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Lett."},{"issue":"51","key":"10.1016\/j.bioorg.2026.110642_bb0330","doi-asserted-by":"crossref","first-page":"14351","DOI":"10.1021\/acs.orglett.5c04886","article-title":"NiCl2\/Hdipm-catalyzed 2-OH-selective alkylation of glycoside trans-diols","volume":"27","author":"Guo","year":"2025","journal-title":"Org. Lett."},{"issue":"9","key":"10.1016\/j.bioorg.2026.110642_bb0335","doi-asserted-by":"crossref","first-page":"7414","DOI":"10.1021\/acscatal.5c01306","article-title":"Site-switchable alkylation of carbohydrates controlled by inexpensive metal ion catalysts","volume":"15","author":"Guo","year":"2025","journal-title":"ACS Catal."},{"issue":"23","key":"10.1016\/j.bioorg.2026.110642_bb0340","doi-asserted-by":"crossref","DOI":"10.3390\/molecules27238258","article-title":"SnCl4 promoted efficient cleavage of acetal\/ketal groups with the assistance of water in CH2Cl2","volume":"27","author":"Luo","year":"2022","journal-title":"Molecules"},{"issue":"18","key":"10.1016\/j.bioorg.2026.110642_bb0345","doi-asserted-by":"crossref","DOI":"10.3390\/molecules27185980","article-title":"Efficient synthesis of 2-OH thioglycosides from glycals based on the reduction of aryl disulfides by NaBH4","volume":"27","author":"Guo","year":"2022","journal-title":"Molecules"},{"issue":"33","key":"10.1016\/j.bioorg.2026.110642_bb0350","doi-asserted-by":"crossref","DOI":"10.1002\/ejoc.202101565","article-title":"SnCl2-catalyzed acetalation\/selective benzoylation sequence for the synthesis of orthogonally protected glycosyl acceptors","volume":"2022","author":"Lv","year":"2022","journal-title":"Eur. 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Org. Chem."},{"issue":"29","key":"10.1016\/j.bioorg.2026.110642_bb0370","doi-asserted-by":"crossref","first-page":"4927","DOI":"10.1002\/ejoc.200700364","article-title":"Synthesis of positional thiol analogs of \u03b2-d-galactopyranose","volume":"2007","author":"Pei","year":"2007","journal-title":"Eur. J. Org. Chem."},{"issue":"23","key":"10.1016\/j.bioorg.2026.110642_bb0375","doi-asserted-by":"crossref","first-page":"7008","DOI":"10.1021\/acs.joc.7b00896","article-title":"Synthesis of deoxyglycosides by desulfurization under UV light","volume":"82","author":"Ge","year":"2017","journal-title":"J. Org. Chem."},{"key":"10.1016\/j.bioorg.2026.110642_bb0380","doi-asserted-by":"crossref","DOI":"10.1002\/cssc.202102483","article-title":"Streamlined iterative assembly of thio-oligosaccharides by aqueous S-glycosylation of diverse deoxythio sugars","volume":"15","author":"Wen","year":"2022","journal-title":"ChemSusChem"},{"issue":"15","key":"10.1016\/j.bioorg.2026.110642_bb0385","doi-asserted-by":"crossref","first-page":"5903","DOI":"10.1021\/acs.orglett.9b02033","article-title":"A one-pot method for removal of thioacetyl group via desulfurization under ultraviolet light to synthesize deoxyglycosides","volume":"21","author":"Ge","year":"2019","journal-title":"Org. Lett."},{"key":"10.1016\/j.bioorg.2026.110642_bb0390","doi-asserted-by":"crossref","DOI":"10.3389\/fchem.2020.00319","article-title":"Improved synthesis of sulfur-sontaining glycosides by suppressing thioacetyl migration","volume":"8","author":"Luo","year":"2020","journal-title":"Front. Chem."},{"issue":"26","key":"10.1016\/j.bioorg.2026.110642_bb0395","doi-asserted-by":"crossref","DOI":"10.1002\/ejoc.202200533","article-title":"Efficient preparation of 2-SAc-glycosyl donors and investigation of their application in synthesis of 2-deoxyglycosides","volume":"2022","author":"Luo","year":"2022","journal-title":"Eur. J. Org. Chem."