{"status":"ok","message-type":"work","message-version":"1.0.0","message":{"indexed":{"date-parts":[[2026,3,6]],"date-time":"2026-03-06T08:06:52Z","timestamp":1772784412990,"version":"3.50.1"},"reference-count":59,"publisher":"Springer Science and Business Media LLC","issue":"57","license":[{"start":{"date-parts":[[2024,11,22]],"date-time":"2024-11-22T00:00:00Z","timestamp":1732233600000},"content-version":"tdm","delay-in-days":0,"URL":"https:\/\/creativecommons.org\/licenses\/by\/4.0"},{"start":{"date-parts":[[2024,11,22]],"date-time":"2024-11-22T00:00:00Z","timestamp":1732233600000},"content-version":"vor","delay-in-days":0,"URL":"https:\/\/creativecommons.org\/licenses\/by\/4.0"}],"funder":[{"DOI":"10.13039\/501100001871","name":"Funda\u00e7\u00e3o para a Ci\u00eancia e a Tecnologia","doi-asserted-by":"publisher","award":["SFRH\/BD\/151346\/2021"],"award-info":[{"award-number":["SFRH\/BD\/151346\/2021"]}],"id":[{"id":"10.13039\/501100001871","id-type":"DOI","asserted-by":"publisher"}]},{"DOI":"10.13039\/501100001871","name":"Funda\u00e7\u00e3o para a Ci\u00eancia e a Tecnologia","doi-asserted-by":"publisher","award":["SFRH\/BD\/143224\/2019"],"award-info":[{"award-number":["SFRH\/BD\/143224\/2019"]}],"id":[{"id":"10.13039\/501100001871","id-type":"DOI","asserted-by":"publisher"}]},{"DOI":"10.13039\/501100001871","name":"Funda\u00e7\u00e3o para a Ci\u00eancia e a Tecnologia","doi-asserted-by":"publisher","award":["2022.04079.CEECIND"],"award-info":[{"award-number":["2022.04079.CEECIND"]}],"id":[{"id":"10.13039\/501100001871","id-type":"DOI","asserted-by":"publisher"}]},{"DOI":"10.13039\/501100015322","name":"Instituto Polit\u00e9cnico de Bragan\u00e7a","doi-asserted-by":"crossref","id":[{"id":"10.13039\/501100015322","id-type":"DOI","asserted-by":"crossref"}]}],"content-domain":{"domain":["link.springer.com"],"crossmark-restriction":false},"short-container-title":["Environ Sci Pollut Res"],"abstract":"<jats:title>Abstract<\/jats:title><jats:p>Single- and bimetallic carbon xerogels were prepared by incorporating iron and iron-cobalt precursors during their synthesis, respectively, and tested in the catalytic wet peroxide oxidation (CWPO) of ibuprofen spiked into a simulated matrix in batch mode. The bimetallic catalyst outperformed single and non-metallic catalyst by 25 and 85% after 360\u00a0min of reaction, at mild temperature (30\u00a0\u00b0C). The best-performing catalyst was further used to treat hospital wastewater in a CWPO system operating in full continuous mode. Process optimization was carried out considering different catalyst loads, temperatures, and pH. The results obtained showed that the best conditions are initial pH 3, <jats:italic>T<\/jats:italic>\u2009=\u200980\u00a0\u00b0C, and a catalyst load of 35.4\u00a0mg\u00a0cm<jats:sup>\u22123<\/jats:sup>. Having maintained values of chemical oxygen demand (COD) removals as high as 80% after 24\u00a0h of continuous operation, the results herein reported revealed the high potential of the bimetallic carbon xerogel for CWPO of hospital wastewater beyond conventional applications in batch mode. Despite some catalytic deactivation, the bimetallic carbon xerogel still delivered a mineralization degree as high as 55% of the initial total organic carbon (TOC) content of the hospital wastewater in the third 24-h cycle of CWPO in continuous mode of operation with successive catalyst reuse, as opposed to a 73% TOC removal in the first cycle. Therefore, our results open prospects for the implementation of CWPO for hospital wastewater treatment in continuous mode of operation.