{"status":"ok","message-type":"work","message-version":"1.0.0","message":{"indexed":{"date-parts":[[2025,6,12]],"date-time":"2025-06-12T07:40:07Z","timestamp":1749714007090,"version":"3.41.0"},"reference-count":91,"publisher":"Springer Science and Business Media LLC","issue":"2","license":[{"start":{"date-parts":[[2025,5,14]],"date-time":"2025-05-14T00:00:00Z","timestamp":1747180800000},"content-version":"tdm","delay-in-days":0,"URL":"https:\/\/www.springernature.com\/gp\/researchers\/text-and-data-mining"},{"start":{"date-parts":[[2025,5,14]],"date-time":"2025-05-14T00:00:00Z","timestamp":1747180800000},"content-version":"vor","delay-in-days":0,"URL":"https:\/\/www.springernature.com\/gp\/researchers\/text-and-data-mining"}],"content-domain":{"domain":["link.springer.com"],"crossmark-restriction":false},"short-container-title":["Geoheritage"],"published-print":{"date-parts":[[2025,6]]},"DOI":"10.1007\/s12371-025-01119-z","type":"journal-article","created":{"date-parts":[[2025,5,14]],"date-time":"2025-05-14T00:12:05Z","timestamp":1747181525000},"update-policy":"https:\/\/doi.org\/10.1007\/springer_crossmark_policy","source":"Crossref","is-referenced-by-count":0,"title":["Antimony Mining and Metallurgy in the Brioude-Massiac District (Massif Central, France): Historical Features and Perspectives"],"prefix":"10.1007","volume":"17","author":[{"ORCID":"https:\/\/orcid.org\/0000-0002-1384-6000","authenticated-orcid":false,"given":"Vincent","family":"Thi\u00e9ry","sequence":"first","affiliation":[]},{"ORCID":"https:\/\/orcid.org\/0000-0003-1440-1465","authenticated-orcid":false,"given":"Migueli","family":"Chedrewih","sequence":"additional","affiliation":[]},{"ORCID":"https:\/\/orcid.org\/0000-0003-0586-5794","authenticated-orcid":false,"given":"Michel","family":"Dubois","sequence":"additional","affiliation":[]},{"ORCID":"https:\/\/orcid.org\/0000-0002-0655-6304","authenticated-orcid":false,"given":"Gavyn K.","family":"Rollinson","sequence":"additional","affiliation":[]},{"ORCID":"https:\/\/orcid.org\/0000-0002-7404-2997","authenticated-orcid":false,"given":"Violeta","family":"Ramos","sequence":"additional","affiliation":[]}],"member":"297","published-online":{"date-parts":[[2025,5,14]]},"reference":[{"key":"1119_CR1","doi-asserted-by":"publisher","first-page":"347","DOI":"10.1134\/S1024856015040028","volume":"28","author":"SF Abdullaev","year":"2015","unstructured":"Abdullaev SF, Maslov VA, Nazarov BI et al (2015) The elemental composition of soils and dust aerosol in the south-central part of Tajikistan. Atmos Ocean Opt 28:347\u2013358. https:\/\/doi.org\/10.1134\/S1024856015040028","journal-title":"Atmos Ocean Opt"},{"key":"1119_CR2","doi-asserted-by":"publisher","first-page":"43","DOI":"10.1007\/s12371-009-0004-y","volume":"1","author":"Z Alexandrowicz","year":"2009","unstructured":"Alexandrowicz Z, Urban J, Mi\u015bkiewicz K (2009) Geological Values of Selected Polish Properties of the UNESCO World Heritage List. Geoheritage 1:43\u201352. https:\/\/doi.org\/10.1007\/s12371-009-0004-y","journal-title":"Geoheritage"},{"key":"1119_CR3","doi-asserted-by":"publisher","first-page":"23","DOI":"10.1007\/s00339-015-9542-0","volume":"122","author":"N Ali","year":"2015","unstructured":"Ali N, Hussain A, Ahmed R et al (2015) Antimony sulphide, an absorber layer for solar cell application. Appl Phys A 122:23. https:\/\/doi.org\/10.1007\/s00339-015-9542-0","journal-title":"Appl Phys A"},{"key":"1119_CR4","doi-asserted-by":"publisher","first-page":"106401","DOI":"10.1016\/j.microc.2021.106401","volume":"168","author":"ML Amadori","year":"2021","unstructured":"Amadori ML, Costantini I, Madariaga Mota JM et al (2021) Calcium antimonate: A new discovery in colour palette of Paestum wall paintings. Microchem J 168:106401. https:\/\/doi.org\/10.1016\/j.microc.2021.106401","journal-title":"Microchem J"},{"key":"1119_CR5","doi-asserted-by":"publisher","unstructured":"Anderson CG (2012) The metallurgy of antimony. Chemie der Erde - Geochemistry 72, Supplement 4:3\u20138.