{"status":"ok","message-type":"work","message-version":"1.0.0","message":{"indexed":{"date-parts":[[2026,6,23]],"date-time":"2026-06-23T04:50:22Z","timestamp":1782190222250,"version":"3.54.5"},"reference-count":55,"publisher":"Elsevier BV","license":[{"start":{"date-parts":[[2025,11,1]],"date-time":"2025-11-01T00:00:00Z","timestamp":1761955200000},"content-version":"tdm","delay-in-days":0,"URL":"https:\/\/www.elsevier.com\/tdm\/userlicense\/1.0\/"},{"start":{"date-parts":[[2025,11,1]],"date-time":"2025-11-01T00:00:00Z","timestamp":1761955200000},"content-version":"tdm","delay-in-days":0,"URL":"https:\/\/www.elsevier.com\/legal\/tdmrep-license"},{"start":{"date-parts":[[2025,8,15]],"date-time":"2025-08-15T00:00:00Z","timestamp":1755216000000},"content-version":"vor","delay-in-days":0,"URL":"http:\/\/creativecommons.org\/licenses\/by-nc\/4.0\/"}],"funder":[{"DOI":"10.13039\/100022764","name":"State of Baden-Wurttemberg Ministry of Food Rural Areas and Consumer Protection","doi-asserted-by":"publisher","id":[{"id":"10.13039\/100022764","id-type":"DOI","asserted-by":"publisher"}]},{"DOI":"10.13039\/501100000780","name":"European Commission","doi-asserted-by":"publisher","id":[{"id":"10.13039\/501100000780","id-type":"DOI","asserted-by":"publisher"}]}],"content-domain":{"domain":["elsevier.com","sciencedirect.com"],"crossmark-restriction":true},"short-container-title":["Analytica Chimica Acta"],"published-print":{"date-parts":[[2025,11]]},"DOI":"10.1016\/j.aca.2025.344548","type":"journal-article","created":{"date-parts":[[2025,8,18]],"date-time":"2025-08-18T05:07:59Z","timestamp":1755493679000},"page":"344548","update-policy":"https:\/\/doi.org\/10.1016\/elsevier_cm_policy","source":"Crossref","is-referenced-by-count":2,"special_numbering":"C","title":["Elaboration of trapping conditions on zirconia for the online SPE-LC-MS\/MS analysis of glyphosate and other polar organophosphonate and \u2013phosphinate pesticide residues in plant-based food extracts"],"prefix":"10.1016","volume":"1373","author":[{"given":"Eric","family":"Eichhorn","sequence":"first","affiliation":[],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Walter","family":"Vetter","sequence":"additional","affiliation":[],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Michelangelo","family":"Anastassiades","sequence":"additional","affiliation":[],"role":[{"vocabulary":"crossref","role":"author"}]}],"member":"78","reference":[{"key":"10.1016\/j.aca.2025.344548_bib1","doi-asserted-by":"crossref","first-page":"1027","DOI":"10.1002\/ps.4652","article-title":"The history and current status of glyphosate","volume":"74","author":"Duke","year":"2017","journal-title":"Pest Manag. Sci."},{"key":"10.1016\/j.aca.2025.344548_bib2","first-page":"447","article-title":"Zwischen Wissen und Metaphysik \u2013 wo steht das Vorsorgeprinzip im Streit um die Risikobewertung des Pflanzenschutzmittelwirkstoffs Glyphosat? ZLR","volume":"43","author":"Hensel","year":"2016"},{"key":"10.1016\/j.aca.2025.344548_bib3","first-page":"5862","article-title":"Review of the existing maximum residue levels for glyphosate according to article 12 of regulation (EC) no 396\/2005 \u2013 revised version to take into account omitted data","volume":"17","year":"2019","journal-title":"EFSA J."},{"key":"10.1016\/j.aca.2025.344548_bib4","article-title":"The 2023 european union report on pesticide residues in food","volume":"23","year":"2025","journal-title":"EFSA J."},{"key":"10.1016\/j.aca.2025.344548_bib5","doi-asserted-by":"crossref","DOI":"10.51694\/AdvWeedSci\/2022;40:seventy-five003","article-title":"The potential future roles of natural compounds and microbial bioherbicides in weed management in crops","volume":"40","author":"Duke","year":"2022","journal-title":"Adv. Weed Sci."