{"status":"ok","message-type":"work","message-version":"1.0.0","message":{"indexed":{"date-parts":[[2026,9,25]],"date-time":"2026-09-25T19:34:42Z","timestamp":1790364882371,"version":"4.1.0"},"reference-count":49,"publisher":"Elsevier BV","license":[{"start":{"date-parts":[[2015,6,1]],"date-time":"2015-06-01T00:00:00Z","timestamp":1433116800000},"content-version":"tdm","delay-in-days":0,"URL":"https:\/\/www.elsevier.com\/tdm\/userlicense\/1.0\/"}],"content-domain":{"domain":["elsevier.com","sciencedirect.com"],"crossmark-restriction":true},"short-container-title":["Carbohydrate Polymers"],"published-print":{"date-parts":[[2015,6]]},"DOI":"10.1016\/j.carbpol.2015.01.054","type":"journal-article","created":{"date-parts":[[2015,2,3]],"date-time":"2015-02-03T18:03:13Z","timestamp":1422986593000},"page":"256-265","update-policy":"https:\/\/doi.org\/10.1016\/elsevier_cm_policy","source":"Crossref","is-referenced-by-count":148,"special_numbering":"C","title":["Crystallization, structural relaxation and thermal degradation in Poly(l-lactide)\/cellulose nanocrystal renewable nanocomposites"],"prefix":"10.1016","volume":"123","author":[{"given":"E.","family":"Lizundia","sequence":"first","affiliation":[],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"J.L.","family":"Vilas","sequence":"additional","affiliation":[],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"L.M.","family":"Le\u00f3n","sequence":"additional","affiliation":[],"role":[{"vocabulary":"crossref","role":"author"}]}],"member":"78","reference":[{"key":"10.1016\/j.carbpol.2015.01.054_bib0075","series-title":"Green chemistry: Theory and practice","first-page":"148","author":"Anastas","year":"1998"},{"key":"10.1016\/j.carbpol.2015.01.054_bib0025","doi-asserted-by":"crossref","first-page":"835","DOI":"10.1002\/mabi.200400043","article-title":"An overview of polylactides as packaging materials","volume":"4","author":"Auras","year":"2004","journal-title":"Macromolecular Bioscience"},{"key":"10.1016\/j.carbpol.2015.01.054_bib0060","doi-asserted-by":"crossref","first-page":"154","DOI":"10.1016\/j.carbpol.2013.01.033","article-title":"Production of nanocrystalline cellulose from lignocellulosic biomass: Technology and applications","volume":"94","author":"Brinchi","year":"2013","journal-title":"Cabohydrate Polymers"},{"key":"10.1016\/j.carbpol.2015.01.054_bib0115","doi-asserted-by":"crossref","first-page":"2225","DOI":"10.1016\/S0014-3057(02)00132-5","article-title":"Crystallinity changes in lyocell and viscose-type fibres by caustic treatment","volume":"38","author":"Colom","year":"2002","journal-title":"European Polymer Journal"},{"key":"10.1016\/j.carbpol.2015.01.054_bib0100","doi-asserted-by":"crossref","first-page":"4698","DOI":"10.1021\/ma902247y","article-title":"A PALS contribution to the supramolecular structure of Poly(L-lactide)","volume":"43","author":"del Rio","year":"2010","journal-title":"Macromolecules"},{"key":"10.1016\/j.carbpol.2015.01.054_bib0055","doi-asserted-by":"crossref","first-page":"9755","DOI":"10.1021\/ma801796u","article-title":"Anisotropic elastic properties of cellulose measured using inelastic X-ray scattering","volume":"41","author":"Diddens","year":"2008","journal-title":"Macromolecules"},{"key":"10.1016\/j.carbpol.2015.01.054_bib0070","first-page":"13","article-title":"Nanocellulose: A new ageless bionanomaterial","author":"Dufresne","year":"2013","journal-title":"Materials Today"},{"key":"10.1016\/j.carbpol.2015.01.054_bib0240","doi-asserted-by":"crossref","first-page":"1293","DOI":"10.1016\/j.polymdegradstab.2013.04.003","article-title":"Effects of repeat unit sequence distribution and residual catalyst on thermal degradation of poly(L-lactide\/(-caprolactone) statistical