\u00a0https:\/\/doi.org\/10.1016\/j.chemer.2012.04.001","DOI":"10.1016\/j.chemer.2012.04.001"},{"key":"1119_CR6","doi-asserted-by":"publisher","DOI":"10.1016\/j.gr.2015.12.003","author":"J Berger","year":"2016","unstructured":"Berger J (2016) Discovery of metamorphic microdiamonds from the parautochthonous units of the Variscan French Massif Central: Comment. Gondwana Res. https:\/\/doi.org\/10.1016\/j.gr.2015.12.003","journal-title":"Gondwana Res"},{"key":"1119_CR7","doi-asserted-by":"publisher","first-page":"52","DOI":"10.1007\/s12371-023-00824-x","volume":"15","author":"F B\u00e9tard","year":"2023","unstructured":"B\u00e9tard F, Rouget I, Hobl\u00e9a F et al (2023) Geoconservation in France: History, key policies, and current tools. Geoheritage 15:52. https:\/\/doi.org\/10.1007\/s12371-023-00824-x","journal-title":"Geoheritage"},{"key":"1119_CR8","first-page":"1","volume":"375","author":"P Blazy","year":"2015","unstructured":"Blazy P, Hermant V (2015) M\u00e9tallurgie extractive de l\u2019antimoine. Techniques De L\u2019ing\u00e9nieur M 375:1\u201315","journal-title":"Techniques De L\u2019ing\u00e9nieur M"},{"key":"1119_CR9","first-page":"13","volume":"528","author":"V Bouchot","year":"1997","unstructured":"Bouchot V, Mil\u00e9si JP, Lescuyer J-L, Ledru P (1997) Les min\u00e9ralisations aurif\u00e8res de la France dans leur cadre g\u00e9ologique autour de 300 Ma. Chron Rech Min 528:13\u201362","journal-title":"Chron Rech Min"},{"key":"1119_CR10","doi-asserted-by":"publisher","first-page":"169","DOI":"10.1016\/j.oregeorev.2005.07.017","volume":"27","author":"V Bouchot","year":"2005","unstructured":"Bouchot V, Ledru P, Lerouge C et al (2005) 5: Late Variscan mineralizing systems related to orogenic processes: the French Massif Central. Ore Geol Rev 27:169\u2013197","journal-title":"Ore Geol Rev"},{"key":"1119_CR11","doi-asserted-by":"publisher","first-page":"1","DOI":"10.1007\/BF01082422","volume":"30","author":"H Bril","year":"1982","unstructured":"Bril H (1982) Fluid inclusions study of Sn\u2212W\u2212Au, Sb\u2212 and Pb\u2212Zn mineralizations from the Brioude-Massiac district (French Massif Central). Tschermaks Min Petr Mitt 30:1\u201316. https:\/\/doi.org\/10.1007\/BF01082422","journal-title":"Tschermaks Min Petr Mitt"},{"key":"1119_CR12","first-page":"340","volume":"77","author":"H Bril","year":"1983","unstructured":"Bril H (1983) \u00c9tude m\u00e9tallog\u00e9nique des min\u00e9ralisations \u00e0 antimoine et associ\u00e9es du district de Brioude-Massiac (Massif central fran\u00e7ais): conditions g\u00e9ochimiques de d\u00e9p\u00f4t; implications g\u00e9n\u00e9tiques. Ann Fac Sci De L\u2019universit\u00e9 De Clermont 77:340","journal-title":"Ann Fac Sci De L\u2019universit\u00e9 De Clermont"},{"key":"1119_CR13","doi-asserted-by":"publisher","first-page":"161","DOI":"10.3406\/bulmi.1985.7866","volume":"108","author":"H Bril","year":"1985","unstructured":"Bril H (1985) Conditions de stabilit\u00e9 des sulfures dans les filons de haute temp\u00e9rature du district de Brioude-Massiac (Massif Central fran\u00e7ais). Bull Min\u00e9r 108:161\u2013171","journal-title":"Bull Min\u00e9r"},{"key":"1119_CR14","doi-asserted-by":"publisher","first-page":"189","DOI":"10.1007\/BF00209257","volume":"26","author":"H Bril","year":"1991","unstructured":"Bril H, Bonhomme MG, Marcoux E, Baubron JC (1991) Ages K\/Ar des min\u00e9ralisations de Brioude-Massiac (W-Au-As-Sb; Pb-Zn), Pontgibaud (Pb-Ag; Sn), et Labessette (As-Pb-Sb-Au): Place de ces districts dans l\u2019\u00e9volution g\u00e9otectonique du Massif central fran\u00e7ais. Miner Deposita 26:189\u2013198","journal-title":"Miner Deposita"},{"key":"1119_CR15","doi-asserted-by":"publisher","first-page":"372","DOI":"10.1071\/CH22253","volume":"76","author":"C Browne","year":"2023","unstructured":"Browne C (2023) Gutenberg, chemistry and the advancement of knowledge. Aust J Chem 76:372\u2013378","journal-title":"Aust J Chem"},{"key":"1119_CR16","doi-asserted-by":"publisher","first-page":"429","DOI":"10.1127\/zdgg\/129\/1978\/429","volume":"129","author":"JP Burg","year":"1978","unstructured":"Burg JP, Matte P (1978) A cross section through the French Massif central and the scope of its Variscan geodynamic evolution. Zeitschrift der deutschen Geologischen Gesellschaft 129:429\u2013460","journal-title":"Zeitschrift der deutschen Geologischen Gesellschaft"},{"key":"1119_CR17","first-page":"303","volume":"102","author":"S Caill\u00e8re","year":"1979","unstructured":"Caill\u00e8re S (1979) Jean Orcel (1896\u20131978). Bull Min\u00e9r 102:303\u2013305","journal-title":"Bull Min\u00e9r"},{"key":"1119_CR18","doi-asserted-by":"publisher","first-page":"19","DOI":"10.1016\/j.culher.2017.09.002","volume":"29","author":"G Capobianco","year":"2018","unstructured":"Capobianco G, Pelosi C, Agresti G et al (2018) X-ray fluorescence investigation on yellow pigments based on lead, tin and antimony through the comparison between laboratory and portable instruments. J Cult Herit 29:19\u201329. https:\/\/doi.org\/10.1016\/j.culher.2017.09.002","journal-title":"J Cult Herit"},{"key":"1119_CR19","doi-asserted-by":"publisher","first-page":"106663","DOI":"10.1016\/j.gexplo.2020.106663","volume":"220","author":"V Cappuyns","year":"2021","unstructured":"Cappuyns V, Campen AV, Helser