},{"key":"10.1016\/j.aca.2025.344548_bib6","first-page":"6782","article-title":"Reasoned opinion on the joint review of maximum residue levels (MRLs) for fosetyl, disodium phosphonate and potassium phosphonates according to articles 12 and 43 of regulation (EC) no 396\/2005","volume":"19","year":"2021","journal-title":"EFSA J."},{"key":"10.1016\/j.aca.2025.344548_bib7","doi-asserted-by":"crossref","DOI":"10.1007\/s13562-024-00953-6","article-title":"Unraveling the multifaceted role of ethephon in plant physiology: from seed germination to crop maturation and harvesting","author":"Kowsalya","year":"2025","journal-title":"J. Plant Biochem. Biotechnol."},{"key":"10.1016\/j.aca.2025.344548_bib8","volume":"1\/15","year":"2024","journal-title":"Orkesterjournalen L"},{"issue":"8","key":"10.1016\/j.aca.2025.344548_bib9","volume":"16","year":"2025","journal-title":"SANCO\/12745\/2013 17\u201318 February 2025 rev."},{"key":"10.1016\/j.aca.2025.344548_bib10","article-title":"Quick method for the analysis of highly polar pesticides in food involving extraction with acidified methanol and LC- or IC-MS\/MS measurement","author":"Anastassiades","year":"2024","journal-title":"Food of plant origin (QuPPe-PO-Method)"},{"key":"10.1016\/j.aca.2025.344548_bib12","doi-asserted-by":"crossref","DOI":"10.1016\/j.teac.2022.e00186","article-title":"Novel liquid chromatography\/mass spectrometry-based approaches for the determination of glyphosate and related compounds: a review","volume":"36","author":"Roc\u00edo-Bautista","year":"2022","journal-title":"Trends Environ. Anal. Chem."},{"key":"10.1016\/j.aca.2025.344548_bib13","doi-asserted-by":"crossref","first-page":"2856","DOI":"10.1007\/s12161-016-0468-8","article-title":"Determination of underivatized glyphosate residues in plant-derived food with low matrix effect by solid phase extraction-liquid chromatography-tandem mass spectrometry","volume":"9","author":"Ding","year":"2016","journal-title":"Food Anal. Methods"},{"key":"10.1016\/j.aca.2025.344548_bib14","doi-asserted-by":"crossref","first-page":"524","DOI":"10.1016\/j.foodchem.2017.03.091","article-title":"Clean-up and matrix effect in LC-MS\/MS analysis of food of plant origin for high polar herbicides","volume":"230","author":"Kaczynski","year":"2017","journal-title":"Food Chem."},{"key":"10.1016\/j.aca.2025.344548_bib15","doi-asserted-by":"crossref","first-page":"93","DOI":"10.1016\/j.chroma.2019.02.024","article-title":"Method validation and application of a selective multiresidue analysis of highly polar pesticides in food matrices using hydrophilic interaction liquid chromatography and mass spectrometry","volume":"1594","author":"Herrera Lopez","year":"2019","journal-title":"J. Chromatogr. A"},{"key":"10.1016\/j.aca.2025.344548_bib16","doi-asserted-by":"crossref","DOI":"10.1016\/j.mex.2021.101306","article-title":"Analysis by LC-MS\/MS of polar pesticides in fruits and vegetables using new hybrid stationary phase","volume":"8","author":"Cutillas","year":"2021","journal-title":"MethodsX"},{"issue":"11","key":"10.1016\/j.aca.2025.344548_bib17","doi-asserted-by":"crossref","first-page":"2165","DOI":"10.1002\/jssc.202001134","article-title":"Influence of different hydrophilic interaction liquid chromatography stationary phases on method performance for the determination of highly polar anionic pesticides in complex feed matrices","volume":"44","author":"Dias","year":"2021","journal-title":"J. Separ. Sci."},{"key":"10.1016\/j.aca.2025.344548_bib18","doi-asserted-by":"crossref","DOI":"10.1016\/j.foodchem.2020.128495","article-title":"Monitoring of polar pesticides and contaminants in edible oils and nuts by liquid chromatography-tandem mass spectrometry","volume":"343","author":"Hidalgo-Ruiz","year":"2021","journal-title":"Food Chem."