},{"issue":"13","key":"10.1016\/j.bioorg.2026.110642_bb0400","doi-asserted-by":"crossref","first-page":"8024","DOI":"10.1021\/acs.joc.3c00046","article-title":"Visible-light-promoted desulfurization to synthesize deoxyglycosides","volume":"88","author":"Luo","year":"2023","journal-title":"J. Org. Chem."},{"issue":"1","key":"10.1016\/j.bioorg.2026.110642_bb0405","doi-asserted-by":"crossref","DOI":"10.3390\/molecules30010185","article-title":"Synthesis of 2-deoxyglycosides with exclusive \u03b2-configuration using 2-SAc glycosyl bromide donors","volume":"30","author":"Guo","year":"2025","journal-title":"Molecules"},{"issue":"18","key":"10.1016\/j.bioorg.2026.110642_bb0410","doi-asserted-by":"crossref","first-page":"8595","DOI":"10.1021\/acs.joc.6b00987","article-title":"Synthesis of 2-thiocarbohydrates and their binding to Concanavalin A","volume":"81","author":"Pavashe","year":"2016","journal-title":"J. Org. Chem."},{"key":"10.1016\/j.bioorg.2026.110642_bb0415","doi-asserted-by":"crossref","first-page":"6474","DOI":"10.1002\/chem.200800352","article-title":"Synthesis and immunochemical characterization of S-linked glycoconjugate vaccines against Candida albicans","volume":"14","author":"Wu","year":"2008","journal-title":"Chem. Eur. J."},{"issue":"8","key":"10.1016\/j.bioorg.2026.110642_bb0420","doi-asserted-by":"crossref","first-page":"3306","DOI":"10.1021\/jo052662i","article-title":"Stereospecific Ester activation in nitrite-mediated carbohydrate epimerization","volume":"71","author":"Dong","year":"2006","journal-title":"J. Org. Chem."},{"issue":"22","key":"10.1016\/j.bioorg.2026.110642_bb0425","doi-asserted-by":"crossref","first-page":"11618","DOI":"10.1021\/jo402036u","article-title":"H-bonding activation in highly Regioselective acetylation of diols","volume":"78","author":"Zhou","year":"2013","journal-title":"J. Org. Chem."},{"issue":"17","key":"10.1016\/j.bioorg.2026.110642_bb0430","doi-asserted-by":"crossref","first-page":"8134","DOI":"10.1021\/jo501343x","article-title":"Regioselective acetylation of diols and polyols by acetate catalysis: mechanism and application","volume":"79","author":"Ren","year":"2014","journal-title":"J. Org. Chem."},{"issue":"10","key":"10.1016\/j.bioorg.2026.110642_bb0435","doi-asserted-by":"crossref","first-page":"3694","DOI":"10.1021\/jo062643o","article-title":"Efficient synthesis of \u03b2-d-mannosides and \u03b2-d-talosides by double parallel or double serial inversion","volume":"72","author":"Dong","year":"2007","journal-title":"J. Org. Chem."},{"issue":"12","key":"10.1016\/j.bioorg.2026.110642_bb0440","doi-asserted-by":"crossref","first-page":"4346","DOI":"10.1021\/jacs.7b01412","article-title":"Catalytic site-selective acylation of carbohydrates directed by cation\u2013n interaction","volume":"139","author":"Xiao","year":"2017","journal-title":"J. Am. Chem. Soc."},{"issue":"9","key":"10.1016\/j.bioorg.2026.110642_bb0445","doi-asserted-by":"crossref","first-page":"5676","DOI":"10.1021\/acs.joc.3c00146","article-title":"Regio and stereoselective one-pot synthesis of 2-deoxy-3-thio pyranoses and their O-glycosides from glycals","volume":"88","author":"Bhardwaj","year":"2023","journal-title":"J. Org. Chem."