J (2021) Antimony leaching from soils and mine waste from the Mau Due antimony mine. North-Vietnam J Geochem Explor 220:106663. https:\/\/doi.org\/10.1016\/j.gexplo.2020.106663","journal-title":"North-Vietnam J Geochem Explor"},{"key":"1119_CR20","doi-asserted-by":"publisher","first-page":"788","DOI":"10.1016\/j.apgeochem.2006.11.007","volume":"22","author":"C Casiot","year":"2007","unstructured":"Casiot C, Ujevic M, Munoz M et al (2007) Antimony and arsenic mobility in a creek draining an antimony mine abandoned 85 years ago (upper Orb basin, France). Appl Geochem 22:788\u2013798","journal-title":"Appl Geochem"},{"key":"1119_CR21","doi-asserted-by":"crossref","unstructured":"Cauuet B (1988) La mine antique des Fouilloux (Jumilhac, Dordogne)\u202f: les premiers r\u00e9sultats de la fouille. Aquitania 181\u2013190","DOI":"10.3406\/aquit.1988.1061"},{"key":"1119_CR22","doi-asserted-by":"crossref","unstructured":"Cauuet B (1991) L\u2019exploitation de l\u2019or en Limousin, des Gaulois aux Gallo-Romains. Annales du Midi 149\u2013181","DOI":"10.3406\/anami.1991.2292"},{"key":"1119_CR23","doi-asserted-by":"publisher","first-page":"111","DOI":"10.3406\/aquit.1994.1123","volume":"12","author":"B Cauuet","year":"1994","unstructured":"Cauuet B (1994) Nouvelles d\u00e9couvertes sur les auri\u00e8res de la haute vall\u00e9e de l\u2019Isle (Dordogne\/Haute-Vienne). Aquitania 12:111\u2013123. https:\/\/doi.org\/10.3406\/aquit.1994.1123","journal-title":"Aquitania"},{"key":"1119_CR24","doi-asserted-by":"publisher","first-page":"219","DOI":"10.1007\/978-94-015-1292-3_15","volume-title":"Prehistoric Gold in Europe: Mines, Metallurgy and Manufacture","author":"B Cauuet","year":"1995","unstructured":"Cauuet B (1995) Celtic Gold Mines in West Central Gaul. In: Morteani G, Northover JP (eds) Prehistoric Gold in Europe: Mines, Metallurgy and Manufacture. Springer, Netherlands, Dordrecht, pp 219\u2013240"},{"key":"1119_CR25","first-page":"423","volume":"13","author":"B Cauuet","year":"2005","unstructured":"Cauuet B, Domergue C, Urteaga M (2005) Mines et m\u00e9tallurgies en Aquitaine et en Hispanie septentrionale sous les Julio-Claudiens. L\u2019aquitaine Et L\u2019hispanie Septentrionale \u00e0 L\u2019\u00e9poque Julio-Claudienne Organisation Et Exploitation des Espaces Provinciaux Suppl 13:423\u2013460","journal-title":"L\u2019aquitaine Et L\u2019hispanie Septentrionale \u00e0 L\u2019\u00e9poque Julio-Claudienne Organisation Et Exploitation des Espaces Provinciaux Suppl"},{"key":"1119_CR26","first-page":"20","volume":"316","author":"B Cauuet","year":"2006","unstructured":"Cauuet B, T\u0103ma\u015f CG, Guillaumet J-P et al (2006) Les exploitations mini\u00e8res en pays \u00e9duen. Dossiers D\u2019arch\u00e9ologie 316:20\u201325","journal-title":"Dossiers D\u2019arch\u00e9ologie"},{"key":"1119_CR27","doi-asserted-by":"publisher","first-page":"66","DOI":"10.1111\/jmi.13228","volume":"294","author":"M Chedrewih","year":"2024","unstructured":"Chedrewih M, Thi\u00e9ry V, Gauthier A, Amin F (2024) Incorporation of antimony-bearing mining wastes into clinker Portland raw feed: the difficulty of Sb analysis in calcium silicates. J Microsc 294:66\u201374","journal-title":"J Microsc"},{"key":"1119_CR28","doi-asserted-by":"crossref","unstructured":"Cheval-Garab\u00e9dian F, Faure M, Marcoux E, Poujol M (2021) The tungsten-gold veins of Bonnac (French Massif central): new constraints for a Variscan granite-related genesis. BSGF - Earth Sci Bull 192(7)","DOI":"10.1051\/bsgf\/2020041"},{"key":"1119_CR29","first-page":"1180","volume":"62","author":"LP Cook","year":"1977","unstructured":"Cook LP, Roth RS, Parker HS, Negas T (1977) The system K2O-Al2O3-SiO2. Part 1. Phases on the KAlSiO4-KAlO2 join. Am Miner 62:1180\u20131190","journal-title":"Am Miner"},{"key":"1119_CR30","doi-asserted-by":"publisher","first-page":"29","DOI":"10.1016\/j.chemer.2012.02.004","volume":"72","author":"A Courtin-Nomade","year":"2012","unstructured":"Courtin-Nomade A, Rakotoarisoa O, Bril H et al (2012) Weathering of Sb-rich mining and smelting residues: Insight in solid speciation and soil bacteria toxicity. Chem Erde 72:29\u201339","journal-title":"Chem Erde"},{"key":"1119_CR31","doi-asserted-by":"publisher","first-page":"563","DOI":"10.1007\/s13563-022-00338-y","volume":"35","author":"P D\u2019Hugues","year":"2022","unstructured":"D\u2019Hugues P, Bourg S, Menard Y (2022) From mineral processing to waste management and recycling: common challenges and needs for innovation in France. Miner Econ 35:563\u2013567. https:\/\/doi.org\/10.1007\/s13563-022-00338-y","journal-title":"Miner