"2020-05-30T00:00:00Z","timestamp":1590796800000},"content-version":"tdm","delay-in-days":0,"URL":"https:\/\/www.springer.com\/tdm"},{"start":{"date-parts":[[2020,5,30]],"date-time":"2020-05-30T00:00:00Z","timestamp":1590796800000},"content-version":"vor","delay-in-days":0,"URL":"https:\/\/www.springer.com\/tdm"}],"content-domain":{"domain":["link.springer.com"],"crossmark-restriction":false},"short-container-title":["Environ Sci Pollut Res"],"published-print":{"date-parts":[[2021,5]]},"DOI":"10.1007\/s11356-020-09178-1","type":"journal-article","created":{"date-parts":[[2020,5,30]],"date-time":"2020-05-30T21:17:11Z","timestamp":1590873431000},"page":"23568-23581","update-policy":"https:\/\/doi.org\/10.1007\/springer_crossmark_policy","source":"Crossref","is-referenced-by-count":6,"title":["Facile fabrication of hybrid titanium(IV) isopropoxide\/pozzolan nanosheets (TnS-Pz) of high photocatalytic activity: characterization and application for Cr(VI) reduction in an aqueous solution"],"prefix":"10.1007","volume":"28","author":[{"given":"Aline M.","family":"Novack","sequence":"first","affiliation":[]},{"given":"Glaydson S.","family":"dos Reis","sequence":"additional","affiliation":[]},{"given":"Fab\u00edola V.","family":"Hackbarth","sequence":"additional","affiliation":[]},{"ORCID":"https:\/\/orcid.org\/0000-0002-6707-3437","authenticated-orcid":false,"given":"Belisa A.","family":"Marinho","sequence":"additional","affiliation":[]},{"given":"Maja B.","family":"\u00d0oli\u0107","sequence":"additional","affiliation":[]},{"given":"Jos\u00e9 A. B.","family":"Valle","sequence":"additional","affiliation":[]},{"given":"Carlos H.","family":"Sampaio","sequence":"additional","affiliation":[]},{"given":"Eder C.","family":"Lima","sequence":"additional","affiliation":[]},{"given":"Guillherme L.","family":"Dotto","sequence":"additional","affiliation":[]},{"given":"Ant\u00f4nio Augusto","family":"Ulson de Souza","sequence":"additional","affiliation":[]},{"given":"V\u00edtor J. P.","family":"Vilar","sequence":"additional","affiliation":[]},{"given":"Selene M. A.","family":"Guelli Ulson de Souza","sequence":"additional","affiliation":[]}],"member":"297","published-online":{"date-parts":[[2020,5,30]]},"reference":[{"key":"9178_CR1","doi-asserted-by":"crossref","unstructured":"A. Gorski C, Scherer M (2010): Determination of nanoparticulate magnetite stoichiometry by Mossbauer spectroscopy, acidic dissolution, and powder X-ray diffraction: a critical review vol 95","DOI":"10.2138\/am.2010.3435"},{"key":"9178_CR2","doi-asserted-by":"crossref","first-page":"11","DOI":"10.1016\/j.apcatb.2006.09.018","volume":"72","author":"C Ad\u00e1n","year":"2007","unstructured":"Ad\u00e1n C, Bahamonde A, Fern\u00e1ndez-Garc\u00eda M, Mart\u00ednez-Arias A (2007) Structure and activity of nanosized iron-doped anatase TiO2 catalysts for phenol photocatalytic degradation. Appl Catal B Environ 72:11\u201317","journal-title":"Appl Catal B Environ"},{"key":"9178_CR3","doi-asserted-by":"crossref","first-page":"205","DOI":"10.1007\/BF00311956","volume":"9","author":"M Akasaka","year":"1983","unstructured":"Akasaka M (1983) 57Fe m\u00f6ssbauer study of clinopyroxenes in the join CaFe3+ AlSiO6 - CaTiAl2O6. Phys Chem Miner 9:205\u2013211","journal-title":"Phys Chem Miner"},{"key":"9178_CR4","doi-asserted-by":"crossref","unstructured":"Allan J, Coey JMD, Resende M, Fabris J (1988): Magnetic properties of iron-rich oxisols vol 15","DOI":"10.1007\/BF00311127"},{"key":"9178_CR5","doi-asserted-by":"crossref","first-page":"5021","DOI":"10.1039\/c3ce42356e","volume":"16","author":"W Avansi","year":"2014","unstructured":"Avansi W, Arenal R, de Mendon\u00e7a VR, Ribeiro C, Longo E (2014) Vanadium-doped TiO2 anatase nanostructures: the role of V in solid solution formation and its effect on the optical properties. Cryst Eng Comm 16:5021\u20135021","journal-title":"Cryst Eng Comm"},{"key":"9178_CR6","doi-asserted-by":"crossref","first-page":"122501","DOI":"10.1063\/1.2355438","volume":"89","author":"L Balcells","year":"2006","unstructured":"Balcells L, Frontera C, Sandiumenge F, Roig A, Mart\u00ednez B, Kouam J, Monty C (2006) Absence of ferromagnetism in Fe-doped TiO2 nanoparticles. Appl Phys Lett 89:122501","journal-title":"Appl Phys Lett"},{"key":"9178_CR7","doi-asserted-by":"crossref","first-page":"1323","DOI":"10.1016\/0022-3697(67)90076-5","volume":"28","author":"SK Banerjee","year":"1967","unstructured":"Banerjee SK, O\u2019Reilly W, Gibb TC, Greenwood NN (1967) The behaviour of ferrous ions in iron-titanium spinels. J Phys Chem Solids 28:1323\u20131335","journal-title":"J Phys Chem