{"status":"ok","message-type":"work","message-version":"1.0.0","message":{"indexed":{"date-parts":[[2025,11,18]],"date-time":"2025-11-18T09:26:23Z","timestamp":1763457983072,"version":"3.37.3"},"reference-count":30,"publisher":"Springer Science and Business Media LLC","issue":"19","license":[{"start":{"date-parts":[[2021,1,9]],"date-time":"2021-01-09T00:00:00Z","timestamp":1610150400000},"content-version":"tdm","delay-in-days":0,"URL":"https:\/\/www.springer.com\/tdm"},{"start":{"date-parts":[[2021,1,9]],"date-time":"2021-01-09T00:00:00Z","timestamp":1610150400000},"content-version":"vor","delay-in-days":0,"URL":"https:\/\/www.springer.com\/tdm"}],"funder":[{"DOI":"10.13039\/501100002322","name":"Coordination for the Improvement of Higher Education Personnel","doi-asserted-by":"crossref","award":["88881.068433\/2014-01"],"award-info":[{"award-number":["88881.068433\/2014-01"]}],"id":[{"id":"10.13039\/501100002322","id-type":"DOI","asserted-by":"crossref"}]},{"DOI":"10.13039\/501100001807","name":"Funda\u00e7\u00e3o de Amparo \u00e0 Pesquisa do Estado de S\u00e3o Paulo","doi-asserted-by":"publisher","award":["2013\/50218-2"],"award-info":[{"award-number":["2013\/50218-2"]}],"id":[{"id":"10.13039\/501100001807","id-type":"DOI","asserted-by":"publisher"}]},{"DOI":"10.13039\/501100002322","name":"Coordination for the Improvement of Higher Education Personnel","doi-asserted-by":"crossref","award":["3300201"],"award-info":[{"award-number":["3300201"]}],"id":[{"id":"10.13039\/501100002322","id-type":"DOI","asserted-by":"crossref"}]}],"content-domain":{"domain":["link.springer.com"],"crossmark-restriction":false},"short-container-title":["Environ Sci Pollut Res"],"published-print":{"date-parts":[[2021,5]]},"DOI":"10.1007\/s11356-020-11885-8","type":"journal-article","created":{"date-parts":[[2021,1,9]],"date-time":"2021-01-09T08:47:11Z","timestamp":1610182031000},"page":"24057-24066","update-policy":"https:\/\/doi.org\/10.1007\/springer_crossmark_policy","source":"Crossref","is-referenced-by-count":8,"title":["Degradation of 2,4,6-trichlorophenol in aqueous systems through the association of zero-valent-copper-mediated reduction and UVC\/H2O2: effect of water matrix and toxicity assessment"],"prefix":"10.1007","volume":"28","author":[{"ORCID":"https:\/\/orcid.org\/0000-0001-7680-103X","authenticated-orcid":false,"given":"Larissa Pinheiro","family":"de Souza","sequence":"first","affiliation":[]},{"given":"C\u00e1tia Alexandra Le\u00e7a","family":"Gra\u00e7a","sequence":"additional","affiliation":[]},{"given":"Antonio Carlos S. C.","family":"Teixeira","sequence":"additional","affiliation":[]},{"given":"Osvaldo","family":"Chiavone-Filho","sequence":"additional","affiliation":[]}],"member":"297","published-online":{"date-parts":[[2021,1,9]]},"reference":[{"key":"11885_CR1","unstructured":"Agency for Toxic Substances and Disease Registry (1999) Toxicological Profile for Chlorophenols. https:\/\/www.atsdr.cdc.gov\/toxprofiles\/tp107.pdf. Accessed 28 August 2019"},{"key":"11885_CR2","volume-title":"Photochemical Technology","author":"AM Braun","year":"1991","unstructured":"Braun AM, Maurette MT, Oliveros E (1991) Photochemical Technology. John Wiley & Sons, Chichester"},{"key":"11885_CR3","volume-title":"Chemistry: the central science","author":"TL Brown","year":"2009","unstructured":"Brown TL, Lemay HE, Bursten BE, Murphy CJ (2009) Chemistry: the central science. Pearson Prentice Hall, Boston"},{"key":"11885_CR4","doi-asserted-by":"publisher","first-page":"S205","DOI":"10.1016\/j.arabjc.2012.07.023","volume":"10","author":"K