{"status":"ok","message-type":"work","message-version":"1.0.0","message":{"indexed":{"date-parts":[[2026,9,15]],"date-time":"2026-09-15T19:46:30Z","timestamp":1789501590669,"version":"build-2803163510"},"reference-count":50,"publisher":"Elsevier BV","license":[{"start":{"date-parts":[[2020,9,1]],"date-time":"2020-09-01T00:00:00Z","timestamp":1598918400000},"content-version":"tdm","delay-in-days":0,"URL":"https:\/\/www.elsevier.com\/tdm\/userlicense\/1.0\/"},{"start":{"date-parts":[[2020,9,1]],"date-time":"2020-09-01T00:00:00Z","timestamp":1598918400000},"content-version":"tdm","delay-in-days":0,"URL":"https:\/\/www.elsevier.com\/legal\/tdmrep-license"},{"start":{"date-parts":[[2020,5,6]],"date-time":"2020-05-06T00:00:00Z","timestamp":1588723200000},"content-version":"vor","delay-in-days":0,"URL":"http:\/\/creativecommons.org\/licenses\/by\/4.0\/"}],"funder":[{"DOI":"10.13039\/501100004063","name":"Knut och Alice Wallenbergs Stiftelse","doi-asserted-by":"publisher","id":[{"id":"10.13039\/501100004063","id-type":"DOI","asserted-by":"publisher"}]},{"DOI":"10.13039\/501100004359","name":"Vetenskapsr\u00e5det","doi-asserted-by":"publisher","id":[{"id":"10.13039\/501100004359","id-type":"DOI","asserted-by":"publisher"}]},{"DOI":"10.13039\/100012337","name":"James Hutton Institute","doi-asserted-by":"publisher","id":[{"id":"10.13039\/100012337","id-type":"DOI","asserted-by":"publisher"}]},{"DOI":"10.13039\/501100003252","name":"Lunds Universitet","doi-asserted-by":"publisher","id":[{"id":"10.13039\/501100003252","id-type":"DOI","asserted-by":"publisher"}]}],"content-domain":{"domain":["elsevier.com","sciencedirect.com"],"crossmark-restriction":true},"short-container-title":["Chemosphere"],"published-print":{"date-parts":[[2020,9]]},"DOI":"10.1016\/j.chemosphere.2020.126937","type":"journal-article","created":{"date-parts":[[2020,4,30]],"date-time":"2020-04-30T17:31:05Z","timestamp":1588267865000},"page":"126937","update-policy":"https:\/\/doi.org\/10.1016\/elsevier_cm_policy","source":"Crossref","is-referenced-by-count":70,"special_numbering":"C","title":["Phosphate competition with arsenate on poorly crystalline iron and aluminum (hydr)oxide mixtures"],"prefix":"10.1016","volume":"255","author":[{"given":"Charlotta","family":"Tiberg","sequence":"first","affiliation":[],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Carin","family":"Sj\u00f6stedt","sequence":"additional","affiliation":[],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Ann Kristin","family":"Eriksson","sequence":"additional","affiliation":[],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Wantana","family":"Klysubun","sequence":"additional","affiliation":[],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Jon Petter","family":"Gustafsson","sequence":"additional","affiliation":[],"role":[{"vocabulary":"crossref","role":"author"}]}],"member":"78","reference":[{"key":"10.1016\/j.chemosphere.2020.126937_bib1","doi-asserted-by":"crossref","first-page":"297","DOI":"10.1016\/j.jcis.2014.09.057","article-title":"Surface loading effects on orthophosphate surface complexation at the goethite\/water interface as examined by extended X-ray absorption fine structure (EXAFS) spectroscopy","volume":"437","author":"Abdala","year":"2015","journal-title":"J.\u00a0Colloid Interface Sci."