Econ"},{"key":"1119_CR32","doi-asserted-by":"publisher","first-page":"205","DOI":"10.1007\/s12371-015-0151-2","volume":"7","author":"P De Wever","year":"2015","unstructured":"De Wever P, Alterio I, Egoroff G et al (2015) Geoheritage, a National Inventory in France. Geoheritage 7:205\u2013247. https:\/\/doi.org\/10.1007\/s12371-015-0151-2","journal-title":"Geoheritage"},{"key":"1119_CR33","doi-asserted-by":"publisher","first-page":"69","DOI":"10.3390\/geosciences13030069","volume":"13","author":"P De Wever","year":"2023","unstructured":"De Wever P, Rouget I (2023) Historical overview of geoheritage in France. Geosciences 13:69. https:\/\/doi.org\/10.3390\/geosciences13030069","journal-title":"Geosciences"},{"key":"1119_CR34","doi-asserted-by":"publisher","first-page":"1013","DOI":"10.1016\/j.crte.2003.09.006","volume":"335","author":"V Ettler","year":"2003","unstructured":"Ettler V, Johan Z, Hradil D (2003) Natural alteration products of sulphide mattes from primary lead smelting. CR Geosci 335:1013\u20131020. https:\/\/doi.org\/10.1016\/j.crte.2003.09.006","journal-title":"CR Geosci"},{"key":"1119_CR35","doi-asserted-by":"publisher","first-page":"837","DOI":"10.1127\/0935-1221\/2009\/0021-1942","volume":"21","author":"V Ettler","year":"2009","unstructured":"Ettler V, Johan Z, Bezdi\u010dka P et al (2009) Crystallization sequences in matte and speiss from primary lead metallurgy. Eur J Mineral 21:837\u2013854. https:\/\/doi.org\/10.1127\/0935-1221\/2009\/0021-1942","journal-title":"Eur J Mineral"},{"key":"1119_CR36","first-page":"695","volume":"168","author":"M Faure","year":"1997","unstructured":"Faure M, Leloix C, Roig J-Y (1997) L\u2019\u00e9volution polycyclique de la chaine hercynienne. Bull Soc Geol Fr 168:695\u2013705","journal-title":"Bull Soc Geol Fr"},{"key":"1119_CR37","doi-asserted-by":"publisher","first-page":"202","DOI":"10.1016\/j.crte.2008.12.001","volume":"341","author":"M Faure","year":"2009","unstructured":"Faure M, Lardeaux J, Ledru P (2009) A review of the pre-Permian geology of the Variscan French Massif Central. Comptes Rendus Geosciences 341:202\u2013202","journal-title":"Comptes Rendus Geosciences"},{"key":"1119_CR38","doi-asserted-by":"publisher","first-page":"93","DOI":"10.1016\/S0269-7491(02)00411-6","volume":"124","author":"HC Flynn","year":"2003","unstructured":"Flynn HC, Meharg AA, Bowyer PK, Paton GI (2003) Antimony bioavailability in mine soils. Environ Pollut 124:93\u2013100","journal-title":"Environ Pollut"},{"key":"1119_CR39","unstructured":"Forestier FH, Vialaron C, Baud C (1992) La famille Chatillon: exploitation et m\u00e9tallurgie de l\u2019antimoine. In: Almanach de Brioude, pp 119\u2013152"},{"key":"1119_CR40","doi-asserted-by":"publisher","first-page":"104637","DOI":"10.1016\/j.apgeochem.2020.104637","volume":"118","author":"S Fu","year":"2020","unstructured":"Fu S, Hu R, Bi X et al (2020) Trace element composition of stibnite: Substitution mechanism and implications for the genesis of Sb deposits in southern China. Appl Geochem 118:104637. https:\/\/doi.org\/10.1016\/j.apgeochem.2020.104637","journal-title":"Appl Geochem"},{"key":"1119_CR41","doi-asserted-by":"publisher","first-page":"203","DOI":"10.1016\/0024-4937(84)90020-3","volume":"17","author":"A Giraud","year":"1984","unstructured":"Giraud A, Marchand J, Dupuy C, Dostal J (1984) Geochemistry of leptyno-amphibolite complex from Haut Allier (French Massif Central). Lithos 17:203\u2013203","journal-title":"Lithos"},{"key":"1119_CR42","first-page":"21","volume":"28","author":"F Gonnard","year":"1905","unstructured":"Gonnard F (1905) Notes Min\u00e9ralogiques. Bull Min\u00e9ral 28:21\u201324","journal-title":"Bull Min\u00e9ral"},{"key":"1119_CR43","doi-asserted-by":"publisher","first-page":"877","DOI":"10.1016\/j.mineng.2005.01.018","volume":"18","author":"WR Goodall","year":"2005","unstructured":"Goodall WR, Scales PJ, Butcher AR (2005) The use of QEMSCAN and diagnostic leaching in the characterisation of visible gold in complex ores. Miner Eng 18:877\u2013886","journal-title":"Miner Eng"},{"key":"1119_CR44","doi-asserted-by":"publisher","first-page":"24","DOI":"10.1007\/s11837-000-0126-9","volume":"52","author":"P Gottlieb","year":"2000","unstructured":"Gottlieb P, Wilkie G, Sutherland D et al (2000) Using quantitative electron microscopy for process mineralogy applications. The Journal of the Minerals. Metals and Materials Society (JOM) 52:24\u201325","journal-title":"Metals and Materials Society (JOM)"},{"key":"1119_CR45","unstructured":"Guiollard PC (2009) L\u2019industrie mini\u00e8re de l\u2019antimoine et du tungst\u00e8ne\u202f: \u00e9mergence, prosp\u00e9rit\u00e9 et disparition des exploitations de France