Solids"},{"key":"9178_CR8","doi-asserted-by":"crossref","unstructured":"Biedermann AR, Pettke T, Bender Koch C, Hirt AM (2015): Magnetic anisotropy in clinopyroxene and orthopyroxene single crystals Journal of Geophysical Research: Solid Earth 120, 1431\u20131451","DOI":"10.1002\/2014JB011678"},{"key":"9178_CR9","doi-asserted-by":"crossref","unstructured":"Bowles J, Jackson M, Berquo T, S\u00f8lheid A P, Gee S J (2013): Inferred time- and temperature-dependent cation ordering in natural titanomagnetites vol 4","DOI":"10.1038\/ncomms2938"},{"key":"9178_CR10","volume-title":"WinNormos M\u00f6ssbauer Fitting Program","author":"R Brand","year":"2008","unstructured":"Brand R (2008) WinNormos M\u00f6ssbauer Fitting Program. Universit\u00e4t Duisburg, Duisburg"},{"key":"9178_CR11","doi-asserted-by":"crossref","first-page":"3531","DOI":"10.1016\/j.jece.2017.07.080","volume":"6","author":"C Byrne","year":"2017","unstructured":"Byrne C, Subramanian G, Pillai SC (2017) Recent advances in photocatalysis for environmental applications. Journal of Environmental Chemical Engineering 6:3531","journal-title":"Journal of Environmental Chemical Engineering"},{"key":"9178_CR12","doi-asserted-by":"crossref","unstructured":"Cabrera A, Rodriguez Torres C, Errico L, S\u00e1nchez FH (2006): Study of Fe-doped rutile TiO2 alloys obtained by mechanical alloying vol 384","DOI":"10.1016\/j.physb.2006.06.040"},{"key":"9178_CR13","doi-asserted-by":"crossref","first-page":"2782","DOI":"10.1016\/j.jece.2017.05.029","volume":"5","author":"CF Carolin","year":"2017","unstructured":"Carolin CF, Kumar PS, Saravanan A, Joshiba GJ, Naushad M (2017) Efficient techniques for the removal of toxic heavy metals from aquatic environment: a review. Journal of Environmental Chemical Engineering 5:2782\u20132799","journal-title":"Journal of Environmental Chemical Engineering"},{"key":"9178_CR14","doi-asserted-by":"crossref","first-page":"136","DOI":"10.1016\/j.cemconcomp.2013.09.003","volume":"45","author":"K Celik","year":"2014","unstructured":"Celik K, Jackson M, Meral Akgul C, Emwas A-H, Mancio M, Mehta P, Monteiro P (2014) High-volume natural volcanic pozzolan and limestone powder as partial replacements for portland cement in self-compacting and sustainable concrete. Cem Concr Compos 45:136\u2013147","journal-title":"Cem Concr Compos"},{"key":"9178_CR15","doi-asserted-by":"crossref","unstructured":"Chakrabarti S, Chaudhuri B, Bhattacharjee S, Ray AK, Dutta BK (2009): Photo-reduction of hexavalent chromium in aqueous solution in the presence of zinc oxide as semiconductor catalyst Chem Eng J 153, 86\u201393","DOI":"10.1016\/j.cej.2009.06.021"},{"key":"9178_CR16","doi-asserted-by":"crossref","unstructured":"Chevrier V, Mathe PE, Rochette P, Gunnlaugsson H (2006): Magnetic study of an Antarctic weathering profile on basalt: Implications for recent weathering on Mars vol 244","DOI":"10.1016\/j.epsl.2006.02.033"},{"key":"9178_CR17","doi-asserted-by":"crossref","first-page":"209","DOI":"10.1016\/S0926-3373(00)00281-2","volume":"31","author":"W Choi","year":"2001","unstructured":"Choi W, Ko JY, Park H, Chung JS (2001) Investigation on TiO2-coated optical fibers for gas-phase photocatalytic oxidation of acetone. Appl Catal B Environ 31:209\u2013220","journal-title":"Appl Catal B Environ"},{"key":"9178_CR18","doi-asserted-by":"crossref","first-page":"182","DOI":"10.1016\/0022-4596(85)90055-6","volume":"56","author":"D Cordischi","year":"1985","unstructured":"Cordischi D, Burriesci N, D'Alba F, Petrera M, Polizzotti G, Schiavello M (1985) Structural characterization of Fe\/Ti oxide photocatalysts by X-ray, ESR, and M\u00f6ssbauer methods. J Solid State Chem 56:182\u2013190","journal-title":"J Solid State Chem"},{"key":"9178_CR19","doi-asserted-by":"crossref","unstructured":"De Grave E, Eeckhout Sigrid G (2003): 57Fe M\u00f6ssbauer-effect studies of Ca-rich, Fe-bearing clinopyroxenes: part III. Diopside vol 88","DOI":"10.2138\/am-2003-0723"},{"key":"9178_CR20","doi-asserted-by":"crossref","first-page":"478","DOI":"10.1346\/000986002320514208","volume":"50","author":"MTG de Oliveira","year":"2002","unstructured":"de Oliveira MTG, Formoso MLL, da Costa MI, Meunier A (2002) The titanomagnetite to titanomaghemite conversion in a weathered basalt profile from southern Paran\u00e1 Basin, Brazil. Clay Clay Miner 50:478\u2013493","journal-title":"Clay Clay Miner"},{"key":"9178_CR21","doi-asserted-by":"crossref","first-page":"294","DOI":"10.1016\/0144-2449(95)00154-9","volume":"16","author":"R Dimitrijevi\u0107","year":"1996","unstructured":"Dimitrijevi\u0107 R, Dondur V, Kremenovi\u0107 A (1996) Thermally induced