copolymers","volume":"98","author":"Fernandez","year":"2013","journal-title":"Polymer Degradation and Stability"},{"key":"10.1016\/j.carbpol.2015.01.054_bib0220","doi-asserted-by":"crossref","first-page":"323","DOI":"10.1002\/pol.1966.110040504","article-title":"A quick, direct method for the determination of activation energy from thermogravimetric data","volume":"4","author":"Flynn","year":"1966","journal-title":"Journal of polymer Science Part B: Polymer Letters"},{"key":"10.1016\/j.carbpol.2015.01.054_bib0050","doi-asserted-by":"crossref","first-page":"2456","DOI":"10.1021\/bm200581h","article-title":"From interfacial ring-opening polymerization to melt processing of cellulose nanowhisker filled polylactide based nanocomposites","volume":"12","author":"Goffin","year":"2011","journal-title":"Biomacromolecules"},{"key":"10.1016\/j.carbpol.2015.01.054_bib0130","series-title":"Poly(lactic acid): Synthesis, structures, properties, processing and applications.","first-page":"97","author":"Goncalves","year":"2010"},{"key":"10.1016\/j.carbpol.2015.01.054_bib0020","doi-asserted-by":"crossref","first-page":"4053","DOI":"10.1016\/j.eurpolymj.2007.06.045","article-title":"New emerging trends in synthetic biodegradable polymer-polylactide: A critique","volume":"43","author":"Gupta","year":"2007","journal-title":"European Polymer Journal"},{"key":"10.1016\/j.carbpol.2015.01.054_bib0065","doi-asserted-by":"crossref","first-page":"2877","DOI":"10.1007\/s10570-013-0058-5","article-title":"Effects of interfacial stereocomplexation in cellulose nanocrystal-filled polylactide nanocomposites","volume":"20","author":"Habibi","year":"2013","journal-title":"Cellulose"},{"key":"10.1016\/j.carbpol.2015.01.054_bib0165","doi-asserted-by":"crossref","first-page":"2906","DOI":"10.1002\/app.29822","article-title":"Effects of microcrystallinity and morphology on physical aging and its associated effects on tensile mechanical and environmental stress cracking properties of poly(ethylene terephthalate)","volume":"112","author":"Hongxia","year":"2009","journal-title":"Journal Applied Polymer Science"},{"key":"10.1016\/j.carbpol.2015.01.054_bib0180","doi-asserted-by":"crossref","first-page":"5046","DOI":"10.1021\/ma981391t","article-title":"Physical aging of polycarbonate: Enthalpy relaxation, creep response, and yielding behavior","volume":"32","author":"Hutchinson","year":"1999","journal-title":"Macromolecules"},{"key":"10.1016\/j.carbpol.2015.01.054_bib0225","doi-asserted-by":"crossref","first-page":"1729","DOI":"10.1016\/j.eurpolymj.2007.02.025","article-title":"Thermal and electrical properties of poly(l-lactide)-graft-multiwalled carbon nanotube composites","volume":"43","author":"Kim","year":"2007","journal-title":"European Polymer Journal"},{"key":"10.1016\/j.carbpol.2015.01.054_bib0170","doi-asserted-by":"crossref","first-page":"3094","DOI":"10.1016\/j.polymer.2006.02.083","article-title":"Physical aging of thin 6FDA-based polyimide membranes containing carboxyl acid groups. Part I. Transport properties","volume":"47","author":"Kim","year":"2006","journal-title":"Polymer"},{"key":"10.1016\/j.carbpol.2015.01.054_bib0205","doi-asserted-by":"crossref","first-page":"217","DOI":"10.6028\/jres.057.026","article-title":"Variation of peak temperature with heating rate in differential thermal analysis","volume":"57","author":"Kissinger","year":"1956","journal-title":"Journal of research of the National Bureau of Standards"},{"key":"10.1016\/j.carbpol.2015.01.054_bib0210","doi-asserted-by":"crossref","first-page":"1702","DOI":"10.1021\/ac60131a045","article-title":"Reaction kinetics in differential thermal analysis","volume":"29","author":"Kissinger","year":"1957","journal-title":"Analytical Chemistry"},{"key":"10.1016\/j.carbpol.2015.01.054_bib0110","doi-asserted-by":"crossref","first-page":"393","DOI":"10.1016\/0032-3861(96)82908-9","article-title":"A