Chanderia","year":"2017","unstructured":"Chanderia K, Kumarb S, Sharmaa J, Ametaa R, Punjabi PB (2017) Degradation of Sunset Yellow FCF using copper loaded bentonite and H2O2 as photo-Fenton like reagent. Arab J Chem 10:S205\u2013S211. https:\/\/doi.org\/10.1016\/j.arabjc.2012.07.023","journal-title":"Arab J Chem"},{"key":"11885_CR5","doi-asserted-by":"publisher","first-page":"984","DOI":"10.1016\/j.jhazmat.2008.12.004","volume":"166","author":"JH Choi","year":"2009","unstructured":"Choi JH, Kim YH (2009) Reduction of 2,4,6-trichlorophenol with zero-valent zinc and catalyzed zinc. J Hazard Mater 166:984\u2013991. https:\/\/doi.org\/10.1016\/j.jhazmat.2008.12.004","journal-title":"J Hazard Mater"},{"key":"11885_CR6","doi-asserted-by":"publisher","first-page":"505","DOI":"10.1016\/j.cej.2017.07.149","volume":"330","author":"J Deng","year":"2017","unstructured":"Deng J, Y-q C, Yu-an L, Crittenden JC, S-q Z, N-y G, Li J (2017) Mesoporous manganese cobaltite nanocages as effective and reusable heterogeneous peroxymonosulfate activators for carbamazepine degradation. Chem Eng J 330:505\u2013517. https:\/\/doi.org\/10.1016\/j.cej.2017.07.149","journal-title":"Chem Eng J"},{"key":"11885_CR7","doi-asserted-by":"publisher","first-page":"765","DOI":"10.1016\/S1001-0742(11)60817-6","volume":"24","author":"PJ Dorathi","year":"2012","unstructured":"Dorathi PJ, Kandasamy P (2012) Dechlorination of chlorophenols by zero valent iron impregnated silica. J Environ Sci 24:765\u2013773. https:\/\/doi.org\/10.1016\/S1001-0742(11)60817-6","journal-title":"J Environ Sci"},{"key":"11885_CR8","doi-asserted-by":"publisher","first-page":"415","DOI":"10.1016\/j.chemosphere.2015.11.030","volume":"144","author":"C Fang","year":"2016","unstructured":"Fang C, Xiao D, Liu W, Lou X, Zhou J, Wang Z (2016) Enhanced AOX accumulation and aquatic toxicity during 2,4,6-trichlorophenol degradation in a Co (II)\/peroxymonosulfate\/Cl\u2013 system. Chemosphere 144:415\u20132420. https:\/\/doi.org\/10.1016\/j.chemosphere.2015.11.030","journal-title":"Chemosphere"},{"key":"11885_CR9","doi-asserted-by":"publisher","first-page":"4255","DOI":"10.1016\/S0043-1354(02)00165-3","volume":"36","author":"AR Fernand\u00e9z-Alba","year":"2002","unstructured":"Fernand\u00e9z-Alba AR, Hernando D, Ag\u00fcera A, C\u00e1ceres J, Malato S (2002) Toxicity assays: a way for evaluating AOPs efficiency. Water Res 36:4255\u20134262. https:\/\/doi.org\/10.1016\/S0043-1354(02)00165-3","journal-title":"Water Res"},{"key":"11885_CR10","doi-asserted-by":"publisher","first-page":"1","DOI":"10.1016\/j.jhazmat.2006.10.063","volume":"140","author":"K Gopal","year":"2007","unstructured":"Gopal K, Tripathy SS, Bersillon JL, Dubey SP (2007) Chlorination byproducts, their toxicodynamics and removal from drinking water. J Hazard Mater 140:1\u20136. https:\/\/doi.org\/10.1016\/j.jhazmat.2006.10.063","journal-title":"J Hazard Mater"},{"key":"11885_CR11","doi-asserted-by":"publisher","first-page":"125461","DOI":"10.1016\/j.chemosphere.2019.125461","volume":"244","author":"CAL Gra\u00e7a","year":"2020","unstructured":"Gra\u00e7a CAL, Mendes MA, Teixeira ACSC, Velosa AC (2020) Anoxic degradation of chlorpyrifos by zerovalent monometallic and bimetallic particles in solution. Chemosphere 244:125461. https:\/\/doi.org\/10.1016\/j.chemosphere.2019.125461","journal-title":"Chemosphere"},{"key":"11885_CR12","doi-asserted-by":"publisher","first-page":"117546","DOI":"10.1016\/j.seppur.2020.117546","volume":"254","author":"Q Guo","year":"2021","unstructured":"Guo