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Res."},{"key":"10.1016\/j.bioadv.2026.215179_bb0890","doi-asserted-by":"crossref","first-page":"19662","DOI":"10.1039\/C5TA05788D","article-title":"Catalyst-free dynamic exchange of aromatic Schiff base bonds and its application to self-healing and remolding of crosslinked polymers","volume":"3","author":"Lei","year":"2015","journal-title":"J. Mater. Chem. 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Rapid Commun."},{"key":"10.1016\/j.bioadv.2026.215179_bb0935","doi-asserted-by":"crossref","DOI":"10.3390\/molecules26113332","article-title":"Thiol- and disulfide-based stimulus-responsive soft materials and self-assembling systems","volume":"26","author":"Beaupre","year":"2021","journal-title":"Molecules"},{"key":"10.1016\/j.bioadv.2026.215179_bb0940","doi-asserted-by":"crossref","DOI":"10.1002\/marc.201800121","article-title":"Self-healing Polycaprolactone networks through Thermo-induced reversible disulfide bond formation","volume":"39","author":"Zhang","year":"2018","journal-title":"Macromol. Rapid Commun."},{"key":"10.1016\/j.bioadv.2026.215179_bb0945","doi-asserted-by":"crossref","DOI":"10.1016\/j.eurpolymj.2021.110636","article-title":"Reprocessable polylactide-based networks containing urethane and disulfide linkages","volume":"156","author":"Borska","year":"2021","journal-title":"Eur. Polym. 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Soc."},{"key":"10.1016\/j.bioadv.2026.215179_bb0970","doi-asserted-by":"crossref","DOI":"10.1016\/j.compscitech.2022.109621","article-title":"Boronic ester bonds crosslinked vitrimer elastomers with mechanical robustness, shape memory, self-healing and recyclability properties","volume":"228","author":"Huang","year":"2022","journal-title":"Compos. Sci. 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J. Hyperth."},{"key":"10.1016\/j.bioadv.2026.215179_bb1040","doi-asserted-by":"crossref","first-page":"8359","DOI":"10.1021\/acsapm.3c01496","article-title":"Thermadapt shape memory PCL- co -PBA network exhibiting tunable properties and dynamics of ester\u2013ester exchange reactions","volume":"5","author":"Lv","year":"2023","journal-title":"ACS Appl. Polym. Mater."},{"key":"10.1016\/j.bioadv.2026.215179_bb1045","article-title":"A 4D printable shape memory Vitrimer with Repairability and recyclability through network architecture tailoring from commercial poly( \u03b5 -caprolactone)","volume":"8","author":"Joe","year":"2021","journal-title":"Adv. Sci."},{"key":"10.1016\/j.bioadv.2026.215179_bb1050","doi-asserted-by":"crossref","first-page":"2411","DOI":"10.1021\/acs.jpcb.0c10403","article-title":"Transesterification in Vitrimer polymers using bifunctional catalysts: modeled with solution-phase experimental rates and theoretical analysis of efficiency and mechanisms","volume":"125","author":"Bhusal","year":"2021","journal-title":"J. Phys. Chem. B"},{"key":"10.1016\/j.bioadv.2026.215179_bb1055","doi-asserted-by":"crossref","first-page":"3335","DOI":"10.1021\/acsapm.3c03156","article-title":"Plasticization of a Diels\u2013Alder covalent adaptable network for fused filament fabrication","volume":"6","author":"Bischoff","year":"2024","journal-title":"ACS Appl. Polym. 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