phase transformations of Ca-exchanged LTA and FAU zeolite frameworks: Rietveld refinement of the hexagonal CaAl2Si2O8 diphyllosilicate structure. Zeolites 16:294\u2013300","journal-title":"Zeolites"},{"key":"9178_CR22","doi-asserted-by":"crossref","first-page":"128","DOI":"10.1016\/j.watres.2015.04.038","volume":"79","author":"H Dong","year":"2015","unstructured":"Dong H, Zeng G, Tang L, Fan C, Zhang C, He X, He Y (2015) An overview on limitations of TiO2-based particles for photocatalytic degradation of organic pollutants and the corresponding countermeasures. Water Res 79:128\u2013146","journal-title":"Water Res"},{"key":"9178_CR23","unstructured":"Dyar M, McGuire AV, Ziegler RD (1989): Redox equilibria and crystal chemistry of coexisting minerals from spinel lherzolite mantle xenoliths vol 74"},{"key":"9178_CR24","doi-asserted-by":"crossref","first-page":"83","DOI":"10.1146\/annurev.earth.34.031405.125049","volume":"34","author":"MD Dyar","year":"2006","unstructured":"Dyar MD, Agresti DG, Schaefer MW, Grant CA, Sklute EC (2006) M\u00f6ssbauer spectroscopy of earth and planetary materials. Annu Rev Earth Planet Sci 34:83\u2013125","journal-title":"Annu Rev Earth Planet Sci"},{"key":"9178_CR25","doi-asserted-by":"crossref","unstructured":"Dyar MD, Klima Rachel L, Fleagle A, Peel Samantha E (2013): Fundamental M\u00f6ssbauer parameters of synthetic Ca-Mg-Fe pyroxenes vol 98","DOI":"10.2138\/am.2013.4333"},{"key":"9178_CR26","doi-asserted-by":"crossref","unstructured":"Eeckhout Sigrid G, Grave E (2003): 57Fe M\u00f6ssbauer-effect studies of Ca-rich, Fe-bearing clinopyroxenes: part I. Paramagnetic spectra of magnesian hedenbergite vol 88","DOI":"10.2138\/am-2003-0721"},{"key":"9178_CR27","doi-asserted-by":"crossref","first-page":"41","DOI":"10.1016\/j.cattod.2018.01.016","volume":"321-322","author":"A El Mragui","year":"2019","unstructured":"El Mragui A, Daou I, Zegaoui O (2019) Influence of the preparation method and ZnO\/(ZnO + TiO2) weight ratio on the physicochemical and photocatalytic properties of ZnO-TiO2 nanomaterials. Catal Today 321-322:41\u201351","journal-title":"Catal Today"},{"key":"9178_CR28","doi-asserted-by":"crossref","first-page":"2773","DOI":"10.1016\/j.jece.2017.05.019","volume":"5","author":"A Enuneku","year":"2017","unstructured":"Enuneku A, Biose E, Ezemonye L (2017) Levels, distribution, characterization and ecological risk assessment of heavy metals in road side soils and earthworms from urban high traffic areas in Benin metropolis, Southern Nigeria. Journal of Environmental Chemical Engineering 5:2773\u20132781","journal-title":"Journal of Environmental Chemical Engineering"},{"key":"9178_CR29","doi-asserted-by":"crossref","first-page":"158","DOI":"10.1016\/j.cej.2015.01.117","volume":"270","author":"H Eskandarloo","year":"2015","unstructured":"Eskandarloo H, Badiei A, Behnajady MA, Ziarani GM (2015) UV-LEDs assisted preparation of silver deposited TiO2 catalyst bed inside microchannels as a high efficiency microphotoreactor for cleaning polluted water. Chem Eng J 270:158\u2013167","journal-title":"Chem Eng J"},{"key":"9178_CR30","doi-asserted-by":"crossref","unstructured":"Fock J et al. (2017): On the \u2018centre of gravity\u2019 method for measuring the composition of magnetite\/maghemite mixtures, or the stoichiometry of magnetite-maghemite solid solutions, via 57Fe M\u00f6ssbauer spectroscopy vol 50","DOI":"10.1088\/1361-6463\/aa73fa"},{"key":"9178_CR31","doi-asserted-by":"crossref","first-page":"1919","DOI":"10.1111\/maps.12172","volume":"48","author":"J Gattacceca","year":"2013","unstructured":"Gattacceca J et al (2013) Opaque minerals, magnetic properties, and paleomagnetism of the Tissint Martian meteorite. Meteorit Planet Sci 48:1919\u20131936","journal-title":"Meteorit Planet Sci"},{"key":"9178_CR32","doi-asserted-by":"crossref","first-page":"812","DOI":"10.1007\/s11814-015-0218-4","volume":"33","author":"M Gholami","year":"2016","unstructured":"Gholami M, Shirzad-Siboni M, Yang J-K (2016) Application of Ni-doped ZnO rods for the degradation of an azo dye from aqueous solutions. Korean J Chem Eng 33:812\u2013822","journal-title":"Korean J Chem Eng"},{"key":"9178_CR33","doi-asserted-by":"crossref","first-page":"337","DOI":"10.1016\/j.apcatb.2017.04.029","volume":"211","author":"F Guayaquil","year":"2017","unstructured":"Guayaquil F, Serrano Rosales B, Valades-Pelayo P, Lasa H (2017) Photocatalytic hydrogen production using mesoporous TiO2 doped with Pt. Appl Catal B Environ 211:337","journal-title":"Appl Catal B Environ"},{"key":"9178_CR34","unstructured":"Gunnlaugsson H et al. (2003): Magnetic anomalies