Fourier transform infra-red spectroscopic analysis of the character of hydrogen bonds in amorphous cellulose","volume":"37","author":"Kondo","year":"1996","journal-title":"Polymer"},{"key":"10.1016\/j.carbpol.2015.01.054_bib0200","doi-asserted-by":"crossref","first-page":"329","DOI":"10.1016\/0141-3910(96)00102-4","article-title":"Thermal decomposition of biodegradable polyesters-II. Poly(lactic acid)","volume":"53","author":"Kopinke","year":"1996","journal-title":"Polymer Degradation and Stability"},{"key":"10.1016\/j.carbpol.2015.01.054_bib0080","first-page":"497","article-title":"Polylactones 6. Influence of various metal salts on the optical purity of poly(L-lactide)","volume":"14","author":"Kricheldorf","year":"1985","journal-title":"Polymer Bulletin"},{"key":"10.1016\/j.carbpol.2015.01.054_bib0160","doi-asserted-by":"crossref","first-page":"222","DOI":"10.1038\/nature03278","article-title":"In and out of equilibrium","volume":"433","author":"Kurchan","year":"2005","journal-title":"Nature"},{"key":"10.1016\/j.carbpol.2015.01.054_bib0015","doi-asserted-by":"crossref","first-page":"246","DOI":"10.1002\/jbm.b.31846","article-title":"Biomedical nanocomposites of poly(lactic acid) and calcium phosphate hybridized with modified carbon nanotubes for hard tissue implants","volume":"98","author":"Lee","year":"2011","journal-title":"Journal of Biomedical Materials Research B: Applied Biomaterials"},{"key":"10.1016\/j.carbpol.2015.01.054_bib0245","article-title":"Improvement of the thermal degradation behaviour of PLLA\/MWCNT composites by nanotube purification","author":"Lizundia","year":"2011","journal-title":"EUROTEC"},{"key":"10.1016\/j.carbpol.2015.01.054_bib0035","doi-asserted-by":"crossref","first-page":"118","DOI":"10.1002\/masy.201251120","article-title":"Physical aging in poly(L-lactide) and its multi-wall carbon nanotube nanocomposites","volume":"321\u2013322","author":"Lizundia","year":"2012","journal-title":"Macromolecular Symposia"},{"key":"10.1016\/j.carbpol.2015.01.054_bib0150","first-page":"230","article-title":"Concurrent \u03b1\u2032 and \u03b1 crystal formation during isothermal crystallizations of Poly(L-lactide)","author":"Lizundia","year":"2011","journal-title":"ANTEC Proceedings"},{"key":"10.1016\/j.carbpol.2015.01.054_bib0010","doi-asserted-by":"crossref","first-page":"870","DOI":"10.1002\/mabi.201200008","article-title":"Biocompatible Poly(L-lactide)\/MWCNT nanocomposites: Morphological characterization, electrical properties and stem cell interaction","volume":"12","author":"Lizundia","year":"2012","journal-title":"Macromolecular Bioscience"},{"key":"10.1016\/j.carbpol.2015.01.054_bib0135","doi-asserted-by":"crossref","first-page":"2412","DOI":"10.1016\/j.polymer.2012.03.046","article-title":"Nano- and microstructural effects on thermal properties of poly(L-lactide)\/multi-wall carbon nanotube composites","volume":"53","author":"Lizundia","year":"2012","journal-title":"Polymer"},{"key":"10.1016\/j.carbpol.2015.01.054_bib0145","doi-asserted-by":"crossref","first-page":"242","DOI":"10.1016\/j.jmbbm.2012.09.006","article-title":"Phase-structure and mechanical properties of isothermally melt- and cold-crystallized poly(L-lactide)","volume":"17","author":"Lizundia","year":"2013","journal-title":"Journal of the Mechanical Behavior of Biomedical Materials"},{"key":"10.1016\/j.carbpol.2015.01.054_bib0045","doi-asserted-by":"crossref","first-page":"4010","DOI":"10.1021\/ma034049b","article-title":"Restricted relaxation in polymer nanocomposites near the glass transition","volume":"36","author":"Lu","year":"2003","journal-title":"Macromolecules"},{"key":"10.1016\/j.carbpol.2015.01.054_bib0005","doi-asserted-by":"crossref","first-page":"145","DOI":"10.1002\/pi.2108","article-title":"Biodegradable