},{"key":"10.1016\/j.chemosphere.2020.126937_bib2","doi-asserted-by":"crossref","first-page":"692","DOI":"10.1021\/es00075a013","article-title":"Surface and bulk characteristics of binary oxide suspensions","volume":"24","author":"Anderson","year":"1990","journal-title":"Environ. Sci. Technol."},{"key":"10.1016\/j.chemosphere.2020.126937_bib3","doi-asserted-by":"crossref","first-page":"413","DOI":"10.1016\/0021-9797(79)90343-6","article-title":"The adsorption of protolyzable anions on hydrous oxides at the isoelectric pH","volume":"72","author":"Anderson","year":"1979","journal-title":"J.\u00a0Colloid Interface Sci."},{"key":"10.1016\/j.chemosphere.2020.126937_bib4","doi-asserted-by":"crossref","first-page":"80","DOI":"10.1006\/jcis.2000.7249","article-title":"X-ray absorption spectroscopic investigation of arsenite and arsenate adsorption at the aluminium oxide-water interface","volume":"235","author":"Arai","year":"2001","journal-title":"J.\u00a0Colloid Interface Sci."},{"key":"10.1016\/j.chemosphere.2020.126937_bib5","doi-asserted-by":"crossref","first-page":"317","DOI":"10.1006\/jcis.2001.7773","article-title":"ATR\u2013FTIR Spectroscopic investigation on phosphate adsorption mechanisms at the ferrihydrite\u2013water interface","volume":"241","author":"Arai","year":"2001","journal-title":"J.\u00a0Colloid Interface Sci."},{"key":"10.1016\/j.chemosphere.2020.126937_bib6","doi-asserted-by":"crossref","first-page":"2537","DOI":"10.1021\/es0486770","article-title":"Arsenate adsorption mechanisms at the allophane - water interface","volume":"39","author":"Arai","year":"2005","journal-title":"Environ. Sci. Technol."},{"key":"10.1016\/j.chemosphere.2020.126937_bib7","doi-asserted-by":"crossref","first-page":"2617","DOI":"10.1016\/S0016-7037(97)00124-5","article-title":"Surface complexation of Pb(II) at oxide-water interfaces. I. XAFS and bond-valence determination of mono- and polynuclear Pb(II) sorption products on aluminum oxides","volume":"61","author":"Bargar","year":"1997","journal-title":"Geochem. Cosmochim. Acta"},{"key":"10.1016\/j.chemosphere.2020.126937_bib8","doi-asserted-by":"crossref","first-page":"2639","DOI":"10.1016\/S0016-7037(97)00125-7","article-title":"Surface complexation of Pb(II) at oxide-water interfaces. 2. XAFS and bond-valence determination of mononuclear Pb(II) sorption products and surface functional groups on iron oxides","volume":"61","author":"Bargar","year":"1997","journal-title":"Geochem. Cosmochim. Acta"},{"key":"10.1016\/j.chemosphere.2020.126937_bib9","doi-asserted-by":"crossref","first-page":"1809","DOI":"10.2134\/jeq2003.1809","article-title":"Speciation of phosphorus in phosphorus-enriched agricultural soils using X-ray absorption near-edge structure spectroscopy and chemical fractionation","volume":"32","author":"Beauchemin","year":"2003","journal-title":"J.\u00a0Environ. Qual."},{"key":"10.1016\/j.chemosphere.2020.126937_bib10","series-title":"The Iron Oxides","author":"Cornell","year":"2003"},{"key":"10.1016\/j.chemosphere.2020.126937_bib11","doi-asserted-by":"crossref","first-page":"7269","DOI":"10.1021\/es400526q","article-title":"Arsenate and phosphate adsorption in relation to oxides composition in soils: LCD modeling","volume":"47","author":"Cui","year":"2013","journal-title":"Environ. Sci. Technol."},{"key":"10.1016\/j.chemosphere.2020.126937_bib12","doi-asserted-by":"crossref","first-page":"437","DOI":"10.1016\/j.jcis.2009.10.057","article-title":"Surface reactivity of \u03b1-Al2O3 and mechanisms of phosphate sorption: in situ ATR-FTIR spectroscopy and \u03b6 potential studies","volume":"342","author":"Del Nero","year":"2010","journal-title":"J.