m\u00e9tropolitaine aux XIXe et XX si\u00e8cles. PhD dissertation, Universit\u00e9 de Haute-Alsace, Mulhouse, p\u00a0400"},{"key":"1119_CR46","doi-asserted-by":"publisher","first-page":"377","DOI":"10.1016\/j.culher.2003.09.001","volume":"4","author":"F Habashi","year":"2003","unstructured":"Habashi F (2003) Cultural heritage in geosciences, mining, and metallurgy. J Cult Herit 4:377\u2013378. https:\/\/doi.org\/10.1016\/j.culher.2003.09.001","journal-title":"J Cult Herit"},{"key":"1119_CR47","first-page":"353","volume":"7","author":"W Haidinger","year":"1827","unstructured":"Haidinger W (1827) On berthierite, a new mineral species. The Edinburgh Journal of Science 7:353\u2013354","journal-title":"The Edinburgh Journal of Science"},{"key":"1119_CR48","doi-asserted-by":"publisher","DOI":"10.1007\/978-3-030-50367-3","volume-title":"Archaeometallurgy - Materials Science Aspects","author":"A Hauptmann","year":"2020","unstructured":"Hauptmann A (2020a) Archaeometallurgy - Materials Science Aspects. Springer"},{"key":"1119_CR49","doi-asserted-by":"publisher","first-page":"199","DOI":"10.1007\/978-3-030-50367-3_5","volume-title":"Archaeometallurgy \u2013 Materials Science Aspects","author":"A Hauptmann","year":"2020","unstructured":"Hauptmann A (2020b) Archaeometallurgical Slags and Other Debris. Archaeometallurgy \u2013 Materials Science Aspects. Springer International Publishing, Cham, pp 199\u2013293"},{"key":"1119_CR50","doi-asserted-by":"publisher","first-page":"377","DOI":"10.1016\/j.culher.2007.07.001","volume":"8","author":"D Hradil","year":"2007","unstructured":"Hradil D, Grygar T, Hradilova J et al (2007) Microanalytical identification of Pb-Sb-Sn yellow pigment in historical European paintings and its differentiation from lead tin and Naples yellows. J Cult Herit 8:377\u2013386. https:\/\/doi.org\/10.1016\/j.culher.2007.07.001","journal-title":"J Cult Herit"},{"key":"1119_CR51","volume-title":"The preparation of thin sections of rocks, minerals, and ceramics","author":"DW Humphries","year":"1992","unstructured":"Humphries DW (1992) The preparation of thin sections of rocks, minerals, and ceramics. Oxford University Press"},{"key":"1119_CR52","doi-asserted-by":"publisher","first-page":"143","DOI":"10.1016\/S0040-1951(00)00253-5","volume":"332","author":"JM Lardeaux","year":"2001","unstructured":"Lardeaux JM, Ledru P, Daniel I, Duchene S (2001) The Variscan French Massif Central\u2013a new addition to the ultra-high pressure metamorphic \u201cclub\u201d: exhumation processes and geodynamic consequences. Tectonophysics 332:143\u2013143","journal-title":"Tectonophysics"},{"key":"1119_CR53","unstructured":"Lasnier B, Marchand J (1982) Carte g\u00e9ol. France (1\/50 000), feuille Brioude (766) - Orl\u00e9ans\u202f: Bureau de recherches g\u00e9ologiques et mini\u00e8res. Notice explicaive par Lasnier, B. et Marchand, J.\u00a0et coll, p 68"},{"key":"1119_CR54","doi-asserted-by":"publisher","first-page":"605","DOI":"10.2113\/gssgfbull.V.3.605","volume":"3","author":"P Ledru","year":"1989","unstructured":"Ledru P, Lardeaux JM, Santallier D et al (1989) O\u00f9 sont les nappes dans le Massif central fran\u00e7ais? Bull Soc Geol Fr 3:605\u2013618","journal-title":"Bull Soc Geol Fr"},{"key":"1119_CR55","doi-asserted-by":"publisher","first-page":"267","DOI":"10.1007\/s12371-011-0040-2","volume":"3","author":"JA L\u00f3pez-Garc\u00eda","year":"2011","unstructured":"L\u00f3pez-Garc\u00eda JA, Oyarzun R, L\u00f3pez Andr\u00e9s S, Manteca Mart\u00ednez JI (2011) Scientific, educational, and environmental considerations regarding mine sites and geoheritage: A perspective from SE Spain. Geoheritage 3:267\u2013275. https:\/\/doi.org\/10.1007\/s12371-011-0040-2","journal-title":"Geoheritage"},{"key":"1119_CR56","doi-asserted-by":"publisher","DOI":"10.1007\/978-3-642-12419-8","volume-title":"Mine Wastes","author":"B Lottermoser","year":"2010","unstructured":"Lottermoser B (2010) Mine Wastes. Springer, Berlin \/ Heidelberg"},{"key":"1119_CR57","doi-asserted-by":"publisher","first-page":"179","DOI":"10.1016\/S1251-8050(00)88666-8","volume":"330","author":"C Mah\u00e9-Le Carlier","year":"2000","unstructured":"Mah\u00e9-Le Carlier C, Carlier Le, de Veslud C, Ploquin A, Royer J-J (2000) L\u2019alt\u00e9ration naturelle des scories de la m\u00e9tallurgie ancienne\u202f: un analogue de d\u00e9chets vitrifi\u00e9s. Comptes Rendus De L\u2019acad\u00e9mie des Sci \u2013 Ser IIA - Earth Planet Sci 330:179\u2013184. https:\/\/doi.org\/10.1016\/S1251-8050(00)88666-8","journal-title":"Comptes Rendus De L\u2019acad\u00e9mie des Sci \u2013 Ser IIA - Earth Planet