polymers applied in tissue engineering research: A review","volume":"56","author":"Martina","year":"2007","journal-title":"Polymer International"},{"key":"10.1016\/j.carbpol.2015.01.054_bib0140","doi-asserted-by":"crossref","first-page":"5717","DOI":"10.1021\/ma9008109","article-title":"Analysis of the C=O stretching band of the \u03b1-crystal of Poly(L-lactide)","volume":"42","author":"Meaurio","year":"2009","journal-title":"Macromolecules"},{"key":"10.1016\/j.carbpol.2015.01.054_bib0250","doi-asserted-by":"crossref","first-page":"243","DOI":"10.1016\/j.polymdegradstab.2003.11.008","article-title":"Effects of chain end structures on pyrolisis of poly(L-lactic) acid containing tin atoms","volume":"84","author":"Mori","year":"2004","journal-title":"Polymer Degradation and Stability"},{"key":"10.1016\/j.carbpol.2015.01.054_bib0030","doi-asserted-by":"crossref","first-page":"240","DOI":"10.1002\/pat.880","article-title":"Synthesis and characterization of poly(L-lactide-co-caprolactone) copolymers: Influence of sequential monomer addition on chain microstructure","volume":"18","author":"Nalampang","year":"2007","journal-title":"Polymers for Advanced Technologies"},{"key":"10.1016\/j.carbpol.2015.01.054_bib0120","doi-asserted-by":"crossref","first-page":"303","DOI":"10.1128\/JB.73.3.303-313.1957","article-title":"Differentiation of microorganisms by means of the infrared spectra of their acetone extracts","volume":"73","author":"OConnor","year":"1957","journal-title":"Journal of bacteriology"},{"key":"10.1016\/j.carbpol.2015.01.054_bib0125","doi-asserted-by":"crossref","first-page":"2376","DOI":"10.1016\/j.carres.2005.08.007","article-title":"Crystalline structure analysis of cellulose treated with sodium hydroxide and carbon dioxide by means of X-ray diffraction and FTIR spectroscopy","volume":"340","author":"Oh","year":"2005","journal-title":"Carbohydrate Research"},{"key":"10.1016\/j.carbpol.2015.01.054_bib0215","doi-asserted-by":"crossref","first-page":"1881","DOI":"10.1246\/bcsj.38.1881","article-title":"A new method of analyzing thermogravimetric data","volume":"38","author":"Ozawa","year":"1965","journal-title":"Bulletin of the Chemical Society of Japan"},{"key":"10.1016\/j.carbpol.2015.01.054_bib0235","doi-asserted-by":"crossref","first-page":"301","DOI":"10.1007\/BF01911411","article-title":"Kinetic analysis of derivative curves in thermal analysis","volume":"2","author":"Ozawa","year":"1970","journal-title":"Journal of Thermal Analysis and Calorimetry"},{"key":"10.1016\/j.carbpol.2015.01.054_bib0185","doi-asserted-by":"crossref","first-page":"9664","DOI":"10.1021\/ma071737c","article-title":"Enthalpy relaxation embrittlement of poly(L-lactide) during physical aging","volume":"40","author":"Pan","year":"2007","journal-title":"Macromolecules"},{"key":"10.1016\/j.carbpol.2015.01.054_bib0095","doi-asserted-by":"crossref","first-page":"2535","DOI":"10.1016\/j.compscitech.2006.12.012","article-title":"Structure and thermal properties of poly(lactic acid)\/cellulose whiskers nanocomposite materials","volume":"67","author":"Petersson","year":"2007","journal-title":"Composite Science and Technology"},{"key":"10.1016\/j.carbpol.2015.01.054_bib0040","doi-asserted-by":"crossref","first-page":"456","DOI":"10.1126\/science.1112217","article-title":"Structural relaxation of polymer glasses at surfaces, interfaces, and in between","volume":"309","author":"Priestley","year":"2005","journal-title":"Science"},{"key":"10.1016\/j.carbpol.2015.01.054_bib0195","doi-asserted-by":"crossref","first-page":"1671","DOI":"10.1021\/bm034519+","article-title":"Effect of sulfate groups from sulfuric acid hydrolysis on the thermal degradation behavior of