<\/jats:p>","DOI":"10.1007\/s11356-024-35546-2","type":"journal-article","created":{"date-parts":[[2024,11,22]],"date-time":"2024-11-22T14:04:12Z","timestamp":1732284252000},"page":"65208-65219","update-policy":"https:\/\/doi.org\/10.1007\/springer_crossmark_policy","source":"Crossref","is-referenced-by-count":3,"title":["Beyond batch experiments: unveiling the potential of bimetallic carbon xerogels for catalytic wet peroxide oxidation of hospital wastewater in continuous mode"],"prefix":"10.1007","volume":"31","author":[{"given":"Adriano","family":"Santos Silva","sequence":"first","affiliation":[]},{"given":"Fernanda Fontana","family":"Roman","sequence":"additional","affiliation":[]},{"given":"Rui S\u00e9rgio","family":"Ribeiro","sequence":"additional","affiliation":[]},{"given":"Juan","family":"Garcia","sequence":"additional","affiliation":[]},{"ORCID":"https:\/\/orcid.org\/0000-0001-6898-2408","authenticated-orcid":false,"given":"Helder Teixeira","family":"Gomes","sequence":"additional","affiliation":[]}],"member":"297","published-online":{"date-parts":[[2024,11,22]]},"reference":[{"key":"35546_CR1","doi-asserted-by":"publisher","unstructured":"Al Azri N, Patel R, Ozbuyukkaya G, et al (2022) Batch-to-Continuous transition in the specialty chemicals industry: impact of operational differences on the production of dispersants. Chemical Engineering Journal 445:. https:\/\/doi.org\/10.1016\/j.cej.2022.136775","DOI":"10.1016\/j.cej.2022.136775"},{"key":"35546_CR2","doi-asserted-by":"publisher","unstructured":"del \u00c1lamo AC, Gonz\u00e1lez C, Pariente MI, et al (2020) Fenton-like catalyst based on a reticulated porous perovskite material: activity and stability for the on-site removal of pharmaceutical micropollutans in a hospital wastewater. Chemical Engineering Journal 401:. https:\/\/doi.org\/10.1016\/j.cej.2020.126113","DOI":"10.1016\/j.cej.2020.126113"},{"key":"35546_CR3","doi-asserted-by":"crossref","unstructured":"Atugoda T, Vithanage M, Wijesekara H, et al (2021) Interactions between microplastics, pharmaceuticals and personal care products: Implications for vector transport. Environ Int 149","DOI":"10.1016\/j.envint.2020.106367"},{"key":"35546_CR4","doi-asserted-by":"publisher","first-page":"497","DOI":"10.1002\/jctb.2538","volume":"86","author":"P Bautista","year":"2011","unstructured":"Bautista P, Mohedano AF, Casas JA et al (2011) Highly stable Fe\/\u03b3-Al2O3 catalyst for catalytic wet peroxide oxidation. J Chem Technol Biotechnol 86:497\u2013504. https:\/\/doi.org\/10.1002\/jctb.2538","journal-title":"J Chem Technol Biotechnol"},{"key":"35546_CR5","doi-asserted-by":"crossref","unstructured":"Bukhtiyarova M V., Nuzhdin AL, Bukhtiyarova GA (2023) Comparative study of batch and continuous flow reactors in selective hydrogenation of functional groups in organic compounds: what is more effective? Int J Mol Sci 24","DOI":"10.3390\/ijms241814136"},{"key":"35546_CR6","doi-asserted-by":"publisher","DOI":"10.1016\/j.watres.2020.116668","volume":"190","author":"P Chakraborty","year":"2021","unstructured":"Chakraborty P, Shappell NW, Mukhopadhyay M et al (2021) Surveillance of plasticizers, bisphenol A, steroids and caffeine in surface water of River Ganga and Sundarban wetland along the Bay of Bengal: occurrence, sources, estrogenicity screening and ecotoxicological risk assessment. Water Res 190:116668. https:\/\/doi.org\/10.1016\/j.watres.2020.116668","journal-title":"Water Res"},{"key":"35546_CR7","doi-asserted-by":"publisher","first-page":"238","DOI":"10.3390\/catal12020238","volume":"12","author":"BG de Freitas","year":"2022","unstructured":"Freitas BG, Roman FF, de Tuesta JLD et al (2022) Assessment of pretreatments for highly concentrated leachate waters to enhance the performance of catalytic wet peroxide oxidation with sustainable low-cost