},{"issue":"5","key":"10.1016\/j.aca.2025.344548_bib19","doi-asserted-by":"crossref","first-page":"1341","DOI":"10.1093\/jaoacint\/qsac019","article-title":"Determination of highly polar and ionic pesticides in grape and pomegranate using liquid chromatography tandem mass spectrometry","volume":"105","author":"Shinde","year":"2022","journal-title":"J. AOAC Int."},{"key":"10.1016\/j.aca.2025.344548_bib20","doi-asserted-by":"crossref","DOI":"10.1016\/j.chroma.2022.463631","article-title":"Direct determination of glyphosate, aminomethylphosphonic acid and glufosinate in food samples with ion chromatography coupled to electrospray ionization tandem mass spectrometry","volume":"1687","author":"Amberger","year":"2023","journal-title":"J. Chromatogr. A"},{"key":"10.1016\/j.aca.2025.344548_bib21","doi-asserted-by":"crossref","unstructured":"A.-K. Sch\u00e4fer, W. Vetter, M. Anastassiades, Analysis of highly polar anionic pesticides in food of plant and animal origin by ion chromatography and tandem mass spectrometry with emphasis on addressing adverse effects caused by matrix co-extractives, Anal. Bioanal. Chem. (2024) , Vol. 416, 4503-4517, doi:10.1007\/s00216-024-05389-4.","DOI":"10.1007\/s00216-024-05389-4"},{"key":"10.1016\/j.aca.2025.344548_bib22","doi-asserted-by":"crossref","first-page":"237","DOI":"10.1039\/D3AY01874A","article-title":"The determination of underivatized chlormequat, fosetyl-aluminium and phosphonic acid residues in maize and soybean by LC-MS\/MS","volume":"16","author":"Yang","year":"2023","journal-title":"Anal. Methods"},{"key":"10.1016\/j.aca.2025.344548_bib23","doi-asserted-by":"crossref","first-page":"881","DOI":"10.1002\/mas.20097","article-title":"Matrix effects in quantitative pesticide analysis using liquid-chromatography mass-spectrometry","volume":"25","author":"Niessen","year":"2006","journal-title":"Mass Spectrom. Rev."},{"key":"10.1016\/j.aca.2025.344548_bib24","unstructured":"Commission Delegated Regulation (EU) 2016\/127 of 25 September 2015 Supplementing Regulation (EU) No 609\/2013 of the European Parliament and of the Council as Regards the Specific Compositional and Information Requirements for Infant Formula and follow-on Formula and as Regards Requirements on Information Relating to Infant and Young Child Feeding (2024, in its last consolidated version). OJEU, L25\/1. http:\/\/data.europa.eu\/eli\/reg_del\/2016\/127\/2024-10-11."},{"key":"10.1016\/j.aca.2025.344548_bib25","author":"Naturkost Naturwaren"},{"key":"10.1016\/j.aca.2025.344548_bib26","doi-asserted-by":"crossref","first-page":"83","DOI":"10.1016\/S0021-9673(01)01253-5","article-title":"Automated trace level determination of glyphosate and aminomethyl phosphonic acid in water by on-line anion-exchange solid-phase extraction followed by cation-exchange liquid chromatography and post-column derivatization","volume":"932","author":"Patsias","year":"2001","journal-title":"J. Chromatogr. A"},{"key":"10.1016\/j.aca.2025.344548_bib27","doi-asserted-by":"crossref","first-page":"139","DOI":"10.1016\/j.chroma.2005.07.063","article-title":"Matrix solid-phase dispersion extraction and determination by high-performance liquid chromatography with fluorescence detection of residues of glyphosate and aminomethylphosphonic acid in tomato fruit","volume":"1093","author":"Garcia de Llasera","year":"2005","journal-title":"J. Chromatogr. A"},{"key":"10.1016\/j.aca.2025.344548_bib28","doi-asserted-by":"crossref","first-page":"357","DOI":"10.1016\/j.chroma.2019.05.013","article-title":"Field-amplified sample injection and sweeping micellar electrokinetic chromatography in analysis of glyphosate and aminomethylphosphonic acid in wheat","volume":"1601","author":"Gotti","year":"2019","journal-title":"J. Chromatogr. A"},{"key":"10.1016\/j.aca.2025.344548_bib29","doi-asserted-by":"crossref","first-page":"675","DOI":"10.1007\/s00216-023-04946-7","article-title":"Determination of highly polar anionic pesticides in beehive products by hydrophilic interaction liquid chromatography coupled to mass spectrometry","volume":"416","author":"Jesus","year":"2023","journal-title":"Anal. Bioanal. Chem."