\u00a0Colloid Interface Sci."},{"key":"10.1016\/j.chemosphere.2020.126937_bib13","doi-asserted-by":"crossref","first-page":"4390","DOI":"10.1021\/es049885v","article-title":"Leaching of heavy metals from contaminated soils: an experimental and modeling study","volume":"38","author":"Dijkstra","year":"2004","journal-title":"Environ. Sci. Technol."},{"key":"10.1016\/j.chemosphere.2020.126937_bib14","series-title":"The Environmental Chemistry of Aluminum","first-page":"271","article-title":"The surface chemistry of aluminum oxides and hydroxides","author":"Goldberg","year":"1996"},{"key":"10.1016\/j.chemosphere.2020.126937_bib15","doi-asserted-by":"crossref","first-page":"319","DOI":"10.1016\/j.jcis.2004.08.041","article-title":"Surface complexation of condensed phosphate to aluminum hydroxide: an ATR-FTIR spectroscopic investigation","volume":"289","author":"Guan","year":"2005","journal-title":"J.\u00a0Colloid Interface Sci."},{"key":"10.1016\/j.chemosphere.2020.126937_bib16","author":"Gustafsson"},{"key":"10.1016\/j.chemosphere.2020.126937_bib17","doi-asserted-by":"crossref","first-page":"1232","DOI":"10.1021\/es0615730","article-title":"Binding of iron(III) to organic soils: EXAFS spectroscopy and chemical equilibrium modeling","volume":"41","author":"Gustafsson","year":"2007","journal-title":"Environ. Sci. Technol."},{"key":"10.1016\/j.chemosphere.2020.126937_bib19","doi-asserted-by":"crossref","first-page":"384","DOI":"10.1016\/j.jcis.2008.03.019","article-title":"Kinetics and energetics of phosphate sorption in a multi-component Al(III)\u2013Fe(III) hydr(oxide) sorbent system","volume":"322","author":"Harvey","year":"2008","journal-title":"J.\u00a0Colloid Interface Sci."},{"key":"10.1016\/j.chemosphere.2020.126937_bib20","doi-asserted-by":"crossref","first-page":"5942","DOI":"10.1021\/la981301d","article-title":"Interfacial charging phenomena of aluminum (hydr)oxides","volume":"15","author":"Hiemstra","year":"1999","journal-title":"Langmuir"},{"key":"10.1016\/j.chemosphere.2020.126937_bib21","doi-asserted-by":"crossref","first-page":"3589","DOI":"10.1021\/acs.est.5b05529","article-title":"Mechanisms of chromate, selenate and sulfate adsorption on Al-substituted ferrihydrite: implications for ferrihydrite surface structure and reactivity","volume":"50","author":"Johnston","year":"2016","journal-title":"Environ. Sci. Technol."},{"key":"10.1016\/j.chemosphere.2020.126937_bib22","doi-asserted-by":"crossref","first-page":"79","DOI":"10.1016\/j.apgeochem.2012.12.007","article-title":"An EXAFS study of arsenic bonding on amorphous aluminum hydroxide","volume":"31","author":"Kappen","year":"2013","journal-title":"Appl. Geochem."},{"key":"10.1016\/j.chemosphere.2020.126937_bib23","series-title":"Methods of Soil Analysis. Part 5. Mineralogical Methods","article-title":"Analysis of soils and minerals using X-ray absorption spectroscopy","author":"Kelly","year":"2008"},{"key":"10.1016\/j.chemosphere.2020.126937_bib24","doi-asserted-by":"crossref","first-page":"2152","DOI":"10.1021\/es049237b","article-title":"XANES investigation of phosphate sorption in single and binary systems of iron and aluminum oxide minerals","volume":"39","author":"Khare","year":"2005","journal-title":"Environ. Sci. Technol."