in Iceland: implications for the magnetic anomalies on Mars"},{"key":"9178_CR35","doi-asserted-by":"crossref","unstructured":"Gunnlaugsson H, Helgason \u00d6, Kristjansson L, N\u00f8rnberg P, Rasmussen H, Stein\u00fe\u00f3rsson S, Weyer G (2006): Magnetic properties of olivine basalt: application to Mars vol 154","DOI":"10.1016\/j.pepi.2005.09.012"},{"key":"9178_CR36","doi-asserted-by":"crossref","first-page":"87","DOI":"10.1007\/s10751-008-9714-9","volume":"182","author":"HP Gunnlaugsson","year":"2008","unstructured":"Gunnlaugsson HP, Rasmussen H, Kristj\u00e1nsson L, Steinthorsson S, Helgason \u00d6, N\u00f8rnberg P, Madsen MB, M\u00f8rup S (2008) M\u00f6ssbauer spectroscopy of magnetic minerals in basalt on Earth and Mars. Hyperfine Interactions 182:87\u2013101","journal-title":"Hyperfine Interactions"},{"key":"9178_CR37","doi-asserted-by":"crossref","unstructured":"Hamdeh H, Barghout K, Ho J-C, Shand P, Miller L. L (1999): A M\u00f6ssbauer evaluation of cation distribution in titanomagnetites vol 191","DOI":"10.1016\/S0304-8853(98)00340-0"},{"key":"9178_CR38","doi-asserted-by":"crossref","first-page":"105","DOI":"10.1016\/j.polymer.2016.11.046","volume":"108","author":"F Huang","year":"2017","unstructured":"Huang F, Tahmasbi Rad A, Zheng W, Nieh MP, Cornelius CJ (2017a) Hybrid organic-inorganic 6FDA-6pFDA and multi-block 6FDA-DABA polyimide SiO2\u2013TiO2 nanocomposites: synthesis, FFV, FTIR, swelling, stability, and X-ray scattering. Polymer 108:105\u2013120","journal-title":"Polymer"},{"key":"9178_CR39","doi-asserted-by":"crossref","first-page":"112","DOI":"10.1016\/j.jallcom.2017.05.132","volume":"718","author":"H Huang","year":"2017","unstructured":"Huang H, Zhang J, Jiang L, Zang Z (2017b) Preparation of cubic Cu2O nanoparticles wrapped by reduced graphene oxide for the efficient removal of rhodamine B. J Alloys Compd 718:112\u2013115","journal-title":"J Alloys Compd"},{"key":"9178_CR40","doi-asserted-by":"crossref","first-page":"123","DOI":"10.1016\/j.jmmm.2015.09.060","volume":"399","author":"A Joos","year":"2016","unstructured":"Joos A, R\u00fcmenapp C, Wagner FE, Gleich B (2016) Characterisation of iron oxide nanoparticles by M\u00f6ssbauer spectroscopy at ambient temperature. J Magn Magn Mater 399:123\u2013129","journal-title":"J Magn Magn Mater"},{"key":"9178_CR41","doi-asserted-by":"crossref","first-page":"226","DOI":"10.1016\/j.cap.2014.12.011","volume":"15","author":"B Kalska-Szostko","year":"2015","unstructured":"Kalska-Szostko B, Satu\u0142a D, Olszewski W (2015) M\u00f6ssbauer spectroscopy studies of the magnetic properties of ferrite nanoparticles. Curr Appl Phys 15:226\u2013231","journal-title":"Curr Appl Phys"},{"key":"9178_CR42","doi-asserted-by":"crossref","first-page":"530","DOI":"10.1016\/j.jphotochem.2017.07.004","volume":"346","author":"TM Khedr","year":"2017","unstructured":"Khedr TM, El-Sheikh SM, Hakki A, Ismail AA, Badawy WA, Bahnemann DW (2017) Highly active non-metals doped mixed-phase TiO2 for photocatalytic oxidation of ibuprofen under visible light. J Photochem Photobiol A Chem 346:530\u2013540","journal-title":"J Photochem Photobiol A Chem"},{"key":"9178_CR43","doi-asserted-by":"crossref","first-page":"135","DOI":"10.1016\/S0043-1354(00)00098-1","volume":"35","author":"Y Ku","year":"2001","unstructured":"Ku Y, Jung I-L (2001) Photocatalytic reduction of Cr(VI) in aqueous solutions by UV irradiation with the presence of titanium dioxide. Water Res 35:135\u2013142","journal-title":"Water Res"},{"key":"9178_CR44","doi-asserted-by":"crossref","unstructured":"Kuhn HJ, Braslavsky SE, Schmidt R (2004): Chemical actinometry (IUPAC Technical Report) vol 76","DOI":"10.1351\/pac200476122105"},{"key":"9178_CR45","unstructured":"Kumar K, Chowdhury A (2018): Use of novel nanostructured photocatalysts for the environmental sustainability of wastewater treatments. In: Reference module in materials science and materials engineering. Elsevier"},{"key":"9178_CR46","doi-asserted-by":"crossref","first-page":"223","DOI":"10.1016\/0038-1098(69)90729-7","volume":"7","author":"W K\u00fcndig","year":"1969","unstructured":"K\u00fcndig W, Steven Hargrove R (1969) Electron hopping in magnetite. Solid State Commun 7:223\u2013227","journal-title":"Solid State Commun"},{"key":"9178_CR47","doi-asserted-by":"crossref","first-page":"205","DOI":"10.1016\/S0926-3373(02)00303-X","volume":"43","author":"M Lackhoff","year":"2003","unstructured":"Lackhoff M, Prieto X, Nestle N, Dehn F, Niessner R (2003) Photocatalytic activity of semiconductor-modified cement-influence of semiconductor type and cement ageing. Appl Catal B Environ 