},{"key":"10.1016\/j.aca.2025.344548_bib30","doi-asserted-by":"crossref","DOI":"10.1016\/j.chroma.2022.463697","article-title":"Direct, automated and sensitive determination of glyphosate and related anionic pesticides in environmental water samples using solid-phase extraction on-line combined with liquid chromatography tandem mass spectrometry","volume":"1687","author":"L\u00f3pez-V\u00e1zquez","year":"2023","journal-title":"J. Chromatogr. A"},{"key":"10.1016\/j.aca.2025.344548_bib31","doi-asserted-by":"crossref","first-page":"12293","DOI":"10.1007\/s11356-017-8844-5","article-title":"Preliminary recovery study of a commercial molecularly imprinted polymer for the extraction of glyphosate and AMPA in different environmental waters using MS","volume":"24","author":"B\u00e9reng\u00e9re","year":"2017","journal-title":"Environ. Sci. Pollut. Res."},{"key":"10.1016\/j.aca.2025.344548_bib32","doi-asserted-by":"crossref","first-page":"5741","DOI":"10.3390\/molecules27175741","article-title":"Method of glyphosate, AMPA, and glufosinate ammonium determination in beebread by liquid chromatography\u2014tandem mass spectrometry after molecularly imprinted solid-phase extraction","volume":"27","author":"Malysiak","year":"2022","journal-title":"Molecules"},{"key":"10.1016\/j.aca.2025.344548_bib33","doi-asserted-by":"crossref","DOI":"10.1016\/j.chroma.2023.464209","article-title":"Development of a specific and sensitive method for the detection of glyphosate pesticide and its metabolite in tea using dummy molecularly imprinte d solid-phase extraction couple d with liquid chromatography-tandem quadrupole mass spectrometry","volume":"1705","author":"Wang","year":"2023","journal-title":"J. Chromatogr. A"},{"key":"10.1016\/j.aca.2025.344548_bib34","doi-asserted-by":"crossref","first-page":"863","DOI":"10.1021\/ac00032a008","article-title":"Development of an eluotropic series for the chromatography of lewis bases on zirconium oxide","volume":"64","author":"Blackwell","year":"1992","journal-title":"Anal. Chem."},{"key":"10.1016\/j.aca.2025.344548_bib35","doi-asserted-by":"crossref","first-page":"1489","DOI":"10.2116\/analsci.22.1489","article-title":"Absolute determination method for trace quantities of enantiomer of glufosinate by g -Cyclodextrin modified capillary zone electrophoresis combined with solid-phase extraction and On-capillary concentration","volume":"22","author":"Asami","year":"2006","journal-title":"Anal. Sci."},{"key":"10.1016\/j.aca.2025.344548_bib36","doi-asserted-by":"crossref","first-page":"703","DOI":"10.1093\/jaoac\/92.3.703","article-title":"New approaches for determination of glyphosate and aminomethylphosphonic acid from different tea samples\u2014Prospects and limits of cleanup with molecularly imprinted polymerand titanium dioxide","volume":"92","author":"Kittlaus","year":"2009","journal-title":"J. AOAC Int."},{"key":"10.1016\/j.aca.2025.344548_bib37","doi-asserted-by":"crossref","first-page":"69","DOI":"10.1016\/j.jchromb.2014.08.004","article-title":"Solid-phase extraction of phosphorous-containing amino acidherbicides from biological specimens with a zirconia-coated silica cartridge","volume":"969","author":"Watanabe","year":"2014","journal-title":"J. Chromatogr. B"},{"key":"10.1016\/j.aca.2025.344548_bib38","doi-asserted-by":"crossref","first-page":"6004","DOI":"10.1021\/acs.analchem.5b00194","article-title":"Evaluation of titanium dioxide as a binding phase for the passive sampling of glyphosate and aminomethyl phosphonic acid in an aquatic environment","volume":"87","author":"Fauvelle","year":"2015","journal-title":"Anal. Chem."