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The synthesis was monitored by IR\u2010spectroscopy and the final product characterized by FT\u2010IR, GC\u2013MS, <jats:sup>1<\/jats:sup>H and <jats:sup>13<\/jats:sup>C NMR. The presence of conjugated double bonds in the aliphatic chain was confirmed, which is a determinant for the proposed autoxidative latexes drying mechanism. Each of the AFAD were subsequently added to a standard acrylic emulsion, in order to study its potential as reactive coalescing agent. The minimum film\u2010forming temperature (MFT), glass transition temperature (<jats:italic>T<\/jats:italic><jats:sub>g<\/jats:sub>), drying time and rubbing resistance to solvents were evaluated. The results showed that, when added to water\u2010borne acrylic resins, an AFAD acts as a non\u2010volatile plasticizer capable of autoxidative crosslinking with itself.<\/jats:p>","DOI":"10.1007\/s11746-012-2114-y","type":"journal-article","created":{"date-parts":[[2012,9,25]],"date-time":"2012-09-25T21:08:14Z","timestamp":1348607294000},"page":"2215-2226","source":"Crossref","is-referenced-by-count":11,"title":["Synthesis and Characterization of Allyl Fatty Acid Derivatives as Reactive Coalescing Agents for Latexes"],"prefix":"10.1002","volume":"89","author":[{"given":"Joana V.","family":"Barbosa","sequence":"first","affiliation":[{"name":"LEPAE, Departamento de Engenharia Qu\u00edmica, Faculdade de Engenharia Universidade do Porto Rua Dr. Roberto Frias Porto 4200\u2010465 Portugal"}]},{"given":"Fernanda","family":"Oliveira","sequence":"additional","affiliation":[{"name":"CIN, Corpora\u00e7\u00e3o Industrial do Norte, S.A. Estrada Nacional 13 (km 6), Apartado 1008 Maia 4471\u2010909 Portugal"}]},{"given":"Jorge","family":"Moniz","sequence":"additional","affiliation":[{"name":"Resiqu\u00edmica, Resinas Qu\u00edmicas, S.A. Rua Francisco Lyon de Castro, 28 Lisbon Mem Martins 2725\u2010397 Portugal"}]},{"given":"Fern\u00e3o D.","family":"Magalh\u00e3es","sequence":"additional","affiliation":[{"name":"LEPAE, Departamento de Engenharia Qu\u00edmica, Faculdade de Engenharia Universidade do Porto Rua Dr. Roberto Frias Porto 4200\u2010465 Portugal"}]},{"given":"Margarida M. S. M.","family":"Bastos","sequence":"additional","affiliation":[{"name":"LEPAE, Departamento de Engenharia Qu\u00edmica, Faculdade de Engenharia Universidade do Porto Rua Dr. Roberto Frias Porto 4200\u2010465 Portugal"}]}],"member":"311","published-online":{"date-parts":[[2012,7,21]]},"reference":[{"key":"e_1_2_6_2_1","doi-asserted-by":"publisher","DOI":"10.1007\/978-94-009-1209-0"},{"key":"e_1_2_6_3_1","doi-asserted-by":"publisher","DOI":"10.1016\/S0141-3910(99)00020-8"},{"key":"e_1_2_6_4_1","doi-asserted-by":"publisher","DOI":"10.1023\/A:1016509208442"},{"key":"e_1_2_6_5_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.ccr.2005.02.002"},{"key":"e_1_2_6_6_1","doi-asserted-by":"publisher","DOI":"10.1002\/ejlt.200501168"},{"key":"e_1_2_6_7_1","unstructured":"ThamesSF PanjnaniKG FrucheyOS(1999)Latex compositions containing ethylenically unsaturated esters of long\u2010chain alkenols. 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