},{"key":"10.1016\/j.chemosphere.2020.126937_bib25","doi-asserted-by":"crossref","first-page":"4405","DOI":"10.1016\/j.gca.2007.07.008","article-title":"Phosphate bonding configuration on ferrihydrite based on molecular orbital calculations and XANES fingerprinting","volume":"71","author":"Khare","year":"2007","journal-title":"Geochem. Cosmochim. Acta"},{"key":"10.1016\/j.chemosphere.2020.126937_bib26","series-title":"Cation Adsorption by Hydrous Metal Oxides, PhD Thesis","author":"Kinniburgh","year":"1974"},{"key":"10.1016\/j.chemosphere.2020.126937_bib28","doi-asserted-by":"crossref","first-page":"930","DOI":"10.1107\/S0909049512040381","article-title":"Performance and status of beamline BL8 at SLRI for X-ray absorption spectroscopy","volume":"19","author":"Klysubun","year":"2012","journal-title":"J.\u00a0Synchrotron Radiat."},{"key":"10.1016\/j.chemosphere.2020.126937_bib29","doi-asserted-by":"crossref","first-page":"9","DOI":"10.1016\/j.envpol.2012.07.045","article-title":"Chemical stabilization of metals and arsenic in contaminated soils using oxides \u2013 a review","volume":"172","author":"Kom\u00e1rek","year":"2013","journal-title":"Environ. Pollut."},{"key":"10.1016\/j.chemosphere.2020.126937_bib30","doi-asserted-by":"crossref","first-page":"6283","DOI":"10.1021\/es201597j","article-title":"Phosphate bonding on noncrystalline Al\/Fe-hydroxide coprecipitates","volume":"45","author":"Liu","year":"2011","journal-title":"Environ. Sci. Technol."},{"key":"10.1016\/j.chemosphere.2020.126937_bib31","doi-asserted-by":"crossref","first-page":"5063","DOI":"10.1002\/chem.200900284","article-title":"Rethinking arsenate coordination at the surface of goethite","volume":"15","author":"Loring","year":"2009","journal-title":"Chem. Eur J."},{"key":"10.1016\/j.chemosphere.2020.126937_bib32","doi-asserted-by":"crossref","first-page":"1364","DOI":"10.1039\/C2DT31906C","article-title":"Hydration of arsenic oxyacid species","volume":"42","author":"M\u00e4hler","year":"2013","journal-title":"Dalton Trans."},{"key":"10.1016\/j.chemosphere.2020.126937_bib33","doi-asserted-by":"crossref","first-page":"3647","DOI":"10.1016\/0016-7037(95)00275-5","article-title":"The mechanism of anion adsorption on iron oxides: evidence for the bonding of arsenate tetrahedra on free Fe(O,OH)6 edges","volume":"59","author":"Manceau","year":"1995","journal-title":"Geochem. Cosmochim. Acta"},{"key":"10.1016\/j.chemosphere.2020.126937_bib34","doi-asserted-by":"crossref","first-page":"121","DOI":"10.2136\/sssaj1996.03615995006000010020x","article-title":"Modeling competitive adsorption of arsenate with phosphate and molybdate on oxide minerals","volume":"60","author":"Manning","year":"1996","journal-title":"Soil Sci. Soc. Am. J."},{"key":"10.1016\/j.chemosphere.2020.126937_bib35","doi-asserted-by":"crossref","first-page":"157","DOI":"10.2136\/sssaj2013.04.0133","article-title":"Surface interactions of arsenite and arsenate on soil colloids","volume":"78","author":"Martin","year":"2014","journal-title":"Soil Sci. Soc. Am. J."},{"key":"10.1016\/j.chemosphere.2020.126937_bib36","doi-asserted-by":"crossref","first-page":"837","DOI":"10.1021\/es061160z","article-title":"Arsenate and arsenite adsorption and desorption behavior on coprecipitated aluminium:iron hydroxides","volume":"41","author":"Masue","year":"2007","journal-title":"Environ. Sci. Technol."