},{"key":"10.1016\/j.aca.2025.344548_bib39","first-page":"313","volume":"112","author":"Wilmers","year":"2016"},{"key":"10.1016\/j.aca.2025.344548_bib40","doi-asserted-by":"crossref","DOI":"10.1016\/j.chroma.2021.462519","article-title":"Titanium dioxide-coated core-shell silica microspheres-based solid-phase extraction combined with sheathless capillary electrophoresis-mass spectrometry for analysis of glyphosate, glufosinate and their metabolites in baby foods","volume":"1659","author":"Liu","year":"2021","journal-title":"J. Chromatogr. A"},{"key":"10.1016\/j.aca.2025.344548_bib41","doi-asserted-by":"crossref","first-page":"315","DOI":"10.1016\/0021-9797(88)90367-0","article-title":"Reactions of metal oxides with aqueous solutions","volume":"122","author":"Regazzoni","year":"1988","journal-title":"J. Colloid Interface Sci."},{"key":"10.1016\/j.aca.2025.344548_bib42","doi-asserted-by":"crossref","first-page":"229","DOI":"10.1016\/0021-9673(93)80284-F","article-title":"Chemistry of zirconia and its use in chromatography","volume":"657","author":"Nawrocki","year":"1993","journal-title":"J. of Chromatogr. A"},{"key":"10.1016\/j.aca.2025.344548_bib43","doi-asserted-by":"crossref","first-page":"43","DOI":"10.1016\/S0021-9673(00)91417-1","article-title":"Study of the fluoride adsorption characteristics of porous microparticulate zirconium dioxide","volume":"549","author":"Blackwell","year":"1991","journal-title":"J. of Chromatogr."},{"key":"10.1016\/j.aca.2025.344548_bib44","doi-asserted-by":"crossref","first-page":"140","DOI":"10.1006\/jfca.1993.1016","article-title":"The sulfate content of foods and beverages","volume":"6","author":"Florin","year":"1993","journal-title":"J. Food Compos. Anal."},{"key":"10.1016\/j.aca.2025.344548_bib45","series-title":"Food Composition and Nutrition Tables, 7th Revised and Completed Edition","author":"Souci","year":"2008"},{"key":"10.1016\/j.aca.2025.344548_bib46","doi-asserted-by":"crossref","first-page":"97","DOI":"10.1016\/j.chroma.2007.01.046","article-title":"Advantages and limitations of on-line solid phase extraction coupled to liquid chromatography\u2013mass spectrometry technologies versus biosensors for monitoring of emerging contaminants in water","volume":"1152","author":"Rodriguez-Mozaz","year":"2007","journal-title":"J. J. Chromatogr. A"},{"key":"10.1016\/j.aca.2025.344548_bib47","series-title":"Food of Plant Origin (QuPPe-PO-Method)","article-title":"Quick method for the analysis of highly polar pesticides in food involving extraction with acidified methanol and LC- or IC-MS\/MS measurement","author":"Anastassiades","year":"2019"},{"key":"10.1016\/j.aca.2025.344548_bib48","doi-asserted-by":"crossref","first-page":"247","DOI":"10.1016\/j.chroma.2004.01.038","article-title":"Reliability of the retention factor estimations in liquid chromatography","volume":"1033","author":"Escuder-Gilabert","year":"2004","journal-title":"J. Chromatogr. A"},{"key":"10.1016\/j.aca.2025.344548_bib49","doi-asserted-by":"crossref","first-page":"1","DOI":"10.1016\/0021-9673(96)00205-1","article-title":"Comparison of an ordered mesoporous aluminosilicate, silica, alumina, titania and zirconia in normal-phase high-performance liquid chromatography","volume":"740","author":"Gr\u00fcn","year":"1996","journal-title":"J. Chromatogr. A"},{"key":"10.1016\/j.aca.2025.344548_bib50","article-title":"Evaluation of strategies for overcoming trifluoroacetic acid ionization suppression resulted in single-column intact level, middle-up, and bottom-up reversed-phase LC-MS analyses of antibody