catalysts. Catalysts 12:238. https:\/\/doi.org\/10.3390\/catal12020238","journal-title":"Catalysts"},{"key":"35546_CR8","doi-asserted-by":"publisher","first-page":"216","DOI":"10.1016\/j.cattod.2019.08.033","volume":"356","author":"JL Diaz de Tuesta","year":"2020","unstructured":"Diaz de Tuesta JL, Quintanilla A, Casas JA et al (2020) The pH effect on the kinetics of 4-nitrophenol removal by CWPO with doped carbon black catalysts. Catal Today 356:216\u2013225. https:\/\/doi.org\/10.1016\/j.cattod.2019.08.033","journal-title":"Catal Today"},{"key":"35546_CR9","doi-asserted-by":"publisher","DOI":"10.1016\/j.cattod.2023.114162","volume":"419","author":"JL Diaz de Tuesta","year":"2023","unstructured":"Diaz de Tuesta JL, Silva AS, Roman FF et al (2023) Polyolefin-derived carbon nanotubes as magnetic catalysts for wet peroxide oxidation of paracetamol in aqueous solutions. Catal Today 419:114162. https:\/\/doi.org\/10.1016\/j.cattod.2023.114162","journal-title":"Catal Today"},{"key":"35546_CR10","doi-asserted-by":"publisher","DOI":"10.1016\/j.jece.2020.105004","volume":"9","author":"JL Diaz De Tuesta","year":"2021","unstructured":"Diaz De Tuesta JL, Saviotti MC, Roman FF et al (2021) Assisted hydrothermal carbonization of agroindustrial byproducts as effective step in the production of activated carbon catalysts for wet peroxide oxidation of micro-pollutants. J Environ Chem Eng 9:105004. https:\/\/doi.org\/10.1016\/j.jece.2020.105004","journal-title":"J Environ Chem Eng"},{"key":"35546_CR11","doi-asserted-by":"publisher","unstructured":"Felis E, Kalka J, Sochacki A, et al (2020) Antimicrobial pharmaceuticals in the aquatic environment - occurrence and environmental implications. Eur J Pharmacol 866:. https:\/\/doi.org\/10.1016\/j.ejphar.2019.172813","DOI":"10.1016\/j.ejphar.2019.172813"},{"key":"35546_CR12","doi-asserted-by":"publisher","first-page":"738","DOI":"10.1016\/j.chemosphere.2017.05.039","volume":"182","author":"A Fischbacher","year":"2017","unstructured":"Fischbacher A, von Sonntag C, Schmidt TC (2017) Hydroxyl radical yields in the Fenton process under various pH, ligand concentrations and hydrogen peroxide\/Fe(II) ratios. Chemosphere 182:738\u2013744. https:\/\/doi.org\/10.1016\/j.chemosphere.2017.05.039","journal-title":"Chemosphere"},{"key":"35546_CR13","doi-asserted-by":"publisher","unstructured":"Gallego-R\u00edos SE, Pe\u00f1uela GA (2021) Evaluation of ibuprofen and diclofenac in the main rivers of Colombia and striped catfish Pseudoplatystoma magdaleniatum. Environ Monit Assess 193:. https:\/\/doi.org\/10.1007\/s10661-021-08922-5","DOI":"10.1007\/s10661-021-08922-5"},{"key":"35546_CR14","doi-asserted-by":"publisher","unstructured":"Gong H, Chu W, Huang Y, et al (2021) Solar photocatalytic degradation of ibuprofen with a magnetic catalyst: effects of parameters, efficiency in effluent, mechanism and toxicity evolution. Environmental Pollution 276:. https:\/\/doi.org\/10.1016\/j.envpol.2021.116691","DOI":"10.1016\/j.envpol.2021.116691"},{"key":"35546_CR15","doi-asserted-by":"publisher","unstructured":"Guari NMC, Silva AS, Diaz de Tuesta JL, et al (2022) Magnetic CoFe2O4@carbon yolk-shell nanoparticles as catalysts for the catalytic wet peroxide oxidation of paracetamol: kinetic insights. https:\/\/doi.org\/10.30955\/gnj.004309","DOI":"10.30955\/gnj.004309"},{"key":"35546_CR16","doi-asserted-by":"publisher","unstructured":"Huaccallo-Aguilar Y, \u00c1lvarez-Torrellas S, Gil M V., et al (2021a) Insights of emerging contaminants removal in real water matrices by CWPO using a magnetic catalyst. J Environ Chem Eng 9:. https:\/\/doi.org\/10.1016\/j.jece.2021.106321","DOI":"10.1016\/j.jece.2021.106321"},{"key":"35546_CR17","doi-asserted-by":"publisher","unstructured":"Huaccallo-Aguilar