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The main objective of this study was to biosynthesize stable and multifunctional silver nanoparticles (AgNP) using different plant by-products as reducers and capping agents. Extracts obtained from <jats:italic>Eucalyptus globulus<\/jats:italic><jats:italic>, <\/jats:italic><jats:italic>Pinus pinaster, Citrus sinensis<\/jats:italic>, <jats:italic>Cedrus atlantica<\/jats:italic> and <jats:italic>Camellia sinensis<\/jats:italic> by-products, were evaluated. From all plant by-products tested, aqueous extract of eucalyptus leaves (EL), green tea (GT) and black tea (BT) were selected due to their higher antioxidant phenolic content and were individually employed as reducers and capping agents to biosynthesize AgNP. The green AgNP showed zeta potential values of -31.8 to -36.3\u00a0mV, with a wide range of particle sizes (40.6 to 86.4\u00a0nm), depending on the plant extract used. Green AgNP exhibited an inhibitory effect against various pathogenic bacteria, including Gram-negative (<jats:italic>P. putida, E. coli<\/jats:italic>, <jats:italic>Vibrio spp.<\/jats:italic>) and Gram-positive (<jats:italic>B. megaterium, S. aureus, S. equisimilis<\/jats:italic>) bacteria with EL-AgNP being the nanostructure with the greatest antimicrobial action. EL-AgNP showed an excellent photodegradation of indigo carmine (IC) dye under direct sunlight, with a removal percentage of up to 100% after 75\u00a0min. A complete cost analysis revealed a competitive total cost range of 8.0\u20139.0 \u20ac\/g for the biosynthesis of AgNP.<\/jats:p>\n                <jats:p><jats:bold>Graphical Abstract<\/jats:bold><\/jats:p>","DOI":"10.1007\/s11356-024-32180-w","type":"journal-article","created":{"date-parts":[[2024,1,27]],"date-time":"2024-01-27T00:07:03Z","timestamp":1706314023000},"page":"14191-14207","update-policy":"https:\/\/doi.org\/10.1007\/springer_crossmark_policy","source":"Crossref","is-referenced-by-count":14,"title":["Valorization of plant by-products in the biosynthesis of silver nanoparticles with antimicrobial and catalytic properties"],"prefix":"10.1007","volume":"31","author":[{"ORCID":"https:\/\/orcid.org\/0000-0002-1260-2936","authenticated-orcid":false,"given":"Ver\u00f3nica","family":"Rocha","sequence":"first","affiliation":[]},{"given":"Pedro","family":"Ferreira-Santos","sequence":"additional","affiliation":[]},{"given":"Cristina","family":"Aguiar","sequence":"additional","affiliation":[]},{"given":"Isabel C.","family":"Neves","sequence":"additional","affiliation":[]},{"given":"Teresa","family":"Tavares","sequence":"additional","affiliation":[]}],"member":"297","published-online":{"date-parts":[[2024,1,26]]},"reference":[{"key":"32180_CR1","doi-asserted-by":"publisher","first-page":"40","DOI":"10.1016\/j.jphotochem.2016.11.001","volume":"335","author":"MF Abdel Messih","year":"2017","unstructured":"Abdel Messih MF, Ahmed MA, Soltan A, Anis SS (2017) Facile approach for homogeneous dispersion of metallic silver nanoparticles on the surface of mesoporous titania for photocatalytic degradation of methylene blue and indigo carmine dyes. 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