43:205\u2013216","journal-title":"Appl Catal B Environ"},{"key":"9178_CR48","doi-asserted-by":"crossref","first-page":"396","DOI":"10.1016\/j.apsusc.2014.10.045","volume":"321","author":"XF Lei","year":"2014","unstructured":"Lei XF, Xue XX, Yang H (2014a) Preparation and characterization of Ag-doped TiO2 nanomaterials and their photocatalytic reduction of Cr(VI) under visible light. Appl Surf Sci 321:396\u2013403","journal-title":"Appl Surf Sci"},{"key":"9178_CR49","doi-asserted-by":"crossref","first-page":"396","DOI":"10.1016\/j.apsusc.2014.10.045","volume":"321","author":"XF Lei","year":"2014","unstructured":"Lei XF, Xue XX, Yang H (2014b) Preparation and characterization of Ag-doped TiO2nanomaterials and their photocatalytic reduction of Cr(VI) under visible light. Appl Surf Sci 321:396\u2013403","journal-title":"Appl Surf Sci"},{"key":"9178_CR50","doi-asserted-by":"crossref","unstructured":"Litter M (2015): Mechanisms of removal of heavy metals and arsenic from water by TiO2-heterogeneous photocatalysis Pure and Applied Chemistry","DOI":"10.1515\/pac-2014-0710"},{"key":"9178_CR51","unstructured":"Liu X et al. (2014): Structural and magnetic properties of Fe2 TiO4 Fe3O4 vol 50"},{"key":"9178_CR52","doi-asserted-by":"crossref","unstructured":"M. da Costa G, De Grave E, Bakker DE, Vandenberghe R (1995): Influence of nonstoichiometry and the presence of maghemite on the M\u00f6ssbauer spectrum of magnetite\u2020 vol 43","DOI":"10.1346\/CCMN.1995.0430602"},{"key":"9178_CR53","doi-asserted-by":"crossref","unstructured":"M. Hassan K, Dekan J (2013): M\u00f6ssbauer study of Fe phases in terrestrial olivine basalts from southern Egypt vol 44","DOI":"10.2478\/mipo-2013-0001"},{"key":"9178_CR54","doi-asserted-by":"crossref","first-page":"208","DOI":"10.1016\/j.apcatb.2016.03.061","volume":"192","author":"BA Marinho","year":"2016","unstructured":"Marinho BA, Crist\u00f3v\u00e3o RO, Loureiro JM, Boaventura RAR, Vilar VJP (2016) Solar photocatalytic reduction of Cr(VI) over Fe(III) in the presence of organic sacrificial agents. Appl Catal B Environ 192:208\u2013219","journal-title":"Appl Catal B Environ"},{"key":"9178_CR55","doi-asserted-by":"crossref","first-page":"18","DOI":"10.1016\/j.apcatb.2016.09.061","volume":"203","author":"BA Marinho","year":"2017","unstructured":"Marinho BA, Crist\u00f3v\u00e3o RO, Djellabi R, Loureiro JM, Boaventura RAR, Vilar VJP (2017a) Photocatalytic reduction of Cr(VI) over TiO2-coated cellulose acetate monolithic structures using solar light. Appl Catal B Environ 203:18\u201330","journal-title":"Appl Catal B Environ"},{"key":"9178_CR56","doi-asserted-by":"crossref","first-page":"76","DOI":"10.1016\/j.cej.2016.05.077","volume":"318","author":"BA Marinho","year":"2017","unstructured":"Marinho BA et al (2017b) Intensification of heterogeneous TiO2 photocatalysis using an innovative micro\u2013meso-structured-reactor for Cr(VI) reduction under simulated solar light. Chem Eng J 318:76\u201388","journal-title":"Chem Eng J"},{"key":"9178_CR57","doi-asserted-by":"crossref","first-page":"555","DOI":"10.1016\/j.jenvman.2018.04.003","volume":"217","author":"BA Marinho","year":"2018","unstructured":"Marinho BA, Crist\u00f3v\u00e3o RO, Djellabi R, Caseiro A, Miranda SM, Loureiro JM, Boaventura RAR, Dias MM, Lopes JCB, Vilar VJP (2018) Strategies to reduce mass and photons transfer limitations in heterogeneous photocatalytic processes: hexavalent chromium reduction studies. J Environ Manag 217:555\u2013564","journal-title":"J Environ Manag"},{"key":"9178_CR58","unstructured":"McCammon C, Mitchell R, Chakhmouradian A (1999): Mossbauer spectra of priderite and synthetic iron-bearing hollandite vol 37"},{"key":"9178_CR59","doi-asserted-by":"crossref","first-page":"320","DOI":"10.1111\/maps.12793","volume":"52","author":"MC McCanta","year":"2017","unstructured":"McCanta MC, Dyar MD (2017) Impact-related thermal effects on the redox state of Ca-pyroxene. Meteorit Planet Sci 52:320\u2013332","journal-title":"Meteorit Planet Sci"},{"key":"9178_CR60","doi-asserted-by":"crossref","first-page":"30523","DOI":"10.1029\/2001JB000180","volume":"106","author":"SA McEnroe","year":"2001","unstructured":"McEnroe SA, Harrison RJ, Robinson P, Golla U, Jercinovic MJ (2001) Effect of fine-scale microstructures in titanohematite on the acquisition and stability of natural remanent magnetization in granulite facies metamorphic rocks, southwest Sweden: Implications for crustal magnetism. J Geophys Res Solid Earth 106:30523\u201330546","journal-title":"J Geophys Res Solid Earth"},{"key":"9178_CR61","doi-asserted-by":"crossref","unstructured":"McEnroe S, Robinson