},{"key":"10.1016\/j.chemosphere.2020.126937_bib37","doi-asserted-by":"crossref","first-page":"263","DOI":"10.1006\/jcis.1996.0030","article-title":"Structure and bonding of orthophosphate ions at the iron oxide\u2013aqueous interface","volume":"177","author":"Persson","year":"1996","journal-title":"J.\u00a0Colloid Interface Sci."},{"key":"10.1016\/j.chemosphere.2020.126937_bib38","doi-asserted-by":"crossref","first-page":"537","DOI":"10.1107\/S0909049505012719","article-title":"ATHENA, ARTEMIS, HEPHAESTUS: data analysis for X-ray absorption spectroscopy using IFEFFIT","volume":"12","author":"Ravel","year":"2005","journal-title":"J.\u00a0Synchrotron Radiat."},{"key":"10.1016\/j.chemosphere.2020.126937_bib39","doi-asserted-by":"crossref","first-page":"5197","DOI":"10.1021\/cg900654m","article-title":"Precipitation of iron and aluminum phosphates directly from aqueous solution as a function of temperature from 50 to 200oC","volume":"9","author":"Roncal-Herrero","year":"2009","journal-title":"Cryst. Growth Des."},{"key":"10.1016\/j.chemosphere.2020.126937_bib40","series-title":"Iron Oxides in the Laboratory: Preparation and Characterization","author":"Schwertmann","year":"2000"},{"key":"10.1016\/j.chemosphere.2020.126937_bib41","doi-asserted-by":"crossref","first-page":"751","DOI":"10.1107\/S0567739476001551","article-title":"Revised effective ionic radii and systematic studies of interatomic distances in halides and chalcogenides","volume":"32","author":"Shannon","year":"1976","journal-title":"Acta Crystallogr. A"},{"key":"10.1016\/j.chemosphere.2020.126937_bib42","doi-asserted-by":"crossref","first-page":"4223","DOI":"10.1016\/S0016-7037(03)00237-0","article-title":"Surface complexation of arsenic(V) to iron(III) (hydr)oxides: structural mechanism from ab initio molecular geometries and EXAFS spectroscopy","volume":"67","author":"Sherman","year":"2003","journal-title":"Geochem. Cosmochim. Acta"},{"key":"10.1016\/j.chemosphere.2020.126937_bib43","doi-asserted-by":"crossref","first-page":"166","DOI":"10.1016\/j.jhazmat.2015.09.065","article-title":"Arsenic adsorption by iron\u2013aluminium hydroxide coated onto macroporous supports: insights from X-ray absorption spectroscopy and comparison with granular ferric hydroxides","volume":"302","author":"Suresh Kumar","year":"2016","journal-title":"J.\u00a0Hazard Mater."},{"key":"10.1016\/j.chemosphere.2020.126937_bib44","doi-asserted-by":"crossref","first-page":"602","DOI":"10.1021\/la00093a015","article-title":"The protonation of phosphate on the surface of goethite as studied by CIR-FTIR and electrophoretic mobility","volume":"6","author":"Tejedor-Tejedor","year":"1990","journal-title":"Langmuir"},{"key":"10.1016\/j.chemosphere.2020.126937_bib45","series-title":"X-ray Data Booklet","author":"Thompson","year":"2009"},{"key":"10.1016\/j.chemosphere.2020.126937_bib46","doi-asserted-by":"crossref","first-page":"140","DOI":"10.1016\/j.gca.2013.06.012","article-title":"Phosphate effects on copper(II) and lead(II) sorption to ferrihydrite","volume":"120","author":"Tiberg","year":"2013","journal-title":"Geochem. Cosmochim. Acta"},{"key":"10.1016\/j.chemosphere.2020.126937_bib47","doi-asserted-by":"crossref","first-page":"144","DOI":"10.1016\/j.apgeochem.2016.02.009","article-title":"Immobilization of Cu and as in two contaminated soils with zero-valent iron \u2013 long-term performance and mechanisms","volume":"67","author":"Tiberg","year":"2016","journal-title":"Appl. Geochem."