Y, \u00c1lvarez-Torrellas S, Larriba M, et al (2021b) Naproxen removal by CWPO with Fe3O4\/multi-walled carbon nanotubes in a fixed-bed reactor. J Environ Chem Eng 9:. https:\/\/doi.org\/10.1016\/j.jece.2021.105110","DOI":"10.1016\/j.jece.2021.105110"},{"key":"35546_CR18","doi-asserted-by":"publisher","unstructured":"Huaccallo-Aguilar Y, Diaz de Tuesta JL, \u00c1lvarez-Torrellas S, et al (2021c) New insights on the removal of diclofenac and ibuprofen by CWPO using a magnetite-based catalyst in an up-flow fixed-bed reactor. J Environ Manage 281:. https:\/\/doi.org\/10.1016\/j.jenvman.2020.111913","DOI":"10.1016\/j.jenvman.2020.111913"},{"key":"35546_CR19","doi-asserted-by":"publisher","unstructured":"Huang H, Zhang H, Yan Y (2021) Preparation of novel catalyst-free Fe3C nanocrystals encapsulated NCNT structured catalyst for continuous catalytic wet peroxide oxidation of phenol. J Hazard Mater 407:. https:\/\/doi.org\/10.1016\/j.jhazmat.2020.124371","DOI":"10.1016\/j.jhazmat.2020.124371"},{"key":"35546_CR20","doi-asserted-by":"publisher","first-page":"641","DOI":"10.1016\/j.apcatb.2011.11.019","volume":"111\u2013112","author":"N Inchaurrondo","year":"2012","unstructured":"Inchaurrondo N, Cechini J, Font J, Haure P (2012) Strategies for enhanced CWPO of phenol solutions. Appl Catal B 111\u2013112:641\u2013648. https:\/\/doi.org\/10.1016\/j.apcatb.2011.11.019","journal-title":"Appl Catal B"},{"key":"35546_CR21","doi-asserted-by":"crossref","unstructured":"Li J, You J, Wang Z, et al (2022) Application of \u03b1-Fe2O3-based heterogeneous photo-Fenton catalyst in wastewater treatment: a review of recent advances. J Environ Chem Eng 10","DOI":"10.1016\/j.jece.2022.108329"},{"key":"35546_CR22","doi-asserted-by":"publisher","first-page":"165","DOI":"10.1016\/j.ab.2009.03.028","volume":"389","author":"P-F Liu","year":"2009","unstructured":"Liu P-F, Avramova LV, Park C (2009) Revisiting absorbance at 230nm as a protein unfolding probe. Anal Biochem 389:165\u2013170. https:\/\/doi.org\/10.1016\/j.ab.2009.03.028","journal-title":"Anal Biochem"},{"key":"35546_CR23","doi-asserted-by":"publisher","unstructured":"Liu Z, Shen Q, Zhou C, et al (2018) Kinetic and mechanistic study on catalytic decomposition of hydrogen peroxide on carbon-nanodots\/graphitic carbon nitride composite. Catalysts 8:. https:\/\/doi.org\/10.3390\/catal8100445","DOI":"10.3390\/catal8100445"},{"key":"35546_CR24","doi-asserted-by":"publisher","unstructured":"Liu N, Jin X, Feng C, et al (2020) Ecological risk assessment of fifty pharmaceuticals and personal care products (PPCPs) in Chinese surface waters: a proposed multiple-level system. Environ Int 136:. https:\/\/doi.org\/10.1016\/j.envint.2019.105454","DOI":"10.1016\/j.envint.2019.105454"},{"key":"35546_CR25","doi-asserted-by":"publisher","unstructured":"Lofrano G, Faiella M, Carotenuto M, et al (2021) Thirty contaminants of emerging concern identified in secondary treated hospital wastewater and their removal by solar Fenton (like) and sulphate radicals-based advanced oxidation processes. J Environ Chem Eng 9:. https:\/\/doi.org\/10.1016\/j.jece.2021.106614","DOI":"10.1016\/j.jece.2021.106614"},{"key":"35546_CR26","doi-asserted-by":"publisher","first-page":"29148","DOI":"10.1007\/s11356-024-33065-8","volume":"31","author":"N Lopez-Arago","year":"2024","unstructured":"Lopez-Arago N, Munoz M, de Pedro ZM, Casas JA (2024) Natural magnetite as an effective and long-lasting catalyst for CWPO of azole pesticides in a continuous up-flow fixed-bed reactor. Environ Sci Pollut Res 31:29148\u201329161. https:\/\/doi.org\/10.1007\/s11356-024-33065-8","journal-title":"Environ Sci Pollut