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The final residue was enzymatically treated to deliver sugars that can undergo fermentation-based biotransformation. This hydrothermal pretreatment was assessed for maximum temperatures (<jats:italic>T<\/jats:italic><jats:sub>max<\/jats:sub>) between 120 to 200\u00a0\u00b0C and severities (<jats:italic>S<\/jats:italic><jats:sub>0<\/jats:sub>) between 1.1 and 3.4. The highest oligosaccharide concentration (5.5\u00a0g\/L) was achieved at <jats:italic>S<\/jats:italic><jats:sub>0<\/jats:sub> of 3.4. The increase of <jats:italic>S<\/jats:italic><jats:sub>0<\/jats:sub> during the process allowed to increase the recovery of interesting bioactive compounds, achieving a maximum TPC and antioxidant activity of 2.8\u00a0g\/L and 17178.5\u00a0\u00b5mol Fe<jats:sup>2+<\/jats:sup>\/L, respectively, when the <jats:italic>T<\/jats:italic><jats:sub>max<\/jats:sub> reached 200\u00a0\u00b0C. However, at this temperature, a significant amount of degradation products such as organic acids and HMF was already formed, and a compromise temperature of 160\u00a0\u00b0C was chosen for further tests. It was possible to obtain a maximum glucose yield of 71% when the pretreated solids were enzymatically hydrolysed. Hence, the use of autohydrolysis, avoiding the use of toxic chemicals, has proved to be a sustainable alternative to obtain different CBS fractions with interesting composition to be potentially employed in multiple sectors.<\/jats:p>","DOI":"10.1007\/s11947-024-03500-2","type":"journal-article","created":{"date-parts":[[2024,7,16]],"date-time":"2024-07-16T09:02:11Z","timestamp":1721120531000},"page":"965-978","update-policy":"https:\/\/doi.org\/10.1007\/springer_crossmark_policy","source":"Crossref","is-referenced-by-count":8,"title":["Cascading Recovery of Added-Value Cocoa Bean Shell Fractions Through Autohydrolysis Treatments"],"prefix":"10.1007","volume":"18","author":[{"given":"Marta","family":"S\u00e1nchez","sequence":"first","affiliation":[]},{"given":"Pedro","family":"Ferreira-Santos","sequence":"additional","affiliation":[]},{"given":"Joana S.","family":"Gomes-Dias","sequence":"additional","affiliation":[]},{"given":"Amanda","family":"Laca","sequence":"additional","affiliation":[]},{"given":"Cristina M. 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