},{"key":"10.1016\/j.chemosphere.2020.126937_bib48","doi-asserted-by":"crossref","first-page":"1788","DOI":"10.2136\/sssaj2002.1788","article-title":"Competitive sorption of arsenate and phosphate on different clay minerals and soils","volume":"66","author":"Violante","year":"2002","journal-title":"Soil Sci. Soc. Am. J."},{"key":"10.1016\/j.chemosphere.2020.126937_bib49","doi-asserted-by":"crossref","first-page":"20","DOI":"10.3390\/soilsystems3010020","article-title":"Phosphate sorption speciation and precipitation mechanisms on amorphous aluminum hydroxide","volume":"3","author":"Wang","year":"2019","journal-title":"Soil Syst"},{"key":"10.1016\/j.chemosphere.2020.126937_bib50","doi-asserted-by":"crossref","first-page":"2251","DOI":"10.1016\/0016-7037(93)90567-G","article-title":"Surface chemistry of ferrihydrite: Part 1. EXAFS studies of the geometry of coprecipitated and adsorbed arsenate","volume":"57","author":"Waychunas","year":"1993","journal-title":"Geochem. Cosmochim. Acta"},{"key":"10.1016\/j.chemosphere.2020.126937_bib51","doi-asserted-by":"crossref","first-page":"46","DOI":"10.1016\/j.chemgeo.2015.04.018","article-title":"Adsorption of monothioarsenate on amorphous aluminium hydroxide under anaerobic conditions","volume":"407\u2013408","author":"Xiao","year":"2015","journal-title":"Chem. Geol."},{"key":"10.1016\/j.chemosphere.2020.126937_bib52","doi-asserted-by":"crossref","first-page":"13261","DOI":"10.1021\/acs.langmuir.6b03214","article-title":"Impacts of surface site coordination on arsenate adsorption: macroscopic uptake and binding mechanisms on aluminum hydroxide surfaces","volume":"32","author":"Xu","year":"2016","journal-title":"Langmuir"}],"container-title":["Chemosphere"],"original-title":[],"language":"en","link":[{"URL":"https:\/\/api.elsevier.com\/content\/article\/PII:S0045653520311309?httpAccept=text\/xml","content-type":"text\/xml","content-version":"vor","intended-application":"text-mining"},{"URL":"https:\/\/api.elsevier.com\/content\/article\/PII:S0045653520311309?httpAccept=text\/plain","content-type":"text\/plain","content-version":"vor","intended-application":"text-mining"}],"deposited":{"date-parts":[[2025,9,23]],"date-time":"2025-09-23T11:16:47Z","timestamp":1758626207000},"score":1,"resource":{"primary":{"URL":"https:\/\/linkinghub.elsevier.com\/retrieve\/pii\/S0045653520311309"}},"subtitle":[],"short-title":[],"issued":{"date-parts":[[2020,9]]},"references-count":50,"alternative-id":["S0045653520311309"],"URL":"https:\/\/doi.org\/10.1016\/j.chemosphere.2020.126937","relation":{},"ISSN":["0045-6535"],"issn-type":[{"value":"0045-6535","type":"print"}],"subject":[],"published":{"date-parts":[[2020,9]]},"assertion":[{"value":"Elsevier","name":"publisher","label":"This article is maintained by"},{"value":"Phosphate competition with arsenate on poorly crystalline iron and aluminum (hydr)oxide mixtures","name":"articletitle","label":"Article Title"},{"value":"Chemosphere","name":"journaltitle","label":"Journal Title"},{"value":"https:\/\/doi.org\/10.1016\/j.chemosphere.2020.126937","name":"articlelink","label":"CrossRef DOI link to publisher maintained version"},{"value":"article","name":"content_type","label":"Content Type"},{"value":"\u00a9 2020 The Authors. Published by Elsevier Ltd.","name":"copyright","label":"Copyright"}],"article-number":"126937"}}