Res"},{"key":"35546_CR27","doi-asserted-by":"publisher","unstructured":"Lu M, Yao Y, Gao L, et al (2015) Continuous treatment of phenol over an Fe2O3\/\u03b3-Al2O3 catalyst in a fixed-bed reactor. Water Air Soil Pollut 226:. https:\/\/doi.org\/10.1007\/s11270-015-2363-0","DOI":"10.1007\/s11270-015-2363-0"},{"key":"35546_CR28","doi-asserted-by":"crossref","unstructured":"M\u00e1rquez JJR, Levchuk I, Sillanp\u00e4\u00e4 M (2018) Application of catalytic wet peroxide oxidation for industrial and urban wastewater treatment: a review. Catalysts 8","DOI":"10.3390\/catal8120673"},{"key":"35546_CR29","doi-asserted-by":"publisher","unstructured":"Mello F V., Cunha SC, Foga\u00e7a FHS, et al (2022) Occurrence of pharmaceuticals in seafood from two Brazilian coastal areas: Implication for human risk assessment. Science of the Total Environment 803:. https:\/\/doi.org\/10.1016\/j.scitotenv.2021.149744","DOI":"10.1016\/j.scitotenv.2021.149744"},{"key":"35546_CR30","doi-asserted-by":"publisher","first-page":"455","DOI":"10.1016\/j.carbon.2004.10.022","volume":"43","author":"C Moreno-Castilla","year":"2005","unstructured":"Moreno-Castilla C, Maldonado-H\u00f3dar FJ (2005) Carbon aerogels for catalysis applications: an overview. Carbon N Y 43:455\u2013465","journal-title":"Carbon N Y"},{"key":"35546_CR31","doi-asserted-by":"publisher","first-page":"2311","DOI":"10.1007\/s10311-022-01447-4","volume":"20","author":"N Morin-Crini","year":"2022","unstructured":"Morin-Crini N, Lichtfouse E, Liu G et al (2022) Worldwide cases of water pollution by emerging contaminants: a review. Environ Chem Lett 20:2311\u20132338","journal-title":"Environ Chem Lett"},{"key":"35546_CR32","doi-asserted-by":"publisher","first-page":"45","DOI":"10.1016\/j.jhazmat.2017.02.017","volume":"331","author":"M Munoz","year":"2017","unstructured":"Munoz M, Mora FJ, de Pedro ZM et al (2017) Application of CWPO to the treatment of pharmaceutical emerging pollutants in different water matrices with a ferromagnetic catalyst. J Hazard Mater 331:45\u201354. https:\/\/doi.org\/10.1016\/j.jhazmat.2017.02.017","journal-title":"J Hazard Mater"},{"key":"35546_CR33","doi-asserted-by":"publisher","unstructured":"Nawaz M, Khan AA, Hussain A, et al (2020) Reduced graphene oxide\u2212TiO2\/sodium alginate 3-dimensional structure aerogel for enhanced photocatalytic degradation of ibuprofen and sulfamethoxazole. Chemosphere 261:. https:\/\/doi.org\/10.1016\/j.chemosphere.2020.127702","DOI":"10.1016\/j.chemosphere.2020.127702"},{"key":"35546_CR34","doi-asserted-by":"publisher","first-page":"242","DOI":"10.1016\/j.jhazmat.2016.04.058","volume":"316","author":"K Noguera-Oviedo","year":"2016","unstructured":"Noguera-Oviedo K, Aga DS (2016) Lessons learned from more than two decades of research on emerging contaminants in the environment. J Hazard Mater 316:242\u2013251","journal-title":"J Hazard Mater"},{"key":"35546_CR35","doi-asserted-by":"publisher","unstructured":"Paparo R, Di Serio M, Roviello G, et al (2024) Geopolymer-based materials for the removal of ibuprofen: a preliminary study. Molecules 29:. https:\/\/doi.org\/10.3390\/molecules29102210","DOI":"10.3390\/molecules29102210"},{"key":"35546_CR36","doi-asserted-by":"publisher","DOI":"10.1073\/pnas.2113947119\/-\/DCSupplemental","author":"EJ Pot","year":"2022","unstructured":"Pot EJ, Milakovic M, Chaumot A et al (2022). Pharmaceutical Pollution of the World\u2019s Rivers. https:\/\/doi.org\/10.1073\/pnas.2113947119\/-\/DCSupplemental","journal-title":"Pharmaceutical Pollution of the World\u2019s Rivers"},{"key":"35546_CR37","doi-asserted-by":"publisher","unstructured":"Rathi BS, Kumar PS, Vo DVN (2021) Critical review on hazardous pollutants in water environment: occurrence, monitoring, fate, removal technologies and risk assessment. Science of the Total Environment 797:. https:\/\/doi.org\/10.1016\/j.scitotenv.2021.149134","DOI":"10.1016\/j.scitotenv.2021.149134"},{"key":"35546_CR38","doi-asserted-by":"crossref","unstructured":"Rayaroth MP, Boczkaj G, Aubry O, et al (2023) Advanced oxidation processes for degradation of water pollutants\u2014ambivalent impact of carbonate species: a review. Water (Switzerland) 15","DOI":"10.3390\/w15081615"},{"key":"35546_CR39","doi-asserted-by":"publisher","first-page":"204","DOI":"10.1016\/j.cattod.2014.10.004","volume":"249","author":"RS Ribeiro","year":"2015","unstructured":"Ribeiro RS, Silva AMT, Pastrana-Mart\u00ednez LM et al (2015) Graphene-based materials for the catalytic wet peroxide oxidation of highly concentrated 4-nitrophenol solutions. Catal Today 249:204\u2013212. https:\/\/doi.org\/10.1016\/j.cattod.2014.10.004","journal-title":"Catal Today"},{"key":"35546_CR40","doi-asserted-by":"publisher","first-page":"170","DOI":"10.1016\/j.apcatb.2016.06.021","volume":"199","author":"RS Ribeiro","year":"2016","unstructured":"Ribeiro RS, Frontistis Z, Mantzavinos D et al (2016a) Magnetic carbon xerogels for the catalytic wet peroxide oxidation of sulfamethoxazole in environmentally relevant water matrices. Appl Catal B 199:170\u2013186. https:\/\/doi.org\/10.1016\/j.apcatb.2016.06.021","journal-title":"Appl Catal B"},{"key":"35546_CR41","doi-asserted-by":"publisher","first-page":"428","DOI":"10.1016\/j.apcatb.2016.01.033","volume":"187","author":"RS Ribeiro","year":"2016","unstructured":"Ribeiro RS, Silva AMT, Figueiredo JL et al (2016b) Catalytic wet peroxide oxidation: a route towards the application of hybrid magnetic carbon nanocomposites for the degradation of organic pollutants. A Review Appl Catal B 187:428\u2013460. https:\/\/doi.org\/10.1016\/j.apcatb.2016.01.033","journal-title":"A Review Appl Catal B"},{"key":"35546_CR42","doi-asserted-by":"publisher","first-page":"645","DOI":"10.1016\/j.apcatb.2017.08.013","volume":"219","author":"RS Ribeiro","year":"2017","unstructured":"Ribeiro RS, Rodrigues RO, Silva AMT et al (2017a) Hybrid magnetic graphitic nanocomposites towards catalytic wet peroxide oxidation of the liquid effluent from a mechanical biological treatment plant for municipal solid waste. Appl Catal B 219:645\u2013657. https:\/\/doi.org\/10.1016\/j.apcatb.2017.08.013","journal-title":"Appl Catal B"},{"key":"35546_CR43","doi-asserted-by":"publisher","first-page":"66","DOI":"10.1016\/j.cattod.2017.06.023","volume":"296","author":"RS Ribeiro","year":"2017","unstructured":"Ribeiro RS, Silva AMT, Figueiredo JL et al (2017b) The role of cobalt in bimetallic iron-cobalt magnetic carbon xerogels developed for catalytic wet peroxide oxidation. Catal Today 296:66\u201375. https:\/\/doi.org\/10.1016\/j.cattod.2017.06.023","journal-title":"Catal Today"},{"key":"35546_CR44","doi-asserted-by":"publisher","first-page":"705","DOI":"10.3390\/catal9090705","volume":"9","author":"A Santos Silva","year":"2019","unstructured":"Santos Silva A, Seitovna Kalmakhanova M, Kabykenovna Massalimova B et al (2019) Wet peroxide oxidation of paracetamol using acid activated and Fe\/Co-pillared clay catalysts prepared from natural clays. Catalysts 9:705. https:\/\/doi.org\/10.3390\/catal9090705","journal-title":"Catalysts"},{"key":"#cr-split#-35546_CR45.1","doi-asserted-by":"crossref","unstructured":"Santos Silva A, Roman FF, da Silva APF, et al (2024) Reactive materials and solutions towards treatment and reuse of waters with contaminants of emerging concern. In: Galv\u00e3o Jo\u00e3o Rafael da Costa Sanches and Brito P and NF dos S and AH de A and MS de JM and