},{"issue":"17","key":"10.1016\/j.bioorg.2026.110642_bb0450","doi-asserted-by":"crossref","first-page":"6952","DOI":"10.1021\/jo050650r","article-title":"Solvent-dependent, kinetically controlled stereoselective synthesis of 3-and 4-thioglycosides","volume":"70","author":"Pei","year":"2005","journal-title":"J. Org. Chem."},{"issue":"16","key":"10.1016\/j.bioorg.2026.110642_bb0455","doi-asserted-by":"crossref","first-page":"4138","DOI":"10.1021\/ol301779e","article-title":"Highly stereoselective synthesis of primary, secondary, and tertiary \u03b1-S-sialosides under Lewis acidic conditions","volume":"14","author":"Noel","year":"2012","journal-title":"Org. Lett."},{"issue":"35","key":"10.1016\/j.bioorg.2026.110642_bb0460","doi-asserted-by":"crossref","first-page":"5385","DOI":"10.1016\/j.tet.2014.07.014","article-title":"S-acetyl migration in synthesis of sulfur-containing glycosides","volume":"70","author":"Zhou","year":"2014","journal-title":"Tetrahedron"},{"issue":"24","key":"10.1016\/j.bioorg.2026.110642_bb0465","doi-asserted-by":"crossref","first-page":"5098","DOI":"10.1039\/D3OB00817G","article-title":"Site-selective introduction of thiols in unprotected glycosides","volume":"21","author":"Reintjens","year":"2023","journal-title":"Org. Biomol. Chem."},{"issue":"29","key":"10.1016\/j.bioorg.2026.110642_bb0470","doi-asserted-by":"crossref","first-page":"5339","DOI":"10.1021\/acs.orglett.2c01992","article-title":"Site-selective dehydroxy-chlorination of secondary alcohols in unprotected glycosides","volume":"24","author":"Zhang","year":"2022","journal-title":"Org. Lett."},{"issue":"3","key":"10.1016\/j.bioorg.2026.110642_bb0475","doi-asserted-by":"crossref","first-page":"801","DOI":"10.1021\/jo9914667","article-title":"Direct stereoselective synthesis of \u03b2-thiomannosides","volume":"65","author":"Crich","year":"2000","journal-title":"J. Org. Chem."},{"issue":"3","key":"10.1016\/j.bioorg.2026.110642_bb0480","doi-asserted-by":"crossref","first-page":"1390","DOI":"10.1039\/C4GC02006E","article-title":"Zempl\u00e9n transesterification: a name reaction that has misled us for 90 years","volume":"17","author":"Ren","year":"2015","journal-title":"Green Chem."},{"key":"10.1016\/j.bioorg.2026.110642_bb0485","doi-asserted-by":"crossref","unstructured":"B. Ren, J. Ge, H. Dong, Reply to the \u2018Comment on \u201cZempl\u00e9n transesterification: a name reaction that has misled us for 90 years\u201d\u2019 by G. Poli, C. Pezzetta, I. Leito and S. Tshepelevitsh, Green Chem. 20 (10) (2018) 2395\u20132397, DOI: https:\/\/doi.org\/10.1039\/c7gc03795c.","DOI":"10.1039\/C8GC00814K"},{"key":"10.1016\/j.bioorg.2026.110642_bb0490","doi-asserted-by":"crossref","DOI":"10.1016\/j.carres.2023.108759","article-title":"Synthesis of 4-thio-d-glucopyranose and interconversion to 4-thio-d-glucofuranose","volume":"524","author":"Porter","year":"2023","journal-title":"Carbohydr. Res."},{"issue":"23","key":"10.1016\/j.bioorg.2026.110642_bb0495","doi-asserted-by":"crossref","first-page":"11457","DOI":"10.1021\/acs.chemrev.8b00442","article-title":"Site-selective functionalization of hydroxyl groups in carbohydrate derivatives","volume":"118","author":"Dimakos","year":"2018","journal-title":"Chem. Rev."},{"issue":"8","key":"10.1016\/j.bioorg.2026.110642_bb0500","doi-asserted-by":"crossref","first-page":"2907","DOI":"10.1039\/D1GC00098E","article-title":"Protecting-group-free S-glycosylation towards thioglycosides and thioglycopeptides in water","volume":"23","author":"Zhang","year":"2021","journal-title":"Green Chem."