Sci"},{"key":"1119_CR58","doi-asserted-by":"publisher","first-page":"472","DOI":"10.1007\/s001260050216","volume":"34","author":"C Marignac","year":"1999","unstructured":"Marignac C, Cuney M (1999) Ore deposits of the French Massif Central\u202f: insight into the metallogenesis of the Variscan collision belt. Miner Deposita 34:472\u2013504","journal-title":"Miner Deposita"},{"key":"1119_CR59","doi-asserted-by":"publisher","first-page":"329","DOI":"10.1016\/0040-1951(86)90237-4","volume":"126","author":"P Matte","year":"1986","unstructured":"Matte P (1986) Tectonics and plate tectonics model for the variscan belt of europe. Tectonophysics 126:329\u2013374","journal-title":"Tectonophysics"},{"issue":"2","key":"1119_CR60","first-page":"62","volume":"7","author":"RI Mccallum","year":"2001","unstructured":"Mccallum RI (2001) Captain James Cook\u2019s antimony cup. Vesalius\u202f: Acta Int Hist Med 7(2):62\u201364","journal-title":"Vesalius : Acta Int Hist Med"},{"key":"1119_CR61","first-page":"531","volume":"15","author":"CP McCord","year":"1973","unstructured":"McCord CP, Baylis SJ (1973) The origin of the names of elemental metals. J Occup Med 15:531\u2013534","journal-title":"J Occup Med"},{"key":"1119_CR62","doi-asserted-by":"publisher","first-page":"2","DOI":"10.1016\/j.jtos.2012.09.003","volume":"11","author":"J Murube","year":"2013","unstructured":"Murube J (2013) Ocular cosmetics in ancient times. Ocul Surf 11:2\u20137. https:\/\/doi.org\/10.1016\/j.jtos.2012.09.003","journal-title":"Ocul Surf"},{"key":"1119_CR63","doi-asserted-by":"publisher","first-page":"194","DOI":"10.1016\/j.gr.2009.08.001","volume":"17","author":"RD Nance","year":"2010","unstructured":"Nance RD, Guti\u00e9rrez-Alonso G, Keppie JD et al (2010) Evolution of the Rheic Ocean. Gondwana Res 17:194\u2013222","journal-title":"Gondwana Res"},{"key":"1119_CR64","doi-asserted-by":"publisher","first-page":"197","DOI":"10.3406\/bulmi.1928.4043","volume":"51","author":"J Orcel","year":"1928","unstructured":"Orcel J (1928) Notes sur les caract\u00e8res microscopiques des min\u00e9raux opaques, principalement en lumi\u00e8re polaris\u00e9e. Bull Soc Fran\u00e7 Min\u00e9ral 51:197\u2013210","journal-title":"Bull Soc Fran\u00e7 Min\u00e9ral"},{"key":"1119_CR65","first-page":"5","volume":"456","author":"JJ P\u00e9richaud","year":"1980","unstructured":"P\u00e9richaud JJ (1980) L\u2019Antimoine, ses minerais et ses gisements: synth\u00e8se g\u00eetologique sur les gisements du Massif Central fran\u00e7ais. Chron Rech Min 456:5\u201364","journal-title":"Chron Rech Min"},{"key":"1119_CR66","first-page":"294","volume":"88","author":"JJ P\u00e9richaud","year":"1965","unstructured":"P\u00e9richaud JJ, Pierrot R (1965) La chapmanite de La Bessade (Haute-Loire). Bull Soc Fran Min\u00e9ral Cristall 88:294\u2013299","journal-title":"Bull Soc Fran Min\u00e9ral Cristall"},{"key":"1119_CR67","unstructured":"P\u00e9richaud JJ (1970) Les gisements m\u00e9talliques du district \u00e0 antimoine de Brioude-Massiac (Massif Central fran\u00e7ais).\u00a0PhD dissertation, Clermont-Ferrand, 5(121):413\u2013418"},{"key":"1119_CR68","doi-asserted-by":"publisher","first-page":"4669","DOI":"10.3390\/ijerph19084669","volume":"19","author":"A Periferakis","year":"2022","unstructured":"Periferakis A, Caruntu A, Periferakis A-T et al (2022) Availability, toxicology and medical significance of antimony. Int J Environ Res Public Health 19:4669. https:\/\/doi.org\/10.3390\/ijerph19084669","journal-title":"Int J Environ Res Public Health"},{"key":"1119_CR69","doi-asserted-by":"crossref","unstructured":"Pirrie D, Butcher AR, Power MR (2004) Rapid quantitative mineral and phase analysis using automated scanning electron microscopy (QemSCAN); potential applications in forensic geoscience. In: Pye K, Croft D (eds) Forensic Geoscience: Principles, Techniques and Applications, Geological Society, London, Special Publication n\u00b0232:123\u2013136","DOI":"10.1144\/GSL.SP.2004.232.01.12"},{"key":"1119_CR70","doi-asserted-by":"publisher","first-page":"235","DOI":"10.1111\/j.1365-2451.2011.00818.x","volume":"27","author":"D Pirrie","year":"2011","unstructured":"Pirrie D, Rollinson GK (2011) Unlocking the applications of automated mineral analysis. Geol Today 27:235\u2013244","journal-title":"Geol Today"},{"key":"1119_CR71","doi-asserted-by":"publisher","DOI":"10.5382\/econgeo.4937","author":"AB Radkov\u00e1","year":"2022","unstructured":"Radkov\u00e1 AB, Jamieson HE, Campbell KM, Hudson-Edwards KA (2022) Antimony in mine wastes: Geochemistry, mineralogy, and microbiology. Econ Geol. https:\/\/doi.org\/10.5382\/econgeo.4937","journal-title":"Econ Geol"},{"key":"1119_CR72","first-page":"76","volume":"92","author":"G