NC","DOI":"10.1007\/978-3-031-48532-9_44"},{"key":"#cr-split#-35546_CR45.2","unstructured":"(ed) Proceedings of the 3rd International Conference on Water Energy Food and Sustainability (ICoWEFS 2023). Springer Nature Switzerland, Cham, pp 477-488"},{"key":"35546_CR46","doi-asserted-by":"crossref","unstructured":"Shah AI, Din Dar MU, Bhat RA, et al (2020) Prospectives and challenges of wastewater treatment technologies to combat contaminants of emerging concerns. Ecol Eng 152","DOI":"10.1016\/j.ecoleng.2020.105882"},{"key":"35546_CR47","doi-asserted-by":"publisher","DOI":"10.1016\/j.jece.2023.110806","volume":"11","author":"AS Silva","year":"2023","unstructured":"Silva AS, Roman FF, Dias AV et al (2023) Hybrid multi-core shell magnetic nanoparticles for wet peroxide oxidation of paracetamol: application in synthetic and real matrices. J Environ Chem Eng 11:110806. https:\/\/doi.org\/10.1016\/j.jece.2023.110806","journal-title":"J Environ Chem Eng"},{"key":"35546_CR48","doi-asserted-by":"publisher","unstructured":"Silva AS, Diaz de Tuesta JL, Henrique A, et al (2024) 3D printed photopolymer derived carbon catalysts for enhanced wet peroxide oxidation. Chemical Engineering Journal 156574. https:\/\/doi.org\/10.1016\/j.cej.2024.156574","DOI":"10.1016\/j.cej.2024.156574"},{"key":"35546_CR49","doi-asserted-by":"publisher","first-page":"146","DOI":"10.1016\/j.jhazmat.2017.09.058","volume":"344","author":"JCG Sousa","year":"2018","unstructured":"Sousa JCG, Ribeiro AR, Barbosa MO et al (2018) A review on environmental monitoring of water organic pollutants identified by EU guidelines. J Hazard Mater 344:146\u2013162","journal-title":"J Hazard Mater"},{"key":"35546_CR50","doi-asserted-by":"publisher","unstructured":"Starling MCVM, Amorim CC, Le\u00e3o MMD (2019) Occurrence, control and fate of contaminants of emerging concern in environmental compartments in Brazil. J Hazard Mater 17\u201336. https:\/\/doi.org\/10.1016\/j.jhazmat.2018.04.043","DOI":"10.1016\/j.jhazmat.2018.04.043"},{"key":"35546_CR51","doi-asserted-by":"publisher","first-page":"1","DOI":"10.1016\/j.apcatb.2018.11.009","volume":"244","author":"Y Sun","year":"2019","unstructured":"Sun Y, Yang Z, Tian P et al (2019) Oxidative degradation of nitrobenzene by a Fenton-like reaction with Fe-Cu bimetallic catalysts. Appl Catal B 244:1\u201310. https:\/\/doi.org\/10.1016\/j.apcatb.2018.11.009","journal-title":"Appl Catal B"},{"key":"35546_CR52","doi-asserted-by":"crossref","unstructured":"Verlicchi P (2021) Trends, new insights and perspectives in the treatment of hospital effluents. Curr Opin Environ Sci Health 19","DOI":"10.1016\/j.coesh.2020.10.005"},{"key":"35546_CR53","doi-asserted-by":"publisher","unstructured":"Vieira Y, Pereira HA, Leichtweis J, et al (2021) Effective treatment of hospital wastewater with high-concentration diclofenac and ibuprofen using a promising technology based on degradation reaction catalyzed by Fe0 under microwave irradiation. Science of the Total Environment 783:. https:\/\/doi.org\/10.1016\/j.scitotenv.2021.146991","DOI":"10.1016\/j.scitotenv.2021.146991"},{"key":"35546_CR54","doi-asserted-by":"publisher","first-page":"96","DOI":"10.1016\/j.jcat.2019.09.045","volume":"381","author":"Y Yu","year":"2020","unstructured":"Yu Y, Tang Z, Wang J et al (2020) Insights into the efficiency of hydrogen peroxide utilization over titanosilicate\/H2O2 systems. J Catal 381:96\u2013107. https:\/\/doi.org\/10.1016\/j.jcat.2019.09.045","journal-title":"J Catal"},{"key":"35546_CR55","doi-asserted-by":"publisher","unstructured":"Zapata NI, Pe\u00f1uela GA (1951) Modified QuEChERS\/UPLC-MS\/MS method to monitor triclosan, ibuprofen, and diclofenac in fish Pseudoplatystoma