P, Miyajima N, Fabian K, Dyar D, Sklute E (2016): Lamellar magnetism and exchange bias in billion-year-old titanohematite with nanoscale ilmenite exsolution lamellae: I. Mineral and magnetic characterization vol 206","DOI":"10.1093\/gji\/ggw155"},{"key":"9178_CR62","doi-asserted-by":"crossref","first-page":"454","DOI":"10.1016\/j.apcatb.2010.12.026","volume":"102","author":"JM Meichtry","year":"2011","unstructured":"Meichtry JM, Quici N, Mailhot G, Litter MI (2011) Heterogeneous photocatalytic degradation of citric acid over TiO2. I: mechanism of 3-oxoglutaric acid degradation. Appl Catal B Environ 102:454\u2013463","journal-title":"Appl Catal B Environ"},{"key":"9178_CR63","doi-asserted-by":"crossref","first-page":"97","DOI":"10.1016\/j.cemconcomp.2014.06.010","volume":"53","author":"J Moon","year":"2014","unstructured":"Moon J, Bae S, Celik K, Yoon S, Kim K-H, Kim KS, PJM M (2014) Characterization of natural pozzolan-based geopolymeric binders. Cem Concr Compos 53:97\u2013104","journal-title":"Cem Concr Compos"},{"key":"9178_CR64","doi-asserted-by":"crossref","first-page":"4597","DOI":"10.1016\/0016-7037(93)90185-Y","volume":"57","author":"RV Morris","year":"1993","unstructured":"Morris RV, Golden DC, Bell JF, Lauer HV, Adams JB (1993) Pigmenting agents in martian soils: inferences from spectral, M\u00f6ssbauer, and magnetic properties of nanophase and other iron oxides in Hawaiian palagonitic soil PN-9. Geochim Cosmochim Acta 57:4597\u20134609","journal-title":"Geochim Cosmochim Acta"},{"key":"9178_CR65","doi-asserted-by":"crossref","first-page":"167","DOI":"10.1016\/j.apcatb.2004.04.006","volume":"52","author":"P Mytych","year":"2004","unstructured":"Mytych P, Stasicka Z (2004) Photochemical reduction of chromium(VI) by phenol and its halogen derivatives. Appl Catal B Environ 52:167\u2013172","journal-title":"Appl Catal B Environ"},{"key":"9178_CR66","doi-asserted-by":"crossref","first-page":"3147","DOI":"10.1088\/0022-3719\/5\/21\/018","volume":"5","author":"AJ Nozik","year":"1972","unstructured":"Nozik AJ (1972) Mossbauer evidence for hole trapping by ferric acceptor states on rutile surfaces. J Phys C Solid State Phys 5:3147\u20133152","journal-title":"J Phys C Solid State Phys"},{"key":"9178_CR67","doi-asserted-by":"crossref","first-page":"415","DOI":"10.1016\/j.jclepro.2017.07.139","volume":"165","author":"M Omrane","year":"2017","unstructured":"Omrane M, Kenai S, Kadri E-H, A\u00eft-Mokhtar A (2017) Performance and durability of self compacting concrete using recycled concrete aggregates and natural pozzolan. J Clean Prod 165:415\u2013430","journal-title":"J Clean Prod"},{"key":"9178_CR68","doi-asserted-by":"crossref","first-page":"012107","DOI":"10.1063\/1.3679071","volume":"2","author":"SKS Patel","year":"2012","unstructured":"Patel SKS, Kurian S, Gajbhiye NS (2012) Phase dependent room-temperature ferromagnetism of Fe-doped TiO2 nanorods. AIP Adv 2:012107","journal-title":"AIP Adv"},{"key":"9178_CR69","doi-asserted-by":"crossref","first-page":"13022","DOI":"10.1016\/j.ijhydene.2019.03.164","volume":"44","author":"SB Patil","year":"2019","unstructured":"Patil SB, Basavarajappa PS, Ganganagappa N, Jyothi MS, Raghu AV, Reddy KR (2019) Recent advances in non-metals-doped TiO2 nanostructured photocatalysts for visible-light driven hydrogen production, CO2 reduction and air purification. Int J Hydrog Energy 44:13022\u201313039","journal-title":"Int J Hydrog Energy"},{"key":"9178_CR70","doi-asserted-by":"crossref","first-page":"2815","DOI":"10.1007\/s11164-015-2179-y","volume":"42","author":"P Pongwan","year":"2016","unstructured":"Pongwan P, Wetchakun K, Phanichphant S, Wetchakun N (2016) Enhancement of visible-light photocatalytic activity of Cu-doped TiO2 nanoparticles. Res Chem Intermed 42:2815\u20132830","journal-title":"Res Chem Intermed"},{"key":"9178_CR71","doi-asserted-by":"crossref","first-page":"84","DOI":"10.1016\/j.matlet.2018.12.139","volume":"240","author":"R Qin","year":"2019","unstructured":"Qin R, Meng F, Khan MW, Yu B, Li H, Fan Z, Gong J (2019) Fabrication and enhanced photocatalytic property of TiO2-ZnO composite photocatalysts. Mater Lett 240:84\u201387","journal-title":"Mater Lett"},{"key":"9178_CR72","doi-asserted-by":"crossref","unstructured":"Redhammer G\u00fcnther J, Amthauer G, Roth G, Tippelt G, Lottermoser W (2006): Single-crystal X-ray diffraction and temperature dependent 57Fe M\u00f6ssbauer spectroscopy on the hedenbergite-aegirine (Ca,Na)(Fe2+,Fe3+)Si2O6 solid solution vol 91","DOI":"10.2138\/am.2006.2173"},{"key":"9178_CR73","doi-asserted-by":"crossref","first-page":"135210","DOI":"10.1088\/0953-8984\/20\/13\/135210","volume":"20","author":"CE