biopharmaceuticals","volume":"233","author":"Maria","year":"2021","journal-title":"Talanta"},{"key":"10.1016\/j.aca.2025.344548_bib52","doi-asserted-by":"crossref","DOI":"10.1016\/j.aca.2023.340994","article-title":"Managing nonspecific adsorption to liquid chromatography hardware: a review","volume":"1250","author":"Guimaraes","year":"2023","journal-title":"Anal. Chim. Acta"},{"key":"10.1016\/j.aca.2025.344548_bib53","doi-asserted-by":"crossref","first-page":"2747","DOI":"10.1002\/rcm.2105","article-title":"Formation of phosphopeptide-metal ion complexes in liquid chromatography\/electrospray mass spectrometry and their influence on phosphopeptide detection","volume":"19","author":"Liu","year":"2005","journal-title":"Rapid Commun. Mass Spectrom."},{"issue":"11","key":"10.1016\/j.aca.2025.344548_bib54","doi-asserted-by":"crossref","first-page":"1980","DOI":"10.1002\/jssc.200800174","article-title":"Considerations on HILIC and polar organic solvent based separations: use of Cyclodextrin and macrocyclic glycopetide stationary phases","volume":"31","author":"Wang","year":"2008","journal-title":"J. Separ. Sci."},{"key":"10.1016\/j.aca.2025.344548_bib55","doi-asserted-by":"crossref","first-page":"6981","DOI":"10.1016\/j.chroma.2011.07.100","article-title":"The retention behaviour of polar compounds on zirconia based stationary phases under hydrophilic interaction liquid chromatography conditions","volume":"1218","author":"Kucera","year":"2011","journal-title":"J. Chromatogr. A"},{"key":"10.1016\/j.aca.2025.344548_bib56","doi-asserted-by":"crossref","first-page":"177","DOI":"10.1016\/S0021-9673(00)96972-3","article-title":"Hydrophilic-interaction chromatography for the separation of peptides, nucleic acids and other polar compounds","volume":"499","author":"Alpert","year":"1990","journal-title":"J. Chromatogr. A"},{"issue":"6\u20137","key":"10.1016\/j.aca.2025.344548_bib57","doi-asserted-by":"crossref","first-page":"698","DOI":"10.1002\/jssc.200900742","article-title":"HILIC methods in pharmaceutical analysis","volume":"33","author":"Dejaegher","year":"2010","journal-title":"J. Separ. Sci."}],"container-title":["Analytica Chimica Acta"],"original-title":[],"language":"en","link":[{"URL":"https:\/\/api.elsevier.com\/content\/article\/PII:S0003267025009420?httpAccept=text\/xml","content-type":"text\/xml","content-version":"vor","intended-application":"text-mining"},{"URL":"https:\/\/api.elsevier.com\/content\/article\/PII:S0003267025009420?httpAccept=text\/plain","content-type":"text\/plain","content-version":"vor","intended-application":"text-mining"}],"deposited":{"date-parts":[[2025,11,2]],"date-time":"2025-11-02T11:52:11Z","timestamp":1762084331000},"score":1,"resource":{"primary":{"URL":"https:\/\/linkinghub.elsevier.com\/retrieve\/pii\/S0003267025009420"}},"subtitle":[],"short-title":[],"issued":{"date-parts":[[2025,11]]},"references-count":55,"alternative-id":["S0003267025009420"],"URL":"https:\/\/doi.org\/10.1016\/j.aca.2025.344548","relation":{},"ISSN":["0003-2670"],"issn-type":[{"value":"0003-2670","type":"print"}],"subject":[],"published":{"date-parts":[[2025,11]]},"assertion":[{"value":"Elsevier","name":"publisher","label":"This article is maintained by"},{"value":"Elaboration of trapping conditions on zirconia for the online SPE-LC-MS\/MS analysis of glyphosate and other polar organophosphonate and \u2013phosphinate pesticide residues in plant-based food extracts","name":"articletitle","label":"Article Title"},{"value":"Analytica Chimica Acta","name":"journaltitle","label":"Journal Title"},{"value":"https:\/\/doi.org\/10.1016\/j.aca.2025.344548","name":"articlelink","label":"CrossRef DOI link to publisher maintained version"},{"value":"article","name":"content_type","label":"Content Type"},{"value":"\u00a9 2025 The Authors. Published by Elsevier B.V.","name":"copyright","label":"Copyright"}],"article-number":"344548"}}