Roger","year":"1969","unstructured":"Roger G (1969) Sur la min\u00e9ralogie et le mode de gisement des filons \u00e0 antimoine du district de Brioude-Massiac (Haute-Loire, Cantal), Massif central fran\u00e7ais. Bull Soc Fran Min\u00e9ral Cristall 92:76\u201385","journal-title":"Bull Soc Fran Min\u00e9ral Cristall"},{"key":"1119_CR73","doi-asserted-by":"publisher","first-page":"360","DOI":"10.1007\/BF00208366","volume":"7","author":"G Roger","year":"1972","unstructured":"Roger G (1972) Un type de min\u00e9ralisations \u00e9pig\u00e9n\u00e9tiques famili\u00e8res: les filons \u00e0 antimoine du Massif Central fran\u00e7ais. Hypoth\u00e8se de la s\u00e9cr\u00e9tion lat\u00e9rale. Miner Deposita 7:360\u2013382","journal-title":"Miner Deposita"},{"key":"1119_CR74","doi-asserted-by":"publisher","first-page":"778","DOI":"10.1016\/j.mineng.2011.02.004","volume":"24","author":"GK Rollinson","year":"2011","unstructured":"Rollinson GK, Andersen JC, Stickland RJ et al (2011) Characterisation of non-sulphide zinc deposits using QEMSCAN\u00ae. Miner Eng 24:778\u2013787","journal-title":"Miner Eng"},{"key":"1119_CR75","doi-asserted-by":"publisher","first-page":"1288","DOI":"10.1080\/10962247.2014.943352","volume":"64","author":"G Salihoglu","year":"2014","unstructured":"Salihoglu G (2014) Immobilization of antimony waste slag by applying geopolymerization and stabilization\/solidification technologies. J Air Waste Manag Assoc 64:1288\u20131298. https:\/\/doi.org\/10.1080\/10962247.2014.943352","journal-title":"J Air Waste Manag Assoc"},{"key":"1119_CR76","doi-asserted-by":"publisher","first-page":"3","DOI":"10.2113\/gssgfbull.IV.1.3","volume":"8","author":"D Santallier","year":"1988","unstructured":"Santallier D, Briand B, Menot R-P, Piboule M (1988) Les complexes leptyno-amphiboliques (C.L.A.): revue critique et suggestions pour un meilleur emploi de ce terme. Bull Soc Geol Fr 8:3\u201312","journal-title":"Bull Soc Geol Fr"},{"key":"1119_CR77","doi-asserted-by":"publisher","first-page":"15","DOI":"10.1007\/978-3-030-85889-6_3","volume-title":"Elements and Mineral Resources","author":"J Sanz","year":"2022","unstructured":"Sanz J, Tomasa O, Jimenez-Franco A, Sidki-Rius N (2022) Antimony (Sb) [Z = 51]. In: Sanz J, Tomasa O, Jimenez-Franco A, Sidki-Rius N (eds) Elements and Mineral Resources. Springer International Publishing, Cham, pp 15\u201318"},{"key":"1119_CR78","doi-asserted-by":"publisher","first-page":"14","DOI":"10.1016\/j.gexplo.2012.03.007","volume":"118","author":"T Sh","year":"2012","unstructured":"Sh T, Liu C-Q, Feng C (2012) Solubility, toxicity and sorption of antimony from smelter release. J Geochem Explor 118:14\u201318","journal-title":"J Geochem Explor"},{"key":"1119_CR79","unstructured":"Siebenschock M, Goldenberg G, Wagner H (1996) Arch\u00e4ometallurgische Untersuchungen zur Verh\u00fcttung von Antimonierzen im Schwarzwald. Gewinnung von Antimonium Crudum im Sp\u00e4tmittelalter und in der Neuzeit bei Sulzburg. In: Arch\u00e4ometallurgische Untersuchungen zum Metallh\u00fcttenwesen im Schwarzwald, Goldenberg G, Otto J, Steuer H (eds)\u00a0Sigmaringen, Thorbecke, 275\u2013336\u00a0"},{"key":"1119_CR80","doi-asserted-by":"publisher","first-page":"241","DOI":"10.1029\/95RG00262","volume":"33","author":"SR Taylor","year":"1995","unstructured":"Taylor SR, McLennan SM (1995) The geochemical evolution of the continental crust: Reviews of Geophysics. Rev Geophys 33:241\u2013265","journal-title":"Rev Geophys"},{"key":"1119_CR81","first-page":"61","volume":"11\u201312","author":"P Thi\u00e9ry","year":"1947","unstructured":"Thi\u00e9ry P (1947) L\u2019antimoine - Aper\u00e7u sur l\u2019industrie mini\u00e8re et m\u00e9tallurgique de l\u2019antimoine. Ann Min 11\u201312:61\u2013105","journal-title":"Ann Min"},{"key":"1119_CR82","doi-asserted-by":"publisher","first-page":"954","DOI":"10.1016\/j.gr.2015.05.009","volume":"28","author":"V Thi\u00e9ry","year":"2015","unstructured":"Thi\u00e9ry V, Rolin P, Dubois M, Caumon M-C (2015) Discovery of metamorphic microdiamonds from the parautochthonous units of the Variscan French Massif Central. Gondwana Res 28:954\u2013960. https:\/\/doi.org\/10.1016\/j.gr.2015.05.009","journal-title":"Gondwana Res"},{"key":"1119_CR83","doi-asserted-by":"publisher","unstructured":"Thi\u00e9ry V, Rolin P, Dubois M, et al (2016) Reply to J. Berger\u2019s comment on the article \u201cDiscovery of metamorphic microdiamonds from the parautochthonous units of the Variscan French Massif\u201d by Thi\u00e9ry, V. et al., (2015), Gondwana Research 28, 954\u2013960. Gondwana Research 