bacterial cellulose","volume":"5","author":"Roman","year":"2004","journal-title":"Biomacromolecules"},{"key":"10.1016\/j.carbpol.2015.01.054_bib0105","doi-asserted-by":"crossref","first-page":"3895","DOI":"10.1021\/ma971545p","article-title":"Crystallization and melting behavior of polylactides","volume":"31","author":"Sarasua","year":"1998","journal-title":"Macromolecules"},{"key":"10.1016\/j.carbpol.2015.01.054_bib0090","doi-asserted-by":"crossref","first-page":"617","DOI":"10.1007\/BF00973910","article-title":"Stannous octoate-versus zinc-initiated polymerization of racemic lactide \u2013 effects on configurational structures","volume":"32","author":"Schwach","year":"1994","journal-title":"Polymer Bulletin"},{"key":"10.1016\/j.carbpol.2015.01.054_bib0085","doi-asserted-by":"crossref","first-page":"6412","DOI":"10.1021\/ma9902753","article-title":"Use of monocarboxylic iron derivatives in the ring-opening polymerization of L-lactide","volume":"32","author":"Stolt","year":"1999","journal-title":"Macromolecules"},{"key":"10.1016\/j.carbpol.2015.01.054_bib0155","doi-asserted-by":"crossref","first-page":"4917","DOI":"10.1016\/j.polymer.2005.03.069","article-title":"Spherulite growth of L-lactide copolymers: Effects of tacticity and comonomers","volume":"46","author":"Tsuji","year":"2005","journal-title":"Polymer"},{"key":"10.1016\/j.carbpol.2015.01.054_bib0255","doi-asserted-by":"crossref","first-page":"183","DOI":"10.1002\/masy.200850520","article-title":"Thermal degradation of poly(-caprolactone), poly(L-lactic acid) and their blends with poly(3-hydroxy-butyrate) studied by TGA\/FT-IR spectroscopy","volume":"265","author":"Vogel","year":"2008","journal-title":"Macromolecular Symposia"},{"key":"10.1016\/j.carbpol.2015.01.054_bib0230","doi-asserted-by":"crossref","first-page":"929","DOI":"10.1007\/s10973-009-0121-5","article-title":"Thermal degradation of poly(lactic acid) measured by thermogravimetry coupled to Fourier transform infrared spectroscopy","volume":"97","author":"Zou","year":"2009","journal-title":"Journal of Thermal Analysis and Calorimetry"}],"container-title":["Carbohydrate Polymers"],"original-title":[],"language":"en","link":[{"URL":"https:\/\/api.elsevier.com\/content\/article\/PII:S0144861715000855?httpAccept=text\/xml","content-type":"text\/xml","content-version":"vor","intended-application":"text-mining"},{"URL":"https:\/\/api.elsevier.com\/content\/article\/PII:S0144861715000855?httpAccept=text\/plain","content-type":"text\/plain","content-version":"vor","intended-application":"text-mining"}],"deposited":{"date-parts":[[2020,8,29]],"date-time":"2020-08-29T16:42:11Z","timestamp":1598719331000},"score":1,"resource":{"primary":{"URL":"https:\/\/linkinghub.elsevier.com\/retrieve\/pii\/S0144861715000855"}},"subtitle":[],"short-title":[],"issued":{"date-parts":[[2015,6]]},"references-count":49,"alternative-id":["S0144861715000855"],"URL":"https:\/\/doi.org\/10.1016\/j.carbpol.2015.01.054","relation":{},"ISSN":["0144-8617"],"issn-type":[{"value":"0144-8617","type":"print"}],"subject":[],"published":{"date-parts":[[2015,6]]},"assertion":[{"value":"Elsevier","name":"publisher","label":"This article is maintained by"},{"value":"Crystallization, structural relaxation and thermal degradation in Poly(l-lactide)\/cellulose nanocrystal renewable nanocomposites","name":"articletitle","label":"Article Title"},{"value":"Carbohydrate Polymers","name":"journaltitle","label":"Journal Title"},{"value":"https:\/\/doi.org\/10.1016\/j.carbpol.2015.01.054","name":"articlelink","label":"CrossRef DOI link to publisher maintained version"},{"value":"article","name":"content_type","label":"Content Type"},{"value":"Copyright \u00a9 2015 Elsevier Ltd. All rights reserved.","name":"copyright","label":"Copyright"}]}}