},{"issue":"1","key":"10.1016\/j.bioorg.2026.110642_bb0505","doi-asserted-by":"crossref","first-page":"42","DOI":"10.1016\/j.bios.2005.11.024","article-title":"Quartz crystal microbalance bioaffinity sensor for rapid identification of glycosyldisulfide lectin inhibitors from a dynamic combinatorial library","volume":"22","author":"Pei","year":"2006","journal-title":"Biosens. Bioelectron."},{"issue":"34","key":"10.1016\/j.bioorg.2026.110642_bb0510","doi-asserted-by":"crossref","DOI":"10.1002\/chem.202200499","article-title":"Acyl group migration in pyranosides as studied by experimental and computational methods","volume":"28","author":"Lassfolk","year":"2022","journal-title":"Chem. Eur. J."},{"key":"10.1016\/j.bioorg.2026.110642_bb0515","doi-asserted-by":"crossref","DOI":"10.1016\/j.carres.2020.108151","article-title":"Protecting group migrations in carbohydrate chemistry","volume":"497","author":"Govindarajan","year":"2020","journal-title":"Carbohydr. Res."},{"key":"10.1016\/j.bioorg.2026.110642_bb0520","doi-asserted-by":"crossref","first-page":"1359","DOI":"10.1039\/b717301f","article-title":"Supramolecular activation in triggered cascade inversion","volume":"11","author":"Dong","year":"2008","journal-title":"Chem. Commun."},{"issue":"26","key":"10.1016\/j.bioorg.2026.110642_bb0525","doi-asserted-by":"crossref","first-page":"7328","DOI":"10.1021\/jo00052a058","article-title":"Reactions of some pyranoside diol monotriflates with nucleophiles and bases","volume":"57","author":"Knapp","year":"1992","journal-title":"J. Org. Chem."},{"issue":"6","key":"10.1016\/j.bioorg.2026.110642_bb0530","doi-asserted-by":"crossref","first-page":"664","DOI":"10.1080\/17415993.2019.1616734","article-title":"Strategies for introducing sulfur atom in a sugar ring: synthesis of 5-thioaldopyranoses and their NMR data","volume":"40","author":"Al Bujuq","year":"2019","journal-title":"J. Sulfur Chem."},{"key":"10.1016\/j.bioorg.2026.110642_bb0535","article-title":"Mild and practical synthesis of 5-thio-D-glucopyranose and its pentaacetate derivatives","volume":"163","author":"Chen","year":"2024","journal-title":"Tetrahedron"},{"issue":"27","key":"10.1016\/j.bioorg.2026.110642_bb0540","doi-asserted-by":"crossref","first-page":"3507","DOI":"10.1021\/acs.biochem.7b00268","article-title":"The sulfur-linked analogue of O-GlcNAc (S-GlcNAc) is an enzymatically stable and reasonable structural surrogate for O-GlcNAc at the peptide and protein levels","volume":"56","author":"De Leon","year":"2017","journal-title":"Biochemistry"},{"issue":"2","key":"10.1016\/j.bioorg.2026.110642_bb0545","doi-asserted-by":"crossref","first-page":"306","DOI":"10.1021\/acs.joc.9b01883","article-title":"Synthesis of (1\u21923) thiodisaccharides of GlcNAc and the serendipitous formation of 2,3-dideoxy-(1\u21922)-thiodisaccharides through a vinyl azide intermediate","volume":"85","author":"Cristofalo","year":"2020","journal-title":"J. Org. Chem."},{"issue":"31","key":"10.1016\/j.bioorg.2026.110642_bb0550","doi-asserted-by":"crossref","first-page":"4972","DOI":"10.1002\/ejoc.202000821","article-title":"Synthesis of S-trifluoromethyl S-arylsulfoximine thioglycosides through Pd-catalyzed Migita cross-coupling","volume":"2020","author":"Bennai","year":"2020","journal-title":"Eur. J. Org. Chem."},{"issue":"5","key":"10.1016\/j.bioorg.2026.110642_bb0555","doi-asserted-by":"crossref","DOI":"10.1002\/chem.202403546","article-title":"Bispecific thio-linked disaccharides as inhibitors of Pseudomonas aeruginosa lectins LecA (PA-IL) and LecB (PA-IIL): dual-targeting strategy","volume":"31","author":"Faltinek","year":"2025","journal-title":"Chem. Eur. 