38:372\u2013374. https:\/\/doi.org\/10.1016\/j.gr.2015.12.002","DOI":"10.1016\/j.gr.2015.12.002"},{"key":"1119_CR84","doi-asserted-by":"publisher","first-page":"103266","DOI":"10.1016\/j.micron.2022.103266","volume":"158","author":"V Thi\u00e9ry","year":"2022","unstructured":"Thi\u00e9ry V, Dubois E, Bellayer S (2022) The good, the bad and the ugly polishing: Effect of abrasive size on standardless EDS analysis of Portland cement clinker\u2019s calcium silicates. Micron 158:103266\u2013103266. https:\/\/doi.org\/10.1016\/j.micron.2022.103266","journal-title":"Micron"},{"key":"1119_CR85","doi-asserted-by":"publisher","DOI":"10.1111\/jmi.13231","author":"V Thi\u00e9ry","year":"2023","unstructured":"Thi\u00e9ry V, Chedrewih M, Rollinson G et al (2023) Slags from roasting of antimony ore in the Brioude-Massiac (France) area used as aggregates: An early example of circular economy. J Microsc. https:\/\/doi.org\/10.1111\/jmi.13231","journal-title":"J Microsc"},{"key":"1119_CR86","unstructured":"Thi\u00e9ry V, Chedrewih M, Guiollard PC (2024) Sur les traces de la m\u00e9tallurgie de l\u2019antimoine du district de Brioude-Massiac (Haute-Loire -Cantal). Mines & Carri\u00e8res 322:40\u201348"},{"key":"1119_CR87","doi-asserted-by":"publisher","first-page":"122","DOI":"10.1177\/003591572601901707","volume":"19","author":"SC Thomson","year":"1926","unstructured":"Thomson SC (1926) Antimonyall Cupps: Pocula Emetica or Calices Vomitorii. Proc R Soc Med 19:122\u2013128. https:\/\/doi.org\/10.1177\/003591572601901707","journal-title":"Proc R Soc Med"},{"key":"1119_CR88","first-page":"30","volume":"117","author":"L Tixier","year":"1978","unstructured":"Tixier L (1978) Une Exploitation Mini\u00e8re Gallo-Romaine. Arch\u00e9ologia 117:30\u201337","journal-title":"Arch\u00e9ologia"},{"key":"1119_CR89","doi-asserted-by":"publisher","first-page":"97","DOI":"10.1084\/jem.37.1.97","volume":"37","author":"S Weiss","year":"1923","unstructured":"Weiss S, Hatcher RA (1923) The mechanism of the vomiting induced by antimony and potassium tartrate (tartar emetic). J Exp Med 37:97\u2013111. https:\/\/doi.org\/10.1084\/jem.37.1.97","journal-title":"J Exp Med"},{"key":"1119_CR90","doi-asserted-by":"crossref","unstructured":"Wothers P (2019) Antimony, gold and Jupiter\u2019s wolf - How the elements were named. Oxford Universtity Press, p 273","DOI":"10.1093\/oso\/9780199652723.001.0001"},{"key":"1119_CR91","doi-asserted-by":"publisher","unstructured":"Yan S, Jin L, Sun H (2005) 51Sb Antimony in medicine. In: Metallotherapeutic Drugs and Metal\u2010Based Diagnostic Agents 441\u2013461.\u00a0https:\/\/doi.org\/10.1002\/0470864052.ch23","DOI":"10.1002\/0470864052.ch23"}],"container-title":["Geoheritage"],"original-title":[],"language":"en","link":[{"URL":"https:\/\/link.springer.com\/content\/pdf\/10.1007\/s12371-025-01119-z.pdf","content-type":"application\/pdf","content-version":"vor","intended-application":"text-mining"},{"URL":"https:\/\/link.springer.com\/article\/10.1007\/s12371-025-01119-z\/fulltext.html","content-type":"text\/html","content-version":"vor","intended-application":"text-mining"},{"URL":"https:\/\/link.springer.com\/content\/pdf\/10.1007\/s12371-025-01119-z.pdf","content-type":"application\/pdf","content-version":"vor","intended-application":"similarity-checking"}],"deposited":{"date-parts":[[2025,6,12]],"date-time":"2025-06-12T07:06:32Z","timestamp":1749711992000},"score":1,"resource":{"primary":{"URL":"https:\/\/link.springer.com\/10.1007\/s12371-025-01119-z"}},"subtitle":[],"short-title":[],"issued":{"date-parts":[[2025,5,14]]},"references-count":91,"journal-issue":{"issue":"2","published-print":{"date-parts":[[2025,6]]}},"alternative-id":["1119"],"URL":"https:\/\/doi.org\/10.1007\/s12371-025-01119-z","relation":{},"ISSN":["1867-2477","1867-2485"],"issn-type":[{"type":"print","value":"1867-2477"},{"type":"electronic","value":"1867-2485"}],"subject":[],"published":{"date-parts":[[2025,5,14]]},"assertion":[{"value":"22 February 2024","order":1,"name":"received","label":"Received","group":{"name":"ArticleHistory","label":"Article History"}},{"value":"25 April 2025","order":2,"name":"accepted","label":"Accepted","group":{"name":"ArticleHistory","label":"Article History"}},{"value":"14 May 2025","order":3,"name":"first_online","label":"First Online","group":{"name":"ArticleHistory","label":"Article History"}},{"order":1,"name":"Ethics","group":{"name":"EthicsHeading","label":"Declarations"}},{"value":"The authors declare that they do not have any competing interest. This research did not receive any funding. No further data will be deposited.","order":2,"name":"Ethics","group":{"name":"EthicsHeading","label":"Conflict of interest"}}],"article-number":"76"}}