Q, Jing L, Lan Y, He M, Xu Y, Xu H, Li H (2021) Construction 3D rod-like Bi3.64Mo0.36O6.55\/CuBi2O4 photocatalyst for enhanced photocatalytic activity via a photo-Fenton-like Cu2+\/Cu+ redox cycle. Sep Purif Technol 254:117546. https:\/\/doi.org\/10.1016\/j.seppur.2020.117546","journal-title":"Sep Purif Technol"},{"issue":"19","key":"11885_CR13","doi-asserted-by":"publisher","first-page":"1920","DOI":"10.1002\/anie.199419201","volume":"33","author":"D Henschler","year":"1994","unstructured":"Henschler D (1994) Toxicity of chlorinated organic compounds: effects of the introduction of chlorine in organic molecules. Angew Chem 33(19):1920\u20131935. https:\/\/doi.org\/10.1002\/anie.199419201","journal-title":"Angew Chem"},{"key":"11885_CR14","doi-asserted-by":"publisher","first-page":"1156","DOI":"10.1002\/jctb.5862","volume":"94","author":"LR Hollanda","year":"2018","unstructured":"Hollanda LR, Gra\u00e7a CAL, Andrade LM, Mendes MA, Chiavone-Filho O, Teixeira ACSC (2018) Non-traditional atrazine degradation induced by zero-valent-copper: process optimization by the Doehlert experimental design, intermediates detection and toxicity assessment. J Chem Technol Biotechnol 94:1156\u20131164. https:\/\/doi.org\/10.1002\/jctb.5862","journal-title":"J Chem Technol Biotechnol"},{"key":"11885_CR15","doi-asserted-by":"publisher","first-page":"104","DOI":"10.1016\/j.chemosphere.2018.06.076","volume":"209","author":"M-C Hsieh","year":"2018","unstructured":"Hsieh M-C, Panchangam SC, Lai WW-P, Lin AY-C (2018) Degradation of methadone by the sunlight\/FC process: Kkinetics, radical species participation and influence of the water matrix. Chemosphere 209:104\u2013112. https:\/\/doi.org\/10.1016\/j.chemosphere.2018.06.076","journal-title":"Chemosphere"},{"key":"11885_CR16","doi-asserted-by":"publisher","first-page":"442","DOI":"10.1016\/j.chemosphere.2018.04.001","volume":"203","author":"Z Huang","year":"2018","unstructured":"Huang Z, Chen Z, Chen Y, Hu Y (2018) Synergistic effects in iron-copper bimetal doped mesoporous g-Al2O3 for Fenton-like oxidation of 4-chlorophenol: Sstructure, composition, electrochemical behaviors and catalytic performance. Chemosphere 203:442\u2013449. https:\/\/doi.org\/10.1016\/j.chemosphere.2018.04.001","journal-title":"Chemosphere"},{"key":"11885_CR17","doi-asserted-by":"publisher","first-page":"183","DOI":"10.1016\/j.cej.2012.12.033","volume":"218","author":"H Ji","year":"2013","unstructured":"Ji H, Chang F, Hu X, Qin W, Shen J (2013) Photocatalytic degradation of 2,4,6- trichlorophenol over g-C3N4 under visible light irradiation. Chem Eng J 218:183\u2013190. https:\/\/doi.org\/10.1016\/j.cej.2012.12.033","journal-title":"Chem Eng J"},{"key":"11885_CR18","doi-asserted-by":"publisher","first-page":"1","DOI":"10.1007\/s11270-014-2143-2","volume":"225","author":"D Juretic","year":"2014","unstructured":"Juretic D, Puric J, Kusic H, Marin V, Bozic AL (2014) Structural influence on photooxidative degradation of halogenated phenols. Water Air Soil Pollut 225:1\u201318. https:\/\/doi.org\/10.1007\/s11270-014-2143-2","journal-title":"Water Air Soil Pollut"},{"key":"11885_CR19","doi-asserted-by":"publisher","first-page":"1455","DOI":"10.1080\/09593330309385690","volume":"24","author":"Y-H Kim","year":"2003","unstructured":"Kim Y-H, Carraway ER (2003) Dechlorination of chlorinated phenols by zero valent zinc. Environ Technol 24:1455\u20131463. https:\/\/doi.org\/10.1080\/09593330309385690","journal-title":"Environ Technol"},{"key":"11885_CR20","doi-asserted-by":"crossref","first-page":"59","DOI":"10.3176\/chem.2001.2.01","volume":"50","author":"R Munter","year":"2001","unstructured":"Munter R (2001) Advanced oxidation processes-current status and prospect. Proc Estonian Acad Sci Chem 50:59\u201380 https:\/\/www.kirj.ee\/public\/va_ke\/k50-2-1.pdf Accessed 09 October 2020","journal-title":"Proc Estonian Acad Sci Chem"},{"key":"11885_CR21","doi-asserted-by":"publisher","first-page":"86","DOI":"10.1016\/j.talanta.2004.10.001","volume":"66","author":"RFP Nogueira","year":"2005","unstructured":"Nogueira RFP, Oliveira MC, Partelini WC (2005) Simple and fast spectrophotometric determination of H2O2 in photo-Fenton reactions using metavanadate. Talanta 66:86\u201391. https:\/\/doi.org\/10.1016\/j.talanta.2004.10.001","journal-title":"Talanta"},{"key":"11885_CR22","volume-title":"Photochemical purification of water and air","author":"T Oppenl\u00e4nder","year":"2003","unstructured":"Oppenl\u00e4nder T (2003) Photochemical purification of water and air. Wiley- VCH, Darmstadt"},{"key":"11885_CR23","doi-asserted-by":"publisher","first-page":"408","DOI":"10.1016\/j.jenvman.2019.02.100","volume":"237","author":"C Pe\u00f1a-Guzm\u00e1n","year":"2019","unstructured":"Pe\u00f1a-Guzm\u00e1n C, Ulloa-Sancheza S, Morab K, Helena-Bustosc R, Lopez-Barrerad E, Alvareza J, Rodriguez-Pinzon M (2019) Emerging pollutants in the urban water cycle in Latin America: aA review of the current literature. J Environ Manag 237:408\u2013423. https:\/\/doi.org\/10.1016\/j.jenvman.2019.02.100","journal-title":"J Environ Manag"},{"key":"11885_CR24","doi-asserted-by":"publisher","first-page":"71","DOI":"10.1016\/j.mrgentox.2006.12.008","volume":"629","author":"TS Pereira","year":"2007","unstructured":"Pereira TS, Rocha JAV, Duccatti A, Silveira GA, Pastoriza TF, Bringuenti L, Vargas VMF (2007) Evaluation of mutagenic activity in supply water at three sites in the state of Rio Grande do Sul, Brazil. Mutat Res 629:71\u201380. https:\/\/doi.org\/10.1016\/j.mrgentox.2006.12.008","journal-title":"Mutat Res"},{"key":"11885_CR25","doi-asserted-by":"publisher","first-page":"169","DOI":"10.1007\/s11270-008-9901-y","volume":"200","author":"P Saritha","year":"2009","unstructured":"Saritha P, Raj DSS, Aparna C, Laxmi PNV, Himabindu V, Anjaneyulu Y (2009) Degradative oxidation of 2,4,6-trichlorophenol using advanced oxidation processes\u2013aA comparative study. Water Air Soil Pollut 200:169\u2013179. https:\/\/link.springer.com\/article\/10.1007\/s11270-008-9901-y","journal-title":"Water Air Soil Pollut"},{"key":"11885_CR26","doi-asserted-by":"publisher","first-page":"907","DOI":"10.1016\/0043-1354(94)00198-G","volume":"29","author":"YS Shen","year":"1995","unstructured":"Shen YS, Ku Y, Lee K-C (1995) The effect of light absorbance on the decomposition of chlorophenols by ultraviolet radiation and UV\/H2O2 processes. Water Res 29:907\u2013914. https:\/\/doi.org\/10.1016\/0043-1354(94)00198-G","journal-title":"Water Res"},{"key":"11885_CR27","first-page":"82","volume":"30","author":"J Sheng-Yang","year":"2010","unstructured":"Sheng-Yang J, Yu-Jun W, Lian-Zhen L, Dong-Mei Z, Shen-Qiang W (2010) Comparison of degradation kinetics of 2,4,6-trichlorophenol using nanometer-and micrometer-sized Fe0. China Environ Sci 30:82\u201387","journal-title":"China Environ Sci"},{"key":"11885_CR28","doi-asserted-by":"publisher","first-page":"348","DOI":"10.1016\/j.psep.2019.05.032","volume":"127","author":"LP Souza","year":"2019","unstructured":"Souza LP, Gra\u00e7a CAL, Taqueda MES, Teixeira ACSC, Chiavone-Filho O (2019) Insights into the reactivity of zero-valent-copper-containing materials as reducing agents of 2,4,6-trichlorophenol in a recirculating packed-column system: Ddegradation mechanism and toxicity evaluation. Process Saf Environ Prot 127:348\u2013358. https:\/\/doi.org\/10.1016\/j.psep.2019.05.032","journal-title":"Process Saf Environ Prot"},{"key":"11885_CR29","unstructured":"World Health Organization (2011) In: WHO (Ed.), Guidelines for Drinking-Water Quality 4:104-108. https:\/\/apps.who.int\/iris\/bitstream\/handle\/10665\/44584\/9789241548151_eng.pdf;jsessionid=9A1140299727C71608B4F93AA166D8CD?sequence=1. Accessed 09 Oct 2020"},{"key":"11885_CR30","doi-asserted-by":"publisher","first-page":"156","DOI":"10.1016\/j.chemosphere.2017.10.023","volume":"191","author":"A Yazdanbakhsh","year":"2018","unstructured":"Yazdanbakhsh A, Eslami A, Moussavi G (2018) Photo-assisted degradation of 2,4,6-trichlorophenol by an advanced reduction process based on sulfite anion radical: degradation, dechlorination and mineralization. Chemosphere 191:156\u2013165. https:\/\/doi.org\/10.1016\/j.chemosphere.2017.10.023","journal-title":"Chemosphere"}],"container-title":["Environmental Science and Pollution Research"],"original-title":[],"language":"en","link":[{"URL":"https:\/\/link.springer.com\/content\/pdf\/10.1007\/s11356-020-11885-8.pdf","content-type":"application\/pdf","content-version":"vor","intended-application":"text-mining"},{"URL":"https:\/\/link.springer.com\/article\/10.1007\/s11356-020-11885-8\/fulltext.html","content-type":"text\/html","content-version":"vor","intended-application":"text-mining"},{"URL":"https:\/\/link.springer.com\/content\/pdf\/10.1007\/s11356-020-11885-8.pdf","content-type":"application\/pdf","content-version":"vor","intended-application":"similarity-checking"}],"deposited":{"date-parts":[[2022,12,11]],"date-time":"2022-12-11T02:21:35Z","timestamp":1670725295000},"score":1,"resource":{"primary":{"URL":"https:\/\/link.springer.com\/10.1007\/s11356-020-11885-8"}},"subtitle":[],"short-title":[],"issued":{"date-parts":[[2021,1,9]]},"references-count":30,"journal-issue":{"issue":"19","published-print":{"date-parts":[[2021,5]]}},"alternative-id":["11885"],"URL":"https:\/\/doi.org\/10.1007\/s11356-020-11885-8","relation":{},"ISSN":["0944-1344","1614-7499"],"issn-type":[{"type":"print","value":"0944-1344"},{"type":"electronic","value":"1614-7499"}],"subject":[],"published":{"date-parts":[[2021,1,9]]},"assertion":[{"value":"14 July 2020","order":1,"name":"received","label":"Received","group":{"name":"ArticleHistory","label":"Article History"}},{"value":"30 November 2020","order":2,"name":"accepted","label":"Accepted","group":{"name":"ArticleHistory","label":"Article History"}},{"value":"9 January 2021","order":3,"name":"first_online","label":"First Online","group":{"name":"ArticleHistory","label":"Article History"}},{"order":1,"name":"Ethics","group":{"name":"EthicsHeading","label":"Compliance with ethical standards"}},{"value":"Not applicable.","order":2,"name":"Ethics","group":{"name":"EthicsHeading","label":"Ethical approval"}},{"value":"All the authors mentioned in the manuscript have agreed for authorship, read, and approved the manuscript, and given consent for submission and subsequent publication of the manuscript.","order":3,"name":"Ethics","group":{"name":"EthicsHeading","label":"Consent to participate"}},{"value":"The authors declare that they have no conflict of interest.","order":4,"name":"Ethics","group":{"name":"EthicsHeading","label":"Conflict of interest"}}]}}