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Lett."},{"issue":"18","key":"10.1016\/j.bioorg.2026.110642_bb0570","doi-asserted-by":"crossref","first-page":"4532","DOI":"10.1002\/chem.201800668","article-title":"Promotion of a reaction by cooling: stereoselective 1,2-cis-\u03b1-thioglycoconjugation by thiol-ene coupling at \u221280\u00b0C","volume":"24","author":"Eszenyi","year":"2018","journal-title":"Chem. Eur. J."},{"issue":"28","key":"10.1016\/j.bioorg.2026.110642_bb0575","doi-asserted-by":"crossref","first-page":"6090","DOI":"10.1002\/chem.201905408","article-title":"Photoinitiated thiol-ene reactions of enoses: a powerful tool for stereoselective synthesis of glycomimetics with challenging glycosidic linkages","volume":"26","author":"Borb\u00e1s","year":"2020","journal-title":"Chem. Eur. 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Chem."},{"issue":"6","key":"10.1016\/j.bioorg.2026.110642_bb0590","doi-asserted-by":"crossref","first-page":"1632","DOI":"10.1002\/anie.201809928","article-title":"Facile formation of \u03b2-thioGlcNAc linkages to thiol-containing sugars, peptides, and proteins using a mutant GH20 hexosaminidase","volume":"58","author":"Tegl","year":"2019","journal-title":"Angew. Chem. Int. Ed."},{"issue":"3","key":"10.1016\/j.bioorg.2026.110642_bb0595","doi-asserted-by":"crossref","first-page":"366","DOI":"10.1002\/ange.200390082","article-title":"Thioglycoligases: mutant glycosidases for thioglycoside synthesis","volume":"115","author":"Jahn","year":"2003","journal-title":"Angew. Chem. Int. Ed."},{"issue":"7","key":"10.1016\/j.bioorg.2026.110642_bb0600","doi-asserted-by":"crossref","first-page":"2202","DOI":"10.1021\/ja057904a","article-title":"Expanding the thioglycoligase strategy to the synthesis of \u03b1-linked thioglycosides allows structural investigation of the parent enzyme\/substrate complex","volume":"128","author":"Kim","year":"2006","journal-title":"J. Am. Chem. Soc."},{"key":"10.1016\/j.bioorg.2026.110642_bb0605","doi-asserted-by":"crossref","first-page":"274","DOI":"10.1039\/B313155F","article-title":"Thioglycosynthases: double mutant glycosidases that serve as scaffolds for thioglycoside synthesis","volume":"3","author":"Jahn","year":"2004","journal-title":"Chem. Commun."},{"issue":"3","key":"10.1016\/j.bioorg.2026.110642_bb0610","doi-asserted-by":"crossref","first-page":"237","DOI":"10.1007\/s00253-005-0156-x","article-title":"Thiosugars: new perspectives regarding availability and potential biochemical and medicinal applications","volume":"69","author":"Witczak","year":"2005","journal-title":"Appl. Microbiol. Biotechnol."},{"issue":"1","key":"10.1016\/j.bioorg.2026.110642_bb0615","doi-asserted-by":"crossref","first-page":"9187","DOI":"10.1038\/s41467-024-53563-0","article-title":"Visible-light-promoted direct desulfurization of glycosyl thiols to access C-glycosides","volume":"15","author":"Xie","year":"2024","journal-title":"Nat. Commun."},{"issue":"38","key":"10.1016\/j.bioorg.2026.110642_bb0620","doi-asserted-by":"crossref","first-page":"8188","DOI":"10.1021\/acs.orglett.4c03124","article-title":"Photocatalytic synthesis of \u03b1-ketonyl glycosyl compounds from glycosyl thiols and silyl enol ethers","volume":"26","author":"Hu","year":"2024","journal-title":"Org. Lett."},{"issue":"23","key":"10.1016\/j.bioorg.2026.110642_bb0625","doi-asserted-by":"crossref","first-page":"17727","DOI":"10.1021\/acscatal.4c05257","article-title":"Iridium photoredox-catalyzed stereoselective C-glycosylation with tetrafluoropyridin-4-yl thioglycosides: a facile synthesis of C-\u03b1\/\u03b2-glucogallins and their antioxidant activity","volume":"14","author":"Li","year":"2024","journal-title":"ACS Catal."},{"issue":"5","key":"10.1016\/j.bioorg.2026.110642_bb0630","doi-asserted-by":"crossref","first-page":"359","DOI":"10.2174\/0113852728314452240524112438","article-title":"1-Thiosugars: from synthesis to applications","volume":"29","author":"Gupta","year":"2025","journal-title":"Curr. Org. 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Lett."},{"issue":"18","key":"10.1016\/j.bioorg.2026.110642_bb0650","doi-asserted-by":"crossref","first-page":"3597","DOI":"10.1039\/D4OB00442F","article-title":"Electrochemical nickel-catalyzed cross-coupling of glycosyl thiols with preactivated phenols and ketones","volume":"22","author":"Li","year":"2024","journal-title":"Org. Biomol. Chem."},{"issue":"48","key":"10.1016\/j.bioorg.2026.110642_bb0655","doi-asserted-by":"crossref","first-page":"9052","DOI":"10.1002\/anie.200904689","article-title":"Diaryliodonium salts: a journey from obscurity to fame","volume":"48","author":"Merritt","year":"2009","journal-title":"Angew. Chem. Int. Ed."},{"key":"10.1016\/j.bioorg.2026.110642_bb0660","doi-asserted-by":"crossref","DOI":"10.1016\/j.carres.2025.109437","article-title":"Synthesis of aryl thioglycosides by metal-free arylation of glycosyl thiols with diaryliodonium salts under basic conditions","volume":"552","author":"Gaurav","year":"2025","journal-title":"Carbohydr. 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Chem."},{"issue":"3","key":"10.1016\/j.bioorg.2026.110642_bb0740","doi-asserted-by":"crossref","first-page":"444","DOI":"10.1016\/j.tetlet.2010.11.097","article-title":"Synthesis of S-glycosyl amino acids and S-glycopeptides via photoinduced click thiol-ene coupling","volume":"52","author":"Fiore","year":"2011","journal-title":"Tetrahedron Lett."},{"issue":"6","key":"10.1016\/j.bioorg.2026.110642_bb0745","doi-asserted-by":"crossref","first-page":"876","DOI":"10.1002\/asia.201901560","article-title":"Photoinitiated thiol-ene reactions of various 2,3-unsaturated O-, C-, S- and N-glycosides-scope and limitations study","volume":"15","author":"Kelemen","year":"2020","journal-title":"Chem. Asian J."},{"issue":"42","key":"10.1016\/j.bioorg.2026.110642_bb0750","doi-asserted-by":"crossref","first-page":"7798","DOI":"10.1002\/anie.200903135","article-title":"Thiyl glycosylation of olefinic proteins: S-linked glycoconjugate synthesis","volume":"48","author":"Floyd","year":"2009","journal-title":"Angew. Chem. Int. Ed."},{"issue":"17","key":"10.1016\/j.bioorg.2026.110642_bb0755","doi-asserted-by":"crossref","first-page":"12420","DOI":"10.1021\/acs.jmedchem.3c00882","article-title":"Strong binding of C-glycosylic 1,2-Thiodisaccharides to Galectin-3 enthalpy-driven affinity enhancement by water-mediated hydrogen bonds","volume":"66","author":"L\u00e1z\u00e1r","year":"2023","journal-title":"J. Med. Chem."},{"issue":"10","key":"10.1016\/j.bioorg.2026.110642_bb0760","doi-asserted-by":"crossref","first-page":"2188","DOI":"10.1039\/D2OB02301F","article-title":"Synthesis of thiodisaccharides related to 4-thiolactose. 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Chem."