Rodr\u00edguez-Torres","year":"2008","unstructured":"Rodr\u00edguez-Torres CE, Cabrera AF, Errico LA, Ad\u00e1n C, Requejo FG, Weissmann M, Stewart SJ (2008) Local structure and magnetic behaviour of Fe-doped TiO2 anatase nanoparticles: experiments and calculations. J Phys Condens Matter 20:135210","journal-title":"J Phys Condens Matter"},{"key":"9178_CR74","doi-asserted-by":"crossref","unstructured":"Roonasi P, Mazinani M (2017) Synthesis and application of barium ferrite\/activated carbon composite as an effective solar photocatalyst for discoloration of organic dye contaminants in wastewater. J Environ Chem Eng 5:3822\u20133827","DOI":"10.1016\/j.jece.2017.07.035"},{"key":"9178_CR75","doi-asserted-by":"crossref","first-page":"90631","DOI":"10.1039\/C6RA15615K","volume":"6","author":"MMFF Salim","year":"2016","unstructured":"Salim MMFF et al (2016) Photochemical UVC\/H2O2 oxidation system as an effective method for the decolourisation of bio-treated textile wastewaters: towards onsite water reuse. RSC Adv 6:90631\u201390645","journal-title":"RSC Adv"},{"key":"9178_CR76","doi-asserted-by":"crossref","first-page":"4784","DOI":"10.1103\/PhysRevB.13.4784","volume":"13","author":"TR Sandin","year":"1976","unstructured":"Sandin TR, Schroeer D, Spencer CD (1976) M\u00f6ssbauer effect for 57Fe and 57Co in TiO2 (rutile). Phys Rev B 13:4784\u20134789","journal-title":"Phys Rev B"},{"key":"9178_CR77","doi-asserted-by":"crossref","first-page":"26","DOI":"10.1016\/j.jphotochem.2015.10.017","volume":"317","author":"PA Soares","year":"2016","unstructured":"Soares PA, Silva TFCV, Ramos Arcy A, Souza SMAGU, Boaventura RAR, Vilar VJP (2016) Assessment of AOPs as a polishing step in the decolourisation of bio-treated textile wastewater: technical and economic considerations. J Photochem Photobiol A Chem 317:26\u201338","journal-title":"J Photochem Photobiol A Chem"},{"key":"9178_CR78","doi-asserted-by":"crossref","unstructured":"Sorescu M, Xu T, Wise A, D\u00edaz-Michelena M, McHenry M (2012): Studies on structural, magnetic and thermal properties of Fe2TiO4-Fe3O4 Pseudo-binary System vol 324","DOI":"10.1016\/j.jmmm.2011.12.012"},{"key":"9178_CR79","doi-asserted-by":"crossref","unstructured":"Stampel PP, Travis JC, Bielefeld MJ (1973): M\u00f6ssbauer spectroscopic studies of iron-doped rutile physica status solidi (a) 15, 181\u2013189","DOI":"10.1002\/pssa.2210150120"},{"key":"9178_CR80","doi-asserted-by":"crossref","first-page":"463","DOI":"10.5636\/jgg.39.463","volume":"39","author":"H Tanaka","year":"1987","unstructured":"Tanaka H, Kono M (1987) Mössbauer spectra of titanomagnetite: a reappraisal. J Geomagn Geoelectr 39:463\u2013475","journal-title":"J Geomagn Geoelectr"},{"key":"9178_CR81","doi-asserted-by":"crossref","first-page":"196","DOI":"10.1016\/j.jhazmat.2018.05.008","volume":"370","author":"M Trejo-Valdez","year":"2019","unstructured":"Trejo-Valdez M, Hern\u00e1ndez-Guzm\u00e1n SR, Manriquez-Ram\u00edrez ME, Sobral H, Mart\u00ednez-Guti\u00e9rrez H, Torres-Torres C (2019) Removal of aqueous chromium and environmental CO2 by using photocatalytic TiO2 doped with tungsten. J Hazard Mater 370:196\u2013202","journal-title":"J Hazard Mater"},{"key":"9178_CR82","doi-asserted-by":"crossref","first-page":"190","DOI":"10.1016\/j.cattod.2014.10.014","volume":"252","author":"M Valari","year":"2015","unstructured":"Valari M, Antoniadis A, Mantzavinos D, Poulios I (2015) Photocatalytic reduction of Cr(VI) over titania suspensions. Catal Today 252:190\u2013194","journal-title":"Catal Today"},{"key":"9178_CR83","doi-asserted-by":"crossref","unstructured":"Van Alboom A, De Grave E, Vandenberghe R (1991): Mossbauer study of the hematite phase formed during synthesis of ferri-diopsides vol 95","DOI":"10.1016\/0022-4596(91)90390-4"},{"key":"9178_CR84","doi-asserted-by":"crossref","first-page":"21807","DOI":"10.1007\/s11356-017-9825-4","volume":"24","author":"AGN Wamba","year":"2017","unstructured":"Wamba AGN et al (2017) Synthesis of grafted natural pozzolan with 3-aminopropyltriethoxysilane: preparation, characterization, and application for removal of Brilliant Green 1 and Reactive Black 5 from aqueous solutions. Environ Sci Pollut Res 24:21807\u201321820","journal-title":"Environ Sci Pollut Res"},{"key":"9178_CR85","doi-asserted-by":"crossref","first-page":"400","DOI":"10.1016\/j.apcatb.2010.01.019","volume":"95","author":"N Wang","year":"2010","unstructured":"Wang N, Zhu L, Deng K, She Y, Yu Y, Tang H (2010) Visible light photocatalytic reduction of Cr(VI) on TiO2 in situ modified with small molecular weight organic