magdaleniatum. https:\/\/doi.org\/10.1007\/s12161-020-01951-9\/Published","DOI":"10.1007\/s12161-020-01951-9\/Published"},{"key":"35546_CR56","doi-asserted-by":"publisher","first-page":"261","DOI":"10.1016\/j.apcatb.2006.02.008","volume":"65","author":"JA Zazo","year":"2006","unstructured":"Zazo JA, Casas JA, Mohedano AF, Rodr\u00edguez JJ (2006) Catalytic wet peroxide oxidation of phenol with a Fe\/active carbon catalyst. Appl Catal B 65:261\u2013268. https:\/\/doi.org\/10.1016\/j.apcatb.2006.02.008","journal-title":"Appl Catal B"},{"key":"35546_CR57","doi-asserted-by":"publisher","first-page":"1405","DOI":"10.1007\/s10695-021-00987-w","volume":"47","author":"N Zhang","year":"2021","unstructured":"Zhang N, Liu X, Pan L et al (2021) Evaluation of ibuprofen contamination in local urban rivers and its effects on immune parameters of juvenile grass carp. Fish Physiol Biochem 47:1405\u20131413. https:\/\/doi.org\/10.1007\/s10695-021-00987-w","journal-title":"Fish Physiol Biochem"},{"key":"35546_CR58","doi-asserted-by":"publisher","first-page":"213","DOI":"10.1080\/10889868.2022.2138823","volume":"28","author":"Z Zhou","year":"2024","unstructured":"Zhou Z, Wu Y, Kuang Y et al (2024) Assessment of ibuprofen toxicity and removal potential of Chlorella vulgaris. Bioremediat J 28:213\u2013221. https:\/\/doi.org\/10.1080\/10889868.2022.2138823","journal-title":"Bioremediat J"}],"container-title":["Environmental Science and Pollution Research"],"original-title":[],"language":"en","link":[{"URL":"https:\/\/link.springer.com\/content\/pdf\/10.1007\/s11356-024-35546-2.pdf","content-type":"application\/pdf","content-version":"vor","intended-application":"text-mining"},{"URL":"https:\/\/link.springer.com\/article\/10.1007\/s11356-024-35546-2\/fulltext.html","content-type":"text\/html","content-version":"vor","intended-application":"text-mining"},{"URL":"https:\/\/link.springer.com\/content\/pdf\/10.1007\/s11356-024-35546-2.pdf","content-type":"application\/pdf","content-version":"vor","intended-application":"similarity-checking"}],"deposited":{"date-parts":[[2024,12,10]],"date-time":"2024-12-10T23:08:03Z","timestamp":1733872083000},"score":1,"resource":{"primary":{"URL":"https:\/\/link.springer.com\/10.1007\/s11356-024-35546-2"}},"subtitle":[],"short-title":[],"issued":{"date-parts":[[2024,11,22]]},"references-count":59,"journal-issue":{"issue":"57","published-online":{"date-parts":[[2024,12]]}},"alternative-id":["35546"],"URL":"https:\/\/doi.org\/10.1007\/s11356-024-35546-2","relation":{},"ISSN":["1614-7499"],"issn-type":[{"value":"1614-7499","type":"electronic"}],"subject":[],"published":{"date-parts":[[2024,11,22]]},"assertion":[{"value":"23 August 2024","order":1,"name":"received","label":"Received","group":{"name":"ArticleHistory","label":"Article History"}},{"value":"6 November 2024","order":2,"name":"accepted","label":"Accepted","group":{"name":"ArticleHistory","label":"Article History"}},{"value":"22 November 2024","order":3,"name":"first_online","label":"First Online","group":{"name":"ArticleHistory","label":"Article History"}},{"order":1,"name":"Ethics","group":{"name":"EthicsHeading","label":"Declarations"}},{"value":"This article does not contain any studies with human participants or animals performed by any of the authors.","order":2,"name":"Ethics","group":{"name":"EthicsHeading","label":"Ethical approval"}},{"value":"Not applicable.","order":3,"name":"Ethics","group":{"name":"EthicsHeading","label":"Consent to participate"}},{"value":"Not applicable.","order":4,"name":"Ethics","group":{"name":"EthicsHeading","label":"Consent for publication"}},{"value":"The authors declare no competing interests.","order":5,"name":"Ethics","group":{"name":"EthicsHeading","label":"Competing interests"}}]}}