},{"issue":"46","key":"10.1016\/j.bioorg.2026.110642_bb0775","doi-asserted-by":"crossref","first-page":"16414","DOI":"10.1021\/acs.joc.5c01820","article-title":"Iron-catalyzed aerobic hydration of Glycal: a route toward deoxy sugars\/glycosides","volume":"90","author":"Yang","year":"2025","journal-title":"J. Org. Chem."},{"key":"10.1016\/j.bioorg.2026.110642_bb0780","doi-asserted-by":"crossref","first-page":"798","DOI":"10.1039\/C4QO00113C","article-title":"Synthesis of 2-deoxy-C-glycosides via Lewis acid-mediated rearrangement of 2,3-anhydro-1-thiopyranosides","volume":"1","author":"Xiong","year":"2014","journal-title":"Org. Chem. Front."},{"issue":"1","key":"10.1016\/j.bioorg.2026.110642_bb0785","doi-asserted-by":"crossref","first-page":"82","DOI":"10.1039\/D0OB02079F","article-title":"Glycosyl disulfides: importance, synthesis and application to chemical and biological systems","volume":"19","author":"Morais","year":"2021","journal-title":"Org. Biomol. Chem."},{"key":"10.1016\/j.bioorg.2026.110642_bb0790","doi-asserted-by":"crossref","DOI":"10.1016\/j.tet.2021.132242","article-title":"Preparation of glycosyl disulfides and sulfides via the formation of glycosyl Bunte salts as thiol surrogates","volume":"158","author":"Kundu","year":"2024","journal-title":"Tetrahedron"},{"issue":"8","key":"10.1016\/j.bioorg.2026.110642_bb0795","doi-asserted-by":"crossref","DOI":"10.3390\/molecules28083527","article-title":"Towards more practical methods for the chemical synthesis of thioamides using sulfuration agents: a decade update","volume":"28","author":"Zhang","year":"2023","journal-title":"Molecules"},{"key":"10.1016\/j.bioorg.2026.110642_bb0800","doi-asserted-by":"crossref","DOI":"10.1016\/j.ejmech.2024.116525","article-title":"Amide bioisosteric replacement in the design and synthesis of quorum sensing modulators","volume":"273","author":"Zhang","year":"2024","journal-title":"Eur. J. Med. Chem."},{"issue":"17","key":"10.1016\/j.bioorg.2026.110642_bb0805","doi-asserted-by":"crossref","DOI":"10.3390\/molecules26175135","article-title":"Heterocyclic chemistry applied to the design of N-acyl homoserine lactone analogues as bacterial quorum sensing signals mimics","volume":"26","author":"Zhang","year":"2021","journal-title":"Molecules"},{"issue":"47","key":"10.1016\/j.bioorg.2026.110642_bb0810","doi-asserted-by":"crossref","first-page":"7903","DOI":"10.1002\/ange.200502179","article-title":"Thiooligosaccharide conjugate vaccines evoke antibodies specific for native antigens","volume":"44","author":"Bundle","year":"2005","journal-title":"Angew. Chem. Int. Ed."},{"issue":"15","key":"10.1016\/j.bioorg.2026.110642_bb0815","doi-asserted-by":"crossref","first-page":"2718","DOI":"10.1039\/C9QO00581A","article-title":"Synthesis of multivalent S-glycoside analogs of a heparan sulfate sequence","volume":"6","author":"Teki","year":"2019","journal-title":"Org. Chem. Front."},{"issue":"1","key":"10.1016\/j.bioorg.2026.110642_bb0820","doi-asserted-by":"crossref","first-page":"76","DOI":"10.2174\/156802609787354270","article-title":"Thiasugars: potential glycosidase inhibitors","volume":"9","author":"Yuasa","year":"2009","journal-title":"Curr. Top. Med. Chem."},{"key":"10.1016\/j.bioorg.2026.110642_bb0825","doi-asserted-by":"crossref","first-page":"1200","DOI":"10.1039\/c39870001200","article-title":"5-Thio-d-mannose from the marine sponge Clathria pyramida (Lendenfeld). The first example of a naturally occurring 5-thiosugar","volume":"15","author":"Capon","year":"1987","journal-title":"J. Chem. Soc. Chem. 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