acids. Appl Catal B Environ 95:400\u2013407","journal-title":"Appl Catal B Environ"},{"key":"9178_CR86","doi-asserted-by":"crossref","first-page":"17394","DOI":"10.1016\/j.ijhydene.2017.04.091","volume":"42","author":"Z Wang","year":"2017","unstructured":"Wang Z, Zhang H, Cao H, Wang L, Wan Z, Hao Y, Wang X (2017) Facile preparation of ZnS\/CdS core\/shell nanotubes and their enhanced photocatalytic performance. Int J Hydrog Energy 42:17394\u201317402","journal-title":"Int J Hydrog Energy"},{"key":"9178_CR87","doi-asserted-by":"crossref","first-page":"539","DOI":"10.1016\/j.apsusc.2017.07.202","volume":"430","author":"D Wang","year":"2018","unstructured":"Wang D, Hou P, Yang P, Cheng X (2018a) BiOBr@SiO2 flower-like nanospheres chemically-bonded on cement-based materials for photocatalysis. Appl Surf Sci 430:539\u2013548","journal-title":"Appl Surf Sci"},{"key":"9178_CR88","doi-asserted-by":"crossref","first-page":"590","DOI":"10.1016\/j.jtice.2018.09.004","volume":"93","author":"L Wang","year":"2018","unstructured":"Wang L, Zhao J, Liu H, Huang J (2018b) Design, modification and application of semiconductor photocatalysts. J Taiwan Inst Chem Eng 93:590\u2013602","journal-title":"J Taiwan Inst Chem Eng"},{"key":"9178_CR89","unstructured":"Whipple ER (1974) Quantitative M\u00f6ssbauer spectra and chemistry of iron. Massachusetts Institute of Technology"},{"key":"9178_CR90","doi-asserted-by":"crossref","unstructured":"Xu W, Peacor Donald R, Dollase Wayne A, Van Der Voo R, Beaubouef R (1997): Transformation of titanomagnetite to titanomaghemite: a slow, two-step, oxidation-ordering process in MORB vol 82","DOI":"10.2138\/am-1997-11-1207"},{"key":"9178_CR91","doi-asserted-by":"crossref","unstructured":"Yan H, Wang X, Yao M, Yao X (2013) Band structure design of semiconductors for enhanced photocatalytic activity: the case of TiO2. Pro Nat Sci-Mater 23:402\u2013407","DOI":"10.1016\/j.pnsc.2013.06.002"},{"key":"9178_CR92","doi-asserted-by":"crossref","first-page":"1677","DOI":"10.1016\/j.chemosphere.2005.10.005","volume":"63","author":"J-K Yang","year":"2006","unstructured":"Yang J-K, Lee S-M (2006) Removal of Cr(VI) and humic acid by using TiO2 photocatalysis. Chemosphere 63:1677\u20131684","journal-title":"Chemosphere"},{"key":"9178_CR93","doi-asserted-by":"crossref","first-page":"1174","DOI":"10.1021\/j150555a010","volume":"61","author":"VA Zeitler","year":"1957","unstructured":"Zeitler VA, Brown CA (1957) The infrared spectra of some Ti-O-Si, Ti-O-Ti and Si-O-Si compounds. J Phys Chem 61:1174\u20131177","journal-title":"J Phys Chem"},{"key":"9178_CR94","doi-asserted-by":"crossref","first-page":"273","DOI":"10.1007\/s10751-006-9277-6","volume":"165","author":"S Zhu","year":"2005","unstructured":"Zhu S, Liu W, Fan C, Li Y (2005) M\u00f6ssbauer study of nano-TiO2 doped with Fe. Hyperfine Interactions 165:273\u2013278","journal-title":"Hyperfine Interactions"}],"container-title":["Environmental Science and Pollution Research"],"original-title":[],"language":"en","link":[{"URL":"https:\/\/link.springer.com\/content\/pdf\/10.1007\/s11356-020-09178-1.pdf","content-type":"application\/pdf","content-version":"vor","intended-application":"text-mining"},{"URL":"https:\/\/link.springer.com\/article\/10.1007\/s11356-020-09178-1\/fulltext.html","content-type":"text\/html","content-version":"vor","intended-application":"text-mining"},{"URL":"https:\/\/link.springer.com\/content\/pdf\/10.1007\/s11356-020-09178-1.pdf","content-type":"application\/pdf","content-version":"vor","intended-application":"similarity-checking"}],"deposited":{"date-parts":[[2021,5,30]],"date-time":"2021-05-30T00:33:04Z","timestamp":1622334784000},"score":1,"resource":{"primary":{"URL":"https:\/\/link.springer.com\/10.1007\/s11356-020-09178-1"}},"subtitle":[],"short-title":[],"issued":{"date-parts":[[2020,5,30]]},"references-count":94,"journal-issue":{"issue":"19","published-print":{"date-parts":[[2021,5]]}},"alternative-id":["9178"],"URL":"https:\/\/doi.org\/10.1007\/s11356-020-09178-1","relation":{},"ISSN":["0944-1344","1614-7499"],"issn-type":[{"value":"0944-1344","type":"print"},{"value":"1614-7499","type":"electronic"}],"subject":[],"published":{"date-parts":[[2020,5,30]]},"assertion":[{"value":"11 February 2020","order":1,"name":"received","label":"Received","group":{"name":"ArticleHistory","label":"Article History"}},{"value":"4 May 2020","order":2,"name":"accepted","label":"Accepted","group":{"name":"ArticleHistory","label":"Article History"}},{"value":"30 May 2020","order":3,"name":"first_online","label":"First Online","group":{"name":"ArticleHistory","label":"Article History"}}]}}